bi

Adhesion, stability, structural and electronic properties of perovskite/BaWO4 heterostructures: first-principles and experimental characterizations

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00231H, Research Article
Yao Guo, Shiding Zhang, Zhaoyu Zhang, Yuanbin Xue, Jianxin Li, Haixiang Song, Yuhua Wang, Qing Shen
The interfacial behavior and mechanism of the CsPbBr3/BaWO4 and MAPbBr3/BaWO4 heterostructures have been extensively investigated by a combined first-principles and experimental analysis.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




bi

Facile access to tetra-substituted FeIIFeII biomimetics for the oxidized state active site of [FeFe]-hydrogenases

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00773E, Research Article
Xin-Ping Gao, Shu-Fen Bai, Yan-Lan Wang, Shuang Lü, Qian-Li Li
This study presents a convenient approach to obtain two distinct types of novel tetra-substituted Fe/Se salts through a dehalogenation reaction. The objective is to advance research in mimicking the FeIIFeII oxidation state in [FeFe]-H2ases.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




bi

Rational design for broad near-infrared emission from a two-sited Rb2LiAlF6:Cr3+ phosphor with high efficiency and thermal stability for spectroscopic applications

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00429A, Research Article
Song Qing, Jing Wan, Tao Yang, Qiang Zhou, Yayun Zhou, Zhengliang Wang, Dawei Wen, Mingmei Wu
A comparative investigation of broadband near-infrared luminescence from two different occupation sites in Rb2LiAlF6:Cr3+ with high efficiency and excellent thermal stability.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




bi

Development of In–Cu binary oxide catalysts for hydrogenating CO2via thermocatalytic and electrocatalytic routes

Inorg. Chem. Front., 2024, 11,2319-2338
DOI: 10.1039/D3QI02499G, Research Article
Open Access
Marco Pietro Mezzapesa, Fabio Salomone, Hilmar Guzmán, Federica Zammillo, Roberto Millini, Letizia Bua, Gianluigi Marra, Alessandra Tacca, Rosamaria Marrazzo, Nunzio Russo, Raffaele Pirone, Simelys Hernández, Samir Bensaid
Carbon dioxide (CO2) hydrogenation to obtain valuable chemicals and fuels via thermocatalysis or electrocatalysis is a promising and sustainable method for CO2 utilization.
The content of this RSS Feed (c) The Royal Society of Chemistry




bi

Three in one: a cadmium bismuth vanadate NLO crystal exhibiting a large second-harmonic generation response and enhanced birefringence

Inorg. Chem. Front., 2024, 11,2384-2391
DOI: 10.1039/D4QI00261J, Research Article
Shuya Liu, Conggang Li, Jinmiao Jiao, Yuheng She, Tinghui Zhang, Dianxing Ju, Ning Ye, Zhanggui Hu, Yicheng Wu
A novel vanadate NLO crystal Cd2BiVO6 was synthesized through spontaneous crystallization, exhibiting a large SHG response, an enhanced birefringence and a wide transmittance range.
The content of this RSS Feed (c) The Royal Society of Chemistry




bi

Boosting structural variety and catalytic activity of porphyrinic metal–organic frameworks by harnessing bifunctional ligands

Inorg. Chem. Front., 2024, 11,2281-2289
DOI: 10.1039/D4QI00314D, Research Article
Wei Wu, Xiu-Liang Lv, Tao He, Guang-Rui Si, Hongliang Huang, Lin-Hua Xie, Yabo Xie, Jian-Rong Li
High catalytic performance of porphyrin-based MOFs has been achieved by introducing multiple functionality into their ligands and modulating their conformation.
The content of this RSS Feed (c) The Royal Society of Chemistry




bi

Achieving a near-unity photoluminescence quantum yield and high stability of CsPbI3 nanoplatelets by hydroiodic acid-assisted ligand treatment

Inorg. Chem. Front., 2024, 11,2392-2401
DOI: 10.1039/D4QI00168K, Research Article
Zongnan Li, Yusheng Song, Sheng Cao, Ke Xing, Zhentao Du, Bingsuo Zou, Jialong Zhao
We demonstrate a near-unity photoluminescence quantum yield and high stability of CsPbI3 nanoplatelets achieved through a hydroiodic acid-assisted ligand treatment strategy, showcasing their application in perovskite LEDs.
The content of this RSS Feed (c) The Royal Society of Chemistry




bi

Structural phase transition drives outright photoluminescence quenching and dielectric duple bistable switching

Inorg. Chem. Front., 2024, 11,2290-2299
DOI: 10.1039/D4QI00303A, Research Article
Open Access
Zhi-Jie Wang, Ming-Jing Shen, Zhi-Peng Rao, Pei-Zhi Huang, Meng-Meng Lun, Bo-Wen Deng, Jun-Yi Li, Chang-Feng Wang, Hai-Feng Lu, Da-Wei Fu, Yi Zhang
(TECA)PbBr3 and (TEBA)PbBr3 have a wide range of photoluminescence signals and undergo coupling of the structural phase transition and photoluminescence quenching.
The content of this RSS Feed (c) The Royal Society of Chemistry




bi

Bulk single crystal growth and optoelectronic properties of the quasi-two-dimensional perovskites (CH3NH3)3Bi2X9 (X− = Br− and I−)

Inorg. Chem. Front., 2024, 11,2442-2456
DOI: 10.1039/D3QI02687F, Research Article
Zhiyuan Li, Xiangjun Wang, Peng Zhao, Jingquan Liu, Xiangxin Tian
Single crystals of MA3Bi2X9 (X = Br, I) with quasi-two-dimensional structures were successfully grown and the relationship between the compositions, dimensionality, and properties were discussed.
The content of this RSS Feed (c) The Royal Society of Chemistry




bi

Electrochemical conversion of 5-hydroxymethylfurfural over CuNi bimetallic catalysts: the synergistic effect of interfacial active sites

Inorg. Chem. Front., 2024, 11,2479-2488
DOI: 10.1039/D4QI00145A, Research Article
Yiwei Zhao, Chao Zhang, Shuangxi Xing, Zuhang Jin, Tingting Xiao
ECO of HMF to FDCA and ECR to BHMF with high yield have been studied on CuNi-based bimetallic catalysts. The presence of the Cu–O–Ni interfacial area was beneficial for promoting the catalytic performance in ECO.
The content of this RSS Feed (c) The Royal Society of Chemistry




bi

N-heterocyclic carbene-stabilized Cu9 clusters with combined thermally activated delayed fluorescence and phosphorescence

Inorg. Chem. Front., 2024, 11,2498-2507
DOI: 10.1039/D4QI00160E, Research Article
Lin-Mei Zhang, Mo Xie, Hui-Zhi Wei, Shang-Fu Yuan, Dong-Sheng Li, Tao Wu
Two NHC-stabilized Cu9 clusters showcase both TADF and direct phosphorescence in thermal equilibrium. The combined harvesting mechanism arises from the simultaneous presence of a small ΔE(S1 − T1) gap and relatively strong spin–orbit coupling.
The content of this RSS Feed (c) The Royal Society of Chemistry




bi

Gold nanoparticles cross cell-subcellular barriers for biological regulation

Inorg. Chem. Front., 2024, 11,2205-2211
DOI: 10.1039/D4QI00316K, Chemistry Frontiers
Xiang Zheng, Guangchao Qing, Yaru Jia, Fangzhou Li, Lanju Xu, Xing-Jie Liang, Jinchao Zhang
Major biological barriers for nanomedicines to cross to reach target sites are the blood barrier, blood–tissue barrier, transmembrane barrier and cell-cellular barrier.
The content of this RSS Feed (c) The Royal Society of Chemistry




bi

New Ultraviolet Transparent Rare-Earth Borates with Enhanced Birefringence Induced by Cation Chemical Substitution

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00840E, Research Article
Guanglian Sun, xiaofang Qi, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu
Birefringence determined by optical anisotropy is one of the most pivotal and fundamental performance of optical materials. However, optimizing the birefringence remains a significant challenge. Herein, a simple and effective...
The content of this RSS Feed (c) The Royal Society of Chemistry




bi

Electrodeposited Superaerophobic Nickel Catalyst on Pencil-Drawn Paper: A Novel Approach for Highly Efficient and Stable Hydrogen Evolution

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00101J, Research Article
Qian Sun, Xiaoyu Hao, Tianyi Zhang, Zelin Ma, Kui Hu, Ming Yang, Xiaolei Huang, Xuqing Liu
Electrocatalytic water splitting stands at the forefront of advancing renewable energy technologies. A critical challenge in this realm is the detrimental effect of gas bubble adhesion on electrode surfaces, which...
The content of this RSS Feed (c) The Royal Society of Chemistry




bi

A wheel-like polyoxometalate for haloperoxidase inspired antibiofouling with H2O2 in-situ provided by electrocatalysis

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00482E, Research Article
Yumeng Bian, Runze Wang, xinxin xu, Jin Chen, Qiang Wang
Biofouling is adhering of micro-organisms on submerged surfaces, which is a common phenomenon presents serious hazard to industry and public health. Nanozymes with haloperoxidase mimic activity are promising options to...
The content of this RSS Feed (c) The Royal Society of Chemistry




bi

Large enhancement of electrochemical biomass oxidation by optimizing the competitive adsorption of HMF and OH− on doped CoOx

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00519H, Research Article
Tianqi Nie, Guihao Liu, Ziheng Song, Tianyang Shen, Xiaoliang Sun, Tianrui Yu, Sha Bai, Lirong Zheng, Yu-Fei Song
By doping transition metals into CoOx, we can regulate the deintercalation capacity of OH. The CoCuOx with enriched oxygen vacancies allowed the optimization of the competitive adsorption between HMF and OH, and accelerated the kinetics of HMFOR.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




bi

Yolk-Shell type Carbon-Silica Nanoarchitecture Dispersed and Stabilized Ru Nanoparticles for Enhanced Hydrogenation of Aromatic Compounds

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00553H, Research Article
Lu Yan, Yue Shen, Zidan Zou, Xiao Zhang, Zhixin Yu, Guozhong Wang, Chun Chen
Hydrogenation of aromatic rings can be used not only for synthesis fine chemicals, but also for hydrogen storage and transportation using organic hydride. In this paper, yolk-shell structural SiO2@Ru@NC catalyst,...
The content of this RSS Feed (c) The Royal Society of Chemistry




bi

Anisotropic ZSM-5 nanorod assemblies: facile synthesis, epitaxial growth, and strikingly enhanced stability in benzene alkylation

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00287C, Research Article
Peng Zhu, Yiren Yu, Guoshu Gao, Yumeng Zhao, Yuting Jiao, Haiou Liu, Guodong Liu, Xiongfu Zhang, Guohui Yang
A novel bundle-like ZSM-5 nanorod assembly was facilely synthesized by adopting a CTAB-aided seed-induced strategy for highly efficient alkylation of benzene with ethanol.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




bi

NaVSeO5: Synergistic Combinations to Excellent Birefringent Materials

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00513A, Research Article
Qiuyuan Feng, Jialong Wang, Changyou Liu, Qun Jing, Xiaoyu Dong
The novel NaVSeO5 birefringent crystals were successfully synthesized using a multifunctional group synergistic strategy, which combines a two-dimensional layered structure, consisting of stereochemically active lone pairs [SeO3], and anomalous [VO6]...
The content of this RSS Feed (c) The Royal Society of Chemistry




bi

SEBI explores feasibility of introducing crude oil ETFs

Such ETFs own futures contracts on crude oil instead of the commodity itself. The ETF price will mimic the spot price.




bi

SEBI panel mulls new category of commodity funds

MF investment in ETCDs is estimated to be under ₹10,000 crore




bi

Aluminium futures retain positive bias

The price region between ₹228 and ₹230 is a demand zone




bi

Manufacturing method of lab grown diamonds should be declared before export and import: CBIC

The new norms, which will help in quick processing and inspection of consignments, are to be effective from December 1




bi

Down the AI rabbit hole, strewn with health benefits and ethical pitfalls 

Regulatory frameworks covering AI need fine-tuning to harness its potential without halting growth 




bi

Calisthenics, rock-climbing and laughter




bi

No turning back on the biotech super highway

Industry experts call for support to firms pursuing cutting-edge technologies as they forge ahead 




bi

‘Closing the gap’ to ensure healthy babies

Despite the benefits, only half of Indian infants are breastfed successfully—what’s holding us back?




bi

Centre launches mobile app for grievance redressal of rice millers

Move to enchance transparency, accountability




bi

India’s H1 agriculture exports a tad lower at $12.13 billion on dip in cereal shipments

As per APEDA, the fall in non-basmati rice exports pulled down the overall cereal shipments by 8.35 per cent to $5.22 billion during April-September period from corresponding last year’s $5.69 billion




bi

Big boost to rice procurement in second fortnight of October, Central purchase reaches 84 lakh tonnes

The purchases were 48 per cent lower at 20.7 lt in until October 15, whereas in the second fortnight over 63 lt rice was procured by the Centre




bi

India’s journey towards biofuel leadership

With continued government support, private sector investment, and public participation, India can become a global biofuel leader




bi

Haresh Vyas is Chairman of World Castor Sustainability Forum

“Vyas brings a wealth of experience and an unfaltering commitment to sustainable agricultural practices, setting the stage for transformative growth and enhanced sustainability within the castor industry”




bi

Govt withdraws sugar stock disclosure order citing comfortable domestic availability

Food Ministry says sufficient quantity of sugar is available in the country to meet the domestic demand throughout the year after reviewing prices and availability of the sweetener




bi

Sluggish start to rabi plantings in Rajasthan




bi

This time for Africa: Asian tea producers to explore possibilities to create market opportunities in Africa

Asia Tea Alliance plans to expand tea market in Africa to increase global consumption, focusing on sustainability and quality




bi

Best Agrolife gets approval for patented herbicide ‘Shot Down’ and insecticide ‘Bestman’

These products are slated for launch in the fourth quarter of the fiscal year.




bi

Indian crop input firms upbeat on rabi season prospects on higher reservoir levels, soil moisture

Sector witnessing good demand for commodity and speciality fertilizers




bi

Cabinet greenlights ₹6,800 crore railway projects in key allies-run States of Andhra Pradesh, Bihar

Emphasises development over politics, with religious and trade significance




bi

Air India suspends ten cabin crew as room sharing rule triggers a row

Crew union seeks labour ministry intervention to stall the move 




bi

Release Viability Gap Funding to Vizhinjam port as grant, not loan, Kerala Chief Minister requests Centre 

Letter to Union Finance Minister requests treatment on a par with Outer Harbour project of VO Chidambaranar Port




bi

Armed forces move to scrap mobility contract, Uber says “ready to discuss our data-security practices”

Concerns about data security practices prompt the move




bi

Vistara bids adieu with last flight to Singapore; integrated Air India takes to the skies

UK115 flight from Delhi to Singapore was the last flight of Vistara with the code 'UK' while UK986 from Mumbai to Delhi was the carrier's last domestic flight




bi

Jindal Steel & Power Ltd. - Disclosures under Reg. 31(1) and 31(2) of SEBI (SAST) Regulations, 2011




bi

Alembic Pharma Q1 profit more than doubles to ₹301.46 crore

Robust sales in international markets drive profits




bi

SEBI imposes penalty of ₹25 cr on YES Bank




bi

Ahammune Biosciences raises Pre-Series A funding from Ideaspring Capital, Indian Angel Network




bi

Goldman Sachs invests in Aragen Life Sciences (GVK Bio)

The company has invested more than $3.6 billion in capital since 2006




bi

IPO: Sresta Natural Bioproducts files draft papers with SEBI

The IPO comprises a fresh issue of equity shares aggregating up to ₹50 crore and an offer sale of up to 70.3 lakh equity shares




bi

The voice that binds

In a conversation with Meena Banerjee, Carnatic vocalist Aruna Sairam talks about the meeting ground between Carnatic and Hindustani music, and the importance of audience.




bi

A bit of rhythm, a bit of soul

Brazilian guitarist Ahmed El-Salamouny on how his life revolves around music