Sacramento, CA — Legislation recently introduced in California would help ensure workers have uninterrupted personal time by establishing a “right to disconnect” from emails, texts and calls outside of work hours.

Hartford, CT — Connecticut Gov. Ned Lamont (D) has signed into law legislation that expands the state’s 13-year-old paid sick leave law.

Frequently using a computer may cause ergonomics issues, warns the Rosemont, IL-based American Academy of Orthopaedic Surgeons.

Chicago — A large majority of workers are either burned out or feel ambivalent about their job, results of a recent survey show.

Prepared Foods profiles refrigerated foods giant Reser’s Fine Foods, Beaverton, Ore., and interviews Chef Sean Dwigans, Culinary Business Development Manager; and Chef Todd Ketterman, Culinary Manager.

Listen to the second installment of Prepared Foods' interview with refrigerated foods giant Reser's Fine Foods, Beaverton, Ore.

The Pharmafill NB1 neck bander features a clear safety door to protect workers from contact with the operating mechanism and allow constant visual monitoring, while safeguarding the shrink bands and machine internals from contamination.

I have heard of "legal connections" on flier talk over the years. Is there a place that defines this. Different for local versus international. Need to recheck baggage. Going thru customs. Guidelines or a real thing? Hope this is the right...

Mad Tea pods are fully compatible with Nespresso machines, allowing consumers to brew teas in under 30 seconds.

With software upgrades, users should not have to relearn what they already know--and user interfaces need to be constructed with the end user in mind.

The agency says people sickened by listeria have recently recounted eating meat that was sliced at deli counters, including ham, turkey and liverwurst.

The Kitchen & Bath Industry Show, will host three international delegation tours and an NKBA Global Connect Pavillion.

Children's Geographies; 02/01/2024
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The post Functional Connectivity Alterations in Suicidal Patients Among Opioid Users was curated by information for practice.

For decades, Cologne-based violinist Geoffry Wharton has played jazzy crowd-pleasing encores written in the 1930s by an obscure composer, Audrey Call. Then Wharton discovered a spooky connection with her.

Actor John Rhys-Davies narrates a reimagined audio drama of "A Christmas Carol," drawn by the story’s themes of transformation, compassion and redemption, which he likens to the journeys of both Scrooge and his Rings character, Gimli, as they overcome prejudice and open their hearts to others.

By Degrees is a new reporting project by NHPR shedding new light on climate change in New Hampshire. That project launches this week. Air pollution is known to cause health problems like premature deaths, hospitalizations, heart attacks, and childhood asthma. It's also closely connected to climate change. Syracuse University Professor Charles Driscoll joined NHPR’s All Things Considered host Peter Biello to talk about what air quality in New Hampshire can tell us about the extent of the problem. So walk us through the basics, if you could. What are the main sources of air pollution in New Hampshire? There are different air pollutants that come from primarily fossil fuel combustion. So that could be through electric utilities, could be industrial processes, could be transportation. And there are a number of air pollutants, but the ones that are most prominent are very fine particulate matter released directly from these processes. But it also can be produced in the atmosphere from

Members of the Lakes Area Vineyard Church in Detroit Lakes, Minnesota, where the late Beau Shroyer and his family were longtime members before moving to Lubango, Angola, to serve as missionaries in 2021, are now reeling in a complex web of emotions after learning that Beau’s wife, Jackie Shroyer, was arrested in connection with his murder in the southern African country just over a week ago.

Health Care Provider Boot Camp Day 5: Preauthorization; Medical Necessity and Utilization Review

Special Technology Report on Mobile Computing /Automatic Identification and Data Capture (AIDC).

RetailTechnologyReview.com.com spoke with leading spokespeople within the vendor and analyst community about current trends and developments within the automatic identification & data capture (AIDC)/mobile computing solutions space, including those related to modern supply chain challenges and omnichannel.

A research group from the George Institute for Global Health in Australia found out that the estrogen levels can be an indicator of a woman's risk of developing dementia. The researchers suggest that some of the reproductive factors (early or late menstruation, early menopause) are a sign of a higher risk of certain neurological problems connected with cognitive and social skills. According to the PloS Medicine journal, pregnancy and abortion are connected with the lower risk of dementia and other neurological problems.

[Inter-Korea] :
A new survey finds that three-quarters of South Koreans believe unification of the two Koreas is necessary.  According to the national unification survey for the third quarter released by the Peaceful Unification Advisory Council on Monday, 74-point-six percent of respondents answered in the ...

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[International] :
Microsoft-backed OpenAI's popular chatbot ChatGPT was restored after a brief connection failure that affected thousands of users worldwide on Friday. In a statement on its website, OpenAI said that issues with ChapGPT have now been resolved. It said most users regained access by 4:34 p.m. Pacific ...

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Modern PCs and Macs use built-in Bluetooth to easily connect to your phone's AirPods. We'll show you how.

Explore Cancer and Taurus compatibility, where stability meets sensitivity. Learn how these signs create lasting love through trust, loyalty, and mutual understanding.

A second crystalline modification of the title compound, C12H19N3S [common name: cis-jasmone thio­semicarbazone] was crystallized from tetra­hydro­furane at room temperature. There is one crystallographic independent mol­ecule in the asymmetric unit, showing disorder in the cis-jasmone chain [site-occupancy ratio = 0.590 (14):0.410 (14)]. The thio­semicarbazone entity is approximately planar, with the maximum deviation from the mean plane through the N/N/C/S/N atoms being 0.0463 (14) Å [r.m.s.d. = 0.0324 Å], while for the five-membered ring of the jasmone fragment, the maximum deviation from the mean plane through the carbon atoms amounts to 0.0465 (15) Å [r.m.s.d. = 0.0338 Å]. The mol­ecule is not planar due to the dihedral angle between these two fragments, which is 8.93 (1)°, and due to the sp3-hybridized carbon atoms in the jasmone fragment chain. In the crystal, the mol­ecules are connected by N—H⋯S and C—H⋯S inter­actions, with graph-set motifs R22(8) and R21(7), building mono-periodic hydrogen-bonded ribbons along [010]. A Hirshfeld surface analysis indicates that the major contributions for the crystal cohesion are H⋯H (67.8%), H⋯S/S⋯H (15.0%), H⋯C/C⋯H (8.5%) and H⋯N/N⋯H (5.6%) [only non-disordered atoms and those with the highest s.o.f. were considered]. This work reports the second crystalline modification of the cis-jasmone thio­semicarbazone structure, the first one being published recently [Orsoni et al. (2020). Int. J. Mol. Sci. 21, 8681–8697] with the crystals obtained in ethanol at 273 K.

The reaction between a racemic mixture of (R,S)-fixolide and 4-methyl­thio­semicarbazide in ethanol with a 1:1 stoichiometric ratio and catalysed with HCl, yielded the title compound, C20H31N3S [common name: (R,S)-fixolide 4-methyl­thio­semicarbazone]. There is one crystallographically independent mol­ecule in the asymmetric unit, which is disordered over the aliphatic ring [site-occupancy ratio = 0.667 (13):0.333 (13)]. The disorder includes the chiral C atom, the neighbouring methyl­ene group and the methyl H atoms of the methyl group bonded to the chiral C atom. The maximum deviations from the mean plane through the disordered aliphatic ring amount to 0.328 (6) and −0.334 (6) Å [r.m.s.d. = 0.2061 Å], and −0.3677 (12) and 0.3380 (12) Å [r.m.s.d. = 0.2198 Å] for the two different sites. Both fragments show a half-chair conformation. Additionally, the N—N—C(=S)—N entity is approximately planar, with the maximum deviation from the mean plane through the selected atoms being 0.0135 (18) Å [r.m.s.d. = 0.0100 Å]. The mol­ecule is not planar due to the dihedral angle between the thio­semicarbazone entity and the aromatic ring, which amounts to 51.8 (1)°, and due to the sp3-hybridized carbon atoms of the fixolide fragment. In the crystal, the mol­ecules are connected by H⋯S inter­actions with graph-set motif C(4), forming a mono-periodic hydrogen-bonded ribbon along [100]. The Hirshfeld surface analysis suggests that the major contributions for the crystal cohesion are [(R,S)-isomers considered separately] H⋯H (75.7%), H⋯S/S⋯H (11.6%), H⋯C/C⋯H (8.3% and H⋯N/N⋯H (4.4% for both of them).

In the paper by Oliveira et al. [IUCrData (2023), 8, x230971], there was an error in the name of the first author.

The equimolar and hydro­chloric acid-catalysed reaction between cis-jasmone and 4-methyl­thio­semicarbazide in ethano­lic solution yields the title compound, C13H21N3S (common name: cis-jasmone 4-methyl­thio­semicarbazone). Two mol­ecules with all atoms in general positions are present in the asymmetric unit. In one of them, the carbon chain is disordered [site occupancy ratio = 0.821 (3):0.179 (3)]. The thio­semicarbazone entities [N—N—C(=S)—N] are approximately planar, with the maximum deviation from the mean plane through the selected atoms being −0.0115 (16) Å (r.m.s.d. = 0.0078 Å) for the non-disordered mol­ecule and 0.0052 (14) Å (r.m.s.d. = 0.0031 Å) for the disordered one. The mol­ecules are not planar, since the jasmone groups have a chain with sp3-hybridized carbon atoms and, in addition, the thio­semicarbazone fragments are attached to the respective carbon five-membered rings and the dihedral angles between them for each mol­ecule amount to 8.9 (1) and 6.3 (1)°. In the crystal, the mol­ecules are connected through pairs of N—H⋯S and C—H⋯S inter­actions into crystallographically independent centrosymmetric dimers, in which rings of graph-set motifs R22(8) and R21(7) are observed. A Hirshfeld surface analysis indicates that the major contributions for the crystal cohesion are from H⋯H (70.6%), H⋯S/S⋯H (16.7%), H⋯C/C⋯H (7.5%) and H⋯N/N⋯H (4.9%) inter­actions [considering the two crystallographically independent mol­ecules and only the disordered atoms with the highest s.o.f. for the evaluation].

The title compound, C10H8BrN3OS2, a brominated di­thio­carbazate imine deriv­ative, was obtained from the condensation reaction of S-methyl­dithio­carbazate (SMDTC) and 5-bromo­isatin. The essentially planar mol­ecule exhibits a Z configuration, with the di­thio­carbazate and 5-bromo­isatin fragments located on the same sides of the C=N azomethine bond, which allows for the formation of an intra­molecular N—H⋯Ob (b = bromo­isatin) hydrogen bond generating an S(6) ring motif. In the crystal, adjacent mol­ecules are linked by pairs of N—H⋯O hydrogen bonds, forming dimers characterized by an R22(8) loop motif. In the extended structure, mol­ecules are linked into a three-dimensional network by C—H⋯S and C—H⋯Br hydrogen bonds, C—Br⋯S halogen bonds and aromatic π–π stacking.

The title di­thio­carbazate imine, C11H11N3OS2, was obtained from the condensation reaction of S-methyl­dithio­carbazate (SMDTC) and 5-methyl­isatin. It shows a Z configuration about the imine C=N bond, which is associated with an intra­molecular N—H⋯O hydrogen bond that closes an S(6) ring. In the crystal, inversion dimers linked by pairwise N—H⋯O hydrogen bonds generate R22(8) loops. The extended structure features C—H⋯S contacts as well as reciprocal carbon­yl–carbonyl (C=O⋯C=O) inter­actions.

The reaction between the (R,S)-fixolide 4-methyl­thio­semicarbazone and PdII chloride yielded the title compound, [Pd(C20H30N3S)2]·C2H6O {common name: trans-bis­[(R,S)-fixolide 4-methyl­thio­semicarbazonato-κ2N2S]palladium(II) ethanol monosolvate}. The asymmetric unit of the title compound consists of one bis-thio­semicarbazonato PdII complex and one ethanol solvent mol­ecule. The thio­semicarbazononato ligands act as metal chelators with a trans configuration in a distorted square-planar geometry. A C—H⋯S intra­molecular inter­action, with graph-set motif S(6), is observed and the coordination sphere resembles a hydrogen-bonded macrocyclic environment. Additionally, one C—H⋯Pd anagostic inter­action can be suggested. Each ligand is disordered over the aliphatic ring, which adopts a half-chair conformation, and two methyl groups [s.o.f. = 0.624 (2):0.376 (2)]. The disorder includes the chiral carbon atoms and, remarkably, one ligand has the (R)-isomer with the highest s.o.f. value atoms, while the other one shows the opposite, the atoms with the highest s.o.f. value are associated with the (S)-isomer. The N—N—C(=S)—N fragments of the ligands are approximately planar, with the maximum deviations from the mean plane through the selected atoms being 0.0567 (1) and −0.0307 (8) Å (r.m.s.d. = 0.0403 and 0.0269 Å) and the dihedral angle with the respective aromatic rings amount to 46.68 (5) and 50.66 (4)°. In the crystal, the complexes are linked via pairs of N—H⋯S inter­actions, with graph-set motif R22(8), into centrosymmetric dimers. The dimers are further connected by centrosymmetric pairs of ethanol mol­ecules, building mono-periodic hydrogen-bonded ribbons along [011]. The Hirshfeld surface analysis indicates that the major contributions for the crystal cohesion are [atoms with highest/lowest s.o.f.s considered separately]: H⋯H (81.6/82.0%), H⋯C/C⋯H (6.5/6.4%), H⋯N/N⋯H (5.2/5.0%) and H⋯S/S⋯H (5.0/4.9%).

The title compound (C14H23N3S, common name: cis-jasmone 4-ethyl­thio­semicarbazone) was synthesized by the equimolar reaction of cis-jasmone and 4-ethyl­thio­semicarbazide in ethanol facilitated by acid catalysis. There is one crystallographically independent mol­ecule in the asymmetric unit, which shows disorder of the terminal ethyl group of the jasmone carbon chain [site-occupancy ratio = 0.911 (5):0.089 (5)]. The thio­semicarbazone entity [N—N—C(=S)—N] is approximately planar, with the maximum deviation of the mean plane through the N/N/C/S/N atoms being 0.0331 (8) Å, while the maximum deviation of the mean plane through the five-membered ring of the jasmone fragment amounts to −0.0337 (8) Å. The dihedral angle between the two planes is 4.98 (7)°. The mol­ecule is not planar due to this structural feature and the sp3-hybridized atoms of the jasmone carbon chain. Additionally, one H⋯N intra­molecular inter­action is observed, with graph-set motif S(5). In the crystal, the mol­ecules are connected through pairs of H⋯S inter­actions with R22(8) and R21(7) graph-set motifs into centrosymmetric dimers. The dimers are further connected by H⋯N inter­actions with graph-set motif R22(12), which are related by an inversion centre, forming a mono-periodic hydrogen-bonded ribbon parallel to the b-axis. The crystal structure and the supra­molecular assembly of the title compound are compared with four known cis-jasmone thio­semicarbazone derivatives (two crystalline modifications of the non-substituted form, the 4-methyl and the 4-phenyl derivatives). A Hirshfeld surface analysis indicates that the major contributions for the crystal cohesion are from H⋯H (70.7%), H⋯S/S⋯H (13.5%), H⋯C/C⋯H (8.8%), and H⋯N/N⋯H (6.6%) inter­faces (only the disordered atoms with the highest s.o.f. were considered for the evaluation).

Catawba County has been awarded one of only two grants presented across the nation, by Motorola and the National Association of Counties (NACo), to local governments that suggested innovative solutions to improve operations within their respective counties. The $30,000 grant will fund the wireless broadband internet capacity needed at Catawba County�s EcoComplex to allow for real-time monitoring between EcoComplex laboratories, universities and businesses.

Improved understanding of the coupled natural-human coastal system will help promote resilience of coastal communities and ecosystems under rapidly changing environmental conditions and support informed decision-making, says a new report from the National Academies of Sciences, Engineering, and Medicine.

In light of the present situation in the U.S., we believe that it is essential to explore a wide range of options for treating the increasing numbers of very ill patients with COVID-19 respiratory illness.

The National Academies of Sciences, Engineering, and Medicine and the National Science Foundation announced today the formation of a Societal Experts Action Network (SEAN) to connect social and behavioral science researchers with decision-makers who are leading the response to COVID-19. SEAN will respond to the most pressing social, behavioral, and economic questions that are being asked by federal, state, and local officials by working with appropriate experts to quickly provide actionable answers.

A new report from the National Academies of Sciences, Engineering, and Medicine says using laboratory dogs in research at the U.S. Department of Veterans Affairs (VA) is scientifically necessary for only a few areas of current biomedical research.

As intense drought and record heat make their way across the Western U.S., the deep and devastating impacts of this extreme weather are clear — electric utilities are asking consumers to ration power and water, farmers are scrambling to sell or save their produce, and officials are making plans to keep their communities safe and cool.

When communicating with parents about getting their children vaccinated against COVID-19, emphasize the safety and efficacy of the vaccines, encourage them to talk with their family doctor, and leverage parents’ social networks.

Nearly 100 students, faculty, and other experts recently gathered online for the first-ever Fall Forum of the Gulf Scholars Program, a pilot program of the National Academies’ Gulf Research Program aimed at preparing undergraduate students to address environmental, health, energy, and infrastructure challenges in the Gulf of Mexico region.

The widespread adoption of cellular connectivity will also contribute to a further reduction in prices for cellular-connected devices, making them more competitive against alternative non-cellular connectivity technologies like LoRa, Sigfox and Wi-SUN, Shah said.

Through five short use cases this powerful four-minute video shows BT innovating to use interactive video conferencing in managing operations and communicating externally and internally across Asia, Africa and the Middle East. Ruth Rowan and Kevin Taylor of BT Global Services describe how high definition video and Dolby quality sound is enabling enhanced and effective collaboration for BT teams serving customers across this geographically diverse 99-country region.

The real-time economy requires instant processes in an increasing number of business functions.

At BT Global Services connections are our business. We are trusted by thousands of enterprises around the world, combining our global strength in networks, IT and innovation with local presence, expertise and delivery. Watch this video to find out how we can help you connect for a better future.

There is never a "good" time to initiate a recall. But the worst time is when you are forced to remove unsafe food from commerce and haven’t effectively planned for it.

With remote monitoring solutions, technical help is never far away.

When it comes to equipment like ovens and proofers, internet connectivity, wider and larger machines, artisanal production methods, shorter bake times, reversible belts, energy efficiency and improved cleaning and sanitation are all top considerations in today’s market.

Bagels continue to tempt consumers, with better-for-you versions attracting attention and dollars.