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Fintech Progcap to digitise supply chains of MSMEs to make them part of formal economy




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Harness information for progress of country, CSIR DG tells IIIT-H graduates

She was addressing the graduating students of IIIT-H at its 23rd convocation here on Saturday




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TAPMI inducts second batch of Integrated Management Programme

The batch has students from various streams, with 52.2% coming from the science stream, 40.3% from the commerce stream, and 7.5% from arts and humanities




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IIM Calcutta’s Summer Placements for MBA programme secures 100% placements




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upGrad expands course offerings amid demand for AI programs, sees international growth

The company has broadened its product portfolio significantly to meet evolving learner demands, particularly in areas like artificial intelligence (AI) and study abroad programs




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India has a lot more scope to pursue progressive capitalism: Joseph Stiglitz

“We live in a highly integrated society where what one person does affects others; So that’s why you need collective action. You need government, you need regulation, you need public investment,” says Nobel Laureate




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Electrocatalytic nitrogen cycle: mechanism, materials, and momentum

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03156C, Review Article
Laiquan Li, Linyuan Xu, Hanyun Wang, Haohong Wei, Cheng Tang, Guisheng Li, Yuhai Dou, Hua Kun Liu, Shi Xue Dou
As a self-sustaining cycle, the electrocatalytic nitrogen cycle represents an avenue for rectifying the nitrogen imbalance and for synthesizing value-added chemicals, thereby contributing to a sustainable and carbon-neutral society.
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Customized structures of hydrogen-bonded organic frameworks towards photocatalysis

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03766A, Review Article
Chengdi Ma, Liyang Qin, Tianhua Zhou, Jian Zhang
This review provides a comprehensive analysis of the unique structural characteristics of HOFs and their diverse functional properties, while further exploring the potential of HOFs in the field of photocatalysis.
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Market optimization and technoeconomic analysis of hydrogen-electricity coproduction systems

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE02394C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Daniel J. Laky, Nicole P. Cortes, John C. Eslick, Alexander A. Noring, Naresh Susarla, Chinedu Okoli, Miguel A. Zamarripa, Douglas A. Allan, John H. Brewer, Arun K. S. Iyengar, Maojian Wang, Anthony P. Burgard, David C. Miller, Alexander W. Dowling
We present an optimization framework to analyze emerging power systems technologies that coproduce power and alternative fuels. Emerging solid oxide-based systems have the potential to enable a reliable, efficient transition to cleaner energy.
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Depressing charge recombination in hybrid perovskites by introducing a dynamic electron/energy relay couple towards enhanced photocatalytic hydrogen production

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03864A, Paper
Jiaqi Liu, Yuxin Xie, Yongxin Jiao, Hefeng Zhang, Junhui Wang, Yuying Gao, Xu Zong
Extraordinary photocatalytic hydrogen evolution is achieved on methylammonium lead iodide perovskites by introducing a dynamic Cu/(CuI2) couple as the electron/energy relay station and the Pt co-catalyst as the charge/energy-releasing promotor.
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Hydrogel electrolytes with an electron/ion dual regulation mechanism for highly reversible flexible zinc batteries

Energy Environ. Sci., 2024, 17,8570-8581
DOI: 10.1039/D4EE03067B, Paper
Fusheng Luo, Song Yang, Qing Wu, Yue Li, Jinlong Zhang, Yanhui Zhang, Jun Huang, Haibo Xie, Yiwang Chen
The unique electron/ion dual regulation mechanism is established in the well-designed hydrogel electrolyte by integrating polyacrylamide network and carboxylated multi-walled carbon nanotubes for high performance flexible ZIBs.
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A techno-economic study of photovoltaic-solid oxide electrolysis cell coupled magnesium hydride-based hydrogen storage and transportation toward large-scale applications of green hydrogen

Energy Environ. Sci., 2024, 17,8429-8456
DOI: 10.1039/D4EE04224G, Analysis
Xusheng Wang, Longfei Shao, Shouyi Hu, Zi Li, Hangzuo Guo, Jiaqi Zhang, Yingyan Zhao, Xi Lin, Binjian Nie, Zhigang Hu, Jianxin Zou
Integrating PV-SOEC for hydrogen production with MgH2-based storage and transportation holds significant potential in advancing the hydrogen supply chain.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Weakened hydrogen bond connectivity promotes interfacial mass transfer for industrial level scalable biomass electrooxidation

Energy Environ. Sci., 2024, 17,8801-8809
DOI: 10.1039/D4EE03482A, Paper
Zhaohui Yang, Lan Chen, Yijun Yin, Chenyang Wei, Zhimin Xue, Tiancheng Mu
The inhomogeneous valence distribution due to in the intrinsic electric field of a material can weaken the interfacial H-bonding connectivity under the bias potential, which promotes the mass transfer of HMF during the HMF electrooxidation reaction.
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Anti-Freezing Hydrogel Electrolyte with Regulated Hydrogen Bond Network Enables High-Rate and Long Cycling Zinc Batteries

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE02772H, Paper
Shaojie Guo, Mengyu Yan, DongMing Xu, Pan He, Kaijian Yan, Jiexin Zhu, Yongkun Yu, Zeya Peng, Yanzhu Luo, Feifei Cao
Zinc-based batteries, utilizing hydrogel electrolytes, present significant promise as power sources for next-generation flexible devices due to their stretchable nature and enhanced safety features. Nonetheless, the current hydrogel electrolytes require...
The content of this RSS Feed (c) The Royal Society of Chemistry




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India’s disaster management story as a work in progress

The Disaster Management (Amendment) Bill could be the first step in revamping the architecture and the processes involved




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Mass transport effects in gas-phase selective hydrogenation of 1,3-butadiene over supported Pd

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00039K, Paper
Open Access
Oscar E. Brandt Corstius, M. Kikkert, S. T. Roberts, E. J. Doskocil, J. E. S. van der Hoeven, P. E. de Jongh
The performance of selective hydrogenation reactions is affected by mass transfer limitations, induced by higher local metal loading and larger catalyst grain size.
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Palladium particle-catalyzed selective butadiene hydrogenation: effect of covalent organic framework modification

React. Chem. Eng., 2024, 9,950-958
DOI: 10.1039/D3RE00606A, Paper
Xianming Li, Yi Wang, Qiao Yuan, Xintai Chen, Xiaoling Mou, Xiangen Song, Li Yan, Ronghe Lin, Yunjie Ding
Deposition of a covalent organic framework on palladium nanoparticles induces geometric and electronic effects on the metal species and improves their selective performance in 1,3-butadiene hydrogenation.
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Machine-learning assisted optimisation during heterogeneous photocatalytic degradation utilising a static mixer under continuous flow

React. Chem. Eng., 2024, 9,872-882
DOI: 10.1039/D3RE00570D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Thomas M. Kohl, Yan Zuo, Benjamin W. Muir, Christian H. Hornung, Anastasios Polyzos, Yutong Zhu, Xingdong Wang, David L. J. Alexander
Machine-learning assisted optimisation of a continuous photodegradation reaction, using a TiO2 coated catalytic static mixer successfully accounting for catalyst degradation.
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From microkinetic model to process: understanding the role of the boron nitride surface and gas phase chemistry in the oxidative dehydrogenation of propane

React. Chem. Eng., 2024, 9,795-802
DOI: 10.1039/D3RE00600J, Paper
Unni Kurumbail, William P. McDermott, Edgard A. Lebrón-Rodríguez, Ive Hermans
In the oxidative dehydrogenation of propane over boron nitride, propylene selectivity is lost due to unselective gas-phase chemistry.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Biomass-based graphene aerogel for the removal of emerging pollutants from wastewater

React. Chem. Eng., 2024, 9,753-776
DOI: 10.1039/D3RE00526G, Review Article
Vijayendra Kumar Tripathi, Manish Shrivastava, Jaya Dwivedi, Raju Kumar Gupta, Lokesh Kumar Jangir, Kumud Malika Tripathi
This review article provides a detailed overview of the synthesis techniques of biomass-based graphene aerogels and highlights the influence of fabrication parameters on the performance of the resulting aerogels for wastewater treatment applications.
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At-line monitoring of hydrogen peroxide released from its photocatalytic and continuous synthesis

React. Chem. Eng., 2024, 9,777-781
DOI: 10.1039/D3RE00659J, Communication
Open Access
Anders Ø. Tjell, Lars-Erik Meyer, Barbara Jud, Selin Kara, Torsten Mayr
Photocatalytic synthesis of H2O2 in a continuous operation set-up using nitrogen-doped carbon nanodots (N-CNDs) and simultaneous determination of generated H2O2.
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Selective hydrogenation of 5-hydroxymethylfurfural to 2,5-bis(hydroxymethyl)furan over Ni–Ga intermetallic catalysts and its kinetic studies

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00129J, Paper
Weixiao Sun, Fuzeyu Zhong, Xiaohu Ge, Wenyao Chen, Gang Qian, Yueqiang Cao, Xuezhi Duan, Xinggui Zhou, Jing Zhang
5-Hydroxymethylfurfural (HMF) has been listed as the “TOP 14” most important biomass-derived platform molecules, which can be converted into 2,5-bis(hydroxymethyl)furan (BHF) via selective hydrogenation of the carbonyl group on HMF.
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Novel TPMS carbon-based monolithic catalysts by three-dimensional printing for enhancement of nitrobenzene hydrogenation reaction

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00049H, Paper
Haoyang Wang, Haoran Tian, Qi Zhang, Li Zhang
Preparation of periodic curved surface, structured, carbon-based catalysts using a 3D printing method achieved good results in the hydrogenation of nitrobenzene to aniline in a packed-bed micro-reactor.
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Efficient aqueous-phase hydrogenation of m-xylylenediamine to 1,3-cyclohexandimethylamine over a highly active and stable ruthenium catalyst

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00712J, Paper
Jing Guo, Heng Shao, Le Gao, Wancheng Ma, Wei Zhang, Long Huang, Haibin Chu
The strong interaction between Ru and –NH2 in Ru/NH2–Al2O3 led to the formation of highly dispersed Ru and modification of its electronic properties, and consequently greatly enhanced its performance and stability.
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Hydrogenolysis of furfuryl alcohol over CuCeMgAl mixed metal oxide catalysts derived from layered double hydroxides

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00070F, Paper
Zhihui Wang, Wenbo Li, Xinyao Fu, Chen Zhang, Wei Zhang, Long Huang, Cuiqing Li
LDH-derived CuCeMgAl mixed metal oxide catalysts were synthesized. Ce addition promoted Cu dispersion and improved catalyst basicity, resulting in high activity in furfuryl alcohol hydrogenolysis and high selectivity toward 1,2-pentanediol.
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Generation of nitrogen by means of electrochemical oxygen depletion

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00104D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Dominik Sachse, Basil Noha Chelachottil, Andreas Glüsen, Martin Müller, Uwe Rau, Ralf Peters
Electrochemical oxygen reduction enables a high depletion of the oxygen content with very high Faraday efficiency at the same time.
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Create SECI-like entity for efficient long-term procurement of green hydrogen: TERI

The policy think tank also recommends creating an SPV for each industrial segment for development of pilot plants




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Biological effects and mechanisms of dietary chalcones: latest research progress, future research strategies, and challenges

Food Funct., 2024, 15,10582-10599
DOI: 10.1039/D4FO03618B, Review Article
Yun Liang Zhang, Shuang Jiao Sun, Li Zeng
Chalcones are widely distributed in food and have multiple biological activities; there are limitations and drawbacks in the application of dietary chalcones in food; future research strategies and key issues for dietary chalcones.
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Inhibitory effect of tea flower polysaccharides on oxidative stress and microglial oxidative damage in aging mice by regulating gut microbiota

Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO03484H, Paper
Yidan Cai, Siyu Liu, Xing Ge, Lu Cheng, Xin Zhang
Tea flower polysaccharides (TFPS) can improve the disorder of gut microbiota, alleviate oxidative damage to glial cells, alleviate neuroinflammation, and play a role in delaying aging.
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Impact of pH on the fabrication of egg white reinforced soy protein composite microgels for gastrointestinal delivery purposes

Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO03997A, Paper
Feng Liu, Yi Liu, Suyun Zhang, Gang Liu, Christos Ritzoulis, Yue Zhang
Protein molecules such as soy protein isolate (SPI) and egg white (EW) are highly promising materials for developing hydrogels (especially micro/nanogels) for the encapsulation, protection and controlled release of bioactive substances.
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Up-regulation of myelin-associated glycoprotein is associated with the ameliorating effect of omega-3 polyunsaturated fatty acids on Alzheimer's disease progression in APP–PS1 transgenic mice

Food Funct., 2024, 15,11236-11251
DOI: 10.1039/D4FO03355H, Paper
Yan Shao, Fei Li, Bo Zou, Yanling Jin, Xiaoyang Wang, Liting Wang, Youying Huang, Yu Xie, Wei Sun, Jing X. Kang, Kai Liu, Yi Huang, Wei Huang, Bin Wang
Our study showed that MAG upregulation might be the new regulatory mechanism for omega-3 PUFAs to exert AD protective effects, which is helpful for expanding our understanding of the health-promoting effects of omega-3 PUFAs.
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Education not a prerogative of the ‘upper caste‘, says Siddaramaiah

Ramayana, Mahabharata authored by “lower castes”, says CM




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Progress in trade between India and Russia: Jaishankar

Since the war in Ukraine and Russia ouster from the international SWIFT payment system, payments have emerged as a major bottleneck between India and Russia




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Redesigned programmes can vastly improve TB treatment outcomes

Doubling the direct benefit transfer to Rs.1,000 per month, disbursing Rs.3,000 at the time of diagnosis, and nutrition support to TB patients can have a huge impact




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Micrographia: Hooke’s monumental masterpiece

A great book written and illustrated by English polymath Robert Hooke, Micrographia appeared in bookshops in January 1665. The advance copy of this book, which details Hooke’s exploration into many things small, far, and sometimes elusive, is believed to have been shown to the Royal Society on November 3, 1664. A.S.Ganesh tries to hook you onto Hooke’s story…  




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Expand your horizon through an LLM programme

The programmes should bring about a conceptual, interdisciplinary and research focused study.




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The price of arrogance

A performance of ‘Dakshayagam’ in the capital city pointed out how inflated egos can rend asunder familial ties.




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Hydrogenation of sulfoxides to sulfides mediated by incomplete cubane-type Mo3S4 clusters: synthetic applications and mechanistic insights

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00987H, Paper
Juanjo Mateu-Campos, María Gutiérrez-Blanco, Eva Guillamón, Vicent S. Safont, Rosa Llusar
Air-stable diamino Mo3S4 clusters are efficient catalysts for the late-stage functionalization of drugs and other valuable products containing sulfide moieties.
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Enhanced catalytic performance of single-atom Cu on Mo2C toward CO2/CO hydrogenation to methanol: a first-principles study

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00703D, Paper
Open Access
Anna Vidal-López, Estefanía Díaz López, Aleix Comas-Vives
First-principles calculations show the crucial role of the Cu/Mo2COx interface in enabling low-energy pathways for CO2/CO hydrogenation to methanol via successive heterolytic H2 cleavages.
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Accelerated design of nickel-cobalt based catalysts for CO2 hydrogenation with human-in-the-loop active machine learning

Catal. Sci. Technol., 2024, 14,6307-6320
DOI: 10.1039/D4CY00873A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yasemen Kuddusi, Maarten R. Dobbelaere, Kevin M. Van Geem, Andreas Züttel
The effect of catalyst synthesis and reaction conditions on catalytic activity were accurately predicted with an interpretable data-driven strategy. The method is demonstrated for CO2 methanation and is extendable to other catalytic processes.
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Sulfonic acid-modified MOFs as heterogeneous bifunctional catalysts for ethylene oligomerization at room temperature without cocatalysts

Catal. Sci. Technol., 2024, 14,6270-6277
DOI: 10.1039/D4CY00502C, Paper
Yao Ning, Yuqi Yang, Dongming Shan, Shuxing Mei, Yibai Yan, Linjie Ding, Ying Zhang
Ethylene oligomerization plays an important role in industrial production.
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Multiscale modelling of CO2 hydrogenation of TiO2-supported Ni8 clusters: on the influence of anatase and rutile polymorphs

Catal. Sci. Technol., 2024, 14,6393-6410
DOI: 10.1039/D4CY00586D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lulu Chen, Ying-Ying Ye, Rozemarijn D. E. Krösschell, Emiel J. M. Hensen, Ivo A. W. Filot
The selection of TiO2 phase, whether anatase or rutile, for supporting small Ni clusters significantly influences the activity and selectivity in CO2 hydrogenation to methane.
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Hydrolysis of ammonia borane for green hydrogen production over a Pd/C3N4 nanocatalyst synthesized by electron beam irradiation

Catal. Sci. Technol., 2024, 14,6338-6350
DOI: 10.1039/D4CY00761A, Paper
Manish Shingole, Seemita Banerjee, Priyanka Ruz, Asheesh Kumar, Pratibha Sharma, V. Sudarsan
Room temperature hydrolysis of ammonia borane in presence of electron beam irradiated Pd-C3N4 catalyst.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Photocatalytic dehydrogenative C(sp2)–P coupling reaction between dibenzo[b,f][1,4]oxazepanes and phosphine oxides

Catal. Sci. Technol., 2024, 14,6176-6179
DOI: 10.1039/D4CY00955J, Communication
Zhaotian Wu, Xuefei Sha, Shan Wang, Huan Yang, Shaojun Zheng, Chunhui Jiang, Shu-Yang Chen, Hongfei Lu
Visible-light-induced cross-dehydrogenative coupling between cyclic imines and diaryl phosphine oxides has been developed to afford their oxyphosphide derivatives, using rhodamine B as a photocatalyst.
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The effect of separation distance on hydrogen spillover in Os promoted Co@HCS catalysts

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00758A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tshepo Molefe, Roy Peter Forbes, Neil John Coville
Decreasing the carbon shell thickness increased the reducibility of Co3O4. The reducibility of Co3O4 was further achieved by adding an Os promoter outside of the sphere showing that H spillover was favoured over H2 diffusion/Co reduction by carbon.
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Identification of Ni3Fe alloy as a candidate catalyst for quinoline selective hydrogenation with computations

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01076K, Paper
Zhaochun He, Yonghua Liu, Tao Wang
We computationally identified Ni3Fe as a promising catalyst for the quinoline (QL) selective hydrogenation to 1,2,3,4-tetrahydroquinoline (py-THQL) using density functional theory calculations and microkinetic modeling.
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One-pot synthesis of 1,4-butanediol via the deep hydrogenation of maleic anhydride over Cu–xMo/SiO2 catalysts

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01006J, Paper
Kai Cui, Jiaming Yang, Yuli Jing, Junwen Chen, Chen Zhao, Peng Wu, Xiaohong Li
A Cu–0.03Mo/SiO2 catalyst realized the one-pot deep hydrogenation of maleic anhydride to 1,4-butanediol at 200 °C, under 5 MPa of hydrogen pressure with 100% conversion and 88.3% selectivity, one of the highest values for this target reaction.
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Investigation on heterogeneous Rh Catalysts for the Hydroformylation of 1,3-Butadiene to adipic aldehyde

Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY00745J, Paper
Lijin Gan, Zekun Liu, Lei Feng, Yi Duan, Guangyuan Xu, Si Chen, Huan Yan
Adipic aldehyde, as a precursor for polymers, has significant industrial applications, where the hydroformylation of 1,3-butadiene is a promising routine to fabricate adipic aldehyde. However, the heterogeneous hydroformylation of 1,3-butadiene...
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The O2-stable [FeFe]-hydrogenase CbA5H reveals high resilience against organic solvents

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01018C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Martin Gerbaulet, Anja Hemschemeier, Thomas Happe
CbA5H from Clostridium beijerinckii is an oxygen-stable [FeFe]-hydrogenase. Here we report that CbA5H is stable in high concentrations of acetone and acetonitrile and also withstands intermediate concentrations of DMSO, ethanol and methanol.
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Heterogeneous oxidative upcycling of polystyrene plastics to benzoic acid under air conditions

Catal. Sci. Technol., 2024, 14,6584-6591
DOI: 10.1039/D4CY00970C, Paper
Chengyang Sun, Yong Guo, Xiaohui Liu, Yanqin Wang
A heterogeneous oxidative upcycling strategy converting polystyrene (PS) waste into benzoic acid.
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