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Reactions of a geminal Sc/P Lewis pair with pyridotetrazole and beyond

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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02838D, Paper
Yiwen Guan, Xian Xu, Xin Xu
An FLP pyridyl nitrene adduct was isolated from the denitrogenative reaction of the Sc/P complex with pyridotetrazole. FLP reactivity of the Sc/P complex with many small molecules were investigated with the generation of metallacyclic complexes.
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Mechanistic studies of NOx reduction reactions involving copper complexes: encouragement of DFT calculations

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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02420F, Frontier
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yohei Kametani, Yoshihito Shiota
Mechanistic analysis of nitrite (NO2−) and nitric oxide (NO) reduction reactions promoted by copper complexes provides a reliable view of electron transfer and atom movement.
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Synthesis of organo-uranium(II) species in the gas-phase using reactions between [UH]+ and nitriles

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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02508C, Paper
Justin G. Terhorst, Theodore A. Corcovilos, Samuel J. Lenze, Michael J. van Stipdonk
A series of gas-phase, σ-bonded [U–R]+ species (R = CH3, C2H3, C2H5, C3H7, or C5H6) can be generated by using preparative tandem mass spectrometry (PTMSn) via ion-molecule reactions between [UH]+ and neutral nitriles.
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Karnataka Ministers seek action against Union Minister Pralhad Joshi for ‘agent’ comment on retired high court judge Michael D’Cunha

By www.thehindu.com
Published On :: Mon, 11 Nov 2024 17:14:22 +0530

The two Ministers told the Governor that Mr. Joshi made a deliberate attempt to politicise and taint a constitutionally sanctioned inquiry, betraying public trust in the process


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Your stone-age brain in the screen age [electronic resource] : coping with digital distraction and sensory overload / Richard E. Cytowic.

By darius.uleth.ca
Published On ::

Cambridge, Massachusetts : The MIT Press, [2024]


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Bank employees in Maharashtra to go on strike on November 16; demand staff security, action against ‘assaulters’

By www.thehindu.com
Published On :: Sat, 19 Oct 2024 14:27:24 +0530

The bank unions forum cited events of abuse and assault on bankers across branches in Maharashtra since August 2024


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Are digital payments gaining traction?

By www.thehindubusinessline.com
Published On :: Sun, 06 Aug 2017 20:19:22 +0530

Non-discretionary categories such as fuel and groceries are seeing dramatic growth


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RBI maintains tight vigil on financial market and takes action when necessary, says RBI Governor Shaktikanta Das

By www.thehindu.com
Published On :: Fri, 18 Oct 2024 17:11:24 +0530

The RBI Governor said that the central bank does not act like a policeman.


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Start, action, campus

By www.thehindu.com
Published On :: Mon, 24 Sep 2012 16:07:17 +0530

What is drawing youngsters to cinema these days?


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Job satisfaction over security?

By www.thehindu.com
Published On :: Wed, 24 Oct 2012 18:48:56 +0530

Given a choice would you opt for an unconventional career? Here’s what a few youngsters had to say…


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24x7 helpline, talent bank, interaction portal among recommendations in youth policy

By www.thehindu.com
Published On :: Fri, 30 Nov 2012 10:11:53 +0530

Chief Minister Jagadish Shettar says Karnataka Youth Policy will be implemented in toto


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Synergistic enhancement of charge extraction and heat dissipation in inverted perovskite solar cells via n-doped top interlayers

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Energy Environ. Sci., 2024, 17,8304-8312
DOI: 10.1039/D4EE02836H, Paper
Sangmi Park, Sang Young Jeong, Jaehoon Kim, Heunjeong Lee, Hye Seung Kim, Young Wook Noh, Ye In Kim, Shinuk Cho, Joon Sang Kang, Han Young Woo, Myoung Hoon Song
n-Doping the fullerene-based interlayer in perovskite solar cells enhances heat dissipation and charge extraction by improving thermal/electrical conductivity, and energy level alignment, which boosts photovoltaic performance and stability.
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Three-step thermodynamic vs. two-step kinetics-limited sulfur reactions in all-solid-state sodium batteries

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Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03160A, Paper
Tongtai Ji, Qingsong Tu, Yang Zhao, Dominik Wierzbicki, Vincent Plisson, Ying Wang, Jiwei Wang, Kenneth S. Burch, Yong Yang, Hongli Zhu
This study unveils the intrinsic three-step thermodynamic and the two-step kinetics-limited pathways in all-solid-state sodium–sulfur batteries, providing crucial insights into sulfur reaction mechanisms for high-performance energy storage solutions.
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Asymmetric evaporation for efficient and simultaneous extraction of freshwater, salt, and electrical energy from seawater

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Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE04201H, Paper
Yitian Wu, Chaoliang Ma, Kangxin Zhu, Lizheng Jin, Lvfu Song, Lanze Li, Yingzhuo Lu, Yu Zheng, Yaoxin Zhang, Xin Zheng, Sai Wu, Yajun Pang, Zhehong Shen, Swee Ching Tan, Hao Chen
This study presents an asymmetric evaporation strategy that simultaneously achieves freshwater production, salt collection, and electrical energy generation.
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Grease trap waste valorization through hydrothermal liquefaction and anaerobic digestion: a circular approach to dairy wastewater treatment

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Energy Environ. Sci., 2024, 17,8926-8941
DOI: 10.1039/D4EE02245A, Paper
Daniela V. Cabrera, Ingrid Adema-Yusta, María J. Santibañez, Crispin Celis, Jefferson W. Tester, Rodrigo A. Labatut
Integrating hydrothermal liquefaction (HTL) with anaerobic digestion (AD) and recycling a fraction of the resulting wastewater (AP) in the HTL allows for recovering 85% of the energy contained in the grease waste while reducing its COD to 700 mg L−1.
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Time for action: on the climate conference huddle in Baku 

By www.thehindu.com
Published On :: Tue, 05 Nov 2024 00:10:00 +0530

Concrete action must take centre stage in climate mitigation 


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​Testing time: On climate action and President Trump

By www.thehindu.com
Published On :: Fri, 08 Nov 2024 00:10:00 +0530

Donald Trump’s second term could add to the stress on climate action plans 


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New Editor-in-Chief for Reaction Chemistry & Engineering

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE90011A, Editorial
Dionisios G. Vlachos, Maria Southall, Klavs F. Jensen
Executive Editor Maria Southall welcomes Dionisios Vlachos as the new Editor-in-Chief of Reaction Chemistry & Engineering and pays tribute to the leadership and many contributions of departing inaugural Editor-in-Chief Klavs Jensen.
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Encapsulation of TixFeyLamOz nanoparticles into NH2-MIL-125(Ti) to fabricate a promising photocatalyst for the C–N coupling reaction

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React. Chem. Eng., 2024, 9,849-860
DOI: 10.1039/D3RE00457K, Paper
Yahya Absalan, Mohammad Rafsanjani Dehghazi, Reza Samavati, Kambiz Souri, Mostafa Gholizadeh
An array of organic compounds and natural products can be synthesized through carbon–nitrogen coupling reactions.
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Interaction of SO2 with a Cu–Mn oxide oxygen carrier during chemical looping with oxygen uncoupling

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React. Chem. Eng., 2024, 9,888-900
DOI: 10.1039/D3RE00498H, Paper
Turna Barua, Bihter Padak
During chemical looping combustion with oxygen uncoupling (CLOU) fuel-sulfur species impact the reactivity of Cu–Mn oxide oxygen carrier with CH4. SO2 oxidation to SO3 competes with fuel for available O2 and lowers CH4 conversion.
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Digital Pareto-front mapping of homogeneous catalytic reactions

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React. Chem. Eng., 2024, 9,787-794
DOI: 10.1039/D3RE00673E, Communication
Open Access
Negin Orouji, Jeffrey A. Bennett, Sina Sadeghi, Milad Abolhasani
We present a digital framework for rapid multi-objective reaction space exploration and optimization of homogeneous catalytic reactions through autonomous experimentation and Bayesian optimization.
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Novel TPMS carbon-based monolithic catalysts by three-dimensional printing for enhancement of nitrobenzene hydrogenation reaction

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00049H, Paper
Haoyang Wang, Haoran Tian, Qi Zhang, Li Zhang
Preparation of periodic curved surface, structured, carbon-based catalysts using a 3D printing method achieved good results in the hydrogenation of nitrobenzene to aniline in a packed-bed micro-reactor.
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Thermokinetic analyses of metal-sensitive reactions in a ceramic flow calorimeter

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00014E, Paper
Open Access
Soritz S., Sommitsch A., Irndorfer S., Brouczek D., Schwentenwein M., Priestley I. J. G., Iosub A. V., Krieger J. P., Gruber-Woelfler H.
A ceramic flow calorimeter for metal-sensitive reactions is characterized and used to obtain thermokinetic data on highly exothermic reactions.
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Enhancing mass transport to accelerate photoreactions and enable scale-up

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00689A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Florian Gaulhofer, Markus Metzger, Alexander Peschl, Dirk Ziegenbalg
The importance of mixing in photoreactors along the direction of light propagation for competitive photochemical reactions is experimentally demonstrated in the MISCOP mini-plant photoreactor.
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Hydrothermal liquefaction of plastics: a survey of the effect of reaction conditions on the reaction efficiency

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D2RE00510G, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Matthijs Justin Boel, Hongqi Wang, Ahmad AL Farra, Laura Megido, José Manuel González-LaFuente, N. Raveendran Shiju
Plastic waste is a major global issue and hydrothermal liquefaction is a promising technique for the chemical recycling of waste plastics. This review summarises the effect of reaction conditions on the liquefaction efficiency.
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Correction: Applying quantum mechanics to deconvolute benchtop 1H NMR reaction data

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE90015D, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jiayu Zhang, Tristan Maschmeyer, Ben Shapiro, Sunil Babu Paudel, Matthew C. Leclerc, Jason E. Hein
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HUL, fintech SRO raise concerns over Trai’s new rules for transactional messages

By www.thehindubusinessline.com
Published On :: Sat, 09 Nov 2024 20:51:47 +0530

The Telecom Regulatory Authority of India, in a consultation paper issued in September, has suggested that users will have the option to opt out of receiving transactional messages


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Correction: A comparative study of the hypolipidemic effects and mechanisms of action of Laminaria japonica- and Ascophyllum nodosum-derived fucoidans in apolipoprotein E-deficient mice

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Food Funct., 2024, 15,10913-10914
DOI: 10.1039/D4FO90102A, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tian Liu, Xue Wang, Yan-Ming Wang, Feng-Rong Sui, Xue-Ying Zhang, Hai-Di Liu, Dong-Yue Ma, Xiao-Xiao Liu, Shou-Dong Guo
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In vivo mechanism of interaction between trimethylamine lyase expresssion and glycolytic pathways

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Food Funct., 2024, Accepted Manuscript
DOI: 10.1039/D4FO03809F, Paper
Qian Li, Di Wu, Yu Song, Lu Zhang, Ting Wang, Min Zhang
Recent findings have confirmed that the interaction between host and gut microbiota can alter the formation of the disease-associated metabolite, trimethylamine (TMA), via intestinal microbial TMA lyase. Nevertheless, little is...
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Interaction of oat bran and exercise training improved exercise adaptability via alleviating oxidative stress and promoting energy homeostasis

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Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO03374D, Paper
Rui Dong, Hamad Rafique, Qianwen Niu, Xin Zeng, Maria Cristina Messia, Li Yuan, Lin Shi, Liang Zou, Lu Li, Xinzhong Hu
Interaction of oat bran (OB) diet and moderate intensity exercise training (MlET) reinforced the positive effect on skeletal muscle function.
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Cardamonin protects against diabetic cardiomyopathy by activating macrophage NRF2 signaling through molecular interaction with KEAP1

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Food Funct., 2024, 15,11083-11095
DOI: 10.1039/D4FO03543G, Paper
Wenshan Nan, Jialin Yin, Wenhao Hao, Huali Meng, Junduo Wu, Xiao Yin, Hao Wu
Cardamonin inhibited macrophage M1 polarization in diabetic cardiomyopathy by binding to KEAP1, leading to the dissociation of NRF2 from KEAP1. This promoted NRF2 nuclear translocation and antioxidant gene expression in M1 polarized macrophages.
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Metagenomic and transcriptomic profiling of the hypoglycemic and hypotriglyceridemic actions of Tremella fuciformis-derived polysaccharides in high-fat-diet- and streptozotocin-treated mice

By pubs.rsc.org
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Food Funct., 2024, 15,11096-11114
DOI: 10.1039/D4FO01870B, Paper
Xiaofei Xu, Xiaofei Liu, Liyan Liu, Jin Chen, Jingjing Guan, Donghui Luo
Tremella fuciformis polysaccharides exhibit hypoglycemic and hypotriglyceridemic activities through altering the taxonomic and functional attributes of the gut microbiota and modulating gene expression in the liver.
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Human milk oligosaccharides and milk fat globule membrane reduce allergic reactions in mice through the modulation of gut microbiota and metabolic functions

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Food Funct., 2024, 15,11252-11265
DOI: 10.1039/D4FO03851G, Paper
Xinzhang Chen, Shengjun Yang, Zhengtao Guo, Bailiang Li, Zhongjiang Wang, Lianzhou Jiang
Human milk oligosaccharides (HMOs) and the milk fat globule membrane (MFGM) represent novel treatments for cow's milk allergy (CMA).
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Why Shah Rukh Needed Action To...

By www.rediff.com
Published On :: Mon, 20 Feb 2023 16:24:12 +0530

Shah Rukh had outgrown the roles that made him a star -- the menacing, obsessive lover in Darr, the regular guy in Kabhi Haan Kabhi Na or the new age boyfriend in Dilwale Dulhania Le Jayenge.By the time he entered his 50s, he was struggling to find his feet, explains Vanita Kohli-Khandekar.


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Environmental innovation [electronic resource] : an action plan for saving the economy and the planet by 2050 / Jack Buffington.

By darius.uleth.ca
Published On ::

Lanham : Rowman & Littlefield, [2024]


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Tangled in a web of distractions?

By www.thehindu.com
Published On :: Sun, 23 Oct 2016 17:00:32 +0530

The power to enter and exit lies in your hands.


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Exploring anodic oxidation reactions in hybrid water electrolysis: special emphasis on substrate choice

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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00907J, Review Article
Baghendra Singh, Neetu Verma
Anodic oxidation reactions have been assessed focusing on essential parameters for the substrate choice.
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Ultrasmall RuO2/CoFe2O4 nanoparticles with robust interfacial interactions for the enhanced acidic oxygen evolution reaction

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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00719K, Paper
Open Access
Ming Wei, Liuhua Mu, Zhiwei Liu, Feng Gao, Guangjian Song, Qiankang Si, Mao Zhang, Fangfang Dai, Min Zhang, Rui Ding, Li Yang, Zhonggui Gao, Sanzhao Song
Ultrasmall RuO2/CoFe2O4 nanoparticles with strong interfacial interactions exhibit enhanced oxygen evolution reaction (OER) performance, driven by efficient charge transfer between RuO2 and CoFe2O4.
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Solar-Driven Tripus Photocatalytic Action of Defective S-doped g-C3N4 for 1,4 NADH Regeneration and Simultaneous Benzylamine Conversion along with CO2 Fixation into HCOOH

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Published On ::

Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY00825A, Paper
Kanchan Sharma, Rajesh K. Yadav, Rajesh Kumar Verma, Satyam Singh, Shaifali Mishra, Rehana Shahin, Atul Pratap Singh, Chandani Singh, Navneet Kumar Gupta, Jin-Ook Baeg, Hwanhui Yun, Hyeongjoong Kim
Incorporating defects through intrinsic defect engineering has emerged as a versatile strategy for finely tuning key properties of materials, particularly the redox capacity. Defects are fundamentally important in enhancement of...
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Influence of redox treatments on the low-temperature water gas shift reaction over Pt/CeO2 catalysts

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Catal. Sci. Technol., 2024, 14,6247-6258
DOI: 10.1039/D4CY00741G, Paper
Open Access
Clément Molinet-Chinaglia, Elizabeth Vera, Philippe Vernoux, Laurent Piccolo, Stéphane Loridant
H2 reducing pretreatment at 500 °C promotes the activity of low-Pt-content Pt/CeO2 catalysts by increasing the number of active Pt0 NPs. A 12 h oxidative post-treatment at 500 °C which forms PtOx species easily activated also leads to improvement.
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Theoretical insights into Pt–Rh alloy nanoparticles: stability, elemental distribution, and catalytic mechanisms for NO + CO reactions

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Catal. Sci. Technol., 2024, 14,6286-6297
DOI: 10.1039/D4CY00755G, Paper
Yuzheng Li, Xianbao Duan, Zhang Liu, Caoran Li, Fangwen Ye, Zhihong Zhang, Liuqing Chen, Chun Du, Qingbo Wang, Bin Shan
Pt–Rh alloy nanoparticles featuring surfaces with both Pt and Rh atoms are poised to demonstrate bifunctional catalytic prowess in the NO + CO reaction.
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Construction of a highly efficient MoS2-based composite electrocatalyst for the oxygen evolution reaction

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Catal. Sci. Technol., 2024, 14,6380-6392
DOI: 10.1039/D4CY00923A, Paper
Mengyan Huang, Bo Liu, Junwei Wu, Junfeng Gu, Yichen Zheng, Peiyan Ma, Bei Li, Zhengyi Fu
The carboxyl groups in CC-MoC@MoS2 play a similar role to the amino acid residues in PS II.
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Photocatalytic dehydrogenative C(sp2)–P coupling reaction between dibenzo[b,f][1,4]oxazepanes and phosphine oxides

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Published On ::

Catal. Sci. Technol., 2024, 14,6176-6179
DOI: 10.1039/D4CY00955J, Communication
Zhaotian Wu, Xuefei Sha, Shan Wang, Huan Yang, Shaojun Zheng, Chunhui Jiang, Shu-Yang Chen, Hongfei Lu
Visible-light-induced cross-dehydrogenative coupling between cyclic imines and diaryl phosphine oxides has been developed to afford their oxyphosphide derivatives, using rhodamine B as a photocatalyst.
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Heteroatom-doped carbon nanomaterials as potential heterogeneous Fenton reaction catalysts

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Catal. Sci. Technol., 2024, 14,6662-6669
DOI: 10.1039/D4CY00248B, Paper
Haobin Tan, Xiuli Hou, Chen Zhou, Shengbo Wang, Qiang Liu, Zhenhui Xu, Peng Zhang
A volcano relationship between the catalytic activity and the adsorption energies of reaction intermediates was found for the H2O2 dissociation on heteroatom-doped carbon nanomaterials.
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Enhancing light-driven photocatalytic reactions through solid solutions of bismuth oxyhalide/bismuth rich photocatalysts: a systematic review

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Published On ::

Catal. Sci. Technol., 2024, 14,6466-6495
DOI: 10.1039/D4CY00820K, Review Article
Open Access
Robert O. Gembo, Rudzani Ratshiedana, Lawrence M. Madikizela, Ilunga Kamika, Cecil K. King'ondu, Alex T. Kuvarega, Titus A. M. Msagati
The pursuit of sustainable environmental remediation strategies has led to intensive research in photocatalysis.
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Material design of biodegradable primary batteries: boosting operating voltage by substituting the hydrogen evolution reaction at the cathode

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Nanoscale, 2024, 16,20027-20036
DOI: 10.1039/D4NR03321C, Minireview
Shunsuke Yamada, Takashi Honda
This review highlights recent progress in increasing the operating voltage of biodegradable primary batteries by suppressing or substituting the hydrogen evolution reaction at the cathode with alternative redox reaction.
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Electrostatic interactions and structural transformations in viral shells

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Nanoscale, 2024, 16,20182-20193
DOI: 10.1039/D4NR02612H, Paper
Open Access
Ivan Yu. Golushko, Daria S. Roshal, Olga V. Konevtsova, Sergei B. Rochal, Rudolf Podgornik
Considering the simplest energy of electrostatic interactions between proteins together with the mechanical energy of the continuum shell, one can model various structural transformations possible in viral capsids.
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Morphology–electronic effects in ultra-model nanocatalysts under the CO oxidation reaction: the case of ZnO ultrathin films grown on Pt(111)

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Nanoscale, 2024, 16,20216-20227
DOI: 10.1039/D4NR02935F, Paper
Hang Liu, Lei Zhang, Sébastien Lebègue, Fabrice Bournel, Jean-Jacques Gallet, Ahmed Naitabdi
Thickness-dependent morphology and electronic properties of ZnO ultrathin films grown on Pt(111) under the CO oxidation reaction at 1 mbar.
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Retraction: Enhanced activity of vancomycin by encapsulation in hybrid magnetic nanoparticles conjugated to a cell-penetrating peptide

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Nanoscale, 2024, 16,20356-20356
DOI: 10.1039/D4NR90195A, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Wenjie Zhang, Reza Taheri-Ledari, Zoleikha Hajizadeh, Ehsan Zolfaghari, Mohammad Reza Ahghari, Ali Maleki, Michael R. Hamblin, Ye Tian
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Cr2TiC2Tx MXene as an Adsorbent Material in Ultrasonic-Assisted d-µ-Solid Phase Extraction for Trace Detection of Heavy Metals

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Published On ::

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR02556C, Paper
Saman Bagheri, Rashmeet Kaur Khurana, Md. Ibrahim Kholil, Michael J. Loes, Shengyuan Luo, Alexander Sinitskii
MXenes are a large family of two-dimensional transition metal carbides, nitrides, and carbonitrides. While MXenes have great potential for applications in analytical chemistry, most of the studies in this field...
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