The structures of seven gold(III) halide derivatives of general formula LAuX3 (L = methyl­pyridines or di­methyl­pyridines, X = Cl or Br) are presented: tri­chlorido­(2-methyl­pyridine)­gold(III), [AuCl3(C6H7N)], 1 (as two polymorphs 1a and 1b); tri­bromido­(2-methyl­pyridine)­gold(III), [AuBr3(C6H7N)], 2; tri­bromido­(3-methyl­pyridine)­gold(III), [AuBr3(C6H7N)], 3; tri­bromido­(2,4-di­meth­yl­pyridine)­gold(III), [AuBr3(C7H9N)], 4; tri­chlorido­(3,5-di­methylpyridine)­gold(III), [AuCl3(C7H9N)], 5; tri­bromido­(3,5-di­methyl­pyridine)­gold(III), [AuBr3(C7H9N)], 6, and tri­chlorido­(2,6-di­methyl­pyridine)­gold(III), [AuCl3(C7H9N)], 7. Additionally, the structure of 8, the 1:1 adduct of 2 and 6, [AuBr3(C6H7N)]·[AuBr3(C7H9N)], is included. All the structures crystallize solvent-free, and all have Z' = 1 except for 5 and 7, which display crystallographic twofold rotation symmetry, and 4, which has Z' = 2. 1a and 2 are isotypic. The coordination geometry at the gold(III) atoms is, as expected, square-planar. Four of the crystals (1a, 1b, 2 and 8) were non-merohedral twins, and these structures were refined using the ‘HKLF 5’ method. The largest inter­planar angles between the pyridine ring and the coordination plane are observed for those structures with a 2-methyl substituent of the pyridine ring. The Au—N bonds are consistently longer trans to Br (average 2.059 Å) than trans to Cl (average 2.036 Å). In the crystal packing, a frequent feature is the offset-stacked and approximately rectangular dimeric moiety (Au—X)2, with anti­parallel Au—X bonds linked by Au⋯X contacts at the vacant positions axial to the coordination plane. The dimers are connected by further secondary inter­actions (Au⋯X or X⋯X contacts, `weak' C—H⋯X hydrogen bonds) to form chain, double chain (`ladder') or layer structures, and in several cases linked again in the third dimension. Only 1b and 7 contain no offset dimers; these structures instead involve C—H⋯Cl hydrogen bonds combined with Cl⋯Cl contacts (1b) or Cl⋯π contacts (7). The packing patterns of seven further complexes LAuX3 involving simple pyridines (taken from the Cambridge Structural Database) are compared with those of 1–8.

Luxme International has supplied a SANILux Tubular Chain Conveyor with automated clean-in-place technology to nutrition bar manufacturer TruFood, enhancing food safety and increasing line efficiency at the company’s Pittsburgh-based facility.

Consumers crave budget-friendly treats.

Multiflux GMS mixers from process equipment manufacturer Gericke USA feature a proprietary, hygienic design as standard to promote fast, complete cleaning, ensure product purity, and minimize risk of batch-to-batch cross-contamination.

Process equipment manufacturer Gericke USA, Somerset, NJ, has introduced the Multiflux GMS Laboratory Mixer.

The luxurious Wythe Hotel in Brooklyn, New York, was once a waterfront barrel and rope factory. This renovated structure now has 72 boutique guest rooms. As part of the update, it was important to retain the character of the original turn of the century building, which opened in 1901. In order to convert the cold, utilitarian factory space into comfortable rooms, a major mechanical update was required. By adding radiant floor heat, they were able to meet and exceed the comfort benchmark of a modern-day hotel while balancing for energy efficiency.

This automatic helmet includes premium features.

For beverage distributors, handling the influx of SKUs has prompted carts and hand truck manufacturers to take a proactive approach so that delivery personnel can tackle the growing challenge.

As the need for business IT services skyrockets amid Covid-era cybersecurity threats and transition to remote work, website redesign allows business owners to find solutions easily, connect immediately to technology experts.

Luxe Life Discovered and 30A Media will produce, develop and distribute the prestigious lifestyle content.

The AI industry and its work product are growing exponentially, well ahead of critical rules and laws needed to provide safeguards, including fair use in the workplace.

Taking Place at the La Peer Hotel, over $40K in Gifts and Trips were given to the world's top athletes

Summit Black Car drives excellence: exciting focus on Aspen market sets new standards in luxury transportation

Revolutionizing Residential Fitness Spaces with Personalized Design and Best-in-Class Equipment Selection

Australian infant formula brand and luxury celebrity gifting lounge gift new-to-market infant formula during awards season

Southern California's Premier FBO to Exhibit at NBAA–BACE 2023

Region's Premier FBO to Exhibit at 2024 NBAA Schedulers & Dispatchers Conference

Holiday Vacation Rentals a premiere resource for Northern Michigan cottage, condominium and fine home rentals, today announced that select rental properties will be available on Homes & Villas by Marriott Bonvoy

GL Homes is excited to introduce Valencia Grand, a resort-style 55+ community.

From Iconic Brands like Veuve Clicquot and Dom Perignon to Louis Roederer Cristal, Discover the Perfect Champagne Gift Baskets and Sets for the Festive Season

Setting a New Standard of Luxury in Des Moines Interior Design

"Our mission has always been to provide top-tier cleaning services that not only meet but exceed our clients' expectations," said owner Vicente Mendoza Escarraga

Hill Country Salon Suites Expands Its List of Tenants with Coloring Stylist

A Stunning Blend of Comfort and Elegance Awaits in Woodstock, IL's Premier Luxury Estate - An Exceptional Opportunity with a Highly Attractive Assumable Loan

GL Homes is excited to announce the highly anticipated sale of it's cutting edge, contemporary model homes at Lotus Palm.

Initiative Includes Enhanced Staffing and Training, More Personalized Service, Broader Selection, And Amazing Discounts and Deals

GL Homes has just unveiled a new luxury spa and nail salon, enriching its array of amenities for residents to enjoy.

VOMOS, a leading provider of premium ground transportation services, proudly announces the newest addition to its distinguished fleet — the Mercedes Maybach Metris with service in PA, DE and the NorthEast Tri-State Area.

Aufait UX, an established UI UX design agency with offshore studios in Bangalore and Kerala, India, announces its entry in the US by opening an office in Cupertino, CA.

According to a recent survey conducted by TechBehemoths between February 19 - March 6, 2024.

Britney A. Arceneaux is a dedicated wife, mother, and successful business owner who juggles work and family

The new Kontrast range of shower cabins by Vidalux is fresh but timeless and highly practical. It's the ideal choice for anyone looking to upgrade their bathroom and give it a luxury look on a budget

Blurring lines between the 'inside and outside' this range captivates the ongoing trend to connect with nature.

Everything's going electric these days and that includes showers. Vidalux is getting ahead of the trend with its new range of electric shower pods. They're perfect for homeowners who're moving away from gas for a greener future (and lower bills)

Top London Luxury PR Agency JPR Media Group works with Starr Luxury Cars to launch Sirius Car Club on the 16th of October 2023 at the new Lotus Cars Showroom in Mayfair beside the 1 Mayfair Hotel.

4849 Nestle Court, Reno Nevada, offered at $4,500,000

Janu Hotel wanted to create an unforgettable ambiance and experience for guests in the lobby

The exclusive ECOLUXE pre-ESPYS Sports Lounge brought together professional athletes, Olympians, and celebrities to benefit Marley Mutts Dog Rescue.

CRUX Is an 8(a) Joint Venture to Support the Transformation of Government Service Delivery

Elaine Antonio Bordeaux channels years of expertise into her work as an attorney and a sculptor

Internationally acclaimed celebrity event designer and Beauty Founder Diann Valentine proudly introduces SLAYYY Hair, a revolutionary hair brand committed to providing safer and healthier alternative to toxic traditional synthetic braiding hair.

It is with great excitement that Windsor Jewelers announces the expansion of their Winston-Salem jewelry store and a liquidation event starting Friday, March 8th!

Trips and Ships Luxury Travel, a distinguished provider of premium and luxury travel experiences, proudly announces its receipt of the prestigious President's Circle distinction by Travel Leaders Network for the second consecutive year.

Summit Black Car: Exclusive Luxury Transport for an Unforgettable Red Rocks Amphitheater Experience

Redefined Wedding Mornings: Grooming and Bonding Like Never Before

Valérarch takes on the challenge of designing an original timepiece that doesn't appear to resemble any other watch design from the past.

EpicVIN announced today the online automotive marketplace is partnering with Bidux, an industry leader in vehicle transportation and shipping, to make the car buying process simple.

From Hosting Sports Stars at the Pre-ESPYs Luxury Lounge to Co-Hosting a Podcast, XOIE Continues to Impress.

Oscar Nominees and A-List Celebrities were Honored with over $100K in Gifts and Trips at the Luxurious Beverly Wilshire Hotel

Redefining the marketing landscape! Explore our cutting-edge video player solutions and discover how these high tech marketing products will transform the way you deliver your marketing message.