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Trump team hostile to Chagos deal, claims Farage

The Reform UK leader said the agreement to hand over the islands is opposed in the United States.




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One dead following blasts at Brazil Supreme Court

Local officials told the AFP news agency that a body was found outside the building in an apparent attack.




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Booking.com’s DMA deadline is approaching — what can hoteliers expect?

On May 13th 2024, Booking.com was the only Online Travel Agency (OTA) to be designated as a “gatekeeper” under the EU’s new Digital Markets Act, meaning they had six months to comply with the law’s stringent regulations.




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One dead after two reported explosions near Brazil’s Supreme Court - Al Jazeera English

  1. One dead after two reported explosions near Brazil’s Supreme Court  Al Jazeera English
  2. Brazil: 1 killed in explosions outside Supreme Court; judges safely evacuated  Hindustan Times
  3. Video: Explosions Go Off Near Brazil’s Government Offices  The New York Times
  4. One dead following blasts at Brazil Supreme Court  BBC.com
  5. One dead after explosion takes place outside Brazil's Supreme Court  The Times of India





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Donald Trump Hires Elon Musk and Vivek Ramaswamy to Bring 'Drastic Change' to the U.S. Government — And Gives Them a 2 Year Deadline

Musk and Ramaswamy have to find ways to cut down on government spending and overall bureaucracy.




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ADM Naveen Babu Death: 'എനിക്ക് രണ്ട് ഒപ്പുണ്ട്'; നവീൻ ബാബുവിനെതിരെ പരാതി നൽകിയത് താനാണെന്ന് ഉറപ്പിച്ച് പ്രശാന്ത്

ADM Naveen Babu Death: എഡിഎം നവീൻ ബാബുവിന്റെ മരണത്തിൽ ആദ്യമായാണ് അന്വേഷണസംഘം പ്രശാന്തിന്റെ മൊഴി എടുത്തത്.  




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Organocatalyzed double dearomatization reaction of non-functionalized phenols and propargylic alcohols: the important regulating effect of steric hindrance

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00103F, Research Article
Xihong Liu, Boyan Zhu, Panpan Zhou, Jingying Zhang, Anqi Chu, Rui Wang
Steric hindrance-regulated double dearomatization reaction of non-functionalized phenols and propargylic alcohols for the efficient synthesis of polycyclic diketones is reported.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Electron donor–acceptor complex photoactivation for deaminative alkynylation, alkenylation and allenylation: a comprehensive study

Org. Chem. Front., 2024, 11,2231-2240
DOI: 10.1039/D4QO00177J, Research Article
Romain Lapierre, Lina Truong, Matthieu Hedouin, Hassan Oulyadi, Bruno Schiavi, Alexandre Jean, Philippe Jubault, Thomas Poisson
Herein, we disclose our study toward photoinduced deaminative alkynylation, alkenylation and allenylation.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A dearomatization–rearomatization strategy for construction of 4H-quinolizin-4-ones via C–H bond functionalization of pyridines

Org. Chem. Front., 2024, 11,2319-2325
DOI: 10.1039/D3QO01990J, Research Article
Dong Qiu, Yijin Su
Herein, the synthesis of 4H-quinolizin-4-ones from N-(2-methoxy-2-oxoethyl) pyridinium salts and alkenes through dearomative cycloaddition and rearomative ring expansion has been developed.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Fully atom-economic access to spiro-cyclic skeletons through photoredox-induced hydrogen transfer/Giese addition/dearomative cyclization/protonation cascade

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00317A, Research Article
Guohui Zeng, Hui Luo, Kai Jiang, Jianpeng Cai, Biaolin Yin
Amine-tethered spiro-cyclic skeletons were obtained through photo-induced 100%-atom-economic dearomatization, involving the cleavage of the α-C(sp3)–H of amines. Pentacyclic framework was achieved from pyridinyl ring within two steps.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Expedient deaminative phosphorylation and sulfonylation of benzylic tertiary amines enabled by difluorocarbene

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00412D, Research Article
Chengbo Li, Yu Guo, Jianke Su, Xinyuan Hu, Qingqing Xuan, Qiuling Song
A deaminative functionalization of aliphatic tertiary amines via the cleavage of C(sp3)–N bonds under transition metal-free conditions was disclosed, which goes through SN2 reaction with various phosphorus and sulfur nucleophiles.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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BRSV and AISF demand thorough probe into RGUKT student’s death




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KTR in Delhi to strike a deal with BJP to escape Formula-E probe: Bhatti

Deputy Chief Minister points to BRS call to Maharashtra voters not to vote for Congress




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'Any relief on bank guarantee will be provided across the sector': Scindia on Vodafone Idea request for waiver of bank guarantees for spectrum




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Vodafone Idea narrows Q2 loss to ₹7,176 crore




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Free and fair inquiry sought into death of snakebite victim in Srikakulam district

Son of the victim alleges that local medical and health officials misleading higher-ups regarding the incident




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No dearth of funds for development works: CM




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IL&FS debt resolution: NCLAT sets March 2025 deadline to lift moratorium on IL&FS entities

Some of the lenders had sought the tribunal’s approval to start proceedings under IBC for recovering dues from the 58 IL&FS entities




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Death of woman after delivery at private hospital in Dharmapuri sparks row; RDO holds inquiry




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Medical college student found dead 




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Prime Minister Internship Scheme: Youth registration deadline extended to November 15, says MCA

More than 5 lakh internship applications received so far from Youth 




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Vodafone Idea Q2 net loss narrows 17% to ₹7,175.9 crore

Subscriber base declines by 14 million users in the quarter




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Tell Everyone Your Startup Idea

This artice is a guest post from Joel Gascoigne. Joel is is the founder of Buffer, a smarter way to share great articles with friends and followers. He Tweets at @joelgascoigne and writes regularly on his blog about startups, life, learning and happiness. I was speaking at an event last week about the lessons I’ve learned along my startup journey, mostlyRead More →

The post Tell Everyone Your Startup Idea first appeared on Rob Walling - Serial Entrepreneur.




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How to Deal With Public Criticism

Every once in a while I receive an email from a reader/podcast listener that goes a little something like: I made a change to my [UX/UI/positioning/pricing/terms] and it seemed to go well. But out of my 900 customers, 3 wrote in with scathing emails (1 even raged at me on Twitter). It had a hugeRead More →

The post How to Deal With Public Criticism first appeared on Rob Walling - Serial Entrepreneur.




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No Compromise With The Culture of Death

Bioethicist Wesley J. Smith joins Fr. Barnabas on this last show of 2015 to discuss the alarming societal attitudes toward the value of a human life.




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When Killing Becomes Medicine: Fighting A Culture of Death

Bioethicist Wesley J. Smith joins Fr. Barnabas to discuss the growing problem of Euthanasia in our society.




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Binghamton University Expands Efforts to Protect Birds From Deadly Collisions

Glass windows are an invisible killer, resulting in billions of bird deaths in the U.S. each year. To prevent collisions on campus. Binghamton University, State University of New York has installed bird-safe windows.




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FTX sues Binance, alleging fraud in 2021 share repurchase deal

Bankrupt cryptocurrency exchange FTX has filed a lawsuit against



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Indian tourist found dead after falling down Samui waterfall

SURAT THANI - Searchers have found and recovered the body of an Indian tourist who fell from a cliff while walking to the top of a popular waterfall on Koh Samui.




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Foreigner blamed for Pattaya crash death

PATTAYA - A foreign woman has been arrested for crashing her car into a motorcycle, killing one person and injuring another.




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Новое видео THE OLD DEAD TREE

"The Lightest Straw", новое видео THE OLD DEAD TREE, доступно для просмотра ниже. Этот трек взят из нового альбома 'Second Thoughts', релиз которого намечен на шестое декабря на Season of Mist:

“Unpredictable”
“Don’t Waste Your Time”
“The Lightest Straw”
“Better Off Dead”
“Without A Second Thought”
“Luke”
“Story Of My Life”
“Fresh Start”
“I Wish I Could”
“The Trap”
“Solastalgia”
“OK”
“The Worst Is Yet To Come”
#The_Old_Dead_Tree #TheOldDeadTree #GothicMetal #Gothic_Metal
Видео: https://www.youtube.com/watch?v=x8KITCrV5dM






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Dear Hipsters, Stop.

Okay, okay. The merry-go-round horse is quirky and fun, but did you seriously have to put pegs on a beach cruiser? Neigh to you, sir.

~NSHA






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All the Best Black Friday Rug Deals to Shop Right Now

There's something for every style and budget. READ MORE...



  • Design Ideas
  • Black Friday & Cyber Monday 2024
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  • Decor & Accessories
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  • Shopping

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Dear, Beatrice, what we had was great, but the cello loves me more and has nicer in-laws.




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Ginsters owner fined £1.28m over worker death

Paul Clarke, 40, died in hospital after he was fatally crushed by the reversing lorry.




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Monfort optimistic about long-term Arenado deal

Rockies owner, chairman and CEO Dick Monfort expressed optimism that the team can reach a multi-year contract with third baseman Nolan Arenado, beyond the one-year, $26 million agreement that was finalized recently.




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Arenado won't set hard deadline on negotiations

Rockies third baseman Nolan Arenado said Thursday he won't make Opening Day a hard deadline for negotiations on a possible multiyear contract.




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Arenado: Manny deal 'really good for baseball'

The baseball field is Rockies third baseman Nolan Arenado's refuge from contract talks. But Tuesday's breaking news -- Manny Machado's 10-year, $300 million contract with the Padres -- made its way onto the field.




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Axford makes 'ideal' return to Blue Jays for '19

The Blue Jays officially added another veteran to their bullpen Saturday morning by signing right-hander John Axford to a Minor League deal with an invitation to Spring Training. Axford hasn't received any guarantees with the short-term contract, but he is a strong candidate to make Toronto's 25-man roster and head north at the end of camp.




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Famous dads no big deal for Blue Jays quartet

It's not rare to see former Major League sons in Major League uniforms, but is it unusual to find four in one clubhouse?




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The deaf will hear

OM Russia develops a stream in their Discipleship Centre programme dedicated to training the deaf, so that more deaf students can participate in missions.




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Death to life

God brings a young boy back to life and his parents recognise Jesus as Lord.




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Dead come to life

OM Lifehope Dancelink holds a workshop for girls in a predominately Muslim area of Birmingham to teach not only dance moves but also about Jesus.




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Life and death on the lake

An English nurse embraces the challenge of a lifetime on Lake Tanganyika.




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Leaving lasting ideas

Restoration and hope: A Bedouin woman and her son earn new income selling beans after listening to an OM worker share ideas about starting a small business.