unique

Penn State Health military couple highlight veterans' unique care needs

Veterans face unique health challenges, and Penn State Health is committed to providing care respecting their experiences. Veterans/employees Mark and Julie Chesney advocate for awareness of those health needs.




unique

Podi + Aloo = A Flavour Bomb! Try This Unique Sabzi Recipe For Your Next Meal

Podi Aloo gives an interesting twist to regular aloo sabzi. To make it, baby potatoes are tossed in flavourful masalas, including podi, giving this sabzi its distinct taste




unique

DNREC, DDA Celebrate World Wetlands Day with Agreement to Manage, Protect Delaware’s Unique Wetland Communities

The Delaware Department of Natural Resources and Environmental Control (DNREC) and the Department of Agriculture (DDA) Forest Service are to celebrate World Wetlands Day today, Thursday, Feb. 2, by signing a cooperative agreement to manage and protect unique wetland communities that occur on state-owned forest, park and wildlife lands.




unique

57+ unique gift ideas for Dad that are way better than a tie

Browse our favorite dad gift ideas for the holiday season. Try to think outside the gift card this year.




unique

In satire Rumours, diplomatic communiques collide with the end times

A stellar cast play leaders of G7 countries facing an existential crisis in Rumours, a smart film about communication, diplomatic nonsense and not coping, says Simon Ings





unique

CodeSOD: Uniquely Validated

There's the potential for endless installments of "programmers not understanding how UUIDs work." Frankly, I think the fact that we represent them as human readable strings is part of the problem; sure, it's readable, but conceals the fact that it's just a large integer.

Which brings us to this snippet, from Capybara James.

    if (!StringUtils.hasLength(uuid) || uuid.length() != 36) {
        throw new RequestParameterNotFoundException(ErrorCodeCostants.UUID_MANDATORY_OR_FORMAT);
    }

StringUtils.hasLength comes from the Spring library, and it's a simple "is not null or empty" check. So- we're testing to see if a string is null or empty, or isn't exactly 36 characters long. That tells us the input is bad, so we throw a RequestParameterNotFoundException, along with an error code.

So, as already pointed out, a UUID is just a large integer that we render as a 36 character string, and there are better ways to validate a UUID. But this also will accept any 36 character string- as long as you've got 36 characters, we'll call it a UUID. "This is valid, really valid, dumbass" is now a valid UUID.

With that in mind, I also like the bonus of it not distinguishing between whether or not the input was missing or invalid, because that'll make it real easy for users to understand why their input is getting rejected.

[Advertisement] ProGet’s got you covered with security and access controls on your NuGet feeds. Learn more.




unique

Press Release: Sustainable Development Goals Offer Unique Opportunity to Transform Management of Critical Water Resources

Targets that promote efficient, nationally and locally appropriate water use will be key to achieving the SDGs.

The post Press Release: Sustainable Development Goals Offer Unique Opportunity to Transform Management of Critical Water Resources first appeared on International Water Management Institute (IWMI).



  • Press releases
  • Sustainable Development Goals (SDG)
  • sustainable water resources development
  • water for food

unique

The unique challenge of implementing anticipatory action in refugee and IDP hosting communities 

Creating measures that balance the needs of refugees and local populations during disaster preparedness presents a complex issue.

The post The unique challenge of implementing anticipatory action in refugee and IDP hosting communities  first appeared on International Water Management Institute (IWMI).




unique

Beyond the Charts: Why Inuit Kids Need Unique Growth Standard

Inuit children, who are Indigenous peoples of the Arctic and subarctic regions, may have different head size norms due to genetic and environmental factors.





unique

Sanju Samson Birthday: Unique record held by Kerala cricketer in T20I that even MS Dhoni couldn't attain

Samson's journey has not been easy. New T20 captain Suryakumar Yadav and head coach Gautam Gambhir gave him confidence after a disappointing tour of Sri Lanka earlier this year when he struggled with form




unique

‘Main aisa kyon hoon’: Exploring the unique factor

David J Linden investigates what makes us human and what makes us distinctly, immutably ourselves




unique

Emerging polymeric materials for treatment of oral diseases: design strategy towards a unique oral environment

Chem. Soc. Rev., 2024, 53,3273-3301
DOI: 10.1039/D3CS01039B, Review Article
Open Access
Bo Jia, Beibei Zhang, Jianhua Li, Jinlong Qin, Yisheng Huang, Mingshu Huang, Yue Ming, Jingjing Jiang, Ran Chen, Yufen Xiao, Jianzhong Du
We highlight the recent progress and design strategies of polymeric materials with tailored functions to overcome the highly movable and wet, microbial and inflammatory environment in the oral cavity for treatment of oral diseases.
The content of this RSS Feed (c) The Royal Society of Chemistry




unique

A unique approach to nurturing Indian motorsport engineers — the L.I.M.E. way

United Motorsports Academy — founded by former Red Bull engineer Sangodkar, and Rane — provides a two-week course to qualify for an internship in the IRL and F4 series as part of a scholarship called Launchpad for Indian Motorsports Engineers; students learn about the basics and intricacies of the sport which gives them an opening into the world of fast-paced action




unique

What makes Kongunadu veeran soru and naatu kozhi saaru so unique?

Game for some flavourful veeran soru and naatu kozhi saaru? The ongoing Kongunadu food festival at Gokulam Park showcases some most-loved dishes and culinary traditions from the region



  • Life & Style

unique

The Conservatory, Bengaluru’s latest event space that plays host to unique food popups is also an ode to Lalbagh

So far the venue has played host to a variety of events including a Thai breakfast popup, a tapas do, where the space was set like a tapas bar, and a Sri Lankan food experience among others



  • Life & Style

unique

Curating unique travel experiences in Udhagamandalam

Accidental hoteliers Vijay Prabhu and Meeta Prabhu of Littlearth chain of boutique hotels in Udhagamandalam give a push to unique travel experiences



  • Life & Style

unique

Attractive and Completely unique Wedding Options

There’s nothing a lot better than a wedding that feels completely unique to you. This makes the celebration even more personal, so we are rounding up some of our favourite lovely marriage ceremony ideas to make your big day time truly wonderful! The Cutest Table Numbers Which can be Guaranteed to Make Your Wedding Come […]




unique

Small animals with unique chemistry – the natural product chemistry of Collembola

Nat. Prod. Rep., 2024, Advance Article
DOI: 10.1039/D4NP00049H, Highlight
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Anton Möllerke, Stefan Schulz
The secondary metabolites of springtails (Collembola) include defensive compounds, cuticular lipids, and semiochemicals, many of which are not known from other natural sources. The springtail chemistry differs largely from that of insects.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




unique

Combination of dimensional reduction and active site addition strategies for preparing unique {RE9}-cluster-based MOFs: efficient CO2 fixation and Knoevenagel condensation

Inorg. Chem. Front., 2024, 11,2071-2080
DOI: 10.1039/D3QI02527F, Research Article
Ying Zhao, Dan Wu, Yidan Qiao, Guo-Ping Yang, Lu-Fang Ma, Yao-Yu Wang
A series of 2D {RE9}-cluster-based rare-earth MOFs were built by dimensional reduction and active site addition strategies. They exhibit excellent catalytic activity in CO2 fixation and Knoevenagel condensation under mild conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry




unique

Electrochemical trifluoromethylation of alkynes: the unique role of DMSO as a masking auxiliary

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06780K, Edge Article
Open Access
Jihoon Jang, Ho Seong Hwang, Haeryeong Jeong, Eun Jin Cho
An electrochemical trifluoromethylation method for terminal alkynes has been developed, facilitating the synthesis of CF3-alkynes with DMSO as a masking auxiliary.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




unique

Rare-earth metal complexes bearing electrophilic and nucleophilic carbon centres and their unique reactivity patterns towards pyridine derivatives

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04197F, Edge Article
Open Access
weikang Wu, Thayalan Rajeshkumar, Shan Zhu, Fuxiang Chai, Dongjing Hong, ZeMing Huang, Qingbing Yuan, Laurent Maron, Shaowu Wang
The rare-earth metal dialkyl complexes (κ2-L1)RE(CH2SiMe3)2(THF)2 [RE = Lu(1a), Yb(1b), Er(1c), Y(1d), Dy(1e)] (L1 = 1-(2-N-C5H10NCH2CH2)-3-(2,6-iPr2C6H3N=CH)-C8H4N) and the rare-earth metal monoalkyl complexes (κ2-L1)2RE(CH2SiMe3)(THF)n [n = 0, RE = Lu(2a), Yb(2b);...
The content of this RSS Feed (c) The Royal Society of Chemistry




unique

Study unravels the recipe that gives mushk budiji rice its unique aroma

Researchers say the rice variety’s export potential can be maximised by cultivating it in places where its flavour compounds are expressed the most




unique

An octanuclear 3-phenyl-5-(2-pyridyl)pyrazolate/phenylsilsesquioxane complex: synthesis, unique structure, and catalytic activity

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02690J, Communication
Alexey Bilyachenko, Victor N Khrustalev, Zhibin Huang, Lidia S. Shul'pina, Pavel Dorovatovskii, Elena Shubina, Nikolay S. Ikonnikov, Nikolai N. Lobanov, Karim G. Rahimov, Di Sun
First metallasilsesquioxane bearing pyrazolylpyridine ligands, Cu8-based complex 1, adopts cage structure with two zigzag-like copper tetramers sandwiched by two cyclic Si5 silsesquioxane ligands. Four 3-phenyl-5-(2-pyridyl)pyrazolate ligands in 1 exhibit dual...
The content of this RSS Feed (c) The Royal Society of Chemistry




unique

Border-Gavaskar Trophy: Australian opener McSweeney braces for "unique" Bumrah challenge

McSweeney was drafted into the Australia squad after a slew of impressive performances in the Sheffield Shield tournament and in the recent ‘A’ series against India




unique

I find Ashwin very unique, says Paras Mhambrey

Former bowling coach looks back at his stint, the process that culminated with India winning the T20 World Cup, the interesting conversations and the road ahead for fast bowlers in the country




unique

Unique silica enclosures form on micelles

Dodecahedral ‘silicages’ could carry drugs or diagnostic agents




unique

McSweeney gearing up for 'unique' Bumrah challenge

Australia opener Nathan McSweeney is gearing up for a challenging debut against India's premier pacer Jasprit Bumrah in the upcoming Border-Gavaskar Trophy.




unique

Sonam Kapoor Ahuja’s Unique Outfits In Throwback Pictures Are What We All Have Our Eyes On!

Sonam Kapoor Ahuja is that one actress in the Bollywood industry, who is always making headlines when it comes to fashion. From her airport looks in casuals to her experimental outfits in events or other public appearances, each outfit of




unique

Sobhita Dhulipala Will Convince You To Up Your Saree Fashion Game And Get A Unique Photoshoot Done

Sobhita Dhulipala's Instagram feed is lit up with perceptive photoshoots. She looks striking in each picture of hers and particularly her sarees looks are what we find the most interesting. Sobhita has sported sarees on a number of occasions




unique

Unique study of net evaporation at a hydroelectric facility in Canada

A first-of-its-kind study of net evaporation at a hydroelectric facility reveals that the project has very little effect on the loss of water to the atmosphere as compared with pre-impoundment conditions.




unique

Pink: Battling COVID-19 with my son was terrifying. But my experience isn't unique.

I know you would do anything to protect your own child, so let’s make sure every mama has the same opportunity and resources to protect theirs.




unique

Unique Country, Unique Scene: The Business of EDM in Canada

Severine Erickson is the president of the recently-launched Triple A Talent, a Vancouver-based artist management and booking agency specializing in the electronic music scene. Severine explains how negative experiences with agents inspired him and the other Triple A co-founders to start their own company with a plan to do things differently. Severine also discusses the unique aspects of being an agent in the EDM scene compared to other genres, the health of underground EDM in Canada, and more.

http://canadianmusician.com http://triplea.agency/

This episode is sponsored by Bandzoogle. Try it free for 30 days and use the promo code “CMPOD” to get 15% off your first year of any subscription. https://bandzoogle.com/?pc=cmpod




unique

South Florida prepares for unique hurricane season...


South Florida prepares for unique hurricane season...


(Third column, 7th story, link)





unique

Australia’s unique approach to helping the unemployed has delivered good results but challenges remain, says OECD

Australia’s labour market reforms over the past 15 years have boosted employment and cut welfare benefit dependency.




unique

Gokul Anandayuvaraj is the Unique Entrepreneur with a Progressive Mindset and Mission

Gokul Anandayuvaraj, the founder and CEO of VINVELI, is one such entrepreneur and tech innovator. From his consistent hard work and contribution, he has been inspiring millions of engineers and budding entrepreneurs all over the world, especially in the field of aerospace.




unique

Hyundai Five Unique Car Finance Schemes: हुंडई ने की 5 यूनीक कार फाइनेंस स्कीम की शुरुआत

कोरियन कार निर्माता कंपनी हुंडई ने भारत में ग्राहकों के लिए पांच तरह ही कार फाइनेंस स्कीम शुरू करने की घोषणा की है। कंपनी का कहना है इन स्कीम की मदद से वह अपने ग्राहकों को ज्यादा से ज्यादा सुविधा पहुंचाने की कोशिश कर रही है।




unique

Mammootty's The Priest Is A Unique Horror Thriller, Reveals This Team Member!

The Priest, the upcoming Mammootty starrer is one of the most-awaited upcoming films of Malayalam cinema. The shooting of the much-awaited project has been put on a hold now due to the all India lockdown. As per the latest updates, The




unique

Hyundai Unique Finance Schemes Announced: Five Ways To Own A New Car

Hyundai India announces unique finance schemes for new vehicle ownership in the country. The new finance schemes are aimed to offer increased convenience and ease of ownership with new vehicle purchases.




unique

Sehwag had a unique technique with great balance, says Latif




unique

NGO charts unique way to induce people into donating

NGO charts unique way to induce people into donating




unique

Unique campaign by Punjab Police to make people 'stay at home' to combat COVID-19




unique

Structure of ClpC1-NTD in complex with the anti-TB natural product ecumicin reveals unique binding interactions

Comparison of the structures of ClpC1-Ecumicin and ClpC1-Rufomycin reveals unique interaction relevant to the mode of action.




unique

First synthesis of a unique icosahedral phase from the Khatyrka meteorite by shock-recovery experiment

Icosahedral quasicrystals (i-phases) in the Al–Cu–Fe system are of great interest because of their perfect quasicrystalline structure and natural occurrences in the Khatyrka meteorite. The natural quasicrystal of composition Al62Cu31Fe7, referred to as i-phase II, is unique because it deviates significantly from the stability field of i-phase and has not been synthesized in a laboratory setting to date. Synthetic i-phases formed in shock-recovery experiments present a novel strategy for exploring the stability of new quasicrystal compositions and prove the impact origin of natural quasicrystals. In this study, an Al–Cu–W graded density impactor (GDI, originally manufactured as a ramp-generating impactor but here used as a target) disk was shocked to sample a full range of Al/Cu starting ratios in an Fe-bearing 304 stainless-steel target chamber. In a strongly deformed region of the recovered sample, reactions between the GDI and the steel produced an assemblage of co-existing Al61.5Cu30.3Fe6.8Cr1.4 i-phase II + stolperite (β, AlCu) + khatyrkite (θ, Al2Cu), an exact match to the natural i-phase II assemblage in the meteorite. In a second experiment, the continuous interface between the GDI and steel formed another more Fe-rich quinary i-phase (Al68.6Fe14.5Cu11.2Cr4Ni1.8), together with stolperite and hollisterite (λ, Al13Fe4), which is the expected assemblage at phase equilibrium. This study is the first laboratory reproduction of i-phase II with its natural assemblage. It suggests that the field of thermodynamically stable icosahedrite (Al63Cu24Fe13) could separate into two disconnected fields under shock pressure above 20 GPa, leading to the co-existence of Fe-rich and Fe-poor i-phases like the case in Khatyrka. In light of this, shock-recovery experiments do indeed offer an efficient method of constraining the impact conditions recorded by quasicrystal-bearing meteorite, and exploring formation conditions and mechanisms leading to quasicrystals.




unique

What makes rainforests unique? History, not ecology.

History and geology, not current ecology, are likely what has made tropical forests so variable from site to site.

The post What makes rainforests unique? History, not ecology. appeared first on Smithsonian Insider.




unique

Golden Frogs with Unique Skin Microbes Survive Frog-Killing Fungus

A new study published this week in the Proceedings of the Royal Society by scientists at the Smithsonian Conservation Biology Institute (SCBI) found unique communities […]

The post Golden Frogs with Unique Skin Microbes Survive Frog-Killing Fungus appeared first on Smithsonian Insider.




unique

Locked and loaded: unique trigger design fires this ant’s snapping jaws

In conflicts between predators and prey, speed is a decided advantage, and evolution has given the trap-jaw ant a distinct advantage with spring-loaded jaws that […]

The post Locked and loaded: unique trigger design fires this ant’s snapping jaws appeared first on Smithsonian Insider.




unique

Structure of the N-terminal domain of ClpC1 in complex with the antituberculosis natural product ecumicin reveals unique binding interactions

The biological processes related to protein homeostasis in Mycobacterium tuberculosis, the etiologic agent of tuberculosis, have recently been established as critical pathways for therapeutic intervention. Proteins of particular interest are ClpC1 and the ClpC1–ClpP1–ClpP2 proteasome complex. The structure of the potent antituberculosis macrocyclic depsipeptide ecumicin complexed with the N-terminal domain of ClpC1 (ClpC1-NTD) is presented here. Crystals of the ClpC1-NTD–ecumicin complex were monoclinic (unit-cell parameters a = 80.0, b = 130.0, c = 112.0 Å, β = 90.07°; space group P21; 12 complexes per asymmetric unit) and diffracted to 2.5 Å resolution. The structure was solved by molecular replacement using the self-rotation function to resolve space-group ambiguities. The new structure of the ecumicin complex showed a unique 1:2 (target:ligand) stoichiometry exploiting the intramolecular dyad in the α-helical fold of the target N-terminal domain. The structure of the ecumicin complex unveiled extensive interactions in the uniquely extended N-terminus, a critical binding site for the known cyclopeptide complexes. This structure, in comparison with the previously reported rufomycin I complex, revealed unique features that could be relevant for understanding the mechanism of action of these potential antituberculosis drug leads. Comparison of the ecumicin complex and the ClpC1-NTD-L92S/L96P double-mutant structure with the available structures of rufomycin I and cyclomarin A complexes revealed a range of conformational changes available to this small N-terminal helical domain and the minor helical alterations involved in the antibiotic-resistance mechanism. The different modes of binding and structural alterations could be related to distinct modes of action.




unique

Elbows of extinct marsupial lion suggest unique hunting style

Scientists from the Universities of Bristol and Málaga have proposed that the long extinct marsupial lion hunted in a very unique way - by using its teeth to hold prey before dispatching them with its huge claws.

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  • Paleontology & Archaeology