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INDIPENDENTISMO E LIBERTÀ D’ESPRESSIONE. Spagna: una questione di giustizia irrisolta e multiforme

AFFARI INTERNAZIONALI
3 Maggio 2018
 
ELENA MARISOL BRANDOLINI
 
Da alcuni mesi, in Spagna la giustizia occupa la scena mediatica. È successo con la vicenda catalana, in cui il ricorso ai tribunali e alla legalità ha sostituito la politica fin dal principio. Poi si è compreso che si trattava solo della punta dell’iceberg e quello che c’era sotto è venuto a galla un po’ alla volta. Si è visto allora che la giustizia spagnola presenta vari problemi.

Sul piano della legislazione, come dimostra il recente caso della sentenza nei confronti degli uomini della ‘Manada’, autori di violenza sessuale, ma puniti per il reato di abuso, differenza prevista nel codice penale. O nella legislazione anti-terrorista, che ha così tanto ampliato il campo di applicazione per cui ora “tutto è Eta”: una rissa da bar che coinvolge due poliziotti della Guardia Civil, la canzone di un rapper, l’interruzione del transito su un’autostrada. Sul terreno dell’ordinamento, con istituti come l’Audiencia Nacional erede del tribunale franchista e quindi inesistente altrove. Su quello infine della debole separazione fra i poteri dello Stato, con una tendenza alla ‘giudiziarizzazione’ della politica e con il rischio di farne il mezzo di competizione tra i partiti della destra spagnola.

A farne le spese è la libertà d’espressione

A farne le spese è la libertà di espressione che la sezione spagnola di Amnesty International segnala essersi ridotta. Perciò la censura si allarga, rasentando il ridicolo nel sequestro di fischietti e magliette di colore giallo nella finale di calcio della Copa del Rey. A farne le spese sono le persone che rischiano il carcere, stanno per finirci o ci sono da tempo, imputate di delitti che non hanno commesso.

E’ il caso di rappers, utenti delle reti sociali, comici, militanti di movimenti. E’ il caso dei nove prigionieri politici catalani in regime di carcerazione preventiva: Oriol Junqueras, Dolors Bassa, Carme Forcadell, Quim Forn, Raül Romeva, Josep Rull, Jordi Turull,  e i Jordis, Jordi Sánchez e Jordi Cuixart, leader del movimento indipendentista, in cella da oltre sei mesi per avere convocato una manifestazione sotto il dipartimento di Economia.

Contro l’indipendentismo, il giudice istruttore Llarena del Tribunal Supremo ha costruito un vero e proprio teorema accusatorio, teso a dimostrare l’uso della violenza nei fatti occorsi nell’autunno 2017, per cui 13 dei 25 imputati nella macro-causa lo sono per ribellione, delitto punito con 25-30 di carcere. La violenza, pur se non esercitata direttamente dagli accusati, sarebbe quella da questi indotta nel comportamento della polizia spagnola il giorno del referendum per farne rispettare il divieto, o quella che si sarebbe potuta determinare per la presenza intimidatoria di un grande assembramento di persone il 20 settembre. Un’imputazione per un delitto inesistente, a detta di diversi giuristi stranieri e di alcuni spagnoli; contestata da Amnesty International che critica il regime di carcerazione preventivo in cui si trovano i Jordis. Per la semplice ragione che è mancante del suo presupposto, la violenza appunto, poiché il movimento indipendentista catalano è sempre stato pacifico e di massa.

La processione dei capi d’accusa

Tanto che la giustizia spagnola starebbe meditando un’eventuale riconsiderazione di questa imputazione attribuita ad alcuni degli esiliati, fino a sostituirla con l’accusa di sedizione, che prevede pene inferiori. Questo, in attesa di riuscire a dimostrare il delitto di malversazione di fondi pubblici, di cui sono accusati tutti i componenti dell’ex-governo per il referendum. Considerando che la Generalitat aveva il bilancio controllato dal governo spagnolo fin dal 2015 e commissariato negli ultimi giorni del settembre scorso. Contraddizione che ha aperto un inedito conflitto tra il ministro del Tesoro Montoro, che deve mostrarsi commissario efficiente, e il giudice Llarena, che teme di vedere compromesso l’altro aspetto del suo impianto processuale.

Per entrambi i delitti la giustizia spagnola ha infatti chiesto l’estradizione degli imputati esiliati: di Carles Puigdemont, prima a Bruxelles e ora in libertà condizionata in Germania, di Clara Ponsatí in libertà condizionata nel Regno Unito, di Toni Comín in libertà condizionata a Bruxelles e di Marta Rovira rifugiatasi in Svizzera, imputati di ribellione; di Lluís Puig e Meritxell Serret a Bruxelles accusati di malversazione; mentre per Anna Gabriel non c’è richiesta di estradizione dalla Svizzera, perché imputata di disobbedienza.

Il movimento indipendentista si è sempre appellato a una mediazione europea senza successo, perché la Commissione ha continuato a sostenere che si tratta di una questione interna allo Stato spagnolo. La strategia di Puigdemont è stata quella d’internazionalizzare il conflitto, per evidenziare il carattere politico della persecuzione giudiziaria. Il suo arresto in Germania e quello successivo di altri cinque dirigenti dell’indipendentismo hanno suscitato più di una perplessità nelle opinioni pubbliche europee e sui media internazionali. Il tribunale tedesco non ha riconosciuto gli estremi di violenza per l’estradizione di Puigdemont; la giustizia britannica si è presa del tempo per esaminare le carte relative all’imputata Ponsatí; in Belgio, la giustizia sta istruendo la richiesta relativa agli altri imputati; la Svizzera ha già detto che non concederà estradizioni per ragioni politiche. E il Comitato dei Diritti Umani dell’Onu, sollecitato da Jordi Sánchez perché era stato impedito a presentarsi come candidato a president della Generalitat, raccomanda che ne siano garantiti i diritti politici. Una vicenda tutta spagnola su cui peserà il giudizio di almeno altri quattro paesi europei.
 
 





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Magnasphere MACS Fence Detection System & MSK Radar Completes Safe Skies Evaluation

National Safe Skies Alliance performs its evaluations under an ISO 9001:2015-approved Quality Management System.




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The 18th Annual Top Systems Integrators Report: Neither Stellar Nor Stagnant

A 9 percent decrease in the 2012 revenue for SDM’s Top Systems Integrators is a deceiving number because individual company results did not recede to that extent.  




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LifeSafety Power’s LED Light Kit Includes Magnetic LED Strips

LifeSafety Power’s ProWire now includes magnetic, LED light strips for the E6, E8 and E12 products — a component that brings instant illumination to enclosures to assist with installing, managing and servicing power solutions.




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ASSA ABLOY’s Shielded Openings Absorb Radio & Magnetic Waves

Electromagnetic and radio frequency interference (EMI-RFI) can disrupt the performance of sensitive communications systems and devices, potentially compromising confidential data.




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Magnet ring carabiner kit

The Magnet Ring/Carabiner Kit includes two magnet rings and two carabiners.




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Innophos: Effective Magnesium

Innophos, a leading producer of minerals for the nutrition industry, released a new whitepaper highlighting the results of an in-vitro study that demonstrates the superior absorption of Chelamax® Magnesium Bisglycinate and Magnesium Citrate. These findings underscore the benefits of chelated magnesium in developing highly absorbable magnesium supplements. 




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Cymbiotika Magnesium L-Threonate

Cymbiotika launched its newest product, Magnesium L-Threonate. The company developed the product to combat magnesium deficiency in adults. Magnesium is an electrolyte and is required for more than 300 processes within the human body.




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How Nuclear Magnetic Resonance Can Combat Honey Fraud

The high value of honey and perceived cachet surrounding its provenance makes it a vulnerable target, whether through fraudsters claiming false geographical origin, declaring false botanical variety or diluting it with cheaper sugar syrups.




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Diagnosing communities’ childcare friendliness: case studies of two South Korean cities.

Children's Geographies; 09/03/2024
(AN 179347240); ISSN: 14733285
Academic Search Premier




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Exploring Parents’ Experiences and Needs During Disclosure of a Cerebral Palsy Diagnosis of Their Young Child: A Scoping Review

ABSTRACT Background Parents often perceive the news that their child has cerebral palsy (CP) as overwhelming and shocking. They are at increased risk of parental stress and mental health problems, which in turn can affect the interaction between the parent and the child. Parental mental health outcomes are known to be affected by the process […]

The post Exploring Parents’ Experiences and Needs During Disclosure of a Cerebral Palsy Diagnosis of Their Young Child: A Scoping Review was curated by information for practice.



  • Meta-analyses - Systematic Reviews


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6.8 magnitude earthquake hits Cuba: 'Crisis without parallel in our nation'

Two strong earthquakes measuring 5.9 and 6.8 on the Richter scale surprised the Cuban population on Sunday.




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The Magnificent Ruins by Roy, Nayantara

In this "rare feast" of a novel, a young Indian American book editor inherits her estranged family’s ancestral home–and their long-buried secrets (Rachel Lyon, author of  Self-Portrait With Boy ). It is the summer of 2015, and Lila De is on the verge of a breakthrough in her career at a prestigious New York publishing house. But when she gets a call from her mother in India, informing her that she’s inherited her family’s sprawling estate, she must confront the legacy of an extended family that




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Nails Diagnose Illnesses

Nails reflect changes in internal organs Illnesses can be diagnosed with the help of people's nails. Yury Zakharov, doctor of medical sciences, director of the Moscow phytotherapy center says, nail diagnostics is practiced in the traditional Chinese medicine, although it is an applied practice used in a combination with other methods. "For example, if a patient has a square nail, we examine their iris, trying to diagnose an oncological illness. As a rule, the iris examination proves it. The main advantage of such an approach is the opportunity to identify many symptoms at early stages, two or three years before a disease develops. Needless to mention that it is extremely important to people." A certain disease is accompanied with certain changes in the structure of human nails. The traditional medicine does not have the exact answer to this question, there has not been a specific research made on the issue yet. The only explanation can be found in the traditional Chinese medicine. Chinese doctors think that every energetic channel that comes out from fingers is linked with this or that organ. Therefore, any changes in an organ are transmitted to nails. For example, a large bulging nail testifies to a lung disease. If the light semicircle at the bottom of the nail is crescent-shaped, this means that an individual suffers from congenital tuberculosis. Thin and shiny nails — as if they are covered with clear nail polish — testify to the severe liver disease — hepatitis. Chinese doctors have a very extensive experience, they have been studying the internal diseases symptoms and their indications for centuries. At present, there are about 30 methods to decode the nail pathology.




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Wife of former San Antonio trucking magnate sentenced in multi-million-dollar fraud scheme

Frances Hall, former co-owner of Bill Hall Jr. Trucking, has been sentenced for her role in a scheme to avoid $9 million in workers’ compensation premiums.




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Former PMC Wagner commander joins Chechen fighters at Akhmat unit

As many as 3,000 Wagner fighters joined the Akhmat special forces of the 2nd Army Corps of the Russian Armed Forces. Their commander Ratibor gathers people who will carry out the "tasks of the state.” The head of Chechnya, Ramzan Kadyrov, reported on Telegram that one of the commanders of the Wagner Group with call sign Ratibor would join the Akhmat special forces and bring in 3,000 fighters along with him too. The agreement was reached as a result of negotiations between the deputy commander of the 2nd Army Corps of the Russian Armed Forces, Apta Alaudinov, and Wagner commander, Alexander Kuznetsov (Ratibor). The Russian Defence Ministry approved the initiative. Kadyrov spoke of Ratibor as "an old comrade with whom he had fought side by side before.”




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KRISS Partners with Domestic University Hospitals to Develop Disease Diagnosis and Treatment Technology, Alleviating Patient Burden

The Korea Research Institute of Standards and Science (KRISS) announced that they have developed an advanced disease diagnosis and treatment system based on nanomaterials.




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KRISS Partners with Domestic University Hospitals to Develop Disease Diagnosis and Treatment Technology, Alleviating Patient Burden

The Korea Research Institute of Standards and Science (KRISS) announced that they have developed an advanced disease diagnosis and treatment system based on nanomaterials.




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Quarantine Agency Develops Differential Diagnosis Technology for Lumpy Skin Disease

[Science] :
The Animal and Plant Quarantine Agency says it has developed, for the first time in the world, a differential diagnosis technology for lumpy skin disease(LSD), a viral disease that affects cattle. With the technology, jointly developed with Median Diagnostics, it can be determined within eight hours if a ...

[more...]







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Spin reorientation and the interplay of magnetic sublattices in Er2CuMnMn4O12

We show that the interplay of multiple magnetic sublattices in Er2CuMnMn4O12 leads to four magnetic phase transitions characterized by the onset of ferrimagnetic order, spin-reorientation, spin canting, and the polarization of Er ions. While we elucidate numerous features of this complex magnetic system, the exact nature of the low-temperature coupling between erbium and manganese, and the origin of a k = (0, 0, ½) modulation, remain intriguing topics for future studies.




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Crystal structure and compressibility of magnesium chloride heptahydrate found under high pressure

In-situ diffraction measurements reveal that magnesium chloride forms a unique high-pressure phase, a heptahydrate, above 2 GPa. The hydrogen-bonding structure appears to contain orientational disorder.




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Symmetry, magnetic transitions and multiferroic properties of B-site-ordered A2MnB'O6 perovskites (B' = [Co, Ni])

A comparative description is presented of the symmetry and the magnetic structures found in the family of double perovskites A2MnB'O6 (mainly B' = Co and some Ni compounds for comparative purposes).




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Review of honeycomb-based Kitaev materials with zigzag magnetic ordering




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Crystal structure and compressibility of magnesium chloride heptahydrate found under high pressure

The odd hydration number has so far been missing in the water-rich magnesium chloride hydrate series (MgCl2·nH2O). In this study, magnesium chloride heptahydrate, MgCl2·7H2O (or MgCl2·7D2O), which forms at high pressures above 2 GPa and high temperatures above 300 K, has been identified. Its structure has been determined by a combination of in-situ single-crystal X-ray diffraction at 2.5 GPa and 298 K and powder neutron diffraction at 3.1 GPa and 300 K. The single-crystal specimen was grown by mixing alcohols to prevent nucleation of undesired crystalline phases. The results show orientational disorder of water molecules, which was also examined using density functional theory calculations. The disorder involves the reconnection of hydrogen bonds, which differs from those in water ice phases and known disordered salt hydrates. Shrinkage by compression occurs mainly in one direction. In the plane perpendicular to this most compressible direction, oxygen and chlorine atoms are in a hexagonal-like arrangement.




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Spin reorientation and the interplay of magnetic sublattices in Er2CuMnMn4O12

Through a combination of magnetic susceptibility, specific heat, and neutron powder diffraction measurements we have revealed a sequence of four magnetic phase transitions in the columnar quadruple perovskite Er2CuMnMn4O12. A key feature of the quadruple perovskite structural framework is the complex interplay of multiple magnetic sublattices via frustrated exchange topologies and competing magnetic anisotropies. It is shown that in Er2CuMnMn4O12, this phenomenology gives rise to multiple spin-reorientation transitions driven by the competition of easy-axis single ion anisotropy and the Dzyaloshinskii–Moriya interaction; both within the manganese B-site sublattice. At low temperature, one Er sublattice orders due to a finite f-d exchange field aligned parallel to its Ising axis, while the other Er sublattice remains non-magnetic until a final, symmetry-breaking phase transition into the ground state. This non-trivial low-temperature interplay of transition metal and rare-earth sublattices, as well as an observed k = (0, 0, ½) periodicity in both manganese spin canting and Er ordering, raises future challenges to develop a complete understanding of the R2CuMnMn4O12 family.




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A differentiable simulation package for performing inference of synchrotron-radiation-based diagnostics

The direction of particle accelerator development is ever-increasing beam quality, currents and repetition rates. This poses a challenge to traditional diagnostics that directly intercept the beam due to the mutual destruction of both the beam and the diagnostic. An alternative approach is to infer beam parameters non-invasively from the synchrotron radiation emitted in bending magnets. However, inferring the beam distribution from a measured radiation pattern is a complex and computationally expensive task. To address this challenge we present SYRIPY (SYnchrotron Radiation In PYthon), a software package intended as a tool for performing inference of synchrotron-radiation-based diagnostics. SYRIPY has been developed using PyTorch, which makes it both differentiable and able to leverage the high performance of GPUs, two vital characteristics for performing statistical inference. The package consists of three modules: a particle tracker, Lienard–Wiechert solver and Fourier optics propagator, allowing start-to-end simulation of synchrotron radiation detection to be carried out. SYRIPY has been benchmarked against SRW, the prevalent numerical package in the field, showing good agreement and up to a 50× speed improvement. Finally, we have demonstrated how SYRIPY can be used to perform Bayesian inference of beam parameters using stochastic variational inference.




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Novel correction procedure for compensating thermal contraction errors in the measurement of the magnetic field of superconducting undulator coils in a liquid helium cryostat

Superconducting undulators (SCUs) can offer a much higher on-axis undulator field than state-of-the-art cryogenic permanent-magnet undulators with the same period and vacuum gap. The development of shorter-period and high-field SCUs would allow the free-electron laser and synchrotron radiation source community to reduce both the length of undulators and the dimensions of the accelerator. Magnetic measurements are essential for characterizing the magnetic field quality of undulators for operation in a modern light source. Hall probe scanning is so far the most mature technique for local field characterization of undulators. This article focuses on the systematic error caused by thermal contraction that influences Hall probe measurements carried out in a liquid helium cryostat. A novel procedure, based on the redundant measurement of the magnetic field using multiple Hall probes at known relative distance, is introduced for the correction of such systematic error.




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Determination of optimal experimental conditions for accurate 3D reconstruction of the magnetization vector via XMCD-PEEM

This work presents a detailed analysis of the performance of X-ray magnetic circular dichroism photoemission electron microscopy (XMCD-PEEM) as a tool for vector reconstruction of magnetization. For this, 360° domain wall ring structures which form in a synthetic antiferromagnet are chosen as the model to conduct the quantitative analysis. An assessment is made of how the quality of the results is affected depending on the number of projections that are involved in the reconstruction process, as well as their angular distribution. For this a self-consistent error metric is developed which allows an estimation of the optimum azimuthal rotation angular range and number of projections. This work thus proposes XMCD-PEEM as a powerful tool for vector imaging of complex 3D magnetic structures.




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Measuring magnetic hysteresis curves with polarized soft X-ray resonant reflectivity

Calculations and measurements of polarization-dependent soft X-ray scattering intensity are presented during a magnetic hysteresis cycle. It is confirmed that the dependence of the intensity on the magnetic moment can be linear, quadratic or a combination of both, depending on the polarization of the incident X-ray beam and the direction of the magnetic moment. With a linearly polarized beam, the scattered intensity will have a purely quadratic dependence on the magnetic moment when the magnetic moment is parallel to the scattering plane. However, with the magnetic moment perpendicular to the scattering plane, there is also a linear component. This means that, when measuring the hysteresis with linear polarization during a hysteresis cycle, the intensity will be an even function of the applied field when the change in the magnetic moment (and field) is confined within the scattering plane but becomes more complicated when the magnetic moment is out of the scattering plane. Furthermore, with circular polarization, the dependence of the scattered intensity on the moment is a combination of linear and quadratic. With the moment parallel to the scattering plane, the linear component changes with the helicity of the incident beam. Surprisingly, in stark contrast to absorption studies, even when the magnetic moment is perpendicular to the scattering plane there is still a dependence on the moment with a linear component. This linear component is completely independent of the helicity of the beam, meaning that the hysteresis loops will not be inverted with helicity.




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X-ray beam diagnostics at the MID instrument of the European X-ray Free-Electron Laser Facility

The Materials Imaging and Dynamics (MID) instrument at the European X-ray Free-Electron Laser Facility (EuXFEL) is equipped with a multipurpose diagnostic end-station (DES) at the end of the instrument. The imager unit in DES is a key tool for aligning the beam to a standard trajectory and for adjusting optical elements such as focusing lenses or the split-and-delay line. Furthermore, the DES features a bent-diamond-crystal spectrometer to disperse the spectrum of the direct beam to a line detector. This enables pulse-resolved characterization of the EuXFEL spectrum to provide X-ray energy calibration, and the spectrometer is particularly useful in commissioning special modes of the accelerator. Together with diamond-based intensity monitors, the imager and spectrometer form the DES unit which also contains a heavy-duty beamstop at the end of the MID instrument. Here, we describe the setup in detail and provide exemplary beam diagnostic results.




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Scattered high-energy synchrotron radiation at the KARA visible-light diagnostic beamline

To characterize an electron beam, visible synchrotron light is often used and dedicated beamlines at synchrotron sources are becoming a more common feature as instruments and methods for the diagnostics are, along with the accelerators, further developed. At KARA (Karlsruhe Research Accelerator), such a beamline exists and is based on a typical infrared/visible-light configuration. From experience at such beamlines no significant radiation was expected (dose rates larger than 0.5 µSv h−1). This was found not to be the case and a higher dose was measured which fortunately could be shielded to an acceptable level with 0.3 mm of aluminium foil or 2.0 mm of Pyrex glass. The presence of this radiation led to further investigation by both experiment and calculation. A custom setup using a silicon drift detector for energy-dispersive spectroscopy (Ketek GmbH) and attenuation experiments showed the radiation to be predominantly copper K-shell fluorescence and is confirmed by calculation. The measurement of secondary radiation from scattering of synchrotron and other radiation, and its calculation, is important for radiation protection, and, although a lot of experience exists and methods for radiation protection are well established, changes in machine, beamlines and experiments mean a constant appraisal is needed.




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3D imaging of magnetic domains in Nd2Fe14B using scanning hard X-ray nanotomography

Nanoscale structural and electronic heterogeneities are prevalent in condensed matter physics. Investigating these heterogeneities in 3D has become an important task for understanding material properties. To provide a tool to unravel the connection between nanoscale heterogeneity and macroscopic emergent properties in magnetic materials, scanning transmission X-ray microscopy (STXM) is combined with X-ray magnetic circular dichroism. A vector tomography algorithm has been developed to reconstruct the full 3D magnetic vector field without any prior noise assumptions or knowledge about the sample. Two tomographic scans around the vertical axis are acquired on single-crystalline Nd2Fe14B pillars tilted at two different angles, with 2D STXM projections recorded using a focused 120 nm X-ray beam with left and right circular polarization. Image alignment and iterative registration have been implemented based on the 2D STXM projections for the two tilts. Dichroic projections obtained from difference images are used for the tomographic reconstruction to obtain the 3D magnetization distribution at the nanoscale.




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Crystal structure and cryomagnetic study of a mononuclear erbium(III) ox­am­ate inclusion com­plex

The synthesis, crystal structure and magnetic properties of an ox­am­ate-con­taining erbium(III) com­plex, namely, tetra­butyl­ammonium aqua­[N-(2,4,6-tri­methyl­phen­yl)oxamato]erbium(III)–di­methyl sulfoxide–water (1/3/1.5), (C16H36N)[Er(C11H12NO3)4(H2O)]·3C2H6OS·1.5H2O or n-Bu4N[Er(Htmpa)4(H2O)]·3DMSO·1.5H2O (1), are reported. The crystal structure of 1 reveals the occurrence of an erbium(III) ion, which is surrounded by four N-phenyl-substituted ox­am­ate ligands and one water mol­ecule in a nine-coordinated environment, together with one tetra­butyl­ammonium cation acting as a counter-ion, and one water and three dimethyl sulfoxide (DMSO) mol­ecules of crystallization. Variable-temperature static (dc) and dynamic (ac) magnetic mea­sure­ments were carried out for this mononuclear com­plex, revealing that it behaves as a field-induced single-ion magnet (SIM) below 5.0 K.




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Orientational ordering and assembly of silica–nickel Janus particles in a magnetic field

The orientation ordering and assembly behavior of silica–nickel Janus particles in a static external magnetic field were probed by ultra small-angle X-ray scattering (USAXS). Even in a weak applied field, the net magnetic moments of the individual particles aligned in the direction of the field, as indicated by the anisotropy in the recorded USAXS patterns. X-ray photon correlation spectroscopy (XPCS) measurements on these suspensions revealed that the corresponding particle dynamics are primarily Brownian diffusion [Zinn, Sharpnack & Narayanan (2023). Soft Matter, 19, 2311–2318]. At higher fields, the magnetic forces led to chain-like configurations of particles, as indicated by an additional feature in the USAXS pattern. A theoretical framework is provided for the quantitative interpretation of the observed anisotropic scattering diagrams and the corresponding degree of orientation. No anisotropy was detected when the magnetic field was applied along the beam direction, which is also replicated by the model. The method presented here could be useful for the interpretation of oriented scattering patterns from a wide variety of particulate systems. The combination of USAXS and XPCS is a powerful approach for investigating asymmetric colloidal particles in external fields.




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The prediction of single-molecule magnet properties via deep learning

This paper uses deep learning to present a proof-of-concept for data-driven chemistry in single-molecule magnets (SMMs). Previous discussions within SMM research have proposed links between molecular structures (crystal structures) and single-molecule magnetic properties; however, these have only interpreted the results. Therefore, this study introduces a data-driven approach to predict the properties of SMM structures using deep learning. The deep-learning model learns the structural features of the SMM molecules by extracting the single-molecule magnetic properties from the 3D coordinates presented in this paper. The model accurately determined whether a molecule was a single-molecule magnet, with an accuracy rate of approximately 70% in predicting the SMM properties. The deep-learning model found SMMs from 20 000 metal complexes extracted from the Cambridge Structural Database. Using deep-learning models for predicting SMM properties and guiding the design of novel molecules is promising.




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Tuning structural modulation and magnetic properties in metal–organic coordination polymers [CH3NH3]CoxNi1−x(HCOO)3

Three solid solutions of [CH3NH3]CoxNi1−x(HCOO)3, with x = 0.25 (1), x = 0.50 (2) and x = 0.75 (3), were synthesized and their nuclear structures and magnetic properties were characterized using single-crystal neutron diffraction and magnetization measurements. At room temperature, all three compounds crystallize in the Pnma orthorhombic space group, akin to the cobalt and nickel end series members. On cooling, each compound undergoes a distinct series of structural transitions to modulated structures. Compound 1 exhibits a phase transition to a modulated structure analogous to the pure Ni compound [Cañadillas-Delgado, L., Mazzuca, L., Fabelo, O., Rodríguez-Carvajal, J. & Petricek, V. (2020). Inorg. Chem. 59, 17896–17905], whereas compound 3 maintains the behaviour observed in the pure Co compound reported previously [Canadillas-Delgado, L., Mazzuca, L., Fabelo, O., Rodriguez-Velamazan, J. A. & Rodriguez-Carvajal, J. (2019). IUCrJ, 6, 105–115], although in both cases the temperatures at which the phase transitions occur differ slightly from the pure phases. Monochromatic neutron diffraction measurements showed that the structural evolution of 2 diverges from that of either parent compound, with competing hydrogen bond interactions that drive the modulation throughout the series, producing a unique sequence of phases. It involves two modulated phases below 96 (3) and 59 (3) K, with different q vectors, similar to the pure Co compound (with modulated phases below 128 and 96 K); however, it maintains the modulated phase below magnetic order [at 22.5 (7) K], resembling the pure Ni compound (which presents magnetic order below 34 K), resulting in an improper modulated magnetic structure. Despite these large-scale structural changes, magnetometry data reveal that the bulk magnetic properties of these solid solutions form a linear continuum between the end members. Notably, doping of the metal site in these solid solutions allows for tuning of bulk magnetic properties, including magnetic ordering temperature, transition temperatures and the nature of nuclear phase transitions, through adjustment of metal ratios.




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Unity gives strength: combining Bertaut's and Belov's concepts and the formalism of aperiodic crystals to solve magnetic structures of unprecedented complexity




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Following the guidelines for communicating commensurate magnetic structures: real case examples

A few real case examples are presented on how to report magnetic structures, with precise step-by-step explanations, following the guidelines of the IUCr Commission on Magnetic Structures [Perez-Mato et al. (2024). Acta Cryst. B80, 219–234]. Four examples have been chosen, illustrating different types of single-k magnetic orders, from the basic case to more complex ones, including odd-harmonics, and one multi-k order. In addition to acquainting researchers with the process of communicating commensurate magnetic structures, these examples also aim to clarify important concepts, which are used throughout the guidelines, such as the transformation to a standard setting of a magnetic space group.




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New insights into the magnetism and magnetic structure of LuCrO3 perovskite

A polycrystalline sample LuCrO3 has been characterized by neutron powder diffraction (NPD) and magnetization measurements. Its crystal structure has been Rietveld refined from NPD data in space group Pnma; this perovskite contains strongly tilted CrO6 octahedra with extremely bent Cr—O—Cr superexchange angles of ∼142°. The NPD data show that below Néel temperature (TN ≃ 131 K), the magnetic structure can be defined as an A-type antiferromagnetic arrangement of Cr3+ magnetic moments, aligned along the b axis, with a canting along the c axis. A noticeable magneto­strictive effect is observed in the unit-cell parameters and volume upon cooling down across TN. The AC magnetic susceptibility indicates the onset of magnetic ordering below 112.6 K; the magnetization isotherms below TN show a nonlinear behaviour that is associated with the described canting of the Cr3+ magnetic moments. From the Curie–Weiss law, the effective moment of the Cr3+ sublattice is found to be μeff = 3.55 μB (calculated 3.7 μB) while the ΘCW parameter yields a value of −155 K, indicating antiferromagnetic interactions. There is a conspicuous increase of TN upon the application of external pressure, which must be due to shortening of the Cr—O bond length under compression that increases the orbital overlap integral.




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Synthesis and properties of Sr2La2NiW2O12, a new S = 1 triangular lattice magnet

Magnetic materials featuring triangular arrangements of spins are frequently investigated as platforms hosting magnetic frustration. Hexagonal perovskites with ordered vacancies serve as excellent candidates for two-dimensional triangular magnetism due to the considerable separation of the magnetic planes. In this work, the effects of chemical pressure on the ferromagnetic ground state of Ba2La2NiW2O12 by substitution of Ba2+ with Sr2+ to produce Sr2La2NiW2O12 are investigated. The two materials are characterized using synchrotron-based XRD, XANES and EXAFS in addition to magnetometry in order to correlate their crystal structures and magnetic properties. Both materials form in space group R3, yet as a result of the enhanced bending of key bond angles due to the effects of chemical pressure, the TC value of the magnetic Ni2+ sublattice is reduced from ∼6 K in Ba2La2NiW2O12 to 4 K in Sr2La2NiW2O12.




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Magnetic space groups versus representation analysis in the investigation of magnetic structures: the happy end of a strained relationship

In recent decades, sustained theoretical and software developments have clearly established that representation analysis and magnetic symmetry groups are complementary concepts that should be used together in the investigation and description of magnetic structures. Historically, they were considered alternative approaches, but currently, magnetic space groups and magnetic superspace groups can be routinely used together with representation analysis, aided by state-of-the-art software tools. After exploring the historical antagonism between these two approaches, we emphasize the significant advancements made in understanding and formally describing magnetic structures by embracing their combined use.




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On the magnetic and crystal structures of NiO and MnO

The magnetic and crystal structures of manganese and nickel monoxides have been studied using high-resolution neutron diffraction. The known 1k-structures based on the single propagation vector [½ ½ ½] for the parent paramagnetic space group Fm3m are forced to have monoclinic magnetic symmetry and are not possible in rhombohedral symmetry. However, the monoclinic distortions from the rhombohedral crystal metric allowed by symmetry are very small, and the explicit monoclinic splittings of the diffraction peaks have not been experimentally observed. We analyse the magnetic crystallographic models metrically compatible with our experimental data in full detail by using isotropy subgroup representation approach, including rhombohedral solutions based on the propagation vector star {[½ ½ ½], [−½ ½ ½], [½−½ ½], [½ ½ −½]}. Although the full star rhombohedral RI3c structure can equally well fit our diffraction data for NiO, we conclude that the best solution for the crystal and magnetic structures for NiO and MnO is the 1k monoclinic model with the magnetic space group Cc2/c (Belov–Neronova–Smirnova No. 15.90, UNI symbol C2/c.1'c[C2/m]).




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Analysis of magnetic structures in JANA2020

JANA2020 is a program developed for the solution and refinement of regular, twinned, modulated, and composite crystal structures. In addition, JANA2020 also includes a magnetic option for solving magnetic structures from powder and single-crystal neutron diffraction data. This tool uses magnetic space and superspace symmetry to describe commensurate and incommensurate magnetic structures. The basics of the underlying formulation of magnetic structure factors and the use of magnetic symmetry for handling modulated and non-modulated magnetic structures are presented here, together with the general features of the magnetic tool. Examples of structures solved in the magnetic option of JANA2020 are given to illustrate the operation and capabilities of the program.




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Determining magnetic structures in GSAS-II using the Bilbao Crystallographic Server tool k-SUBGROUPSMAG

The embedded call to a special version of the web-based Bilbao Crystallographic Server tool k-SUBGROUPSMAG from within GSAS-II to form a list of all possible commensurate magnetic subgroups of a parent magnetic grey group is described. It facilitates the selection and refinement of the best commensurate magnetic structure model by having all the analysis tools including Rietveld refinement in one place as part of GSAS-II. It also provides the chosen magnetic space group as one of the 1421 possible standard Belov–Neronova–Smirnova forms or equivalent non-standard versions.




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Synchrotron CT dosimetry for wiggler operation at reduced magnetic field and spatial modulation with bow tie filters

The Australian Synchrotron Imaging and Medical Beamline (IMBL) uses a superconducting multipole wiggler (SCMPW) source, dual crystal Laue monochromator and 135 m propagation distance to enable imaging and computed tomography (CT) studies of large samples with mono-energetic radiation. This study aimed to quantify two methods for CT dose reduction: wiggler source operation at reduced magnetic field strength, and beam modulation with spatial filters placed upstream from the sample. Transmission measurements with copper were used to indirectly quantify the influence of third harmonic radiation. Operation at lower wiggler magnetic field strength reduces dose rates by an order of magnitude, and suppresses the influence of harmonic radiation, which is of significance near 30 keV. Beam shaping filters modulate the incident beam profile for near constant transmitted signal, and offer protection to radio-sensitive surface organs: the eye lens, thyroid and female breast. Their effect is to reduce the peripheral dose and the dose to the scanned volume by about 10% for biological samples of 35–50 mm diameter and by 20–30% for samples of up to 160 mm diameter. CT dosimetry results are presented as in-air measurements that are specific to the IMBL, and as ratios to in-air measurements that may be applied to other beamlines. As CT dose calculators for small animals are yet to be developed, results presented here and in a previous study may be used to estimate absorbed dose to organs near the surface and the isocentre.