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Bicycles and Car Accidents

One of the reasons driving is such a delicate task requiring your utmost concentration is that you're sharing the road with many different kinds of vehicles.




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Atlanta Accident Injury Lawyers Remind You to Be Careful on Your Motorcycle this Winter

The accident lawyers in Atlanta would like to remind motorcyclists to drive safely this winter. These vehicles are not meant for driving on slick roads, and they are much more difficult to control than cars or trucks when sliding does occur.




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Car Accidents Involving Motorcycles

Motorcycling has become very popular in recent years.




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A Windshield Wiper for Motorcycle Helmet Visors

A motorcyclist riding through rainy weather might coat their visor with a water repellent spray. However, they then have to travel fast enough for wind resistance to blow their visor clear. At slower speeds, their visibility remains compromised.

This Bikerguard invention, created by two engineers in Slovenia, is a remote-controlled wiper blade for motorcycle helmet visors. You do have to drive two screws through the top of your visor to attach the mounting base, and you can then pop the Bikerguard on and off as needed. A wireless remote control attaches to your bike's handlebars.

The POV demonstration does seem convincing:

The developers claim that motorcycle police bodies in Slovenia, Hungary and Germany "are in the process of evaluating BIKERGUARD for potential integration into their motorcycle fleet." In the meantime, they sell these online for €319 (USD $339) a pop. A three-pack of replacement wiper blades runs €25 (USD $27).

I wouldn't be surprised if, in the future Oakley develops a visor for runners with one of these attached.




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Aramsco spins up the Syclone


The Syclone answers the need for an efficient yet low-cost air mover. This low-amp-draw machine allows more units to be used in one room concurrently, resulting in a faster drying time.




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Request for pre-qualification: Life-Cycle Support and Technical Consultative Services for the Integrated Notification Application (INA) Software

Secretariat
RFPQ/SEC/17/2016
Invitation for Prequalification (IFP)
Mon, 2016-08-01 (All day)
28 August 2016

For more details please see attached the Request for pre-qualification.

 

 

 

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Potential Tropical Cyclone 19 forms, likely to become Tropical Storm Sara and may impact Florida




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Saskatoon Loraas truck driver hears noise, finds man inside compacted recycling

A Saskatoon Loraas recycling truck driver got a shock on Monday when he heard noise coming from the back of his truck and found a man inside.



  • News/Canada/Saskatoon

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NM startup Gilz set to launch its product for motorcyclists

Prior to forming Gilz, founder Josh Kefauver worked for the U.S. Agency for International Development, specifically at the U.S. Embassy in Rwanda. During that time, he always had a motorcycle to commute to and from work and for recreational use.




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A Pd(II)-catalyzed denitrative alkyne annulation reaction for the synthesis of cyclopenta[b]chromanes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00344F, Research Article
Pratiksha Bhorali, Deep J. Kalita, Babulal Das, Sanjib Gogoi
The first denitrative Pd(II)-catalyzed alkyne annulation reaction is reported for the synthesis of cyclopenta[b]chromanes.
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Highly selective separation of toluene/methylcyclohexane based on pagoda[5]arene nonporous adaptive crystals

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00364K, Research Article
Zhongwen Liu, Ming Li, Shuai Fang, Li Shao, Bin Hua, Feihe Huang
Herein the selective separation of toluene/methylcyclohexane based on pagoda[5]arene nonporous adaptive crystals is investigated.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Recent advances in the metal-catalyzed asymmetric alkene hydrogenation of cyclic conjugated carbonyl compounds

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00227J, Review Article
Min Tan, Bram B. C. Peters, Pher G. Andersson, Taigang Zhou
This review summarizes the recent advances (2016–2023) in the stereoselective metal-catalyzed hydrogenation of cyclic α,β-unsaturated ketones, lactams and lactones since considerable developments were made. Where possible the application of these methodologies in synthesis is outlined.
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Modular synthesis of C2-symmetric nitrogen-containing polyaromatics via visible light-enabled reductive aza-6π electrocyclization

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00140K, Research Article
Qun-Liang Zhang, Qing-Tian Fan, Yirong Zhou, Jingli Zhang, Fang-Lin Zhang
Here, an unprecedented one-step modular construction of C2-symmetric N-PACs through  reduction/aza-6π electrocyclization was reported and the resultant C2-symmetric N-PAC could be  converted into  a powerful organic photocatalyst.
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Palladium-catalyzed [4 + 4] cycloaddition of 2-pyrones with 2-alkylidenetrimethylene carbonates: access to bridged eight-membered oxygen heterocycles

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00329B, Research Article
Huawei Lin, Biming Mao, Bing Han, Jiayi Luo, Yanqing Ge, Xuerui Zhang, Chang Wang, Hongchao Guo, Chunhao Yuan
A novel palladium-catalyzed [4 + 4] cycloaddition of 2-pyrones with 2-alkylidenetrimethylene carbonates has been developed for the synthesis of bridged eight-membered oxygen heterocycles in good yields and with excellent stereoselectivities.
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Neighboring group-directed asymmetric [2 + 2 + 2] cycloaddition to access C–N axially chiral indoles

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00042K, Research Article
Xuan Zhang, Qi Teng, Yanru Ren, Baitong Wei, Chen-Ho Tung, Zhenghu Xu
A Rh-catalyzed neighboring group-directed asymmetric [2 + 2 + 2] cycloaddition of 1,6-diynes and ynamides to generate C–N axially chiral indole derivatives has been developed.
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Chiral guanidine catalyzed cyclization reactions of 1,3-enynes for lactone synthesis: switchable H-bond catalysis

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00374H, Research Article
Yongyan Zhang, Lichao Ning, Tianxin Zhu, Zheng Xie, Shunxi Dong, Xiaoming Feng, Xiaohua Liu
Cyclization and 1,4-conjugate addition/cyclization between 2-activated 1,3-enynes and azlactones were achieved with chiral guanidine-amides for enol-type activation to yield a range of δ-lactone derivatives.
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Asymmetric [3 + 2] cycloaddition of donor–acceptor cyclopropanes with azadienes enabled by Brønsted base catalysis

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00002A, Research Article
Shu Li, Zhi-Hong Dong, Si-Yu Dan, Mei-Jun Zheng, Teng Long, Jie Zhan, Qing Zhou, Wen-Dao Chu, Quan-Zhong Liu
A chiral bifunctional Brønsted base-catalyzed enantioselective [3 + 2] cycloaddition of D–A cyclopropanes and azadienes is reported. The protocol features broad substrate scope, mild reaction conditions and high functional group tolerance.
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Organocatalytic formal [4 + 2] cycloaddition of o-quinone-methyl derivatives and 2-isocyanatomalonate diesters for the construction of chroman derivatives with adjacent quaternary chiral centers

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00141A, Research Article
Tong Xiong, Yi-Zhao Xu, Yao Wang, You-Cai Xiao, Fen-Er Chen
An asymmetric organocatalytic formal [4 + 2] cycloaddition/annulation cascade of ortho-quinone methides with 2-isocyanatomalonate diesters has been reported.
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Cyclization reactions of 1,6-dienes and 1,6-enynes by dual cobalt photocatalysis

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00311J, Research Article
Pei-Ting Li, Zi-Fa Shi, Wei Yu
Two triphenylamine-derived organophotocatalysts were developed. Their photocatalytic capacity was exploited to enable the [CoIII]-H-mediated cycloisomerization of 1,6-dienes and reductive cyclization of 1,6-enynes under visible light irradiation.
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Iron(III)/quinoxaline-derived N,N-ligand catalyzed oxygen transfer reaction of N-vinyl nitrones through selective 4π-electrocyclization and N–O bond cleavage

Org. Chem. Front., 2024, 11,2277-2282
DOI: 10.1039/D3QO01999C, Research Article
Yan-Jiao Lu, Feng-Lan Lu, Jin-Qi Zhang, Chun-Hua Chen, Cui Liang, Xiao-Pan Ma, Dong-Liang Mo
We describe an iron(III)/quinoxaline-derived N,N-ligand promoted O-transfer reaction of N-vinyl nitrones through selective O-4π-electrocyclization and N–O bond cleavage to prepare a variety of 2,5-dihydrooxazoles in good yields.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Deoxygenation of N-heterocyclic N-oxides using isopropanol as a recyclable reductant

Org. Chem. Front., 2024, 11,2249-2268
DOI: 10.1039/D4QO00208C, Research Article
Ho Kyeong Ryu, Yun Do Song, Jun Hee Lee
An organic photoredox-based recyclable strategy that facilitates the chemoselective deoxygenation of various functionalised N-heterocyclic N-oxides is presented.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of enantiopure 1,2,3-triazolylidene-type mesoionic carbene (MIC) conjugate acids featuring a rigid bicyclic scaffold

Org. Chem. Front., 2024, 11,2178-2181
DOI: 10.1039/D4QO00269E, Research Article
Vojtěch Dočekal, Mohand Melaimi, Simona Petrželová, Jan Veselý, Xiaoyu Yan, Guy Bertrand
Chiral NHCs have found numerous applications as ligands for transition metals and in their own right for asymmetric catalysis. We report a synthetic route from L-malic acid to enantiopure 1,2,3-triazoliums with the chiral center in a fused ring.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Visible light/copper catalysis enabled Heck-like coupling between alkenes and cyclic sulfonium salts via selective C–S bond cleavage

Org. Chem. Front., 2024, 11,2195-2200
DOI: 10.1039/D3QO02009F, Research Article
Xianqin Liu, Xufeng Li, Linyuan Wang, Yongjia Shi, Jian Lv, Daoshan Yang
A Heck-like coupling of cyclic sulfonium salts with alkenes via selective C–S bond cleavage using a copper complex as a photosensitizer through a visible-light-driven redox-neutral process has been developed.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Prins cyclization of 1,3-dioxinone: synthesis of 11-epi-badkhysin

Org. Chem. Front., 2024, 11,2332-2338
DOI: 10.1039/D4QO00162A, Research Article
Xiaoliang Xu, Ping Hua, Yiren Xu, Baoqing He, Jingfeng Zhao, Liang Li, Wen Chen, Hongbin Zhang
The asymmetric synthesis of highly functional 11-epi-badkhysin has been accomplished using a structure-unit based approach.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Palladium-catalyzed asymmetric [4 + 3] cycloaddition of acyclic α,β-unsaturated imines with trimethylenemethane donors: access to chiral non-fused azepines

Org. Chem. Front., 2024, 11,2326-2331
DOI: 10.1039/D4QO00064A, Research Article
Ting-Peng Li, Shuixiu Su, Jia-Huan Shen, Meng Zang, Yang-Zi Liu, Quannan Wang, Wei-Ping Deng
An efficient approach for the construction of non-fused azepines in good yields with high enantioselectivity via Pd-catalyzed asymmetric [4 + 3] cycloaddition was developed.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Aculeatones A and B, epimeric lovastatin derivatives with a 6/6/3-tricyclic carbon skeleton from Aspergillus aculeatus and their chemical transformation

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00351A, Research Article
Fei Liu, Fengqing Wang, Qin Li, Bingbing Dai, Weiguang Sun, Jianguo Li, Chunmei Chen, Yonghui Zhang, Hucheng Zhu
Lovastatin derivatives aculeatones A–F (1–6) with lipid-lowering activity were isolated from Aspergillus aculeatus. 1 and 2 represent the first examples with a 6/6/3-tricyclic scaffold and the biomimetic formation of 1 was achieved starting from 3.
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Concise synthesis of succinimide-fused densely 1,3-cyclohexadienes via Co-catalyzed [2+2+2] cycloaddition of 1,6-diynes and maleimides

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO00435C, Research Article
Jinhui Cai, Kaili Cen, Ziyi Zhai, Yuan Liu, Jiahao Wei, Mixia Ouyang, Guojun He, Shuyu Huang, Feng Zhao
Herein, we report a new route towards succinimide-fused densely 1,3-cyclohexadienes through the reaction of 1,6-diynes with electron-deficient alkenes under cobalt catalysis. This method shown high efficiency, wide substrate scope, good...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Efficient Synthesis of Benzophosphole Oxides by Ag-Promoted Radical Cycloisomerization

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO00552J, Research Article
Open Access
Liyao Ma, Sonia Mallet-Ladeira, Julien MONOT, Blanca Maria MARTIN VACA, Didier Bourissou
Cycloisomerization reactions involving C–P bond formation have been overlooked to prepare P-heterocycles. We discovered here a simple, efficient and versatile route to benzophosphole oxides by reacting ortho-alkynyl secondary phosphine oxides...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Fully atom-economic access to spiro-cyclic skeletons through photoredox-induced hydrogen transfer/Giese addition/dearomative cyclization/protonation cascade

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00317A, Research Article
Guohui Zeng, Hui Luo, Kai Jiang, Jianpeng Cai, Biaolin Yin
Amine-tethered spiro-cyclic skeletons were obtained through photo-induced 100%-atom-economic dearomatization, involving the cleavage of the α-C(sp3)–H of amines. Pentacyclic framework was achieved from pyridinyl ring within two steps.
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Substituent-controlled divergent cyclization reactions of benzo[c][1,2]dithiol-3-ones and hexahydro-1,3,5-triazines

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00356J, Research Article
Bohao Zhang, Sifan He, Na Dong, Antong Zhu, Haojie Duan, Dunjia Wang, Yao Zhou
An unprecedented metal-free divergent cyclization reaction of benzo[c][1,2]dithiol-3-ones with hexahydro-1,3,5-triazines to assemble six- and eight-membered N-containing heterocycles has been developed.
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Palladium-catalyzed and ligand-controlled divergent cycloadditions of vinylidenecyclopropane-diesters with para-quinone methides enabled by zwitterionic π-propargyl palladium species

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00368C, Research Article
Jia-Hao Shen, Yong-Jie Long, Min Shi, Yin Wei
A palladium-catalyzed and ligand-controlled divergent synthesis of spiro-cyclohexadienones from p-quinone methides and VDCP-diesters was realized via zwitterionic π-propargyl palladium species and the mechanism was clarified by DFT calculations.
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Upcycling polymethyl methacrylate to methacrylic acid

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00341A, Paper
Yanfa Zhuang, Nooshin Saadatkhah, Tien-Dat Nguyen, Jacopo De Tommaso, Clive Yi Jie Ng, Chunyu Wang, Abdellah Ajji, Gregory S. Patience
Upcycling PMMA to methacrylic acid rather than methyl methacrylate is a viable economic alternative to treat end-of-life plastic.
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Scalable electrified cementitious materials production and recycling

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03529A, Paper
Open Access
Xiao Kun Lu, Wenxin Zhang, Brianna N. Ruggiero, Linsey C. Seitz, Jiaqi Li
Our electrochemical production uses carbon-free rocks, water electrolysis, and CO2 capture/circulation for carbon-neutral/negative cement and green H2, turning cement from the second-largest industrial CO2 emitter to a gigaton-scale CCUS enabler.
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Electric field distribution regulation of zinc anode toward long cycle life zinc metal battery

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00629A, Paper
Xintao Long, Yizhou Liu, Dongxin Wang, Yihang Nie, Xiaoyong Lai, Dan Luo, Xin Wang
Zinc ion batteries are expected to be the next generation of rechargeable aqueous metal ion batteries, but their application is limited by its severe dendrite growth caused by inhomogeneous plating...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Deciphering cycling voltage-dependent failures of O3-layered cathode for sodium ion battery

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07967H, Paper
Xuejiao Zhao, Lihan Zhang, Xiaoqi Wang, Jinhui Li, Lin Zhang, Di Liu, Rui Yang, Xu Jin, Manling Sui, Pengfei Yan
Interfacial degradations dominate the performance decay of O3-layered cathode during low-voltage cycling; high voltage cycling induced bulk failures cause rapid performance decay due to transition metal cation migration.
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A high-current initiated formation strategy for improved cycling stability of anode-free lithium metal batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01043D, Paper
Kangning Cai, Mengtian Zhang, Geng Zhong, Guohuang Kang, Jie Biao, Chuang Li, Yanru Liu, Guangmin Zhou, Feiyu Kang, Yidan Cao
Anode-free lithium metal batteries (AFLMBs) are considered as one of the most promising candidates for next-generation high-energy-density rechargeable lithium batteries. An efficient high-current initiated formation strategy is developed for AFLMBs.
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Insights into the Enhanced Cycling Stability of Cobalt-Free Single-Crystal Layered Oxide Cathodes at Elevated Voltage

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA02135E, Paper
Tiancheng Liu, Ke Fan, Changsheng Chen, Mingxia Dong, Yanping Zhu, Gao Chen, Jiangtong Li, Zezhou Lin, Liuqing Li, Ye Zhu, Huangxu Li, Haitao Huang
Co-free single-crystal cathodes Li(NixMn1-x)O2 have been proposed as promising candidates due to remarkable thermal stability and low cost. Unfortunately, insufficient in-depth understanding on the failure mechanisms hinders the development of...
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Green solvents in battery recycling: status and challenges

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07905H, Review Article
Wenyuan Qiao, Ren Zhang, Yikai Wen, Xinyi Wang, Zheng Wang, Guoqiang Tang, Minghao Liu, Hyokyeong Kang, Zafar Said, Jang-Yeon Hwang, Changhui Liu
A green solvent hybrid system will bring about sustainable development in the battery industry by efficiently and environmentally friendly recycling of valuable resources contained in waste batteries.
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Pi-extended hypervalent iodine macrocycles and their supramolecular assembly with Buckminsterfullerene

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC04251D, Paper
Krishna Pandey, Samsul Arafin, Grayson Venus, Eli Jones, Yachu Du, Mina Dumre Pandey, Tahir Awais, Lichang Wang, Kyle N. Plunkett
Hypervalent iodine based macrocycles with enlarged aromatic cores can form extended supramolecular assemblies with Buckminsterfullerene.
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Photocatalytic 1,3-Oxyheteroarylation of Aryl Cyclopropanes with Azine N-oxides

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06723A, Edge Article
Open Access
Doyoung Kim, Hyewon Ju, Wooseok Lee, Sungwoo Hong
Cyclopropanes, valuable C3 building blocks in organic synthesis, possess high strain energy and inherent stability. We present an efficient, environmentally benign 1,3-oxyheteroarylation of aryl cyclopropanes using azine N-oxides as bifunctional...
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In vitro identification of oridonin hybrids as potential anti-TNBC agents inducing cell cycle arrest and apoptosis by regulation of p21, γH2AX and cleaved PARP

RSC Med. Chem., 2024, 15,3674-3694
DOI: 10.1039/D4MD00580E, Research Article
Jinhua Ning, Nini Zhan, Zhanpan Wu, Yuzhe Li, Die Zhang, Yadian Shi, Yingxun Zhou, Chuan-Huizi Chen, Wenbin Jin
Oridonin analogue 11a showed significant antitumor efficacy in vitro via cell cycle arrest and apoptosis by regulation of p21, γH2AX and cleaved PARP accumulation, meanwhile, displayed much more stable than oridonin in human plasma.
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Phuket to update motorcycle taxi rules

Local authorities in Phuket's Patong area are working to overhaul the city's motorcycle taxi service following a recent fight among drivers over passengers.




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Neoarchean-Paleoproterozoic supercycles

Salminen, J; Pehrsson, S J; Evans, D A D; Wang, C. Ancient supercontinents and the paleogeography of Earth; by Pesonen, L J (ed.); Salminen, J (ed.); Elming, S -Å (ed.); Evans, D A D (ed.); Veikkolainen, T (ed.); 2021 p. 465-498, https://doi.org/10.1016/B978-0-12-818533-9.00014-X




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Simulating sedimentary burial cycles: I. investigating the role of apatite fission track annealing kinetics using synthetic data

McDannell, K T; Issler, D R. Geochronology vol. 3, 2021 p. 321-335, https://doi.org/10.5194/gchron-3-321-2021
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/20200758.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/20200758.jpg" title="Geochronology vol. 3, 2021 p. 321-335, https://doi.org/10.5194/gchron-3-321-2021" height="150" border="1" /></a>




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Global Hg cycle over Ediacaran-Cambrian transition and its implications for environmental and biological evolution

Wu, Y; Yin, R; Li, C; Chen, D; Grasby, S E; Li, T; Ji, S; Tian, H; Peng, P. Earth and Planetary Science Letters vol. 587, 117551, 2022 p. 1-10, https://doi.org/10.1016/j.epsl.2022.117551
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/20220035.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/20220035.jpg" title="Earth and Planetary Science Letters vol. 587, 117551, 2022 p. 1-10, https://doi.org/10.1016/j.epsl.2022.117551" height="150" border="1" /></a>




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Whitehorse Trough record of Late Triassic-Cretaceous accretionary orogenic cycle from detrital mineral thermochronometry, British Columbia, Northwest Territories, and Yukon

Kellett, D A; Coutand, I; Zagorevski, A; Grujic, D; Dewing, K. Geological Survey of Canada, Open File 8879, 2022, 1 sheet, https://doi.org/10.4095/329781
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/gid_329781.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/gid_329781.jpg" title="Geological Survey of Canada, Open File 8879, 2022, 1 sheet, https://doi.org/10.4095/329781" height="150" border="1" /></a>