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Recent Progress on Transition Metal-catalysed Regioselective C–H Transformations Based on Noncovalent Interactions

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Published On ::

Org. Biomol. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0OB00703J, Review Article
Yoichiro Kuninobu, Takeru Torigoe
Transition metal-catalysed C–H transformations are powerful tools to obtain functionalised organic molecules from simple starting materials. To control regioselectivity is one of the most important issues in C–H transformations. Since...
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Synthesis of unsymmetrical benzils via palladium-catalysed α-arylation–oxidation of 2-hydroxyacetophenones with aryl bromides

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Org. Biomol. Chem., 2020, Advance Article
DOI: 10.1039/D0OB00575D, Paper
Open Access
Takanori Matsuda, Souta Oyama
Unsymmetrical benzils are synthesised by a one-pot tandem palladium-catalysed α-arylation and oxidation of 2-hydroxyacetophenones with aryl bromides.
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Copper(I)/Ganphos catalysis: enantioselective synthesis of diverse spirooxindoles using iminoesters and alkyl substituted methyleneindolinones

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Org. Biomol. Chem., 2020, Advance Article
DOI: 10.1039/D0OB00546K, Paper
Hao Cui, Ke Li, Yue Wang, Manman Song, Congcong Wang, Donghui Wei, Er-Qing Li, Zheng Duan, François Mathey
A copper/Ganphos-catalyzed asymmetric 1,3-dipolar cycloaddition of glycine iminoesters with alkyl substituted 3-methylene-2-oxindoles is described, producing the spiro[pyrrolidin-3,3'-oxindole]s in good yields with high ee.
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Blue emissive dimethylmethylene-bridged triphenylamine derivatives appending cross-linkable groups

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Org. Biomol. Chem., 2020, Advance Article
DOI: 10.1039/D0OB00622J, Paper
Kangyu Zhou, Hongfei Pan, Yongjie Zhang, Houchen Wang, Xiaofei Dong, Xiangkui Ren, Xianggao Li, Shirong Wang, Zhijian Chen
Blue-emissive and cross-linkable dimethylmethylene-bridged triphenylamine derivatives were synthesized and their optical and electrochemical properties were investigated.
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Phenylboronic acid-catalyzed tandem construction of S–S and C–S bonds: a new method for the synthesis of benzyl disulfanylsulfone derivatives from S-benzyl thiosulfonates

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Published On ::

Org. Biomol. Chem., 2020, 18,3243-3248
DOI: 10.1039/D0OB00442A, Communication
Raju Jannapu Reddy, Md. Waheed, Gamidi Rama Krishna
A novel and unique phenylboronic acid-catalyzed tandem construction of S–S and C–S bonds via dimerization–sulfonylation has been disclosed for the synthesis of benzyl disulfanylsulfone derivatives.
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Synthesis of methylene cyclopropane-fused chromenes and dihydroquinolines by sequential [4 + 2]- and [1 + 2]-annulation

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Org. Biomol. Chem., 2020, 18,3303-3311
DOI: 10.1039/D0OB00389A, Paper
Tianyu Lu, Xuange Zhang, Zhiwei Miao
A base promoted sequential [4 + 2]- and [1 + 2]-annulation of 2-hydroxychalcones or 2-tosylaminochalcones with prop-2-ynylsulfonium salts was developed.
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Base-promoted 1,6-conjugate addition of alkylazaarenes to para-quinone methides

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Org. Biomol. Chem., 2020, 18,3354-3359
DOI: 10.1039/D0OB00419G, Paper
Amritha Rayaroth, Rajat Kumar Singh, Kalyanakrishnan A. V., Krishna Hari, Alagiri Kaliyamoorthy
1,1,2-Triarylethanes embedded with an azaarene unit were prepared in a single step at ambient temperature via the sodium hexamethyldisilazide mediated 1,6-conjugate addition of unactivated alkylazaarenes on para-quinone methides (p-QMs).
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Chiral bifunctional sulfide-catalyzed asymmetric bromoaminocyclizations

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Org. Biomol. Chem., 2020, 18,3367-3373
DOI: 10.1039/D0OB00459F, Paper
Takumi Nakamura, Ken Okuno, Kazuma Kaneko, Masahiro Yamanaka, Seiji Shirakawa
A chiral bifunctional sulfide catalyst bearing a urea moiety promotes the enantioselective bromoaminocyclization of 2-allylanilines to produce optically active 2-substituted indolines.
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Synthesis of gem-difluoroalkenes via nickel-catalyzed allylic defluorinative reductive cross-coupling of trifluoromethyl alkenes with epoxides

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Published On ::

Org. Biomol. Chem., 2020, Advance Article
DOI: 10.1039/D0OB00535E, Communication
Xiao-Yu Lu, Run-Chuang Jiang, Jia-Mei Li, Chuang-Chuang Liu, Qing-Qing Wang, Hai-Pin Zhou
A nickel-catalyzed defluorinative reductive cross-coupling of trifluoromethyl alkenes with epoxides has been developed.
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CISF needs 4,500 addl personnel to man new 'Metro' routes

By archive.indianexpress.com
Published On :: Fri, 07 Aug 2009 11:37:35 GMT

With the Delhi Metro expanding its wings beyond Delhi, the CISF will require additional 4,500 personnel to guard the new operations of the mass rapid transport system.


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Climbing Everest, I've proved a tribal girl can do something: Malavath Poorna

By timesofindia.indiatimes.com
Published On :: Wed, 18 Jun 2014 00:04:38 IST

At just 13 years, Malavath Poorna from Telangana has become the youngest female climber in the world to scale Mount Everest. Speaking with Rohit E David, Poorna discussed how she has emerged from a family of agricultural labourers to become a mountaineer, the difficulties she faced while navigating Mount Everest, the one thought that kept her going — and how she wants to climb many more mountains now.


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Plea on metro card-address proof linking declined

By timesofindia.indiatimes.com
Published On :: Sat, 09 May 2020 16:37:36 IST


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Astronomers detect gravitational waves when Black Holes with asymmetric masses collided

By www.dnaindia.com
Published On :: Tue, 21 Apr 2020 07:03:00 GMT

The detection of Gravitational-wave in a collision between two black holes of substantially different masses has made astronomers excited.


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NASA's Hubble captures breakup of comet ATLAS into more than two dozen pieces

By www.dnaindia.com
Published On :: Wed, 29 Apr 2020 05:42:00 GMT

Hubble identified about 30 fragments on April 20, and 25 pieces on April 23.


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When McSher met Thor...

By www.rediff.com
Published On :: Mon, 24 Jun 2019 15:47:25 +0530

'When I met him, I was a behaving like a 16 year old!''He is incredible, very casual and chilled out.''He told me he would watch Gully Boy and then he said a dialogue from Gully Boy, 'Bahut hard!'.'


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Shraddha does something she has NEVER DONE BEFORE

By www.rediff.com
Published On :: Tue, 03 Mar 2020 17:02:02 +0530

'I have to pinch myself to believe that 10 years have just gone by.'


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'When #MeToo broke in India, I felt liberated'

By www.rediff.com
Published On :: Wed, 25 Mar 2020 19:50:27 +0530

'Nobody can put back and seal what the movement has unleashed -- conversation, awareness and support.'


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[ASAP] Controlling Surface Phase Transition and Chemical Reactivity of O3-Layered Metal Oxide Cathodes for High-Performance Na-Ion Batteries

By dx.doi.org
Published On :: Fri, 01 May 2020 04:00:00 GMT

ACS Energy Letters
DOI: 10.1021/acsenergylett.0c00700


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Blog: Can MeToo lead to a political party for and by women?

By blogs.timesofindia.indiatimes.com
Published On :: Sun, 14 Oct 2018 11:03:27 IST


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Blog: MeToo is about restoring civility

By blogs.timesofindia.indiatimes.com
Published On :: Sun, 14 Oct 2018 11:18:01 IST


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Blog: What 'good' guys need to know about #MeToo

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Published On :: Sun, 14 Oct 2018 11:29:51 IST


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Biometrics under Biomedical Considerations Amine Nait-Ali, editor

By library.mit.edu
Published On :: Sun, 20 Jan 2019 12:54:47 EST

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Gravitational Biology II: Interaction of Gravity with Cellular Components and Cell Metabolism / Wolfgang Hanke [and more]

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Published On :: Sun, 27 Jan 2019 13:01:18 EST

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Integrative structural biology with hybrid methods / editors, Haruki Nakamura, Gerard Kleywegt, Stephen K. Burley and John L. Markley

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Published On :: Sun, 17 Feb 2019 13:12:16 EST

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Biomimetic lipid membranes: fundamentals, applications, and commercialization / Fatma N. Kök, Ahu Arslan Yildiz, Fatih Inci, editors

By library.mit.edu
Published On :: Sun, 19 May 2019 07:20:37 EDT

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Encyclopedia of Biometrics edited by Stan Z. Li, Anil K. Jain

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Published On :: Sun, 18 Aug 2019 09:32:39 EDT

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Encyclopedia of metagenomics / edited by Karen E. Nelson

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Published On :: Sun, 18 Aug 2019 09:32:39 EDT

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Plant-Metal Interactions

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Published On :: Sun, 18 Aug 2019 09:32:39 EDT

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Aldehyde Dehydrogenases: From Alcohol Metabolism to Human Health and Precision Medicine / Jun Ren, Yingmei Zhang, Junbo Ge, editors

By library.mit.edu
Published On :: Sun, 1 Sep 2019 09:33:23 EDT

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Radiation in bioanalysis: spectroscopic techniques and theoretical methods / Alice S. Pereira, Pedro Tavares, Paulo Limão-Vieira, editors

By library.mit.edu
Published On :: Sun, 13 Oct 2019 07:39:15 EDT

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Hormones, Metabolism and the Benefits of Exercise.

By library.mit.edu
Published On :: Sun, 10 Nov 2019 07:38:48 EST

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Biometric recognition: 14th Chinese Conference, CCBR 2019, Zhuzhou, China, October 12-13, 2019, Proceedings / Zhenan Sun, Ran He, Jianjiang Feng, Shiguang Shan, Zhenhua Guo (eds.)

By library.mit.edu
Published On :: Sun, 17 Nov 2019 07:51:28 EST

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Genomics, proteomics, and metabolomics: stem cells monitoring in regenerative medicine / Babak Arjmand, editor

By library.mit.edu
Published On :: Sun, 22 Dec 2019 07:46:07 EST

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A semiotic methodology for animal studies Pauline Delahaye

By library.mit.edu
Published On :: Sun, 22 Dec 2019 07:46:07 EST

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Advances in biometrics: modern methods and implementation strategies / editor, G.R. Sinha

By library.mit.edu
Published On :: Sun, 19 Jan 2020 07:42:04 EST

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The microflow cytometer / [edited by] Frances S. Ligler, Jason S. Kim

By library.mit.edu
Published On :: Sun, 15 Mar 2020 07:45:28 EDT

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Genomics data analysis: false discovery rates and empirical Bayes methods / David R. Bickel, University of Ottawa, Ottawa Institute of Systems Biology, Department of Biochemistry, Microbiology and Immunology, Department of Mathematics and Statistics

By library.mit.edu
Published On :: Sun, 22 Mar 2020 07:24:15 EDT

Dewey Library - QH438.4.S73 B53 2019


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[ASAP] Exposure to Trichloroethylene Metabolite <italic toggle="yes">S</italic>-(1,2-Dichlorovinyl)-L-cysteine Causes Compensatory Changes to Macronutrient Utilization and Energy Metabolism in Placental HTR-8/SVneo Cells

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Published On :: Thu, 30 Jan 2020 05:00:00 GMT

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.9b00356


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[ASAP] Identifying Cysteine, <italic toggle="yes">N</italic>-Acetylcysteine, and Glutathione Conjugates as Novel Metabolites of Aristolochic Acid I: Emergence of a New Detoxification Pathway

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Published On :: Tue, 25 Feb 2020 05:00:00 GMT

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.9b00488


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[ASAP] Analysis of the Different Metabolic Phenotypes of Metalaxyl Enantiomers in Adolescent Rat by Using <sup>1</sup>H NMR Based Urinary Metabolomics

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Published On :: Tue, 10 Mar 2020 04:00:00 GMT

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.0c00011


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[ASAP] <italic toggle="yes">In Vitro</italic> Metabolism of Isopropylated and <italic toggle="yes">tert</italic>-Butylated Triarylphosphate Esters Using Human Liver Subcellular Fractions

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Published On :: Wed, 18 Mar 2020 04:00:00 GMT

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.0c00002


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[ASAP] Comprehensive <italic toggle="yes">In Vitro</italic> Metabolism Study of Bisphenol A Using Liquid Chromatography-High Resolution Tandem Mass Spectrometry

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Published On :: Thu, 02 Apr 2020 04:00:00 GMT

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.0c00042


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[ASAP] Synergy between Experiments and Computations: A Green Channel for Revealing Metabolic Mechanism of Xenobiotics in Chemical Toxicology

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Published On :: Fri, 10 Apr 2020 04:00:00 GMT

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.9b00448


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[ASAP] Cellular Metabolism in High-Throughput <italic toggle="yes">In Vitro</italic> Reporter Gene Assays and Implications for the Quantitative <italic toggle="yes">In Vitro</italic>–<italic toggle="yes&

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Published On :: Mon, 13 Apr 2020 04:00:00 GMT

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.0c00037


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[ASAP] Binding and Metabolism of Brominated Flame Retardant ß-1,2-Dibromo-4-(1,2-dibromoethyl)cyclohexane in Human Microsomal P450 Enzymes: Insights from Computational Studies

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Published On :: Wed, 15 Apr 2020 04:00:00 GMT

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.0c00076


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[ASAP] In Vitro Phase I Metabolic Profiling of the Synthetic Cannabinoids AM-694, 5F-NNEI, FUB-APINACA, MFUBINAC, and AMB-FUBINACA

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Published On :: Tue, 28 Apr 2020 04:00:00 GMT

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.9b00466


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[ASAP] Particulate Matter Toxicity Is Nrf2 and Mitochondria Dependent: The Roles of Metals and Polycyclic Aromatic Hydrocarbons

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Published On :: Thu, 30 Apr 2020 04:00:00 GMT

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.0c00007


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[ASAP] Effects of Arsenic on wnt/ß-catenin Signaling Pathway: A Systematic Review and Meta-analysis

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Published On :: Wed, 06 May 2020 04:00:00 GMT

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.0c00019


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