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Pawar attacks Modi at rally, calls for parivartan




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Private actions in the presence of externalities [electronic resource] : the health impacts of reducing air pollution peaks but not ambient exposure / Susanna B. Berkouwer, Joshua T. Dean

Cambridge, MA. : National Bureau of Economic Research, 2023




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Prithvi Theatre gears up for another edition of its annual festival

Set up in 1978 by Shashi Kapoor and his wife Jennifer, Prithvi Theatre has been a launch pad or grooming ground for many theatre personalities.




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Maharashtra Assembly Elections: Gopal Shetty withdraws Independent nomination from Borivali constituency

Former BJP MP Gopal Shetty withdraws nomination from Borivali, Mumbai, after being denied ticket for upcoming elections





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In rare bonhomie, Shivakumar & Tejasvi Surya inspect trial metro service in K'taka




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Guru Nanak Jayanti 2024: Know date, time and significance of festival

Guru Nanak Dev Ji, the founder of Sikhism, was the first of the ten Sikh gurus and is recognised as a philosopher, poet, and spiritual leader. He emphasised the principles of equality, compassion, and devotion to one universal God.




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Telcos creating a false equivalence with satellite operators on spectrum pricing : Amazon, Starlink

Reliance Jio, which is pushing for auctioning spectrum, said that arguments that satellite frequencies are always assigned in a shared mode and on a non-exclusive basis are both factually and technically incorrect and should be ignored




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Deconstructive annulation mediated one-pot synthesis of xanthene derivatives

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00093E, Paper
Balasubramaniyam Manikandan, Subbiah Thamotharan, Olivier Blacque, Subramaniapillai Selva Ganesan
One-pot, two-step methodology utilized for the sequential C–O/C–N cleavage followed by intramolecular/intermolecular annulation reaction.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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A water mediated multicomponent reaction for the synthesis of novel spirooxindole derivatives and their antifungal activity

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00256C, Paper
Min Zhang, Liang Shi, Li Chen, Zhengyu Liu, Ting Zhao, Chunyin Zhu, Liuqing Yang
A total of 27 novel spirooxindoles were synthesized through a water mediated three-component reaction of isatin, 4-aminocoumarin, and 1,3-cyclodicarbonyl compounds. Several compounds showed excellent antifungal activity against Physalospora piricola.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Kinetic resolution of 1,1'-binaphthyl-2,2'-diamine derivatives by chiral calcium phosphate-catalyzed acylation

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00355A, Paper
Tatsuhiro Uchikura, Yuki Kanno, Yukino Fukuda, Mikoto Sato, Takahiko Akiyama
Chiral calcium phosphate-catalyzed kinetic resolution of BINAM derivatives.
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A rhodium-catalyzed cascade C–H activation/annulation strategy for the expeditious assembly of pyrrolidinedione-fused 1,2-benzothiazines

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00193A, Paper
Yinsong Wu, Guanghao Shi, Yanan Liu, Yangzilin Kong, Mengdi Wu, Demao Wang, Xiaobing Wu, Yongjia Shang, Xinwei He
We have developed a cascade annulation strategy triggered by rhodium(III)-catalyzed C–H activation for the expeditious assembly of pyrrolidinedione-fused 1,2-benzothiazines from free NH-sulfoximines with maleimides under mild conditions.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Electrochemical nickel-catalyzed cross-coupling of glycosyl thiols with preactivated phenols and ketones

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00442F, Communication
Fuxin Li, Hui Liu, Wanyu Xing, Qingju Zhang, Liming Wang
Here we report an efficient electrochemical nickel-catalyzed cross-coupling reaction for the synthesis of S-glycosides from preactivated phenols and ketones.
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Recent advances in spirocyclization of maleimides via transition-metal catalyzed C–H activation

Org. Biomol. Chem., 2024, 22,2916-2947
DOI: 10.1039/D3OB01904G, Review Article
Swadhin Swaraj Acharya, Sagarika Patra, Rojalini Maharana, Manaswini Dash, Liza Mama Barad, Bibhuti Bhusan Parida
In recent years, the maleimide scaffold has received a great deal of attention in C–H activation.
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Photogenerated chlorine radicals activate C(sp3)–H bonds of alkylbenzenes to access quinazolinones

Org. Biomol. Chem., 2024, 22,2968-2973
DOI: 10.1039/D4OB00129J, Communication
Xin-Yao Pan, Gui-Xia Sun, Fang-Ping Huang, Wen-Jian Qin, Qing-Hu Teng, Kai Wang
An Fe-catalyzed visible-light induced condensation of alkylbenzenes with anthranilamides has been developed.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Stereoselective synthesis of (R)- and (S)-1,2-diazetidine-3-carboxylic acid derivatives for peptidomimetics

Org. Biomol. Chem., 2024, 22,2974-2977
DOI: 10.1039/D4OB00278D, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Matthew Nutter, Henry Stone, Michael Shipman, Stefan Roesner
Stereoselective synthesis of both enantiomers of orthogonally protected 1,2-diazetidine-3-carboxylic acid (aAze) from homochiral glycidol and its application in peptidomimetics.
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Iron-catalyzed selective construction of indole derivatives via oxidative C(sp3)–H functionalization of indolin-2-ones

Org. Biomol. Chem., 2024, 22,3073-3079
DOI: 10.1039/D4OB00133H, Paper
Wei Chen, Lang-Qi Wen, Xiao-Bing Lu, Hui Zhou
We have developed a clean and efficient iron-catalyzed C(sp3)–H functionalization of indolin-2-ones for the chemodivergent synthesis of value-added indole derivatives, including isatins, and symmetrical and non-symmetrical isoindigos.
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Photochromism of phenazine-2,3-diol derivatives through excited state intermolecular proton transfer based on keto–enol tautomerization

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00387J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kazuki Ohira, Kumpei Kozuka, Naoki Kaneda, Masahiro Yamamoto, Keiichi Imato, Yousuke Ooyama
It was found that phenazine-2,3-diol derivatives exhibit photochromism through excited state intermolecular proton transfer (ESInterPT) processes based on keto–enol tautomerization.
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3-Halo-5,6-dihydro-4H-1,2-oxazine N-oxides as synthetic equivalents of unsaturated nitrile oxides in the [3 + 2]-cycloaddition with arynes: synthesis of substituted 3-vinyl-1,2-benzisoxazoles

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00391H, Communication
Alexander A. Lukoyanov, Svetlana A. Aksenova, Andrey A. Tabolin, Alexey Yu. Sukhorukov
3-Halo-1,2-oxazine N-oxide derivatives act as surrogates of vinyl nitrile oxides in tandem [3 + 2]-cycloaddition/[3 + 2]-cyclofragmentation with arynes leading to benzisoxazoles.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Facile synthesis of tetrahydroquinoline containing dithiocarbamate derivatives via one-pot sequential multicomponent reaction

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00490F, Communication
SIDDHARTHA KUMAR SENAPATI, Anit Pal, Animesh Das
An efficient sequential multi-component method for the synthesis of tertrahydroquinoline containing dithiocarbamate has been developed. This reaction involved a boronic acid-catalyzed reduction of quinoline to tertrahydroquinoline, followed by nucleophilic addition...
The content of this RSS Feed (c) The Royal Society of Chemistry




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N-Functionalization of beta-aminophosphonates; Cytotoxic effect of the new derivatives

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00243A, Paper
György Keglevich, Petra Regina Varga, Emőke Dinnyési, Zsuzsanna Szalai, Szilvia Bősze, Rita Oláhné Szabó, Laszlo Drahos, Konstantin Karaghiosoff
Beta-Aminophosponates obtained by the Michael addition of primary amines to the double bond of diethyl vinylphosphonate proved to be suitable starting materials (amine components) in the Kabachnik–Fields reaction with formaldehyde...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Why has private capital not been taken to Indian aviation 

With banks becoming increasingly cautious and credit flows tightening, private capital must be explored and enticed




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National Mental Health Festival 2024 kicks off in Bengaluru




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'Shivani Is Thali Ka Baigan'

'I always wanted to be a part of a platform like this which enables you to show your true personality to the world. But after entering the show, I realised this show is more suitable for people like Armaan Malik, who backbite and indulge in unnecessary arguments. I am not cut out for such things.'




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Revival of a glorious tradition

Assam’s Nati dance tradition is set on the path to regaining respect.




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Mango arrivals in Salem market increase to 40 metric tonnes per day




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How Kalki penned Ponniyin Selvan dipping into archival books in an old steel trunk

For the historical book, the author travelled widely across Tamil Nadu and Sri Lanka




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Sidhartha Siva’s Malayalam film, ‘Aanu’, narrates the predicament of two women

Aanu, starring Sajitha Madathil and Namitha Pramod, will be screened at the 27th International Film Festival of Kerala




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Bellamkonda Sreenivas on ‘Chatrapathi’ remake: This is our tribute to SS Rajamouli

Actor Bellamkonda Sreenivas talks about his debut in Hindi cinema with the redux of Rajamouli-Prabhas blockbuster ‘Chatrapathi’




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Suzy Embo : foto's = photos, 1953-1980 / textes, Ivan Alechine, Tamara Berghmans, Ann Deckers, Pieter De Reuse.

Bruxelles : CFC-Editions, [2017]




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The Gilbert and Sullivan companion / Leslie Ayre ; foreword by Martyn Green ; illustrated from the Raymond Mander and Joe Mitchenson Theatre Collection.

London : Pan Books, 1974.




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Edith Stein : essential writings / selected with an introduction by John Sullivan.

New York : Orbis Books, [2002]




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Interface passivation strategies for high-performance perovskite solar cells using two-dimensional perovskites

Mater. Chem. Front., 2024, 8,3528-3557
DOI: 10.1039/D4QM00560K, Review Article
He Huang, Xiaobo Zhang, Wencai Zhou, Yong Huang, Zilong Zheng, Xiaoqing Chen, Yongzhe Zhang, Hui Yan
A review of recent advancements in interface passivation strategies, with a particular focus on the implementation of 2D/3D perovskite passivation across buried interfaces, grain boundaries, and top interfaces.
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Spiro-[4,5]-cyclohexadiene-8-one Polymers: Photoactivated Crosslinking and Switch-On Fluorescence for Lithography

Mater. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QM00688G, Research Article
Yi Yuan, Mi Chao, Yunyi Shang, Yujia Gao, Guangle Niu, Wanggang Fang, Liqing He, Hui Wang
Developing multiple photoresponsive polymers is crucial for creating versatile intelligent materials; however, it poses a significant challenge due to the limited availability of photoactivated moieties. Herein, we present a novel...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Sandra Wachter: Exploring fairness, privacy and advertising in an algorithmic world

Sandra Wachter is a Lawyer, Associate Professor and Senior Research Fellow at University of Oxford. In this video, Sandra discusses how the law can keep up with new technology. Particularly, she spoke about her recent work on targeted advertising – a big issue for tech giants including Facebook and Amazon. The law already protects against discrimination based on certain identity traits such as race or gender. But targeted advertisers claim to group people according to “affinity” – an aggregate measure of their online behaviour – not identity. Wachter believes, however, that existing concepts in the law may have something to say about discrimination by affinity. ABOUT WIRED PULSE: AI AT THE BARBICAN 450 business executives, technologists and enthusiasts gathered at The Barbican Centre’s Concert Hall in London, for WIRED Pulse: AI at the Barbican on June 15, 2019. Discover some of the fascinating insights from speakers here: http://wired.uk/ai-event ABOUT WIRED PULSE AND WIRED EVENTS The WIRED Pulse series offers an engaging, top-level perspective on how disruptive technology and fast-changing industries - such as artificial intelligence, deep tech and health - are impacting the human experience. The aim is to distill the most pertinent strands of themes within each complex topic and to share it with the wider public as a thought-provoking conversation-starter. WIRED events shine a spotlight on the innovators, inventors and entrepreneurs who are changing our world for the better. Explore this channel for videos showing on-stage talks, behind-the-scenes action, exclusive interviews and performances from our roster of events. Join us as we uncover the most relevant, up-and-coming trends and meet the people building the future. ABOUT WIRED WIRED brings you the future as it happens - the people, the trends, the big ideas that will change our lives. An award-winning printed monthly and online publication. WIRED is an agenda-setting magazine offering brain food on a wide range of topics, from science, technology and business to pop-culture and politics. CONNECT WITH WIRED Events: http://wired.uk/events Web: http://po.st/WiredVideo Twitter: http://po.st/TwitterWired Facebook: http://po.st/FacebookWired Google+: http://po.st/GoogleWired Instagram: http://po.st/InstagramWired Magazine: http://po.st/MagazineWired Newsletter: http://po.st/NewslettersWired




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Data Security vs. Privacy: Can You Have Both? | WIRED Brand Lab

BRANDED CONTENT | Produced by WIRED Brand Lab with ExtraHop | Data is the most valuable enterprise asset. Encryption keeps it secure but can hide malicious traffic from security teams. With personal data and corporate reputations at stake, security experts Jesse Rothstein (ExtraHop) and Mikko Hyppönen (F-Secure) spoke with WIRED's Digital Director Brian Barrett to answer the key question: how can enterprise security and data privacy co-exist?




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Tech Support - Survivorman Les Stroud Answers Survival Questions From Twitter

Survivorman host Les Stroud uses the power of Twitter to answer the internet's burning questions about outdoor survival. How do survivalists subsist on one bug a day? How does one keep from inhaling too much smoke from a fire? How does Les prepare for a trip? How does he keep his camera batteries charged during excursions? Host and producer of Survivorman, Les Stroud is credited with creating the genre known as Survival TV. He is an award winning producer-director of several series and an author and musician and he launches Surviving Disasters with Les Stroud (March 2021) on all PBS stations along with Les Stroud’s Wild Harvest and his new children's book: Wild Outside with Annick Press.




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Mastering Modern Work: Cultivating Innovation in a Hybrid World | WIRED Brand Lab

Produced by WIRED Brand Lab with Opentext | Mark J. Barrenechea, the CEO & CTO of OpenText, Bill Schaninger, Senior Partner at McKinsey, and the CIOs of the NIAID, OpenText, and the Auto Club Group talk about how they are driving innovation, implementing new technologies, and motivating and attracting the talented workforce necessary for their organizations to succeed over the next year, and into the decade beyond.




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Obsessed - Meet the Self-Taught Medicinal Mushroom Cultivator

You think you like mushrooms? William Padilla-Brown might just have a step up on you. As the founder of MycoSymbiotics, William has cultivated hundreds of thousands of mushrooms from dozens of species; he's barcoded them, and turned them into various extracts and tinctures. William sits down with WIRED to break down his mushroom obsession.




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Why Music Festivals Sound Better Than Ever

Did you know that a simple speaker completely transformed modern music festivals? A vertical line array is a loudspeaker system that stacks speakers on top of each other so that sound is more evenly distributed on a horizontal plane. To learn more about line array, WIRED spoke with sound engineer Dave Rat. Dave, who has provided audio for Coachella since 2001, breaks down exactly how these speakers work, and why modern music festivals sound so much better than they used to. Director: Efrat Kashai Director of Photography: Ricardo Pomares Editor: Richard Trammell Expert: Dave Rat Producer: Efrat Kashai Line Producer: Joseph Buscemi Associate Producer: Brandon White Production Manager: Peter Brunette Production Coordinator: Kevin Balash Camera Operator: Shay Eberle-Gunst Audio: Will Miller Production Assistant: Phillip Arliss Post Production Supervisor: Alexa Deutsch Post Production Coordinator: Ian Bryant Supervising Editor: Doug Larsen Assistant Editor: Billy Ward




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Tech Support - Survivalist Answers Survival Questions From Twitter | Tech Support

Survivalist Donny Dust answers your questions about primitive skills and surviving in the wild from Twitter. How do you start a campfire without any matches? If igloos are made of ice, how do they keep you warm? What is the most nutritious insect to eat? What does it mean to die by exposure? Answers to these questions and many more await—it's Survivalist Support.Check out Donny Dust's new book, Wild Wisdom, and pick up a copy at https://www.simonandschuster.com/books/Wild-Wisdom/Donny-Dust/9781668013434Director: Justin WolfsonDirector of Photography: Josh BaneEditor: Cory StevensExpert: Donny DustLine Producer: Joseph BuscemiAssociate Producer: Brandon WhiteProduction Manager: Peter BrunetteProduction & Equipment Manager: Kevin BalashCasting Producer: Nicholas SawyerCamera Operator: Freddie OchoaSound Mixer: Carlos HernandezProduction Assistant: Chloe SmithPost Production Supervisor: Christian OlguinPost Production Coordinator: Ian BryantSupervising Editor: Doug LarsenAdditional Editor: Jason MaliziaAssistant Editor: Billy Ward




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Tech Support - Private Investigator Answers PI Questions

Private investigator Mike LaCorte joins WIRED to answer the internet's burning questions about the profession of private investigator. How often are the people they're hired to watch cheating on their partner? What are PI's allowed and not allowed to do on the job, legally? Has anyone ever caught him investigating them? Answers to these questions and more await on Private Investigator Support.Mike LaCorte is CEO of Conflict International https://conflictinternational.com/Director: Anna O'DonohueDirector of Photography: James FoxEditor: Richard TrammellExpert: Mike LaCorteLine Producer: Joseph BuscemiAssociate Producer: Brandon WhiteProduction Manager: Peter BrunetteProduction Coordinator: Rhyan LarkTalent Booker: Nicholas SawyerCamera Operator: Neill FrancisSound Mixer: Mark CheffinsProduction Assistant: Jack HaynesPost Production Supervisor: Christian OlguinPost Production Coordinator: Ian BryantSupervising Editor: Doug LarsenAdditional Editor: JC ScruggsAssistant Editor: Andy Morell




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Musi River revival project triggers political row

Sensing swelling anger against demolitions, CM, Ministers attempt to douse the fire




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Festival sales: It’s not a cracker of a Diwali but neither a damp squib

Brands that have onboarded e-commerce channels report better sales




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IISc receives its single largest private donation of Rs 425 crore

The unique school and the 800-bed multispeciality hospital on campus will create ‘physician-scientists’




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This Documentary Will Make You Deactivate Your Social Media

If you are reading this article, chances are you found it through social media. And that means the platform that used it to get your attention knows you are here. While you are reading these words, Facebook, Twitter, or Google are likely reading you.

That is the premise of the new Netflix documentary The Social Dilemma from filmmaker Jeff Orlowski, which features repentant Silicon Valley figures sounding the alarm that big tech companies are doing three very dangerous things: (1) Spying on you. (2) Manipulating your feeds to keep you engaged. (3) Deepening your biases and blind spots by pushing away everything else.




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Google Podcasts now supports private RSS feeds so you can listen to the shows you pay to access

Google Podcasts is finally getting a feature that’s already standard across most listening apps: private RSS feed support. The head of product for Google Podcasts, Zack Reneau-Wedeen, made the announcement on Twitter today and shouted out some networks that are especially reliant on private feeds, including Patreon, Slate, RedCircle, and Supercast.

To access the feature, tap over to the activity tab in the bottom right-hand corner and slide over to the Subscriptions tab, then tap the plus symbol.




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CrysGraphFormer: an equivariant graph transformer for prediction of lattice thermal conductivity with interpretability

J. Mater. Chem. A, 2024, 12,30707-30721
DOI: 10.1039/D4TA04495A, Paper
Zhengyu Sun, Weiwei Sun, Shaohan Li, Zening Yang, Mutian Zhang, Yang Yang, Huayun Geng, Jin Yu
We propose an innovative GNN model, CrysGraphFormer, which accurately predicts lattice thermal conductivity and enhances insights for material discovery.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A review on instability factors of mono- and divalent metal ion batteries: from fundamentals to approaches

J. Mater. Chem. A, 2024, 12,30190-30248
DOI: 10.1039/D4TA05386A, Review Article
Elmira Kohan, Roushan Khoshnavazi, Mir Ghasem Hosseini, Abdollah Salimi, Mehdi Salami-Kalajahi
Degradation phenomena in different components (cathode, anode, current collectors (CCs)) of mono- and divalent metal-based batteries affect their performance.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A sustainable redox-mediated pathway for improved transition metal organic framework activation and CO2 uptake performance

J. Mater. Chem. A, 2024, 12,30454-30464
DOI: 10.1039/D4TA02526A, Paper
Taylor Jade Self, Jiabin Niu, Wen Liu, Chaobin He, Mei Chee Tan
Sustainable substitutions in MOF fabrication and processing can confidently be made by employing redox engineering for synergistic valency and defect constitution, based on application, without sacrificing active site functionality.
The content of this RSS Feed (c) The Royal Society of Chemistry