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Multi-task Rhodium-Catalyzed Remote C(sp3)–H Functionalization Reactions of Acyclic Dienes to Yield Benzene-fused Heterocycles

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04927F, Paper
Yuta Sato, Momoko Nagafuchi, Masaharu Takatsuki, Tsuyoshi Matsuzaki, Takeyuki Suzuki, Makoto Sako, Mitsuhiro Arisawa
Remote C(sp3)–H bond functionalization reactions are environmentally benign methods for not only acyclic molecules but also cyclic molecules. However, previous reports' products have been limited to aliphatic five-membered ring structures....
The content of this RSS Feed (c) The Royal Society of Chemistry




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Maharashtra Assembly elections: Deadline to withdraw nomination ends, 3 Pune Congress rebels refuse to pull out




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Elon Musk was never a liberal hero. We just refused to see it




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California Sheriff Refuses to Arrest People Defying Stay-at-Home Order: “There cannot be a new normal”

The following article, California Sheriff Refuses to Arrest People Defying Stay-at-Home Order: “There cannot be a new normal”, was first published on 100PercentFedUp.com.

Riverside, California Sheriff Chad Bianco spoke to the Riverside Board of Supervisors on May 5th to say that he will not enforce the stay-at-home order in California. He tells people who are afraid of contracting the coronavirus that they should stay home if they want to. Bianco continues with the suggestion that any business owner […]

Continue reading: California Sheriff Refuses to Arrest People Defying Stay-at-Home Order: “There cannot be a new normal” ...




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Father heartbroken after son refused entry to province

Hossein Arefi had moved to New Brunswick in January and by the end of April had convinced his son to join the family in Moncton. But telling peace officers at the airport the wrong thing when he arrived upended those plans.



  • News/Canada/New Brunswick

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College student says inconsistent border enforcement makes no sense, leaves students confused

The first time Robyn Hedden tried to cross the Nova Scotia-New Brunswick border, she was turned away. The next day, she was waved through without much hassle.



  • News/Canada/New Brunswick

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How to diffuse intergenerational tensions

The millennials are accustomed to having things at the click of a mouse. Want to watch a movie? Access Netflix. Want to plan a holiday? Do so on Makemytrip. Want to shop? Buy almost anything under the sun, any time, on Amazon or Flipkart. Want beauty treatment? Call Urbanclap. Want a date? Simply swipe right!




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As promoters fail to infuse capital, recast loans of Rs 50,000 cr fail at CDR cell in FY12

Aggregate recast loans worth around Rs 50,000 crore (Rs 49,332 crore) failed at the corporate debt restructuring (CDR) cell in FY17, taking total failures since the inception of the cell in 2001 to Rs 1.37 lakh crore.




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'I want the real thing!' Justin Gaethje REFUSES to wear interim belt after UFC 249 win, calls for unification bout with Khabib

Justin Gaethje could be forgiven for being in celebratory mood after capturing the UFC interim lightweight title at UFC 249, but "The Highlight" insisted his work was far from done, and he wants to face Khabib Nurmagomedov next.
Read Full Article at RT.com





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"I thought I was going to die": Kashmera Shah, wife of Krushna Abhishek of The Kapil Sharma Show, slams Mumbai hospitals after Bigg Boss contestant Sambhavna Seth refused treatment - Janta Ka Reporter

  1. "I thought I was going to die": Kashmera Shah, wife of Krushna Abhishek of The Kapil Sharma Show, slams Mumbai hospitals after Bigg Boss contestant Sambhavna Seth refused treatment  Janta Ka Reporter
  2. Kashmera Shah says Krushna Abhishek is okay with her bold photoshoots: ‘One of the reasons he fell for...  Hindustan Times
  3. Bigg Boss contestant Kashmera Shah on casting couch: I faced it, but never went through with it  Bollywood Life
  4. View Full coverage on Google News




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First OECD PISA financial literacy test finds many young people confused by money matters

Around one in seven students in the 13 OECD countries and economies that took part in the first OECD PISA international assessment of financial literacy are unable to make even simple decisions about everyday spending, and only one in ten can solve complex financial tasks.




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Bengaluru hospitals refuse to admit auto-driver in need of brain surgery; DIPR steps in

Several government hospitals denied admission to Suresh, an auto-driver in Bengaluru, before a Twitter user highlighted his ordeal and prompted the DIPR to provide help.




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Confused about what to watch during lockdown? LetsOTT might be your destination [Exclusive]

During an exclusive conversation with International Business Times, India, founder of LetsOTT, Sunita Kumar shared her ideas about the co-existing nature of theatrical releases and OTT releases.




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Britain's biggest unions threaten to tell workers to refuse return unless workplaces are made safe

Leaders of unions such as Unite, Unison and the General have written an open letter to Boris Johnson demanding the government puts policies in place to make workplaces safe.




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Australian family in Coronavirus epicentre Wuhan in China refuse to come back home

Public servant Malcolm Scriber and his family, who live in Hobart, were on holiday visiting relatives in the coronavirus epicentre of Wuhan when the city was put under quarantine on January 23.




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Qantas workers launch legal action after they were refused sick leave in airline's stand-down period

The Transport Workers Union took the airline to the Federal Court on behalf of workers on sick leave who can no longer access the entitlement after Qantas stood down two thirds of its workforce.




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Britain's biggest unions threaten to tell workers to refuse return unless workplaces are made safe

Leaders of unions such as Unite, Unison and the General have written an open letter to Boris Johnson demanding the government puts policies in place to make workplaces safe.




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Banned Akmal refuses to divulge details of two meetings with suspected bookies: PCB sources

Pakistan batsman Umar Akmal has refused to divulge details of his two meetings with suspected bookies before the Disciplinary Panel which handed him a three-year ban after a hearing, according to Board sources. According to the source, Akmal had a meeting with two unidentified men in Defence Housing Society in Lahore. "Umar claims both these gentlemen met him at parties thrown by friends in DHA. But he has refused to even tell the Anti-Corruption officials what was discussed at these meetings," a reliable source in the Pakistan Cricket Board told PTI. "Even when the Anti-Corruption officials first presented their report to him on the night between 19th and 20th February in Karachi, Akmal admitted he committed a mistake by not reporting the meetings to them but refrained from giving any details, the source said. Akmal was found guilty of two charges under the PCB Anti-Corruption Code and on April 27, he was banned from cricket activities till February 19, 2023. The 29-year-old has 14 ..




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Girls get the power to refuse child marriage


In West Bengal, girls are being empowered to refuse early marriage thanks to a state government initiative that enables them to stay longer in school. The Kanyashree Prakalpa scheme has been remarkably successful in curbing child marriage and promoting girl child education, says Saadia Azim.




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Akmal refuses to divulge details of two meetings with suspected bookies

Umar Akmal, who was found guilty of two charges under the PCB Anti-Corruption Code has refused to divulge details of his two meetings with suspected bookies. According to the source, Akmal had a meeting with two unidentified men in Defence Housing Society in Lahore. The PCB source said Akmal also gave conflicting statements before the Disciplinary Panel hearing on April 27.




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Kerala HC refuses to interfere with plea for state to impose 14-day institutional quarantine for foreign returnees




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Kerala HC refuses to interfere with plea for state to impose 14-day institutional quarantine for foreign returnees




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When families refuse to lit pyre of Covid-19 patients in Punjab




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Punjab COVID-19 patient's family refuse to claim his body, district officials perform last rites




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Banned Umar Akmal refuses to divulge details of two meetings with suspected bookies: PCB sources




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Diffuse scattering and partial disorder in complex structures

This review discusses the state of the field of single-crystal diffuse scattering (SCDS), including detectors, data collection and the modelling techniques. High quality, three-dimensional volumes of SCDS data can now be collected at synchrotron light sources, allowing increasingly detailed and quantitative analyses to be undertaken.




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Ultrafast calculation of diffuse scattering from atomistic models

Diffuse scattering is a rich source of information about disorder in crystalline materials, which can be modelled using atomistic techniques such as Monte Carlo and molecular dynamics simulations. Modern X-ray and neutron scattering instruments can rapidly measure large volumes of diffuse-scattering data. Unfortunately, current algorithms for atomistic diffuse-scattering calculations are too slow to model large data sets completely, because the fast Fourier transform (FFT) algorithm has long been considered unsuitable for such calculations [Butler & Welberry (1992). J. Appl. Cryst. 25, 391–399]. Here, a new approach is presented for ultrafast calculation of atomistic diffuse-scattering patterns. It is shown that the FFT can actually be used to perform such calculations rapidly, and that a fast method based on sampling theory can be used to reduce high-frequency noise in the calculations. These algorithms are benchmarked using realistic examples of compositional, magnetic and displacive disorder. They accelerate the calculations by a factor of at least 102, making refinement of atomistic models to large diffuse-scattering volumes practical.




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Confused on Finder display of external drives after attempted encryption & parti




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Chromebook charger blew fuse twice




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Waste potential: more of our refuse electronics, furniture and leisure goods could be re-used, suggests German study

Between 13% and 16% of waste electric and electronic equipment (WEEE), furniture and leisure goods disposed of at household waste collection centres are in excellent working condition and could be easily be prepared for re-use, finds a new study from Bavaria, Germany. Improvements to waste collection, storage and treatment practices to prevent damage to disposed items could free up a further 13%-29% of these waste streams for re-use. Notably, weatherproof storage for WEEE at collection points could have prevented up to 86% of the damage endured by the studied items.




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This cannabis-infused vodka tastes more like gin (and it won't get you high)

The 2014 farm bill removed some of the barriers to growing hemp. Humboldt Distillery ran with it.




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Wine-infused coffee blurs the wine o'clock rule

This new drink makes all your coffee and wine meme dreams come true.




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Cooking with Herbs: Infuse a Four-Course Meal with Flavor

Basil, parsley, cilantro, thyme and mint bring fresh flavors from the garden into a four-course meal, from appetizer to dessert.



  • Organic Farming & Gardening

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Frozun Spirits Infusion 
Launches Alcohol Infused Frozen Cocktails & Desserts

A one-of-a-kind product that delights consumers




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Tired of Those Complicated "Smart" Home Gadgets? Try this User-Friendly Aroma Diffuser

VASO has smart sensors to ensure unique add-water-to-start function. The built-in natural sounds are kind of "white noise", which helps to improve sleeping & creativity. All the functions are designed for easily use, rather than "smart" concept.




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Halifax Consumsers Sit Down with Chris Rafuse, Owner of Bath Fitter and 9 Year Winner of Consumer Choice Award

Bath Fitter is a company specializing in one day bath remodelling and lone-piece acrylic wall surrounds, servicing the Nova Scotia region. As the owner, Chris is responsible for ensuring every Bath Fitter customer smiles when they see their bathroom.




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Prüvit's KETO//OS® PRO™: a Ketone Infused Protein for a Ketogenic Lifestyle

Muscle Preservation and Promotion Made Simple




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Many Online Retailers Refuse to Allow Bulletproof Products for Children Going Back to School

Retailers restrict the ability of consumers to purchase armored products to protect themselves and those that they love. Many retailers believe that consumers do not want or need ballistic protection and therefore do not offer armored products.




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The NYS Supreme Court Officers Association Chooses Fuse Systems

Fuse Systems, a leading software provider, and systems solutions company, is pleased to announce that the New York State Supreme Court Officers Association has chosen Fuse Systems as their Systems Provider.




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Fight COVID-19 (Corona) Virus with Potent Antibacterial Cannabinoid Infused Hand Sanitizer Available Now from Global Cannabinoids

Cannabinoids have potent antibacterial properties and studies have shown that cannabidiol (CBD) and cannabigerol (CBG) have potent effects against antibiotic resistant bacteria which makes it an ideal ingredient to add in the fight against COVID-19




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5 ways to improve CX with AI-infused knowledge management

By making the most relevant information shareable and reusable across the organization, AI-infused KM tools can bring an organization closer to the holy grail of frictionless service




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RBI to infuse Rs 3.74 lakh cr liquidity into financial system

RBI to infuse Rs 3.74 lakh cr liquidity into financial system





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Why Sweden refused to impose a lockdown

My country's rules are based on trust — both on the part of citizens and officials. But I know this doesn't work for every society.




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What happens if my visa is refused or cancelled due to my character?

If you have your visa refused or cancelled, you need to get expert advice a soon as possible. Strict time limits apply to drafting submissions and appeals. A visa refusal or cancellation can limit the type or visas you can apply for in the future or even prohibit you from applying for any visa to […]

The post What happens if my visa is refused or cancelled due to my character? appeared first on Visa Australia - Immigration Lawyers & Registered Migration Agents.




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Dain Yoon’s Make-up Art Will Confuse You

If you follow Dain Yoon’s Instagram, you get the pleasant surprise to regularly get totally surreal photos of her. The 22 years old artist, based in Seoul, Korea, likes to disrupt reality by using herself as a model for stunning make-up art. You can discover more of her work on her website.




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Fused heterocyclic derivative, medicinal composition containing the same, and medicinal use thereof

The present invention provides a compound useful as an agent for the prevention or treatment of a sex hormone-dependent disease or the like. That is, the present invention provides a fused heterocyclic derivative represented by the following general formula (I), a pharmaceutical composition containing the same, a medicinal use thereof and the like. In the formula (I), ring A represents 5-membered cyclic unsaturated hydrocarbon or 5-membered heteroaryl; RA represents halogen, alkyl, alkenyl, alkynyl, carboxy, alkoxy, carbamoyl, alkylcarbamoyl or the like ; ring B represents aryl or heteroaryl; RB represents halogen, alkyl, carboxy, alkoxy, carbamoyl, alkylcarbamoyl or the like; E1 and E2 represent an oxygen atom or the like; U represents a single bond or alkylene; X represents a group represented by Y, —SO2—Y, —O—(alkylene)—Y, —O—Z in which Y represents Z, amino or the like; Z represents cycloalkyl, heterocycloalkyl, aryl, heteroaryl or the like; or the like.




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Subsurface system for the collection of refuse

The present invention relates to a subsurface refuse collection system comprising an underground bunker (4), a refuse container (3), a deposit bin (1) and a cover (2) with automatic opening and closing which can be powered electrically using a solar system. The container (3) is collected by means of an automated crane (18) with automatic hitching to facilitate collection. The system is equipped with multiple devices to measure volume and weight of the refuse deposited in the deposit bin (1), for the purpose of system monitoring or improvements to the management of truck routes. It also includes a safety device to prevent accidental fails into the underground bunker during collection.




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Photochromic materials that include indeno-fused naphthopyrans

The present invention relates to photochromic materials that include one or more indeno-fused naphthopyrans that have particular groups at the 7, 11, and 13 positions thereof, and at the position alpha to the oxygen of the pyran ring thereof. With some embodiments, hydrogen or an alkoxy group is bonded to the 7 position, an optionally substituted phenyl is bonded to the 11 position, two alkyl groups are bonded to the 13 position, and two optionally substituted phenyl groups are bonded to the position alpha to the oxygen of the pyran ring of the indeno-fused naphthopyran compound. The 13 position of the indeno-fused naphthopyrans is free of ether groups in which an ether oxygen is bonded to the 13 position, and hydroxyl. The present invention also relates to photochromic articles and compositions that include such indeno-fused naphthopyrans.




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Substituted fused pyrimidinones and dihydropyrimidinones

The use of substituted fused pyrimidinones and dihydropyrimidinones of the formula (I) or salts thereof where the radicals of the formula (I) are each as defined in the description, for enhancing stress tolerance in plants to abiotic stress, and for invigorating plant growth and/or for increasing plant yield.