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Transformation from helical to layered supramolecular organization of asymmetric perylene diimides via multiple intermolecular hydrogen bonding

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01911A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Mengmeng Li, Wojciech Zajaczkowski, Gangamallaiah Velpula, Daniel Jänsch, Robert Graf, Tomasz Marszalek, Sapun H. Parekh, Yulian Zagranyarski, Kunal Mali, Manfred Wagner, Steven De Feyter, Chen Li, Klaus Müllen, Wojciech Pisula
The solid-state supramolecular organization of asymmetric perylene diimide is transformed from helical to layered self-assembly after thermal annealing.
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Nitric oxide monooxygenation (NOM) reaction of cobalt-nitrosyl {Co(NO)}8 to CoII-nitrito {CoII(NO2−)}: base induced hydrogen gas (H2) evolution

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01572E, Edge Article
Open Access
Sandip Das, Kulbir, Somnath Ghosh, Subash Chandra Sahoo, Pankaj Kumar
Base-induced hydrogen (H2) gas evolution in the nitric oxide monoxygenation reaction.
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Nickel catalysis enables convergent paired electrolysis for direct arylation of benzylic C–H bonds

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01445A, Edge Article
Open Access
Lei Zhang, Xile Hu
A direct arylation of benzylic C–H bonds is achieved by integrating Ni-catalyzed benzyl–aryl coupling into convergent paired electrolysis.
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Rapidly Self-deoxygenating Controlled Radical Polymerization in water via in-situ Disproportionation of Cu(I)

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01512A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
David Haddleton, Evelina Liarou, Yisong Han, Marc Walker, Ana Sanchez
The first rapidly self-deoxygenating Cu-RDRP in aqueous media is investigated. The disproportionation of Cu(I)/Me6Tren in water towards Cu(II) and highly reactive Cu(0) leads to O2-free reaction environments within the first...
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Structural trends in the dehydrogenation selectivity of palladium alloys

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00875C, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Stephen C. Purdy, Ranga Rohit Seemakurthi, Garrett M. Mitchell, Mark Davidson, Brooke A. Lauderback, Siddharth Deshpande, Zhenwei Wu, Evan C. Wegener, Jeffrey Greeley, Jeffrey T. Miller
Alloying is well-known to improve the dehydrogenation selectivity of pure metals, but there remains considerable debate about the structural and electronic features of alloy surfaces that give rise to this behavior.
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General and selective synthesis of primary amines using Ni-based homogeneous catalysts

Chem. Sci., 2020, 11,4332-4339
DOI: 10.1039/D0SC01084G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kathiravan Murugesan, Zhihong Wei, Vishwas G. Chandrashekhar, Haijun Jiao, Matthias Beller, Rajenahally V. Jagadeesh
A Ni-triphos based homogeneous catalyst enabled the synthesis of all kinds of primary amines by reductive amination of carbonyl compounds with ammonia and hydrogenation of nitroarenes.
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Tetrazine as a general phototrigger to turn on fluorophores

Chem. Sci., 2020, 11,4410-4415
DOI: 10.1039/D0SC01009J, Edge Article
Open Access
Axel Loredo, Juan Tang, Lushun Wang, Kuan-Lin Wu, Zane Peng, Han Xiao
Tetrazine was demonstrated for the first time as a general phototrigger to design photoactivatable fluorophore probes.
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Chemical synthesis and immunological evaluation of new generation multivalent anticancer vaccines based on a Tn antigen analogue

Chem. Sci., 2020, 11,4488-4498
DOI: 10.1039/D0SC00544D, Edge Article
Open Access
Carlo Pifferi, Ane Ruiz-de-Angulo, David Goyard, Claire Tiertant, Nagore Sacristán, Diego Barriales, Nathalie Berthet, Juan Anguita, Olivier Renaudet, Alberto Fernández-Tejada
A fully-synthetic anticancer vaccine candidate incorporating an hexadecavalent Tn antigen analogue display via oxime linkages induced tumor-specific IgG antibodies and cellular immune responses in mice coadministered with QS-21 as an adjuvant.
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Hydrogen peroxide reduction on single platinum nanoparticles

Chem. Sci., 2020, 11,4416-4421
DOI: 10.1039/D0SC00379D, Edge Article
Open Access
Xin Chang, Christopher Batchelor-McAuley, Richard G. Compton
At the single platinum nanoparticle scale the hydrogen peroxide reduction reaction is a surface limited process.
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Self-assembly of reversed bilayer vesicles through pnictogen bonding: water-stable supramolecular nanocontainers for organic solvents

Chem. Sci., 2020, 11,4374-4380
DOI: 10.1039/D0SC00206B, Edge Article
Open Access
Shiva Moaven, Brandon T. Watson, Shelby B. Thompson, Veronica J. Lyons, Daniel K. Unruh, Dominick J. Casadonte, Dimitri Pappas, Anthony F. Cozzolino
A new air and moisture stable antimony thiolate compound has been prepared that spontaneously forms stable hollow vesicles.
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Functional group interaction profiles: a general treatment of solvent effects on non-covalent interactions

Chem. Sci., 2020, 11,4456-4466
DOI: 10.1039/D0SC01288B, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Mark D. Driver, Mark J. Williamson, Joanne L. Cook, Christopher A. Hunter
Functional group interaction profiles are a quantitative tool for predicting the effect of solvent on the free energy changes associated with non-covalent interactions.
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Synthesis and properties of hypervalent electron-rich pentacoordinate nitrogen compounds

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00002G, Edge Article
Open Access
Chenting Yan, Masato Takeshita, Jun-ya Nakatsuji, Akihiro Kurosaki, Kaoko Sato, Rong Shang, Masaaki Nakamoto, Yohsuke Yamamoto, Yohei Adachi, Ko Furukawa, Ryohei Kishi, Masayoshi Nakano
Structural characterization of hypervalent electron-rich pentacoordinate nitrogen species has long been a synthetic challenge. Here we report the first nitrogen cationic radical (11-N-5) species featuring a weak hypervalent 3c-5e interaction.
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Quinone Methide Dimers Lacking Labile Hydrogen Atoms Are Surprisingly Excellent Radical-Trapping Antioxidants

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC02020F, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Derek A. Pratt, Mark A R Raycroft, Jean-Philippe R Chauvin, Matthew Galliher, Kevin Romero, Corey Stephenson
Hydrogen atom transfer (HAT) is the mechanism by which the vast majority of radical-trapping antioxidants (RTAs), such as hindered phenols, inhibit autoxidation. As such, at least one weak O–H bond...
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Vibrational characterization of a diiron bridging hydride complex – a model for hydrogen catalysis

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01290D, Edge Article
Open Access
Leland Bruce Gee, Vladimir Pelmenschikov, Hongxin Wang, Nakul Mishra, Yu-Chiao Liu, Yoshitaka Yoda, Kenji TAMASAKU, Ming-Hsi Chiang, Stephen P Cramer
A diiron complex containing a bridging hydride and a protonated terminal thiolate of the form [(μ,κ2-bdtH)(μ-PPh2)(μ-H)Fe2(CO)5]+ has been investigated through 57Fe nuclear resonance vibrational spectroscopy (NRVS) and interpreted using density...
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Direct and quantitative monitoring of catalytic organic reactions under heterogeneous conditions using direct analysis in real time mass spectrometry

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00021C, Edge Article
Open Access
Koichiro Masuda, Shū Kobayashi
A direct and quantitative method for monitoring heterogeneous organic reactions has been developed by using direct analysis in real time mass spectrometry (DART-MS) with an isotope-labeled reaction product as an internal standard.
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Cancer cell discrimination and dynamic viability monitoring through wash-free bioimaging using AIEgens

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01213K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ruoyao Zhang, Guangle Niu, Qing Lu, Xiaolin Huang, Joe H. C. Chau, Ryan T. K. Kwok, Xiaoqiang Yu, Min-Hui Li, Jacky W. Y. Lam, Ben Zhong Tang
We present a series of AIEgens for cancer cell discrimination and dynamic viability monitoring.
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Electrochemical Radical Reactions of Alkyl Iodides: A Highly Efficient, Clean, Green Alternative to Tin Reagents

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01694B, Edge Article
Open Access
diyuan Li, Tsz-Kan Ma, Reuben J Scott, Jonathan David Wilden
An electrochemical ‘redox-relay’ system has been developed which allows the generation of C-centered radicals. Intermolecular ‘tin-like’ radical reactions can subsequently be conducted under the most benign of conditions. The yields...
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Interim report : first steps for improving educational opportunities for Aboriginal and Torres Strait Islander students / House of Representatives Standing Committee on Indigenous Affairs

Australia. Parliament. House of Representatives. Standing Committee on Indigenous Affairs, author, issuing body




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Professional development, instructional intelligence and teacher emotions : a mixed methods study of a four-year systemic change initiative / by Rebecca Ann Saunders

Saunders, Rebecca Ann, author




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The abandoned generation : democracy beyond the culture of fear / Henry A. Giroux

Giroux, Henry A




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A study on the effectiveness of anonymous agents in computer-supported collaborative learning (CSCL) for the facilitation of student learning and execution of team projects / Wudhijaya Philuek

Philuek, Wudhijaya, author




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Educational psychology : windows on classrooms / Paul Eggen, Don Kauchak

Eggen, Paul D., 1940- author




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The power of education : from surviving to thriving : educational opportunities for Aboriginal and Torres Strait Islander students / House of Representatives, Standing Committee on Indigenous Affairs

Australia. Parliament. House of Representatives. Standing Committee on Indigenous Affairs




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Turning on learning : five approaches for multicultural teaching plans for race, class, gender, and disability / Carl A. Grant, Christine E. Sleeter

Grant, Carl A., author




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Reimagining the purpose of schools and educational organisations : developing critical thinking, agency, beliefs in schools and educational organisations / Anthony Montgomery, Ian Kehoe, editors

International Conference on Reimagining Schooling (1st : 2013 : Thessaloniki, Greece),




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Implementing change : patterns, principles, and potholes / Gene E Hall, President, Concerns Based Systems, Inc., Professor Emeritus, University of Nevada, Las Vegas, Shirley M. Hord, Scholar Laureate, Learning Forward ; forewords by Bruce Joyce, Barrie Be

Hall, Gene E., 1941- author




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Topology Optimization Design of Heterogeneous Materials and Structures


 
This book pursues optimal design from the perspective of mechanical properties and resistance to failure caused by cracks and fatigue. The book abandons the scale separation hypothesis and takes up phase-field modeling, which is at the cutting edge of research and is of high industrial and practical relevance. Part 1 starts by testing the limits of the homogenization-based approach when the size of the representative volume element is non-negligible

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Human Genetics and Genomics: A Practical Guide


 
Finally meeting the need for a laboratory manual on human genetics, this practical guide is the perfect companion title to all major standard textbooks on the subject. The authors all have a high-level research background and are actively involved in teaching and counseling.
Based on a standard curriculum in human genetics, each chapter equals one practical unit of the course and topics range from basics in human inheritance to genetics in major disease

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Advances in computational intelligence techniques Shruti Jain, Meenakshi Sood, Sudip Paul, editors

Online Resource




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Next-Generation Machine Learning with Spark: Covers XGBoost, LightGBM, Spark NLP, Distributed Deep Learning with Keras, and More / Butch Quinto

Online Resource




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Maple in mathematics education and research: Third Maple Conference, MC 2019, Waterloo, Ontario, Canada, October 15-17, 2019, Proceedings / Jürgen Gerhard, Ilias Kotsireas (eds.)

Online Resource




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Genetic and evolutionary computing: proceedings of the thirteenth International Conference on Genetic and Evolutionary Computing, November 1-3, 2019, Qingdao, China / Jeng-Shyang Pan, Jerry Chun-Wei Lin, Yongquan Liang, Shu-Chuan Chu, editors

Online Resource




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The tobacco plant genome / Nikolai V. Ivanov, Nicolas Sierro, Manuel C. Peitsch, editors

Online Resource




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Orthogonal polynomials: 2nd AIMS-Volkswagen Stiftung Workshop, Douala, Cameroon, 5-12 October 2018 / Mama Foupouagnigni, Wolfram Koepf, editors

Online Resource




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Social networking and computational intelligence: proceedings of SCI-2018 / Rajesh Kumar Shukla, Jitendra Agrawal, Sanjeev Sharma, Narendra S. Chaudhari, K.K. Shukla, editors

Online Resource




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General type-2 fuzzy logic in dynamic parameter adaptation for the harmony search algorithm / Fevrier Valdez, Cinthia Peraza, Oscar Castillo

Online Resource




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Climate change perception and changing agents in Africa & South Asia / edited by Suiven John Paul Tume & Vincent Itai Tanyanyiwa

Hayden Library - QC903.2.A35 C55 2018




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Cyber security intelligence and analytics: proceedings of the 2020 International Conference on Cyber Security Intelligence and Analytics (CSIA 2020). / Zheng Xu, Reza M. Parizi, Mohammad Hammoudeh, Octavio Loyola-González, editors

Online Resource




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Polynomial rings and affine algebraic geometry: PRAAG 2018, Tokyo, Japan, February 12-16 / Shigeru Kuroda, Nobuharu Onoda, Gene Freudenburg, editors

Online Resource




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Proceedings of the third International Conference on Computational Intelligence and Informatics: ICCII 2018 / edited by K. Srujan Raju, A. Govardhan, B. Padmaja Rani, R. Sridevi, M. Ramakrishna Murty

Online Resource




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The citrus genome Alessandra Gentile, Stefano La Malfa, Ziniu Deng, editors

Online Resource




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Regenerating Japan: organicism, modernism and national destiny in Oka Asajiro's evolution and human life / Gregory Sullivan

Hayden Library - QH333.S85 2018




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Statistical modeling in biomedical research: contemporary topics and voices in the field / Yichuan Zhao, Ding-Geng (Din) Chen, editors

Online Resource




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Cyber security intelligence and analytics: Proceedings of the 2020 International Conference on Cyber Security Intelligence and Analytics (CSIA 2020). / Zheng Xu, Reza M. Parizi, Mohammad Hammoudeh, Octavio Loyola-González, editors

Online Resource




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Machine learning for intelligent decision science Jitendra Kumar Rout, Minakhi Rout, Himansu Das, editors

Online Resource




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Proceedings of the International Conference on Artificial Intelligence and Computer Vision (AICV2020 Aboul-Ella Hassanien, Ahmad Taher Azar, Tarek Gaber, Diego Oliva, Fahmy M. Tolba, editors

Online Resource




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Thermophysical Basis of Energy Technologies (TBET 2019): 09-11 October 2019, Tomsk, Russia / editors, Geniy Kuznetsov, Dmitry Feoktistov and Evgeniya Orlova

Online Resource




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Continuum mechanics, applied mathematics and scientific computing: a Liber Amicorum to Professor Godunov / Gennadii V. Demidenko, Evgeniy Romenski, Eleuterio Toro, Michael Dumbser, editors

Online Resource




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Decoding the HIV genome

Learn how a UNC team became the first to unlock this mystery at December's Current Science Forum.




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Star Families: Greek Myths and Legends

This might be a fun choice for any Percy Jackson fans out there!