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Supramolecular self-sorting predicted by a simple harmonic oscillator model

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05336B, Communication
Open Access
Adriana Sacristán-Martín, Nerea Álvarez-Llorente, Eric Masson, Alberto Diez-Varga, Héctor Barbero
The self-sorting process of homobimetallic Pt(II) terpyridyl acetylide dimers secured by a pair of Cucurbit[8]uril macrocycles with recognition motif mismatch can be quantified using a model comprising two coupled harmonic oscillators.
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Directed nucleophilic aromatic substitution reaction

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04912H, Communication
Yasuyuki Nitta, Takashi Nishikata, Michinori Sumimoto, Yusei Nakashima
In this study, we discovered a directed nucleophilic aromatic substitution reaction, "directed SNAr (dSNAr)", in the reaction of ortho-iodobezamides and amine in the presence of pyridine. The reaction proceeded ortho-specifically...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Machine Learning Directed Discovery and Optimisation of a Platinum-Catalysed Amide Reduction

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05273K, Communication
Open Access
Eleonora Casillo, Benon Maliszewski, Cesar Blanco, Thomas Scattolin, Catherine Cazin, Steven P Nolan
The discovery and optimisation of reaction conditions leading to the reduction of amides, a fundamental large-scale industrial reaction, is achieved using a machine learning (ML) platform and a platinum catalyst....
The content of this RSS Feed (c) The Royal Society of Chemistry




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Pesticide residues above limits detected in curry powders sold in Kerala

Eight samples had no manufacturer details, while the rest were from leading brands




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Metal–organic frameworks constructed using acid–base mixed ligands, carboxylic acids and N-containing chalcone, and their catalytic performance for Knoevenagel condensation

New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ05164A, Paper
Limin Cheng, Junyong Zhang, Caihong Zhan, Hao Xu, Chunhua Gong, Jingli Xie
MOF materials constructed using acid–base mixed ligands serve as efficient and economical porous heterogeneous catalysts for Knoevenagel condensation.
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Isolation and characterization of novel degradation products in Fenoverine by LC-QTOF-MS/MS, LC-MSn and 2D-NMR

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D3NJ05623F, Paper
Krishnam Raju CH, Shanmukha Kumar Jagarlapudi, Yesudas Kada, Sanath Kumar Goud Palusa
This study investigates the degradation profile of Fenoverine (FEN), an antispasmodic drug, following the International Conference on Harmonization (ICH) Q1A (R2) guidelines. FEN is stable in the presence of light,...
The content of this RSS Feed (c) The Royal Society of Chemistry




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3D interconnected polymer/mesoporous silica nanoparticle hybrid materials with hierarchical macro/meso-structures for heavy metal adsorption

New J. Chem., 2024, 48,7503-7516
DOI: 10.1039/D3NJ05887E, Paper
Jae-Seo Park, Young Sunwoo, Debabrata Chakraborty, Chamila Gunathilake, Yanhai Du, Eun-Bum Cho
This work offers nanohybrid structures for heavy metal ion adsorption from water, which include a unique 3D cross-linked structure that combines organic polymer chains with mesoporous materials to improve adsorption efficiency.
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Design and synthesis of few-layer molybdenum oxide selenide encapsulated in a 3D interconnected nitrogen-doped carbon anode toward high-performance sodium storage

New J. Chem., 2024, 48,7370-7378
DOI: 10.1039/D4NJ00389F, Paper
Yonghong Qin, Shahriman Zainal Abidin, Azhari Bin Md Hashim, Oskar Hasdinor Hassan, Xiaojun Zhao
Novel few-layered MoO3–MoSe2 encapsulated in a 3D NC skeleton is constructed to improve the electrochemical performances of SIBs.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Copper(II) complexes of sterically hindered phenolic Schiff bases: synthesis, characterization, interaction with biomolecules, and antioxidant and antimicrobial activity

New J. Chem., 2024, 48,7134-7147
DOI: 10.1039/D4NJ00430B, Paper
Iveta S. Turomsha, Maxim Y. Gvozdev, Nikolai P. Osipovich, Viktoryia A. Staravoitava, Dmitriy I. Shiman, Natalia V. Loginova
Phenolic Schiff bases and their Cu(II) complexes have been synthesized and characterized by physicochemical methods. The complexes exhibit low cell toxicity and high antioxidant and antibacterial activity, as evidenced by molecular docking studies.
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Performance analysis and structure characterization of polylactic acid modified with three flame retardants

New J. Chem., 2024, 48,7469-7479
DOI: 10.1039/D3NJ05967G, Paper
Zhu Yuqin, Wang Di, Guo Zhongliang, Wen Huiying
Three flame retardant composites were prepared by incorporating flame retardants (FRs), including triphenyl phosphate (TPP), polysiloxane (PSQ) and phosphite functionalized polysiloxane (PPSQ), respectively into a polylactic acid (s/PLLA) matrix.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Theoretical investigation of the effect of radical substituents on the open-shell character of polycyclic aromatic hydrocarbons

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00555D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tomohito Shinozuka, Daiki Shimizu, Kenji Matsuda
Radical substituents was found to significantly alter the open-shell character y of PAHs compared to non-radical substituents.
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Synthesis and characterization of magnetite coated by maltodextrin for application in magnetic hyperthermia

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ01034E, Paper
Yasmin Milena Loth Bueno, Filipe Kalil da Silva Naves, Tamires Pereira Rosa, Odivaldo Cambraia Alves, Marcel Guimarães Martins, Marla Karolyne dos Santos Horta, Giane Gonçalves Lenzi, Celio Lucas Valente Rodrigues, Jéssica Dornelas da Silva, Rodrigo Brackmann
This study aimed to synthesize magnetite nanoparticles proposing a new core with maltodextrin using the coprecipitation method in an alkaline medium, with the potential application in magnetic hyperthermia for cancer treatment.
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Self-Sacrificial templated-directed synthesis of ultrathin 0D/2D FeNi3-NC/NiFeOx Schottky junction as hydrogen evolution reaction electrode for alkaline seawater electrolysis

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01321B, Paper
Zili Xu, Yuankang Bao, Xun Xu, Ping Li, Hao Zhang, Deliang Li, Shuwang Duo
Seawater, a plentiful natural resource, is promising for hydrogen production compared to traditional electrocatalytic methods based on high-purity freshwater. This strategy shift addresses the challenge of limited freshwater resources and...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Highly radiation-resistant Al-MOF selected based on the radiation stability rules of metal–organic frameworks with ultra-high thorium ion adsorption capacity

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00076E, Paper
Xiaofan Ding, Zhanjun Zhang, Xinyan Li, Ke Ma, Tiantian Jin, Zhaoning Feng, Tian Lan, Jing Zhao, Songtao Xiao
Al-MOF synthesized based on MOF irradiation stability rules exhibits high stability against β-irradiation and ultra-high thorium adsorption capacity, which proves its huge potential application value in the field of radionuclide adsorption.
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Biowaste valorization: multifunctional hybrid lignin/TiO2 nanostructures for bacterial-biocide disinfection and dye removal

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00091A, Paper
Open Access
Marica Gallo, Virginia Venezia, Marica Muscetta, Rossella Grappa, Mariavittoria Verrillo, Gianluca Landi, Raffaele Marotta, Giuseppina Luciani
Hybrid lignin TiO2 nanoparticles: red-ox activity enables biocide disinfection and dye removal.
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Comparative analysis of the insecticidal activity against Sitophilus oryzae (L.) and agro-morphological characteristics of maize using non-biogenic and biogenic ZnO nanoparticles

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00839H, Paper
S. Aisvarya, M. Kalyanasundaram, M. Kannan, P. Arunkumar, S. Preetha, K. Elango, K. Govindaraju
Utilizing environmentally friendly nanomaterials to address insect pests and promote plant growth is imperative.
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Rapid Synthesis of MXenes and Its Potential Risk to Bacterial Communities in Tomato Rhizosphere

Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D3EN00827D, Communication
cheng chen, Yuchen Liu, Houpu Zhang, Jie Ren, Chao Zhang, Mao Xu, Dan Liu, Yuru Wang, Weiwei Lei, Xiaoli Zhao
As a thriving group of two-dimensional (2D) nanomaterials, MXenes offer tremendous application and development prospects because of their excellent physical and chemical properties. Rhizosphere bacteria colonize the narrow ecosystem region...
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Characterization of black carbon and silica nanoparticle interactions with human plasma proteins

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00773A, Communication
Si-si Chen, Hong-juan Chen, Xue-wen Guo, Wei-juan Zheng, Hong-zhen Lian
Black carbon and silica nanoparticles, modeling different sources of PM, differ in protein corona composition and effects on protein structure.
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Fractionation and preconcentration of silver nanoparticles at environmentally relevant concentrations through induced eco-corona formation and spICP-MS characterization

Environ. Sci.: Nano, 2024, 11,1559-1570
DOI: 10.1039/D3EN00933E, Paper
Aline Martins de Andrade, Anerise de Barros, Italo Odone Mazali, Marco Aurélio Zezzi Arruda
The release of nanoparticles (NPs) into environmental matrices has raised concerns regarding the contamination of environmental matrices. An induced eco-corona method was used to preconcentrate silver NPs in environmental waters analysed by spICP-MS.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Magnetic and structural characteristics associated with the transformation of As(V)-coprecipitated ferrihydrite to hematite: implications for magnetic enhancement in soils and sediments

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00739A, Paper
Guoqing Zhang, Yixuan Tang, Jinru Lin, Jiaxing Xu, Zidan Yuan, Lingyun Chen, Fei Wu, Chengshuai Liu, Zongmin Zhu, Xiangyang Bi, Wei Zou, Zhiguo Cao, Kai Jiang, Yuanming Pan, Roman Chernikov, Yongfeng Jia, Shaofeng Wang
The transformation of metastable ferrihydrite to stable hematite has been linked to magnetic enhancement in soils and sediments.
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Correction: Nano-pelargonidin modulates p53/PARP/HSP 90/XRCC1 signaling axis to combat cypermethrin-induced genotoxicity and metabolic dysfunction in fish: a molecular docking predicted in vivo approach

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN90017K, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Priyanka Sow, Sudatta Dey, Rishita Dey, Asmita Samadder, Sisir Nandi, Debojyoti Tarafdar, Anisur Rahman Khuda-Bukhsh
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Thermal fluctuation-induced selective CO2 uptake of seemingly nonporous N,C-protected dipeptide crystals as elucidated by in situ X-ray crystallographic analysis

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01018J, Paper
Kazuaki Yamanaka, Ryusei Oketani, Yuya Mori, Takashi Sato, Seiji Tsuzuki, Hiroki Takahashi, Hirohito Tsue
A novel N,C-protected dipeptide deposited nonporous but yet CO2-sorbing molecular crystals, of which the CO2 sorption state was disclosed.
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Flux growth and characterization of gallium-rare earth borates

CrystEngComm, 2024, 26,2180-2189
DOI: 10.1039/D3CE01269G, Paper
Victor V. Maltsev, Elizaveta V. Koporulina, Elena A. Volkova, Diana D. Mitina, Anna I. Jiliaeva, Vladimir L. Kosorukov, Alexey E. Afanasev, Daniil A. Naprasnikov
YGa3(BO3)4 single crystals were grown from a K2Mo3O10-based flux, and also RGa3(BO3)4 (R = Y, Pr–Yb) spontaneous crystals (RGB) were obtained by a high-temperature flux growth technique from a complex R2O3–Bi2O3–B2O3–Ga2O3 solvent.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Majority of Indian parents say their kids addicted to social media, OTT: Survey

It further revealed that 73 per cent of urban Indian parents surveyed want the data protection law to ensure mandatory parental consent is sought for children under 18




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India’s coal bed methane output expected at 759 MSCM in FY23

India’s coal bed methane production is estimated to grow to 1,072 MSCM in FY24 and 1,508 MSCM in FY25




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Telangana attracted ₹2.60 lakh crore investment during 2014-23

New Congress Govt to continue thrust on industrial growth with a focus on MSMEs




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Drone technology is expected to revolutionise India's marine fisheries sector




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Vijayawada-Srisailam seaplane trial run conducted successfully




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Gujarat introduces stricter safety rules for boating activities




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Bharti Airtel Q2 preview: Consolidated net profit expected to grow multifold

According to analysts, industry-leading ARPU and support from other businesses bode well for Airtel’s revenue growth during the quarter




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New 2-pyridone-based donor–acceptor dyes: the effect of the donor group position, type of π-linker and acid–base characteristics of the medium on the photophysical properties

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00177J, Paper
Saveliy P. Sorokin, Mikhail Yu. Ievlev, Oleg V. Ershov
Synthesis of a series of new donor–acceptor dyes based on 2-pyridone and the study of the effect of the position of the donor group, the type of π-linker and the acid–base characteristics of the medium on their photophysical properties.
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Covalently linked thieno[2,3-b]thiophene-fullerene dimers: synthesis and physical characterization

Org. Biomol. Chem., 2024, 22,2978-2984
DOI: 10.1039/D4OB00027G, Paper
Abdulrahman M. Alazemi, Mohammad H. BinSabt, Hamad M. Al-Matar, Alan L. Balch, Mona A. Shalaby
Linked thieno[2,3-b]thiophene-fullerene Dimers.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Tuberculosis infected 8 million people last year, the most WHO has ever tracked

The World Health Organization says more than 8 million people were diagnosed with tuberculosis last year




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Air passenger with suspected mpox symptoms isolated at Tiruchi govt. hospital

When contacted, a senior hospital official told The Hindu that the patient’s blood sample has been sent for further testing




cte

'I have been rejected many times because of my colour'

'I have trained Ravish Kumar, Virender Sehwag, Harbhajan Singh, Irfan Pathan...''But if I approach somebody for work, I never get it.'




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'Everybody rejected me'

'I have been trying to make a movie for seven years. I got a chance only now.''I have taken my script to every office from Dharma to Tips to Eros.''I have narrated my script to every actor possible. Nobody believed me.''Because of OTT, people like me are finally getting a chance to make something.'




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'Nobody Expected Armaan To Slap Vishal'

'It is difficult to understand Armaan's game plan because there is a vast difference between what he says and what goes on in his head.'




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‘Dasara’ trailer: Nani, Keerthy Suresh in an intense action drama directed by Srikanth Odela

Director Srikanth Odela’s Telugu film ‘Dasara’, starring Nani and Keerthy Suresh, is set in the vicinity of coal mines in rural Telangana




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Director Venu Yeldandi on ‘Balagam’: Every character stems from real-life observations

As the Telugu film ‘Balagam’ wins hearts and international awards, director Venu Yeldandi talks about how he wanted the film to reflect native culture and relationships in Sircilla, Telangana




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Anand Deverakonda: Vaishnavi Chaitanya’s character is the soul of ‘Baby’

‘Baby’ is the most emotional film he has done so far, says actor Anand Deverakonda, while asserting that it’s a gender-sensitive film with Vaishnavi Chaitanya’s character as its backbone




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India one of the 10 most-affected by stalkerware: Report

Russia, Brazil and the USA are at the top of Kaspersky’s 2020 list of countries hit by the secret surveillance software



  • Computers & Laptops

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Helmut by June (1995) / written and directed by June Newton [DVD].

[Germany] : Helmut Newton Foundation, [date of distribution not identified]




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Helmut Newton : frames from the edge (1989) / written and directed by Adrian Maben [DVD].

Halle : ArtHaus Musik, [2013]




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Short stories by Ernest Hemingway / selected and with an introduction by David Hughes ; illustrations by Ian Beck.

London : The Folio Society, 1986




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Oh, to be a painter! / Virginia Woolf ; introduced and selected by Claudia Tobin.

New York, New York : David Zwirner Books, [2021]




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4 X D (1964) / written, narrated and directed by Philippe Labro [DVD].

[France] : uniFrance, [2015]




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David Lynch : the art life (2016) / directed by Jon Nguyen, Rick Barnes, Olivia Neergaard-Holm [DVD].

[France] : Potemkine, [2017]




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La guerra dei vulcani (2012) / directed by Francesco Patierno [DVD].

[Rome] : Luce Cinecittà, [2012]




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Time of violence (1987) / directed by Ludmil Staikov [DVD].

[U.S.A.] : BG Media, [2003]




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Reus (2011) / directed by Pablo Fernández, Eduardo Piñero, Alejandro Pi [DVD].

Montevideo : BuenCine Producciones, [2011]