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Unexpected reversal of reactivity in organic functionalities when immobilized together in a metal–organic framework (MOF)

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Published On ::

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D3ME00185G, Communication
Pricilla Matseketsa, Donovan Mafukidze, Lahiru Pothupitiya, Udo P. Otuonye, Yasemin Çimen Mutlu, Boris B. Averkiev, Tendai Gadzikwa
The reactivity of hydroxyl-bearing MOF linkers with isocyanates is influenced by their mutual confinement with amine-bearing linkers within the pores of the framework.
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Engineering the interaction of short antimicrobial peptides with bacterial barriers

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Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00021H, Minireview
Open Access
Costanza Montis, Elisa Marelli, Francesco Valle, Francesca Baldelli Bombelli, Claudia Pigliacelli
Designing short antimicrobial peptides and tuning their interaction with bacterial barriers.
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The fabrication of the photothermal antibacterial platform for bacterial infectious skin wound healing: A review

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Mol. Syst. Des. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4ME00010B, Review Article
Mei Han, Wenjing Sun, Yi Chen, Hongbin Li
Antibiotics are currently the main strategy to treat bacterial infections, but they can cause bacterial resistance, and it is urgent to solve this problem. The emergence of photothermal therapy provides...
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School’s out for those not connected

By www.thehindubusinessline.com
Published On :: Fri, 18 Sep 2020 20:06:33 +0530

Online education during the pandemic blacks out marginalised students in Odisha’s rural districts


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Crystallization ripening and erosion of calcium oxalate under the effect of bacteria and a polymer materials surface

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J. Mater. Chem. B, 2024, 12,10893-10901
DOI: 10.1039/D4TB01780C, Paper
Xiran Shen, Wentao Chen, Li Guo, Huayu Li, Hong Chen, Fan Liu
New insights into the role of bacteria in pathological biomineralization inspire novel anti-encrustation polymer material design for biomedical use.
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Decellularization of caprine forestomach rumen tissue modified with silver nanowires as an antibacterial skin substitute scaffold in wound care therapeutics

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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01560F, Paper
Athmana P. A., Asna Jaleel K. I., Sinduja Malarkodi Elangovan, Riza Paul, Naveen Subbaiyan, Parthiban Shanmugam, Gopal Shankar Krishnakumar
Caprine forestomach native collagen (CFNC) modified with silver nanowires (AgNWs) as a new class of biomimetic xenograft for skin regeneration with strong antimicrobial properties.
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Cell-specific spatial profiling of targeted protein expression to characterize the impact of intracortical microelectrode implantation on neuronal health

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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01628A, Paper
Open Access
Lindsey N. Druschel, Niveda M. Kasthuri, Sydney S. Song, Jaime J. Wang, Allison Hess-Dunning, E. Ricky Chan, Jeffrey R. Capadona
Multiplex immunochemistry for proteins examining neuronal structure or function in NeuN+ regions adjacent intracortical microelectrodes (MEA) more closely matched historic intracortical MEA recording performance than traditional IHC quantification.
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Evaluation of Alkyl Chain Length and Photocatalytic Antibacterial Performance of Cation g-C3N4

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J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01118J, Paper
Junling Leng, Xuanwei Liu, Yin Xu, shien zhu, Yuefei Zhang, Zhongbing Tan, Xiaofei Yang, Jia-En Jin, YuFeng Shi, Fan Hongying, Yi Yang, Hang Yao, Yu Zhang, Hui Chong, Chengyin Wang
Several cation graphite carbon nitrides (g-C3N4-(CH2)n-ImI+) were synthesized by chemically attaching imidazolium appended alkane chains with different lengths (n = 2, 4, 8, 12 and 16) to g-C3N4. Introduction of...
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One-pot rapid preparation of long-term antioxidant and antibacterial biomedical gels based on lipoic acid and eugenol for accelerating cutaneous wound healing

By pubs.rsc.org
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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01844C, Paper
Yungang Feng, Fangrui Xie, Rui Ding, Qingrong Zhang, Youzhi Zeng, Li Li, Lianbin Wu, Yunlong Yu, Linxuan Fang
A medical antibacterial gel with long term and high antioxidant activity prepared from eugenol and lipoic acid showed good tissue repair and regeneration for burns and trauma.
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A guanidiniocarbonyl-pyrrole functionalized cucurbit[7]uril derivative as a cytomembrane disruptor for synergistic antibacterial therapy

By pubs.rsc.org
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J. Mater. Chem. B, 2024, 12,11105-11109
DOI: 10.1039/D4TB01840K, Communication
Ruixue Han, Kehan Du, Shengke Li, Minzan Zuo, Ponmani Jeyakkumar, Hao Jiang, Leyong Wang, Xiao-Yu Hu
A guanidiniocarbonyl-pyrrole functionalized cucurbit[7]uril derivative as a cytomembrane disruptor has been successfully constructed for synergistic antibacterial therapy.
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Dual-functional PCN-242 (Fe2Co) MOF for sensitive bacterial endotoxin detection

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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01944J, Paper
Sivasankar Kulandaivel, Yung-Kang Lu, Chia-Her Lin, Yi-Chun Yeh
This work introduces a novel bimetallic MOF with superior endotoxin detection and enhanced catalytic activity for broader diagnostic applications.
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Bigg Boss 10: Rahul Dev is finally evicted

By www.rediff.com
Published On :: Mon, 19 Dec 2016 12:46:52 +0530

Do the producers want us to see more of Nitibha and Manveer?Is that why the less popular contestant got to stay on


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Sonakshi: 'Sexual harassment at work is neglected'

By www.rediff.com
Published On :: Wed, 15 Mar 2017 17:16:33 +0530

'Women are ashamed of the repercussions that will come when they speak about it.''Women also feel they will be blamed for whatever has happened to them.''Unless women support each other and stand by each other, that will not change.' Sonakshi Sinha speaks out.


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Bigg Boss 11: Who will get evicted? PREDICT!

By www.rediff.com
Published On :: Wed, 13 Dec 2017 09:14:01 +0530

Will the celebs win over the commoners?


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Bigg Boss 11: 'I can't believe I am evicted!'

By www.rediff.com
Published On :: Mon, 18 Dec 2017 15:43:12 +0530

'Arshi never crossed her boundary.''Initially, Akash was entertaining but slowly, he's become irritating because he changes groups without being loyal to anyone.' Hiten Tejwani discusses the contestants on Bigg Boss 11, and reserves the worst for Hina Khan.


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#Bigg Boss12: Who will get evicted? PREDICT!

By www.rediff.com
Published On :: Tue, 23 Oct 2018 16:53:17 +0530

Three celebrities and one commoner are up for eviction. Who will get the final shove?


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Sajid Khan To Be Evicted From Bigg Boss?

By www.rediff.com
Published On :: Fri, 07 Oct 2022 10:46:33 +0530

There is now a behind-the-scenes discussion to evict Sajid immediately.


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Bigg Boss 16: Look Who's EVICTED!

By www.rediff.com
Published On :: Tue, 25 Oct 2022 12:55:57 +0530

Manya Singh got eliminated, and it did not come as a surprise.


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Bigg Boss 16: Will Soundarya Get Evicted? PREDICT!

By www.rediff.com
Published On :: Fri, 25 Nov 2022 12:33:45 +0530

After Gautam Vig, will his rumoured girlfriend Soundarya Sharma exit the Bigg Boss house?


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Bigg Boss 16: Should MC Stan Be Evicted Next? VOTE

By www.rediff.com
Published On :: Wed, 30 Nov 2022 10:56:26 +0530

Namrata Thakker lists why it's time for MC Stan to go home.


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Bigg Boss 16: Will Sumbul Get Evicted? Tell Us

By www.rediff.com
Published On :: Fri, 02 Dec 2022 13:25:00 +0530

Will Sumbul Toqueer Khan get eliminated from the game? Namrata Thakker feels her chances of going home are high.


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Should MC Stan Be Evicted? VOTE!

By www.rediff.com
Published On :: Thu, 15 Dec 2022 14:55:43 +0530

Until last week, MC Stan was hellbent on leaving Bigg Boss.


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Bigg Boss: Who Will Get Evicted This Week? PREDICT!

By www.rediff.com
Published On :: Fri, 23 Dec 2022 12:11:37 +0530

Christmas may be around the corner but will that stop an elimination from the Bigg Boss 16 house this weekend?


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Bigg Boss: Superstar Evicted In 24 Hrs!

By www.rediff.com
Published On :: Mon, 19 Jun 2023 11:41:57 +0530

The second season of Bigg Boss OTT premiered over the weekend on JIO Cinema and it was an exciting watch, thanks to host Salman Khan and an interesting line-up of contestants.


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Material-agnostic characterization of spatially offset Raman spectroscopy in turbid media via Monte Carlo simulations

By pubs.rsc.org
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Analyst, 2024, 149,5463-5475
DOI: 10.1039/D4AN01044B, Paper
Zuriel Erikson Joven, Piyush Raj, Ishan Barman
Monte Carlo simulations of spatially offset Raman spectroscopy (SORS) produce widely-applicable, quantitative frameworks for optimizing and interpreting SORS experiments.
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Electrochemically modulated surface plasmon waves for characterization and interrogation of DNA-based sensors

By pubs.rsc.org
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Analyst, 2024, Advance Article
DOI: 10.1039/D4AN01164C, Paper
Anil Sharma, Thomas Hulse, Aymen H. Qatamin, Monica Moreno, Klester S. Souza, Marcelo B. Pereira, Fabricio S. Campos, Leandro B. Carneiro, Antonio M. H. de Andrade, Paulo M. Roehe, Flavio Horowitz, Sergio B. Mendes
This article focuses on the application of electrochemically modulated surface plasmon waves for structural characterization and for assessing signal transduction performance of redox-labeled DNA-based sensing platforms.
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Structural and sorption characteristics of an aerogel composite material loaded with flufenamic acid: insights from MAS NMR and high-pressure NOESY studies

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Phys. Chem. Chem. Phys., 2024, 26,27301-27313
DOI: 10.1039/D4CP03217A, Paper
Valentina V. Sobornova, Valeriya V. Mulloyarova, Konstantin V. Belov, Alexey A. Dyshin, Peter M. Tolstoy, Mikhail G. Kiselev, Ilya A. Khodov
The structural and sorption characteristics of a composite material consisting of a silica aerogel loaded with flufenamic acid were investigated using a variety of nuclear magnetic resonance techniques.
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Simulated conformality of atomic layer deposition in lateral channels: the impact of the Knudsen number on the saturation profile characteristics

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Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP00131A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christine Gonsalves, Jorge A. Velasco, Jihong Yim, Jänis Järvilehto, Ville Vuorinen, Riikka L. Puurunen
Systematic analysis of saturation profile characteristics allowed development of an extended slope method that relates the slope of the adsorption front to the sticking coefficient for any Knudsen number.
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High-level ab initio characterization of the OH + CH3NH2 reaction

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Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP01470G, Paper
Open Access
Balázs Gruber, Gábor Czakó
High-level ab initio computations considering post-CCSD(T), core correlation, scalar relativistic, and spin–orbit effects reveal the stationary-point properties and rate coefficients of the OH + CH3NH2 reaction.
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Insight into physico-chemical properties of oxalatoborate-based ionic liquids through combined experimental-theoretical characterization

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Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP02296C, Paper
Open Access
Matteo Palluzzi, Giorgia Mannucci, Akiko Tsurumaki, Matteo Busato, Maria Assunta Navarra, Paola D’Angelo
An anion–anion attraction was inferred from the thermal behavior of oxalate-borate ionic liquids and confirmed through computational methods.
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Effects of oxide platforms on the dynamics and reduction characteristics of hydrogen spillover

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Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03093A, Paper
Kazuki Shun, Akihito Fujimoto, Kohsuke Mori, Hiromi Yamashita
The interparticle hydrogen spillover can be facilitated over TiO2 and WO3 as a consequence of the interfacial diffusion of H+ and e− pairs, while the e− diffusion coupled with H+ is inhibited on MgO and CeO2.
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Keen contest expected as an on-the-rise India takes on World No. 2 Germany

By www.thehindu.com
Published On :: Tue, 22 Oct 2024 23:41:57 +0530

The host is struggling with a few injuries; Harmanpreet will have Vivek Sagar Prasad as his deputy while the visiting team will sport a new look


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‘383 toilets constructed’

By www.thehindu.com
Published On :: Sat, 18 Jul 2015 00:00:00 +0530


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The next scientist : the unexpected beginnings and unwritten future of the world's great scientists / by Kate Messner ; illustrated by Julia Kuo

By darius.uleth.ca
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Messner, Kate, author


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The Journey Prize : stories : the best of Canada's new writers / selected by Kevin Hardcastle, Grace O'Connell, Ayelet Tsabari

By darius.uleth.ca
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Loss of fluorine during crosslinking by the biarylitide P450Blt proceeds due to restricted peptide orientation

By pubs.rsc.org
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04092A, Communication
Yongwei Zhao, Jemma Gullick, Mathias H. Hansen, Laura Coe, Maxine Treisman, Ralf B. Schittenhelm, Alasdair McKay, Lauren A. M. Murray, Julien Tailhades, James J. De Voss, Elizabeth H. Krenske, Max J. Cryle
Crosslinking of the ribosomal peptide by Cytochrome P450Blt leads to the formation of a C–N bond with specific loss of fluorine during the reaction.
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