Manganese phthalocyanine catalyst shows preference for least-hindered benzylic C–H bonds

Catalyst spurs insoluble salts into action as nucleophiles for enantioselective reactions

Dual-catalyst approach allows chemists to construct connections between a vast array of aliphatic and aromatic molecules

'A dynamic bond fund acts like a gilt fund in a rate cut scenario and like a conservative short-term bond fund when rates rise.'

The rupee fell in the wake of the US election but held up better than most other Asian currencies, which were hit by a dollar rally

According to Arpita Mandal, the City of Joy, now that she’s two decades older, is today less suitable for pandal-hopping, due to the massive crowds, and more suitable for cafe-hopping, with plenty of eateries mushrooming even in residential neighbourhoods

'A dynamic bond fund acts like a gilt fund in a rate cut scenario and like a conservative short-term bond fund when rates rise.'

Foreign investors were net sellers of domestic debt in October for the first time since the official inclusion of Indian government bonds in the JP Morgan bond indices, with net outflow worth Rs 4,697 crore.

Office provider’s move to skip rent payments and renegotiate leases knocks CMBS market

The gross borrowing programme announced by the government to the tune of Rs 12 lakh crores for FY 2021 is likely to see a sharp spike in bond yields, when markets open on Monday. The gross borrowing programme was originally pegged

The gross borrowing programme announced by the government to the tune of Rs 12 lakh crores for FY 2021 is likely to see a sharp spike in bond yields, when markets open on Monday. The gross borrowing programme was originally pegged

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Gold bonds open tomorrow for subscription when investment demand is rising  LivemintHere's All You Need to Know About Sovereign Gold Bond Scheme Opening on Monday  News18Sovereign Gold Bond opens tomorrow: Issue price fixed at Rs 4,...

A Barclays report estimates that the central government’s revenue benefit from the additional hikes in fuel taxes could be as much as Rs 1.4 lakh crore on an annual basis.

It has been proven that portfolio allocation leads to long-term optimum results on investments. Awareness among investors is gradually increasing on the imperative of allocation.

State Bank of India (SBI), may approach the debt market to issue additional tier-1 bonds or perpetual bonds, according to sources in the bond market.

In contrast, Indonesia’s improving fiscal status and aggressive monetary policy stance in the face of global headwinds have burnished the nation’s assets in the eyes of investors.

The initial price guidance stood at 210 bps over the US Treasury. The bank indicated that with 3.5 times over-subscription, the final price tightened by 25 bps.

The total corporate bond issuance in FY19 was Rs 6.1 lakh crore, just slightly higher than `6 lakh crore mopped up in FY18.

Banks don’t want to lend, so if `2-3 lakh crore of deposits flow to a 5% govt bond, a Covid-plan can be part-financed.

Chris Bondhus explains how Brightcove's video platform can support B2B ABM initiatives

On 1 June 2014, China’s State Administration of Foreign Exchange (the SAFE)’s Provisions on the Administration of Foreign Exchange for Cross-Border Security (??????????) and the Administration of Foreign Exchange for Cross-Border Securit...

Eversheds Sutherland property column: September 2018 Originally published in Practical law In these uncertain times, if cash is king, income is emperor. As a consequence, investors are looking for long-term, lower risk investments in the real estate...

Adult child struggles with relationships with parents who don't accept sexuality.

It was the company’s first bond sale since a $5 billion offering in March 2015.

The post Malaysia’s state oil giant Petronas raises $6b in first bond offering in five years appeared first on DealStreetAsia.

This expert seminar aims to get a better understanding of the features, limitations and preliminary findings from the use of SIBs, and to a lesser extent, of DIBs in developing countries from a multidimensional and multi-stakeholder perspective.

The purpose of the seminar is to provide the practical information about how to implement SIBs in Poland using international experiences. The seminar is addressed to the potential applicants interested in the implementation of SIB within the call for proposals planned to be launched by the Ministry of Economic Development.

This expert seminar aims to get a better understanding of the features, limitations and preliminary findings from the use of SIBs, and to a lesser extent, of DIBs in developing countries from a multidimensional and multi-stakeholder perspective.

The purpose of the seminar is to provide the practical information about how to implement SIBs in Poland using international experiences. The seminar is addressed to the potential applicants interested in the implementation of SIB within the call for proposals planned to be launched by the Ministry of Economic Development.

This expert seminar aims to get a better understanding of the features, limitations and preliminary findings from the use of SIBs, and to a lesser extent, of DIBs in developing countries from a multidimensional and multi-stakeholder perspective.

The purpose of the seminar is to provide the practical information about how to implement SIBs in Poland using international experiences. The seminar is addressed to the potential applicants interested in the implementation of SIB within the call for proposals planned to be launched by the Ministry of Economic Development.

Guidelines for investors concerned about volatility

1. Inside Salman Khan's Panvel farmhouse: Actor bonds with Jacqueline, Iulia Vantur, and Waluscha - entertainment  Mid-Day
2. Salman Khan on life during the lockdown: This is the longest I have been sitting idle  India Today
3. Tere Bina teaser: Salman Khan romances Jacqueline Fernandez in his ‘cheapest production’. Watch  Hindustan Times
4. Salman Khan and Jacqueline Fernandez share the inspiration behind their upcoming track 'Tere Bina' in the  Times of India
5. Salman Khan reveals lockdown journey and COVID-19 relief initiatives  NEWS9 live
6. View Full coverage on Google News

1. Gold bonds open tomorrow for subscription when investment demand is rising  Livemint
2. Here's All You Need to Know About Sovereign Gold Bond Scheme Opening on Monday  News18
3. Sovereign Gold Bond opens tomorrow: Issue price fixed at Rs 4,590 per gram; here's all you need to know...  Firstpost
4. RBI fixes Sovereign Gold Bond issue price at Rs 4,590/gm of gold  Hindustan Times
5. Next Sovereign Gold Bond Issue Opens On 11 May: Should You Invest?  Goodreturns
6. View Full coverage on Google News

The five-time Grammy award winner, 18, who recorded the title track to 007's No Time to Die, in London last month, will take to the stage at the O2 on Tuesday for the 40th BRIT Awards ceremony.

Billie Eilish will perform her Bond theme for the first time at Tuesday night's BRIT Awards.

On Friday, the Reserve Bank of India (RBI) released a notification on the issue price of the latest tranche of the SGB scheme that will open on 11 May. It will be Series II of the Sovereign Gold Bond Scheme 2020-21

COVID-19 strengthens hill-valley bond: Titular king

The bond-valence method was performed on 51 crystal data sets from nitrogenase proteins, indicating the presence of molybdenum(III) in FeMo cofactors and vanadium(III) with more reduced iron complements in FeV cofactors.

In the title compound, C61H15ClN2O3, the heterocyclic ring adopts an envelope conformation, folded across the N⋯N line, with the 2,5-di­meth­oxy­phenyl unit occupying a quasi-axial site. There are two N—H⋯O hydrogen bonds in the structure: one hydrogen bond links mol­ecules related by a 41 screw axis to form a C(6) chain, and the other links inversion-related pairs of mol­ecules to form an R22(8) ring. The ring motif links all of the chains into a continuous three-dimensional framework structure. Comparisons are made with the structures of some related compounds.

From solutions of prehnitene and the ternary halides (SnCl)[MCl4] (M = Al, Ga) in chloro­benzene, the new cationic SnII–π-arene complexes catena-poly[[chlorido­aluminate(III)]-tri-μ-chlorido-4':1κ2Cl,1:2κ4Cl-[(η6-1,2,3,4-tetra­meth­yl­benzene)­tin(II)]-di-μ-chlorido-2:3κ4Cl-[(η6-1,2,3,4-tetra­methyl­benzene)­tin(II)]-di-μ-chlorido-3:4κ4Cl-[chlorido­aluminate(III)]-μ-chlorido-4:1'κ2Cl], [Al2Sn2Cl10(C10H14)2]n, (1) and catena-poly[[chlorido­gallate(III)]-tri-μ-chlor­ido-4':1κ2Cl,1:2κ4Cl-[(η6-1,2,3,4-tetra­methyl­benzene)­tin(II)]-di-μ-chlorido-2:3κ4Cl-[(η6-1,2,3,4-tetra­methyl­benzene)­tin(II)]-di-μ-chlorido-3:4κ4Cl-[chlor­ido­gallate(III)]-μ-chlorido-4:1'κ2Cl], [Ga2Sn2Cl10(C10H14)2]n, (2), were isolated. In these first main-group metal–prehnitene complexes, the distorted η6 arene π-bonding to the tin atoms of the Sn2Cl22+ moieties in the centre of [{1,2,3,4-(CH3)4C6H2}2Sn2Cl2][MCl4]2 repeating units (site symmetry overline{1}) is characterized by: (i) a significant ring slippage of ca 0.4 Å indicated by the dispersion of Sn—C distances [1: 2.881 (2)–3.216 (2) Å; 2: 2.891 (3)–3.214 (3) Å]; (ii) the non-methyl-substituted arene C atoms positioned closest to the SnII central atom; (iii) a pronounced tilt of the plane of the arene ligand against the plane of the central (Sn2Cl2)2+ four-membered ring species [1: 15.59 (11)°, 2: 15.69 (9)°]; (iv) metal–arene bonding of medium strength as illustrated by application of the bond-valence method in an indirect manner, defining the π-arene bonding inter­action of the SnII central atoms as s(SnII—arene) = 2 − Σs(SnII—Cl), that gives s(SnII—arene) = 0.37 and 0.38 valence units for the aluminate and the gallate, respectively, indicating that comparatively strong main-group metal–arene bonding is present and in line with the expectation that [AlCl4]− is the slightly weaker coordinating anion as compared to [GaCl4]−.