action Illegal sand extraction: 16 boats seized in Addoor By www.thehindu.com Published On :: Fri, 08 Nov 2024 21:30:40 +0530 Full Article Mangaluru
action Collective action can promote culture of honesty, Maharashtra Upa Lokayukta By www.thehindu.com Published On :: Mon, 11 Nov 2024 20:44:08 +0530 Full Article Mangaluru
action Complaint filed with Lokayukta against DDPI citing inaction against unauthorised schools By www.thehindu.com Published On :: Mon, 11 Nov 2024 16:00:26 +0530 Associated Managements of English Medium Schools in Karnataka says photographic evidence of unauthorised buildings and violations of various regulations were provided but permissions were granted Full Article Education
action Jack Reacher- Never Go Back : Less action thriller, more family drama By www.thehindu.com Published On :: Thu, 20 Oct 2016 19:58:36 +0530 What starts out as a high-paced exciting action-fuelled film soon unravels to become a family drama. Full Article Cinema
action ‘Macharla Niyojakavargam’ movie review: An extra loud, outdated actioner By www.thehindu.com Published On :: Fri, 12 Aug 2022 15:35:36 +0530 This cringey Telugu potboiler starring Nithiin and Krithi Shetty is a test of patience Full Article Movies
action ‘Custody’ movie review: Venkat Prabhu’s mix of conflict and humour works for this Naga Chaitanya, Arvind Swami actioner By www.thehindu.com Published On :: Fri, 12 May 2023 15:57:16 +0530 Director Venkat Prabhu’s Telugu-Tamil bilingual ‘Custody’ is not among his best, but has plenty going for it Full Article Movies
action Real estate transactions drop 71% in Q3 2024, private equity dominates By www.thehindubusinessline.com Published On :: Mon, 14 Oct 2024 13:41:56 +0530 Despite the overall fall, the number of deals rose 5% quarter-on-quarter and 54% year-on-year, with a potential revival in Q4. Full Article Real Estate
action Pune’s home sales value surges 19% in Q3 2024 despite a slight dip in transactions By www.thehindubusinessline.com Published On :: Tue, 22 Oct 2024 15:20:42 +0530 Based on data from the Inspector General of Registration (IGR), the city’s home sales value jumped 19 per cent year-on-year (YoY), reaching ₹13,865 crore Full Article Real Estate
action Synthesis of C-glycosides enabled by palladium-catalyzed glycosylation reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01619J, Review ArticleWenli Tong, Jie-Ping Wan, Jianchao LiuThis review highlights the recent progress in palladium-catalyzed C-glycosylation reactions for the synthesis of C-glycosides.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Visible-light heterogeneous photocatalysis with an ionic porous organic polymer (IPOP): synthesis of β-keto sulfoxides and benzothiophene diesters by tandem radical addition–oxidation reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01382D, Research ArticleAjay Kumar Sahoo, Parag Tamuly, Jarugu Narasimha MoorthyAn IPOP, constructed constructed from cyanuric chloride and the readily accessible 2,5-di(pyridin-4-yl)thiazolo[5,4-d]thiazole (BpyTzTz), is shown to exhibit excellent visible light absorption and serve as a metal-free heterogeneous photocatalyst.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action HSAB theory guiding electrophilic substitution reactions of o-carborane By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01546K, Research ArticleYan Wang, Yi-Ge Li, Feijing Chen, Yan-Na Ma, Xuenian ChenHerein, we systematically compared the reactivity of o-carborane and benzene toward different electrophiles and explained the results with the HSAB principle.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Mechanistic insight into the dehydrogenation reaction catalyzed by an MLC catalyst with dual ancillary ligand sites By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01767F, Research ArticleGui-Xiang Zhou, Cheng HouThis study reveals a mechanism in which a ruthenium complex catalyst improves catalytic efficiency and lowers the energy barrier in the dehydrogenation of benzyl alcohol by dynamically switching ligand sites.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action The reactivity of alkenyl boron reagents in catalytic reactions: recent advances and perspectives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01703J, Review ArticleYa-Li Feng, Bo-Wen Zhang, Youzhi Xu, Shengnan Jin, Daniele Mazzarella, Zhong-Yan CaoRecent advances focusing on novel reactivity of alkenyl boron reagents in polar or radical pathways within catalytic reactions by employing transition metal catalysis, organocatalysis have been summarized and discussed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Phosphine-controlled divergent reactions of MBH-carbonates with azaheptafulvenes: access to o-anilinyl diene and benzazepine derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6418-6425DOI: 10.1039/D4QO01298D, Research ArticleWei Hao, Yiwen Zhang, Xiao Han, Zhen Wang, Weijun YaoA phosphine controlled divergent cascade reaction of MBH-carbonates with azaheptafulvenes was disclosed. PPh3 provided o-aminophenyl diene while PCy3 offered benzazepine derivative through formal [8 + 3] annulation/ring contraction cascade.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Chiral synthetic unprecedented spiro[indoline-2,3'-thiophen]-3-ones via an organocatalytic asymmetric sulfa-Michael/aldol cascade reaction By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6426-6436DOI: 10.1039/D4QO01551G, Research ArticleMao Zhang, Xing-Hai Fei, Gui-Ping Yang, Cheng Lin, Wen-Jie Li, Ming-Liang Rao, Meng Zhou, Chong Zhao, Bin He, Yong-Long ZhaoA cinchona-derived squaramide-catalyzed asymmetric sulfa-Michael/aldol cascade reaction of 2-ylideneoxindoles with 1,4-dithiane-2,5-diol was developed to realize the chiral synthesis of spiro[indoline-2,3'-thiophen]-3-ones.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Nickel-catalysed enantioselective cross-electrophile coupling reaction with the retention of the β-fluorine atom By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6459-6469DOI: 10.1039/D4QO01555J, Research ArticleXin-Yi Shi, Xueyuan Yan, Xiaodong Tang, Shi-Jing Zhai, Genping Huang, Jun-An Ma, Fa-Guang ZhangA nickel-catalysed enantioselective reductive cross-coupling reaction of a new monofluoromethyl building block with acid chlorides is developed to give chiral α-monofluoromethyl acyloin derivatives.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Carbonate-assisted selectively deoxygenative cross-coupling reaction between aryl and aliphatic aldehydes: a straightforward route to access α-alkylated aryl ketones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6510-6517DOI: 10.1039/D4QO01517G, Research ArticleYu Sun, Yi Wang, Zhijun ZuoA novel reductive cross-coupling reaction of two different aldehydes for rapidly assembling α-alkylated aryl ketones has been developed. The inexpensive carbonate served not only as a base but also as an efficient electron donor.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Transition-metal-catalyzed C–Ge coupling reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6558-6572DOI: 10.1039/D4QO01637H, Review ArticleJie Ke, Cadmus Du Chen, Li-Qing Ren, Bing Zu, Bin Li, Chuan HeThis review covers the development and recent progress in transition-metal-catalyzed C–Ge coupling reactions. The goal is to provide a clear overview of the field, identify current challenges, and inspire further applications in this growing area.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action A two-step Kinugasa/Conia-ene-type sequential reaction for the asymmetric synthesis of 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01388C, Research ArticleShanyue Li, Qicai Ma, Bohua Wu, Haowen Ma, Wei Zhou, Qian CaiA two-step Kinugasa/Conia-ene-type sequential reaction is developed. The process provided a simple and efficient access to chiral 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action DABSO-Mediated Pummerer Reaction Enables One-Pot Synthesis of Pyrroloquinolines for Accessing Marinoquinolines: Mechanistic, Photophysical and Pharmacological Investigations By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01512F, Research ArticleRahimuddin Khan, Dipun Kumar Penthi, Aditi Chatterjee, Chandrakanta Sahoo, Shanti Gopal Patra, Viswanathan Arun Nagaraj, Tabrez KhanA new one-pot acid- and exogenous oxidant-free synthesis of pyrrolo[2,3-c]quinolines has been developed. The strategy involves chemoselective reduction of the 3-(2-nitrophenyl)-1H-pyrroles (pyrrolnitrin derivatives) and subsequent DABSO-facilitated Pummerer reaction in the...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action A Stereoselective Organocatalyzed C-Glycosylation of Indole: Implications of Acceptor-Catalyst-Donor Interaction By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01873G, Research ArticleLihuang Xie, Wenchao Liu, Zhenbo Guo, Qinbo Jiao, Xiaomin Shen, Tianfei Liu, Chunfa XuA stereoselective pyridinium hexafluorophosphate-catalyzed C-glycosylation of indole is presented, featuring the plausible formation of a catalyst-acceptor complex and a crucial H-bond between the indole N-H and the oxygen at C6...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Mechanism and origins of regioselectivity of selenium-catalyzed allylic amination reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01794C, Research ArticleXiaoxiao Hu, Dengmengfei Xiao, Yu Chen, Yi Lu, Zhihan Zhang, Peiyuan YuThe mechanism of selenium-catalyzed allylic amination reactions with different ligands has been explored using density functional theory calculations.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Officials demand strict action against those involved in ‘confrontation’ at Vikarabad village By www.thehindu.com Published On :: Tue, 12 Nov 2024 00:48:38 +0530 Full Article Telangana
action Graphene-supported organoiridium clusters catalyze N-alkylation of amines via hydrogen borrowing reaction By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35163-35171DOI: 10.1039/D4RA06595F, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Tsun-Ren Chen, Siang-Yu Chiu, Wen-Jen Lee, Yi-Siou Tsai, Yu-Sheng HuangGraphene-supported organic iridium clusters (GSOIC) exhibit excellent N-alkylation on various substrates under green processes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Carbonate weakens the interactions between potassium and calcareous soil By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35275-35285DOI: 10.1039/D4RA05988C, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Wei Du, Shifeng Wang, Yizhe Yang, Chenyang Xu, Feinan Hu, Wuquan Ding, Jialong LvAdsorption energies of K+ in carbonate-removed (CREM) and carbonate-reserved (CRES) calcareous soil.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Phenylsulfonate as a photolabile group for intramolecular carbon–carbon cross-coupling reactions By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35227-35231DOI: 10.1039/D4RA06592A, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Simon Plaize, Jean-François MorinThis study reports the use of phenylsulfonates as photolabile groups to generate aryl radicals, which undergo radical cyclization to yield triphenylene derivatives. The reaction is efficiently carried out under 365 nm with a triplet sensitizer.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action In vitro bioactivity, mechanical, and cell interaction of sodium chloride-added calcium sulfate–hydroxyapatite composite bone cements By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35460-35474DOI: 10.1039/D4RA06034B, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Pharatree Jaita, Chamnan Randorn, Anucha Watcharapasorn, Parkpoom JarupoomIn this research, sodium chloride-added calcium sulfate–hydroxyapatite composite bone cements (0.70CaS–0.30HAP)/xNaCl were studied.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action DFT investigation of the mechanism and role of N-heterocyclic carbene (NHC) in constructing asymmetric organosilanes using NHC-catalyzed [4+2] cycloaddition reaction By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35475-35489DOI: 10.1039/D4RA03676J, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Batoul AlipourThe mechanism and origin of stereoselectivity for the synthesis of asymmetric organosilanes using NHC are theoretically investigated.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Comparing diverse extraction methodologies to infer the performance of 1,8-cineole extraction from Eucalyptus cinerea: process optimization, kinetics, and interaction mechanisms By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35529-35552DOI: 10.1039/D4RA06050D, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Divya Baskaran, Madhumitha Sathiamoorthy, Ramasamy Govindarasu, Hun-Soo ByunDifferent extraction techniques were used to extract 1,8-cineole from Eucalyptus cinerea leaves, and their performance efficiency was evaluated through optimization and kinetic studies.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Reaction of unsymmetrical α-bromo-1,3-diketones with N-substituted thioureas: regioselective access to 2-(N-arylamino)-5-acyl-4-methylthiazoles and/or rearranged 2-(N-acylimino)-3-N-aryl-4-methylthiazoles By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35585-35600DOI: 10.1039/D4RA05436A, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ranjana Aggarwal, Shilpa Sharma, Naman Jain, Dionisia Sanz, Rosa M. Claramunt, Patricia Delgado, M. Carmen TorralbaHantzsch's [3 + 2] cyclic condensation of α-bromo-1,3-diketones with N-substituted thioureas.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action An efficient extraction device for microplastics in marine sediments and its applications By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35610-35617DOI: 10.1039/D4RA04347B, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Wang Jiahan, Liu Xiaowei, Yang Feng, Yang Xiujiu, Jiao Wenguang, Tang Kai, Wang Jinli, Chen YanMicroplastics, defined as small pieces of plastic with a size less than 5 millimeters, constitute a significant sink for microplastics in marine sediments.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Retraction: Fabrication of novel quantum dots for the estimation of COVID-19 antiviral drug using green chemistry: application to real human plasma By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35696-35696DOI: 10.1039/D4RA90133A, Retraction Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Baher I. Salman, Adel Ehab Ibrahim, Sami El Deeb, Roshdy E. SarayaThe content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Retraction: Highly sensitive cadmium sulphide quantum dots as a fluorescent probe for estimation of doripenem in real human plasma: application to pharmacokinetic study By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35992-35992DOI: 10.1039/D4RA90134G, Retraction Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Marwa F. B. Ali, Baher I. Salman, Samiha A. Hussein, Mostafa A. MarzouqThe content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Developing Ni0.5Zn0.5Fe2O4 ferrite with controlled particle size and morphology through optimized processing conditions of low energy solid state reaction By pubs.rsc.org Published On :: RSC Adv., 2024, 14,36264-36272DOI: 10.1039/D4RA07076C, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sarah Baayyad, Fatima-Zahra Semlali, El Kébir Hlil, Tarik Mahfoud, Hassan El Moussaoui, Mounir El AchabySoft magnetic materials, like Ni0.5Zn0.5Fe2O4, require high temperatures and regulated environments for their manufacture and processing, which can be highly energy intensive.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Physicochemical properties and mechanism of action of a new copper(II) pyrazine-based complex with high anticancer activity and selectivity towards cancer cells By pubs.rsc.org Published On :: RSC Adv., 2024, 14,36295-36307DOI: 10.1039/D4RA06874B, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.B. Rogalewicz, T. Sierański, M. Szczesio, A. Olczak, K. Gobis, C. Orlewska, I. Korona-Głowniak, A. Korga-Plewko, M. Iwan, M. Michalczuk, J. Kubik, G. Adamczuk, M. Korga, N. Rutkowska, T. Boruta, K. Gas, M. Sawicki, E. Poleszak, W. Maniukiewicz, M. Świątkowski, A. CzylkowskaThe presented work underlines the importance of coordination compounds in the development of new anticancer agents that are safer and more efficient.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action AIUDF meets Assam Governor, seeks action against communal groups By www.thehindu.com Published On :: Mon, 26 Aug 2024 21:52:37 +0530 Several organisations representing indigenous communities have asked migrant Muslims, referred to as Miya, to leave eastern Assam following a gang-rape case Full Article Assam
action How much can US president-elect Donald Trump derail global climate action? By www.thehindu.com Published On :: Tue, 12 Nov 2024 16:03:45 +0530 Trump is a climate change denier who has promised to increase fossil fuel production and withdraw the US from the Paris climate deal, among other worrying pledges. Full Article Environment
action Ancelotti calls for Real Madrid’s positive reaction after consecutive losses By www.thehindu.com Published On :: Fri, 08 Nov 2024 19:00:36 +0530 Ancelotti's side sit second in the league standings with 24 points from 11 matches, nine points behind leaders Barcelona, who have played a game more Full Article Football
action Gold ETF gains traction as prices hit new high By www.thehindubusinessline.com Published On :: Tue, 09 Apr 2024 19:04:36 +0530 The asset under management of gold ETF has gone up 33 per cent to ₹28,530 crore as of February against ₹21,400 crore in February, 2023 Full Article Gold & Silver
action Unravelling the potential of low-valent tunable vanadium complexes in the nitrogen reduction reaction (NRR) By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02217C, PaperBijoy Ghosh, Sahtaz Ahmed, Ashwini K. PhukanComprehensive computational investigations predict the potential of several hitherto unknown tripodal vanadium complexes in the nitrogen reduction reaction (NRR) without the probability of generation of hydrazine as a side product.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Construction of efficient Pb(II) carboxylate catalysts for Oxygen and Hydrogen Evolution Reactions By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02958E, PaperJanak ., Vijay Sarjerao Sapner, Bhaskar Ramchandra Sathe, Sadhika KhullarThe development of cost-effective and efficient electrocatalysts can solve the problem in the production of energy via water splitting reactions. In this work, we focused on two lead-based coordination polymers...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Syntheses and structures of dimesitylphosphinite complexes of alkali metals and their catalytic activity in hydrophosphorylation reactions By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02721C, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Benjamin E. Fener, Philipp Schüler, Phil Liebing, Helmar Görls, Matthias WesterhausenThe diarylphosphinite complexes of the alkali metals exhibit a broad structural variety. Especially for potassium dimesitylphosphinite, the heterocubane cage can be broken down into dimeric K2O2 units by adding oligodentate ether molecules.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Accelerating the reaction kinetics of Ni1−xO/Ni(OH)2/NF by defect engineering for urea-assisted water splitting By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02871F, PaperYuan Rui, Zong Li, Miaohui Wang, Yunxia Liu, Haiping Lin, Peipei Huang, Qing LiThe reaction kinetics of Ni1-xO/Ni(OH)2/NF are accelerated through a defect engineering strategy by combining Zn doping and acid etching, leading to improved intrinsic activities for UOR.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Electrostatic vs. electronic interactions within oxidized multinuclear Pt(bipyridine)(dithiolene) complexes By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02514H, PaperKhalil Youssef, Antoine Vacher, Thanaphon Khrueawatthanawet, Thierry Roisnel, Frédéric Barrière, Dominique LorcyMultinuclear complexes involving two or three redox active Pt(dithiolene) moieties were synthesized and electronic interactions were analysed through a combination of experimental and theoretical investigations.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Co-doping regulation on Ni-based electrocatalysts to adjust the selectivity of oxygen reduction reaction for Zn–air batteries and H2O2 production By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17819-17828DOI: 10.1039/D4DT01625D, PaperSonghan Hu, Kai Wang, Xinxin Xu, Qiang WangTwo Ni-based electrocatalysts with different ORR selectivity were synthesized from a NiMOF, which show promising prospects in Zn–air batteries and H2O2 production.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action An insightful study on the reduction and extraction of neptunium assisted by molybdenum By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17909-17917DOI: 10.1039/D4DT02547D, PaperHuaixin Hao, Yaoyang Liu, Hong Cao, Zhipeng Wang, Chao Xu, Jing ChenMo dramatically boosts the extraction of Np(V) by TRPO through the catalytic reduction effect in both the aqueous phase and organic phase.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action Coinage metal(I) clusters supported by a 1,10-phenanthroline-phosphine: orange-to-NIR phosphorescence, metallophilic interactions and enhanced cytotoxicity By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18027-18036DOI: 10.1039/D4DT02642J, PaperAlexander V. Artem'ev, Maria P. Davydova, Lyubov S. Klyushova, Evgeniy H. Sadykov, Mariana I. Rakhmanova, Taisiya S. SukhikhBased on 2-(diphenylphosphino)-1,10-phenanthroline, a series of small metal(I) clusters, exhibiting orange to NIR phosphorescence and strong dose-dependent cytotoxicity.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action The role of the stabilizing/leaving group in palladium catalysed cross-coupling reactions By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18013-18020DOI: 10.1039/D4DT02533D, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lorenzo Palio, Francis Bru, Tommaso Ruggiero, Laurens Bourda, Kristof Van Hecke, Catherine Cazin, Steven P. NolanDespite the widespread use of well-defined PdII complexes as pre-catalysts for cross-coupling processes, the role of the throw-away ligand is still underexplored.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action The effect of second coordination sphere interactions on the magnetic anisotropy of transition metals By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02873B, PaperSofie S. Leiszner, Mauro Perfetti, Emil Damgaard-Møller, Yu-Sheng Chen, Bo B. IversenBy investigating second coordination sphere effects on the magnetic anisotropy of a Co(II) single molecule magnet (SMM), we aim to clarify their role in magneto-structural correlations to enhance the performance of transition metal SMMs.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
action A mechanistic study of chiral manganese porphyrin-catalyzed enantioselective C–H hydroxylation reaction By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02452D, PaperJing-Kun Gao, Wandong Chen, Junjie Tai, Zhengwei Chen, Hang Liu, Yuxin Du, Yiting Jiang, Yuanbin She, Yun-Fang YangThis study uses DFT to explain the enantioselectivity of C–H hydroxylation by a chiral manganese porphyrin. A two-point hydrogen bonding favors pro-(S) C–H bond abstraction by 1.9 kcal mol−1, leading to (S)-hydroxylated products.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
