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Magic effect of diphenylprolinol silyl ether for the enantioselective allenation of 2-alkynals

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00984C, Research Article
Guolin Wu, Zhen Liu, Shiwen Fan, Wenyao Li, Xue Zhang, Hui Qian, Shengming Ma
Chiral diphenylprolinol silyl ethers have been successfully identified for the enantioselective allenation reaction of terminal alkynes and 2-alkynals, delivering a diverse set of chiral allenynes with high efficiency.
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Palladium-catalyzed cascade decarboxylative cyclization of alkyne-tethered aryl iodides with o-bromobenzoic acids for the synthesis of fused isoquinolinones

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01573H, Research Article
Zhaolin Quan, Yubo Duan, Zhengkai Chen
A straightforward approach for the preparation of fused isoquinolinone derivatives via palladium-catalyzed cascade decarboxylative cyclization of alkyne-tethered aryl iodides with o-bromobenzoic acids is described.
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Intermolecular Defluorinative 1,2-Diamination of Fluoroalkenyl Iodides with Sulfonamides: Synthesis of Acyclic and Cyclic Fluorinated 1,2-Enediamines

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01913J, Research Article
Xue-Qiang Chu, Yu-Lan Chen, Chi Zhang, Xue-Ying Huang, Yu Ding, Danhua Ge, Zhi-Liang Shen
Alkene diamination represents one of the most straightforward strategies for 1,2-diamine derivatives synthesis. However, transition-metal-free 1,2-diamination of fluoroalkenes has been less studied. Here we report an intermolecular defluorinative vicinal diamination...
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Why everyone is talking about the Big Temple 

Mani Ratnam’s Ponniyin Selvan has brought this Chola architectural marvel under the spotlight once again



  • History & Culture

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Graphene-supported organoiridium clusters catalyze N-alkylation of amines via hydrogen borrowing reaction

RSC Adv., 2024, 14,35163-35171
DOI: 10.1039/D4RA06595F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tsun-Ren Chen, Siang-Yu Chiu, Wen-Jen Lee, Yi-Siou Tsai, Yu-Sheng Huang
Graphene-supported organic iridium clusters (GSOIC) exhibit excellent N-alkylation on various substrates under green processes.
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Enhancing skin delivery of tranexamic acid via esterification: synthesis and evaluation of alkyl ester derivatives

RSC Adv., 2024, 14,34996-35004
DOI: 10.1039/D4RA06266C, Paper
Open Access
Yutong Zeng, Mengrui Ma, Yongfeng Chen, Huichao Xie, Pingtian Ding, Keda Zhang
An alkyl esterification prodrug strategy enhances skin penetration and deposition of tranexamic acid.
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A safe and efficient synthesis of N-Boc-β3-amino acid methyl esters from α-amino acids: applications in the formal synthesis of sedum alkaloids

RSC Adv., 2024, 14,36016-36021
DOI: 10.1039/D4RA07506D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bohua Long, Lijie Ren, Mengmeng Jiang, Shengquan Hu, Qianqian Jiang, Limin Li, Xuanluan Chen, Zhengzhi Wu
β3-Amino acids are essential components in the synthesis of biologically active compounds.
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After raping and murdering doctor, accused went to sleep, washed his clothes: Kolkata Police

West Bengal Chief Minister Mamata Banerjee vowed to seek death penalty for the perpetrator in the Kolkata doctor rape and murder case




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Kolkata doctor rape and murder: Victim had 10 injuries, death due to throttling and smothering

Signs of sexual assault evident in inquest and post-mortem report




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RJD leader Pankaj Yadav shot in Bihar on morning walk

The attack on Pankaj Yadav, a state general secretary of the RJD, took place in Safiabad locality




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Police constable suspended for stalking woman in Ratlam




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NSCN (I-M) seeks third-party intervention to break talks deadlock

Accusing the Centre of betraying the Framework Agreement of 2015, the Naga extremist group led by Thuingaleng Muivah threatened to return to violent ways




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Race walker Suraj loses Paris ticket as World Athletics cancels results of Nationals

World body marks results of Indian meet as ‘invalid’)




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PIX: Diwali with the Tendulkars

Legendary cricketer Sachin Tendulkar took to X to extend his heartfelt wishes, emphasising the significance of togetherness and spreading happiness during this festive season.




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Fight over including carbon border tax in agenda delays climate talks on day one

Agenda disputes are common at UN climate conferences but this one is especially significant as countries have limited time to agree on a new climate finance goal.




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Trump talks Xi, tariffs and aliens in freewheeling Joe Rogan podcast

The conversation stretched long enough that Trump ended up hours late for a rally in swing-state Michigan, where hundreds of supporters trickled out of the venue as temperatures dropped while waiting for him to arrive




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World Bank in talks to help finance $28 billion Turkish energy upgrade, Anadolu reports

Humberto Lopez was quoted on Saturday as saying the World Bank was in talks with Turkey's ministry of energy about the matter



  • Money & Banking

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UN climate talks to focus on money to help poor nations cut carbon pollution

About 77% of the heat-trapping gas in the atmosphere now comes from the G20 rich nations, many of whom are now cutting back on their pollution, something that is not happening in most poor nations or China




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Harry Belafonte: 1927-2023 | Staying alive in Kolkata

With American singer Harry Belafonte passing away at 96, here’s looking back at the hold he had on the country  




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Write Alt Text Like You’re Talking To A Friend

“There was this dog wearing safety glasses, surrounded by chemistry equipment, saying ‘I have no idea what I’m doing.’”




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Warriors shake off a fighting Malappuram, enter SLK semifinal




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Sai Silks Kalamandir to launch ethnic silver jewellery under ‘Rasamayi’

The new segment will cater to connoisseurs of fine jewellery seeking unique and sophisticated pieces



  • Gold & Silver

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Milk and Dairy Products

Abstract: China has a long history of dairy production and consumption. Milk was appreciated for its culinary and medicinal uses, with successive dynasties expanding production and acquisition of pastoral animals. Now China is one of the world’s great dairy nations. Dairy was first commercially available in cities, but advances in packing and shipping have

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Bulk photovoltaic effect in a zero-dimensional room-temperature molecular ferroelectric [C8N2H22]1.5[Bi2I9]

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02698E, Paper
Zhibo Chen, Tianhong Luo, Jinrong Wen, Zhanqiang Liu, Jingshan Hou, Yongzheng Fang, Ganghua Zhang
Non-toxic molecular ferroelectrics have attracted significant interest due to their unique flexibility, low costs, and environmental friendliness. However, the variety of such materials with narrow bandgaps and above room temperature...
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Alkyl initiated ring opening polymerization of lactide by indium complexes supported by NCN pincer ligands

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02603A, Paper
Takeo Iwase, Afagh Habibzadeh, Chatura Goonesinghe, Kudzanai Nyamayaro, Joseph Chang, Jason Wai-Lok Poon, Salik Hasan Rushdy, Justin Koh, Brian O. Patrick, Parisa Mehrkhodavandi
Alkyl-indium NCN pincer complexes supported by amine donors are significantly more active for lactide polymerization than the analogous imine derivatives.
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Bicyclic (Alkyl)(Amino)Carbenes (BICAACs): Synthesis, Characteristics, and Applications

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02696A, Perspective
Ankita Sharma, Unnikrishnan Nair K, Subrata Kundu
Carbenes in general and isolable NHCs (N-heterocyclic carbenes) in particular have been useful ligands in recent years. The emergence of CAACs [cyclic(alkyl)(amino)carbenes], BICAACs [bicyclic(alkyl)(amino)carbenes], and many other carbenes has marked...
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Syntheses and structures of dimesitylphosphinite complexes of alkali metals and their catalytic activity in hydrophosphorylation reactions

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02721C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Benjamin E. Fener, Philipp Schüler, Phil Liebing, Helmar Görls, Matthias Westerhausen
The diarylphosphinite complexes of the alkali metals exhibit a broad structural variety. Especially for potassium dimesitylphosphinite, the heterocubane cage can be broken down into dimeric K2O2 units by adding oligodentate ether molecules.
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Stable homogeneous silver(I) catalysts for the highly efficient cycloaddition of azides onto terminal alkynes in water

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02825B, Communication
Meysam Kakavand, Anna Kozakiewicz, Abdollah Neshat
To develop stable and efficient silver(I) catalysts and evaluate the role of sulfur and phosphorus donor ligands in the catalytic cycloaddition of selected organic azides and alkynes (AAC), a series...
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Advances in metal–organic frameworks for optically selective alkaline phosphatase activity monitoring: a perspective

Dalton Trans., 2024, 53,17742-17755
DOI: 10.1039/D4DT01727G, Perspective
Eduarda Andrade, Filipe A. Almeida Paz, Flávio Figueira
MOFs can play three essential roles in ALP monitoring: they can serve as fluorescent probes, function in oxidation or peroxidation mechanisms, or combine both processes.
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Talking about menopause

Media explore gender disparity largely, but it has failed to explicitly probe this transformative stage in a woman’s life




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BJP MLA B.P. Yatnal walks out of event after crowd objects to political speech over mention of Waqf land row

Mr. Yatnal raised the issue of waqf during an Allammaprabhu temple event




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Rajkumar Patil Telkur refutes allegations against KKHRACS




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Environmental and private property contamination following the Norfolk Southern chemical spill and chemical fires in Ohio

Environ. Sci.: Water Res. Technol., 2024, 10,3007-3023
DOI: 10.1039/D4EW00456F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Paula B. Coelho, Gracie Fitzgerald, Kristofer Isaacson, Rasul Diop, Gouri Prabhakar, Stephanie Heffner, Akshat Verma, Jeffrey P. Youngblood, Youn Jeong Choi, Stefanie Surdyka, Samuel A. Spears, Marty D. Frisbee, Katherine R. Del Real, Lauren A. Gustafson, Ana María Núñez-Torres, Caitlin R. Proctor, Linda S. Lee, Heather D. Whitehead, Kyle Doudrick, Brock A. Harpur, Andrew J. Whelton
In February 2023, a train derailment in Ohio caused a chemical spill and fires releasing contaminants into the air, soil, waterways, and buildings.
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Kulkarni boost for Mumbai




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Fabulous, brilliant, says Tendulkar on Mumbai’s Ranji Trophy win




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Facing the camera is more challenging than playing the game: Tendulkar




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The Pakistan and IMF talks: What lies ahead?

Why was the Extended Fund Facility (EFF) signed between the two? Why is IMF important for Pakistan’s economy?




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Twitter claims Musk is ‘slow-walking’ trial over $44 billion deal

The two sides will make their arguments about the trial's proposed start date to a Delaware Court of Chancery judge on Tuesday




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Putin heads to Tehran for talks with leaders of Iran, Turkey

The gathering has symbolic meaning for Vladimir Putin’s domestic audience as well, showing off Russia’s international clout even as it grows increasingly isolated and plunges deeper into confrontation with the West




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India, Australia push forward on CECA talks




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Harvestec launches online learning platform for rice milling, bulk storage technology

The subjects are rarely discussed and have great potential, says its MD Munishwar Vasudeva




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Talking health to youth, creatively

Talking about diabetes and heart disease to young people need not be in obscure medical terms, but can take a fun route




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Talking to the tightrope

A tightrope walker from Chhattisgarh performs on the streets of Tiruchi




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I was raised by one family, but I think it represents so many of our families: Priyanka Mattoo, author of Bird Milk and Mosquito Bones

Priyanka Mattoo on her journey across countries, and why she sees herself as the ‘megaphone’ for a culture




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The milk-sisters of Oman | Interview with author Jokha Alharthi on her new novel Silken Gazelles

Omani society is as multifaceted and paradoxical as any other, filled with competing narratives and lived realities; the female friendships in the novel are a reflection of the same, says the International Man Booker-winning writer




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Efficient 1.77 eV-bandgap perovskite and all-perovskite tandem solar cells enabled by long-alkyl phosphonic acid

Energy Environ. Sci., 2024, 17,8219-8227
DOI: 10.1039/D4EE02483D, Paper
Hongling Guan, Shiqiang Fu, Guojun Zeng, Weiqing Chen, Chen Wang, Hongsen Cui, Dexin Pu, Peng Jia, Weiwei Meng, Guojia Fang, Weijun Ke
Incorporating dodecylphosphonic acid additives into 1.77 eV-bandgap perovskites enabled single-junction solar cells to achieve a PCE of 20.2%. Tandem cells further reached impressive PCEs of 27.41% (two-terminal) and 28.65% (four-terminal).
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Reduction of bulk and interface defects via photo-annealing treatment for high-efficiency antimony selenide solar cells

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE02877E, Paper
Xiaoyang Liang, Xinhua Wang, Qiwei Chang, Bingxin Yang, Wei Dang, Zheng Zhang, Yingnan Guo, Lin Yang, Zhiqiang Li
A novel interface engineering strategy with a photo-annealing treatment is proposed for regulating the interface of the Sb2Se3/CdS heterojunction.
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Weaving electron-rich alkynes: a durable in situ skin for stabilizing zinc anodes

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03164D, Paper
Xin Liu, Weimian Zhang, Ying Liu, Xiaodong Li, Deyi Zhang, Kun Wang, Lifeng Liu, Changshui Huang
An electron-rich alkyne of thiophdiyne (e-TDYP) is engineered in situ onto a zinc anode to regulate the EDL properties. The synergy between the conjugated thiophene and alkyne groups of e-TDYP facilitates the desolvation and ion-capture.
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​Sharing resources: on fishermen and the Palk Bay dispute 

Fishermen from both sides of Palk Bay must meet to resolve dispute




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Human breast milk-derived phospholipid DOPE ameliorates intestinal injury associated with NEC by inhibiting ferroptosis

Food Funct., 2024, 15,10811-10822
DOI: 10.1039/D4FO03904A, Paper
Yanjie Chen, Wenjuan Chen, Yu Dai, Xiangyun Yan, Chengyao Jiang, Fan Zhang, Min Zhang, Xiaoshan Hu, Juyi Zhao, Tingyue Wu, Shushu Li, Shuping Han, Xiaohui Chen
Human breast milk-derived dioleoyl phosphatidylethanolamine (DOPE) mitigates intestinal dysfunction in Necrotizing Enterocolitis (NEC) through the suppression of ferroptosis.
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