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Ultrasound-assisted ionic liquid-mediated green method for synthesis of 1,3-diphenylpyrazole-based spirooxindolopyrrolizidines, their anti-tubercular activity, molecular docking study and ADME predictions

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00563E, Paper
Sravanthi Baddepuri, G. Rama Krishna, Jyothi Kumari, Sriram Dharmarajan, Srinivas Basavoju
The aim of the study is to develop the synthesis of a novel series of potent anti-tubercular (anti-TB) activity of 1,3-diphenylpyrazole-based spirooxindolopyrrolizidine derivatives via an efficient green approach achieved by...
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WhatsApp’s latest update: Undo feature empowers users with message deletion flexibility

This new functionality complements the existing “Delete for Everyone” option, allowing users to undo message deletions within a brief window of five seconds




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A window to the North East

Rohan K. Abraham, founder of India Trail, clears the picture about what the region holds for an avid traveller




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Financial aid and social mobility [electronic resource] : evidence from Colombia's Ser Pilo Paga / Juliana Londono-Velez, Catherine Rodriguez, Fabio Sanchez, Luis E. Alvarez-Arango

Cambridge, MA. : National Bureau of Economic Research, 2023




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How costs limit contraceptive use among low-income women in the U.S [electronic resource] .: a randomized control trial / Martha J. Bailey, Vanessa Wanner Lang, Alexa Prettyman, Iris Vrioni, Lea J. Bart, Daniel Eisenberg, Paula Fomby, Jennifer Barber, Van

Cambridge, MA. : National Bureau of Economic Research, 2023




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Hoax bomb threat to Air India's Delhi-Indore-Mumbai flight; FIR registered

‘The message about a pipe bomb being placed in the Air India flight was proved to be fake in our investigation,’ says official.




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Rani-Kajol's Beautiful Sindoor Khela

Kajol and Rani Mukerji looked beautiful in shades of red, as they indulged in the Bengali ritual of Sindoor Khela at the North Bombay Sarbojanin's Durga puja pandal in Mumbai.




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Enhancing Military Diplomacy in the Indo-Pacific: A US Foreign Area Officer’s Perspective

Enhancing Military Diplomacy in the Indo-Pacific: A US Foreign Area Officer’s Perspective Enhancing Military Diplomacy in the Indo-Pacific: A US Foreign Area Officer’s Perspective

jacksonl




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How Will the Prabowo Administration Shape Indonesia’s Foreign Policy as a Middle Power?

How Will the Prabowo Administration Shape Indonesia’s Foreign Policy as a Middle Power? How Will the Prabowo Administration Shape Indonesia’s Foreign Policy as a Middle Power?

jacksonl




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Indo-Pacific Lens on the Arctic: How US Partners in Asia View Arctic Security and Governance

Indo-Pacific Lens on the Arctic: How US Partners in Asia View Arctic Security and Governance Indo-Pacific Lens on the Arctic: How US Partners in Asia View Arctic Security and Governance

jacksonl




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Strategic Partners or Fickle Friends? Indonesia’s Perceptions of the US-Australia Defense and Security Relationship

Strategic Partners or Fickle Friends? Indonesia’s Perceptions of the US-Australia Defense and Security Relationship Strategic Partners or Fickle Friends? Indonesia’s Perceptions of the US-Australia Defense and Security Relationship

jacksonl




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A novel way of cleaning indoor and outdoor air

A ‘filterless’ purifier range promises to keep the surrounding space pollution-free




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Researchers observes what exactly happens at beginning of possible endosymbiosis




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How to Fix: Windows WASD Keys Reversed with Arrow Keys

This past weekend I had the opportunity to be what every father wants, if only for a moment: the “cool dad”. My wife was out of town and my youngest son wanted to play PUBG. I caved in, taught him the basic FPS key binds, and he was having a great time. While he was […]

The post How to Fix: Windows WASD Keys Reversed with Arrow Keys appeared first on David Walsh Blog.




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How to Retrieve WiFi Password on Windows

Remembering the WiFi password when on a guest network is never easy. Even worse is when it’s no longer posted and someone else is asking you for it. Luckily there’s a built in Windows command to recover the password of a given WiFi network. The Shell Code Open cmd and execute the following command: netsh […]

The post How to Retrieve WiFi Password on Windows appeared first on David Walsh Blog.




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PIX: Lewandowski 'tricks; Frankfurt defies Bayern

Roundup of the matches being held across major football leagues in Europe on Sunday




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A Telugu novel’s stupendous success revives hopes for book publishing

‘Amma diarylo konni pageelu’ by a techie is sold over one lakh copies, backed by social media posts




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A water mediated multicomponent reaction for the synthesis of novel spirooxindole derivatives and their antifungal activity

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00256C, Paper
Min Zhang, Liang Shi, Li Chen, Zhengyu Liu, Ting Zhao, Chunyin Zhu, Liuqing Yang
A total of 27 novel spirooxindoles were synthesized through a water mediated three-component reaction of isatin, 4-aminocoumarin, and 1,3-cyclodicarbonyl compounds. Several compounds showed excellent antifungal activity against Physalospora piricola.
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Dehydrative alkynylation of 3-hydroxyisoindolinones with terminal alkynes for the synthesis of 3-alkynylated 3,3-disubstituted isoindolinones

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00190G, Paper
Kai-Cheng Yang, Shi-Lu Zheng, Zhong Wen, Yu-Shan Zhang, Hai-Liang Ni, Long Chen
A HOTf or Fe(OTf)3-catalyzed dehydrative alkynylation of 3-hydroxyisoindolinones with terminal alkynes was developed, which represents a brand-new procedure for the synthesis of 3-alkynylated 3,3-disubstituted isoindolinones.
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Diastereoselective synthesis of functionalized spiroindolines via intramolecular ipso-iodocyclization/nucleophile addition cascade reactions of indole-tethered ynones

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00112E, Paper
Debojyoti Bag, Sanghapal D. Sawant
Herein, we describe a highly diastereoselective approach for synthesizing polyfunctionalized spiroindolines from indolyl-ynones involving an ipso-iodocyclization/nucleophile addition cascade.
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HFIP-mediated C-3-alkylation of indoles and synthesis of indolo[2,3-b]quinolines & related natural products

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00414K, Paper
Auqib Rashid, Waseem I. Lone, Preeti Dogra, Showkat Rashid, Bilal A. Bhat
An expeditious metal free C-3 alkylation of indoles and its NIS-mediated deviation to indolo[2,3-b]quinolines is reported. Applications of these strategies in accessing bioactive natural products have also been demonstrated.
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Iron-catalyzed selective construction of indole derivatives via oxidative C(sp3)–H functionalization of indolin-2-ones

Org. Biomol. Chem., 2024, 22,3073-3079
DOI: 10.1039/D4OB00133H, Paper
Wei Chen, Lang-Qi Wen, Xiao-Bing Lu, Hui Zhou
We have developed a clean and efficient iron-catalyzed C(sp3)–H functionalization of indolin-2-ones for the chemodivergent synthesis of value-added indole derivatives, including isatins, and symmetrical and non-symmetrical isoindigos.
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Cu(OTf)2/HFIP catalyzed regioselective cycloisomerization of indole-C3-functionalized alkynols to carbazoles

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00421C, Communication
Srinivasarao Yaragorla, Tabassum Khan, Sayonika Chakroborty
We report here a simple and atom economic cycloisomerization reaction of indole-tethered alkynols for constructing diverse carbazoles via 1,2-alkly migration using Cu(OTf)2/HFIP as the excellent promoter system.
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K2CO3-Mediated (3+3-1) Annulation of 1,3-Acetonedicarboxylates with 2-Fluoro-1-nitroarenes: Synthesis of Indoles

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00488D, Paper
Meng-Yang Chang, Chin-Huey Ho, Hsing-Yin Chen
The K2CO3-mediated one-pot reaction of 1,3-acetonedicarboxylates with 2 equiv. of substituted 2-fluoro-1-nitrobenzenes has been developed to synthesize various 2,3-dicarboxylate indoles via a tandem (3 + 3 − 1) annulation pathway....
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Indonesia bans sales of Google phones days after blocking Apple's iPhone 16

Indonesia said it has banned sales of smartphones made by Alphabet's Google due to rules requiring the use of locally manufactured components




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A window to the world

Danseuse Ranjana Gauhar says classical dance forms make children aware of their roots




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‘We are with you’: 22 East London housing estates stand in solidarity with Grenfell

A gesture of love and solidarity from estates and communities in East London to Grenfell and their local community.




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Solitary splendour in Maldives

For those who want to get away from it all, there’s always the Maldives




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Acer launches six new Windows 11 laptops in India

The new range also comes with Office 2021 pre-loaded on it



  • Computers & Laptops

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A field guide to tropical reef fishes of the Indo-Pacific / Gerald R. Allen ; illustrated by Roger Swainston & Jill Ruse.

Tokyo ; Rutland, Vermont ; Singapore : Tuttle Publishing, 2020.




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Critique du De mundo de Thomas White / Thomas Hobbes ; introduction, texte critique et notes par Jean Jacquot et Harold Whitmore Jones.

Paris : Librairie Philosophique J. Vrin, 1973.




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The international power couple: London and migrant entrepreneurs

In partnership with Museum of London: London has long been a magnet for talent and investment, attracting the brightest minds from every corner of the globe. It is now Europe’s largest and most vibrant tech hub – but what is it about this drizzly grey metropolis that contributes to the astonishing success of migrant start-ups? In partnership with the Museum of London as part of their City Now City Future season, we look to Sadiq Khan, thriving migrant entrepreneurs, and global tech pioneers to understand what London’s got that nowhere else has – uncovering why being an outsider could be the key to disruptive innovations.




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Autocomplete Interview - Noah Centineo & Lana Condor Answer the Web's Most Searched Questions

"To All the Boys: P.S. I Still Love You" stars Noah Centineo and Lana Condor take the WIRED Autocomplete Interview and answers the internet's most searched questions about themselves. Is Noah Centineo related to Mark Ruffalo? Does Lana Condor have a Snapchat? Is Noah Australian? Where is Lana RIGHT NOW?! Lana and Noah answer all these questions and much more! Noah Centineo and Lana Condor star in TO ALL THE BOYS: P.S. I STILL LOVE YOU. Streaming exclusively on Netflix February 12, 2020.




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Obsessed - How This Girl Takes Indoor Skydiving to the Next Level

Sydney Kennett is one of the world's best indoor skydivers. The 14-year-old champion moves with the grace of a ballerina inside wind tunnels that propel air in excess of 100 miles per hour. Sydney holds numerous top prizes at competitions around the world, and she's even a Guinness World Record holder.




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Review: Nintendo Switch OLED

A significantly improved kickstand, a bigger 7-inch screen, and lovely matte texture that feels like an eggshell are just some of the features of the new Nintendo Switch OLED. Not to mention the vibrant colors and wonderfully deep blacks from the OLED screen. Reviews editor Julian Chokkatu shows us which features on the Switch are worth the money.




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Tech Support - Lando Norris & Oscar Piastri Answer Formula 1 Questions From Twitter

Formula 1 drivers Lando Norris and Oscar Piastri of Team McLaren answer your questions about F1 racing from Twitter. What is the hardest track in F1? Why are drivers weighed before each race? How do drivers know it's time for a pit stop? Answers to these questions and many more await—it's Formula 1 Support.




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Protein corona potentiates recovery of nanoparticle-induced disrupted tight junctions in endothelial cells

Nanoscale Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D4NH00178H, Communication
Muhammad Daniyal Ghouri, Ayesha Tariq, Jabran Saleem, Abdul Muhaymin, Rong Cai, Chunying Chen
Nanoparticle interactions with biological systems are intricate processes influenced by various factors, among which the formation of a protein corona plays a pivotal role. This research investigates a novel aspect...
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Trump’s second term unlikely to upset the Indo-US pharma apple-cart, say industry voices

IP may become a point of contention, as new administration may seek greater reciprocity




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Adrian Mendonza joins Rediffusion

Adrian Mendonza has joined Rediffusion as a senior national creative resource. He will oversee creatives for the agency’s North India operations. He will be based in Delhi.




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‘Building a strong personal brand is about showcasing your authentic self with humbition,’ says Landor’s Lulu Raghavan

Formula for personal growth: Brand and design evangelist Lulu Raghavan says one has to be grounded and humble to nurture ambitions




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Aurobindo Pharma Ltd. - Disclosures under Reg. 31(1) and 31(2) of SEBI (SAST) Regulations, 2011




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Smc Credits Ltd. - Board Meeting Intimation for Intimation Under Regulation 29 Of SEBI (Listing Obligations And Disclosures Requirements) Regulations, 2015 And Closure Of Trading Window.




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A matter of design and coupling: high indoor charging efficiencies with organic solar modules directly coupled to a sodium ion battery

J. Mater. Chem. A, 2024, 12,30862-30871
DOI: 10.1039/D4TA04729J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Li-Chung Kin, Andreas Distler, Oleksandr Astakhov, Bakary Kone, Hans Kungl, André Karl, Tsvetelina Merdzhanova, Rüdiger-A. Eichel, Christoph J. Brabec, Uwe Rau
Generalized framework for the design of indoor power units for autonomous Internet of Things (IOT) devices results in record efficiency combination of organic PV and sodium ion battery.
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Cost-free Anti Spyware For Windows 10

Spyware may be a type of trojans that monitors your digital habits, like the websites you visit, pressed keys used for passwords, and even more. Unlike other sorts of viruses, spyware and adware is designed to be hard to find. This makes it easy for hackers of stealing sensitive info from you while using your […]




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Cost-free Anti Spyware and adware Windows 12 Review

Free Anti Spyware Glass windows 10 The best spyware detection application can be a lifesaver when it comes to keeping your computer secure. These totally free programs can quickly scan your system for spy ware and other dangers that may be slowing it down or causing unwanted behavior. Once the spyware and adware is detected, […]




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Not just a random digging programme

MGNREGS has created assets that have made farming viable. But funds cutback and rural vested interests can erode its impact. A BusinessLine analysis




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Watch The Cure Perform a Three-Hour Concert in London, Celebrating the Release of Their New Album

Last Friday, The Cure celebrated the release of their new album, Songs of a Lost World, with a three-hour set at the Troxy in London. The band kicked off the show by performing all eight tracks from the album, before then playing another 23 songs, mostly hits from their large catalog of music. Originally live […]




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It’s official: The five-second food window is a myth



  • Policy & Issues

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Progress and challenges in structural, in situ and operando characterization of single-atom catalysts by X-ray based synchrotron radiation techniques

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00967J, Review Article
Yuhang Liu, Xiaozhi Su, Jie Ding, Jing Zhou, Zhen Liu, Xiangjun Wei, Hong Bin Yang, Bin Liu
Single-atom catalysts (SACs) represent the ultimate size limit of nanoscale catalysts, combining the advantages of homogeneous and heterogeneous catalysts.
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Lessons from London

The impact of Brexit on the global realty market