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Met faces service cuts without more cash, says chief

Sir Mark Rowley says he is "deeply troubled" by negotiations so far on the force's funding next year.




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College Football Playoff: Texas, Penn State join Top 4; Georgia, Miami plummet in rankings

Oregon, Ohio State, Texas and Penn State are the Top 4 teams in the latest edition of the College Football Playoff rankings, the selection committee announced. Week 11 losers Georgia and Miami plummeted in the rankings.




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After latest hit to helmet, Dolphins' Tua Tagovailoa says it's 'too hard' to protect himself

Tua Tagovailoa often gives fans pause by putting his head in harm's way, but the Miami Dolphins' quarterback, with a history of high-profile concussions, says it's "too hard" to protect himself in High-speed action.




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Americans Fell in Love With Science When the Breathtaking Leonid Meteor Shower Lit Up the Skies Across the Nation

In 1833, hundreds of thousands of shooting stars inspired songs, prophecies and a crowdsourced research paper on the origins of meteors




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Watch a Starlink Satellite Plummet Through the Atmosphere in Videos Captured Last Weekend

The fireball—one of many decommissioned satellites from SpaceX's internet service—was spotted by dozens of people across at least four states, and many mistook it for a meteor




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How to See the Stunning Leonid Meteor Shower This Weekend

Though the nearly full moon will likely outshine some of these speedy meteors, you may still be able to catch a glimpse of bright fireballs and low Earth-grazers




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Performance Bond Requirements - Metal Margin - Effective November 14, 2024





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Meta to Offer Less Personalised Ads in Europe to Appease Regulators

Meta Platforms plans to offer Instagram and Facebook users in Europe the option to receive "less personalised ads". These ads will also target users based on age, gender, and location, with some being unskippable for a few seconds.




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North Taurid Meteor Shower Peaks, Bringing Fireballs to US Night Skies

The North Taurid meteor shower, peaking November 11, offered skywatchers in the US a view of rare bright fireballs across the sky. Part of the Taurid meteor system, these meteors are known for their intensity and visibility, even under strong moonlight. Though fewer meteors occur in these showers, their brightness will make for a striking display originating from debris of Comet 2P/Encke.




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Meta Pushes Back Against FTC Effort to Toughen Privacy Order

A Meta lawyer told the FTC’s five commissioners at a hearing Tuesday that the consumer protection agency doesn’t have authority to modify the agreement without the company’s consent.




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Manila's first Muslim cemetery: Isko Moreno’s legacy

MANILA, Philippines — Former Manila Mayor Francisco “Isko Moreno” Domagoso has left an enduring mark on the city’s Muslim community by establishing Manila’s first Muslim Cemetery and Cultural Hall. Located in the Manila South Cemetery, the 2,400-square-meter site pays tribute to the Muslim community’s deep historical roots in the capital. “This is for all Muslims, particularly those in Manila, who have contributed to our nation’s capital,” Moreno said, stressing the cemetery’s importance as a symbol of Manila’s rich cultural heritage. The site is also a reminder for future generations of Manila’s historical identity as the “Land of the Rajahs,” ruled […]...

Keep on reading: Manila's first Muslim cemetery: Isko Moreno’s legacy





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FSRU Prometheas to leave Shanghai next month

The floating storage and regasification unit (FSRU) Prometheas, which will form part of the liquefied natural gas (LNG) project at he, will set sail for Cyprus from Shanghai at the beginning of December, Energy Minister George Papanastasiou said on Wednesday. Speaking at a meeting of the Nicosia chamber of commerce and industry (Evel), he said […]




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Half a metric tonne of meat smuggled from Republic found in Famagusta

A total of 448kgs of meat smuggled from the Republic were found by local police in Famagusta on Wednesday, the town’s Turkish Cypriot municipality said. The meat, all of it beef, was found in a refrigerator at a butcher’s shop in the town. It was confiscated by the municipality, while legal action was taken against […]




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Timothée Chalamet unveils Bob Dylan 'modified' his biopic script

Bob Dylan biopic 'A Complete Unknown' is set to release on December 25Timothée Chalamet, who has been taken on-board to play Bob Dylan’s biopic, revealed that the veteran singer and songwriter made alterations in the script of the upcoming movie. Wonka actor shared that Dylan was the...




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John Krasinski recalls love at first sight with wife Emily Blunt, 'the second I met her'

John Krasinski knew Emily Blunt was the right one for him “the second” he met her.In an interview with People for his Sexiest Man Alive cover story, he recalled the spark he felt in him when he met her Blunt.“I don't know what happened, but I remember someone introduced us, and...




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Meta Will Get Its Unwanted Day in Antitrust Court



A federal judge ruled on Wednesday that an FTC complaint alleging that Facebook's acquisitions of Instagram and WhatsApp were anticompetitive should proceed to a jury trial.




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Biden imposes a new methane emissions tax as he prepares to leave the White House

President Joe Biden's Environmental Protection Agency finalized a new rule Tuesday taxing methane emissions from the oil and gas sector, but critics argue the move is "irrelevant" and will serve to boost Big Oil and stifle innovation.



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Metabolic Compound Found to Regulate Appetite and Body Weight

Until now, β-hydroxybutyrate (BHB) has been known as a compound produced by the liver to be used as fuel.

The post Metabolic Compound Found to Regulate Appetite and Body Weight appeared first on Sci.News: Breaking Science News.




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Meta will have to defend itself from antitrust claims after all

The Federal Trade Commission will get a chance to argue its case for Meta’s breakup in court. On Wednesday, US District Judge James Boasberg allowed the FTC’s lawsuit against the social media giant to move forward (PDF link). The FTC first sued Meta in 2020 in an attempt to force the company, then known as Facebook, to divest itself of Instagram and WhatsApp. Alongside dozens of attorneys general, the agency alleged Meta acquired the platforms in 2012 and 2014 to stifle growing competition in the social media market.

This past April, Meta asked Judge Boasberg to dismiss the case. In addition to noting that the FTC had previously approved both acquisitions, Meta argued that the agency had failed to show that the company held monopoly power in the social networking services market, and that, in buying Instagram and WhatsApp, it had harmed consumers. Additionally, the company claimed that it had invested billions of dollars in both platforms and made them better as a result, to the benefit of social media users everywhere.

While he did not entirely dismiss the lawsuit, Boasberg did force the FTC to narrow its case, dismissing an allegation that Facebook had provided preferential access to developers who agreed not to compete with it.

“We are confident that the evidence at trial will show that the acquisitions of Instagram and WhatsApp have been good for competition and consumers. More than 10 years after the FTC reviewed and cleared these deals, and despite the overwhelming evidence that our services compete with YouTube, TikTok, X, Apple’s iMessage, and many others, the Commission is wrongly continuing to assert that no deal is ever truly final, and businesses can be punished for innovating,” a Meta spokesperson told Engadget. “We will review the opinion when it’s filed.”

Judge Boasberg will meet with the two sides on November 25 to schedule the trial. The FTC lawsuit, it should be noted, was filed under the previous Trump administration, though whether it moves forward and in what form will depend on who President-elect Trump appoints to lead the agency.

This article originally appeared on Engadget at https://www.engadget.com/big-tech/meta-will-have-to-defend-itself-from-antitrust-claims-after-all-155730259.html?src=rss




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Meta will reportedly bring ads to Threads as soon as January

Threads could start getting ads much sooner than Meta has let on. The company is now planning to bring ads to its newest app “early next year” with the first ads arriving in January of 2025, according to a new report in The Information.

That suggests Meta is looking to start making money on the rapidly growing service far sooner than Meta executives have previously suggested. In August, when the app reached 200 million users, Mark Zuckerberg said Threads could become the company’s next billion-user service. He said making money off the app would be a "multi-year" effort. 

“All these new products, we ship them, and then there's a multi-year time horizon between scaling them and then scaling them into not just consumer experiences but very large businesses,” Zuckerberg said. In the company’s most recent earnings call, Meta CFO Susan Li said the company doesn’t “expect Threads to be a meaningful driver of 2025 revenue at this time.”

According to The Information, Meta is planning a slow rollout for ads on Threads. The company will start with “a small number” of advertisers in January. It’s unclear how quickly the effort may expand. "Since our priority is to build consumer value first and foremost, there are no ads or monetization features currently on Threads," a Meta spokesperson said in a statement. 

Meta’s reported plans highlight just how quickly the service has grown in recent months. Threads has 275 million monthly users and is seeing more than 1 million new sign-ups a day, according to Zuckerberg. That makes it by far the largest of the X alternatives that have sprung up over the last couple years.

Bluesky, another popular Twitter-like service, has also seen significant growth recently, adding a million new users in the last week, the company said Tuesday. It is still much smaller than Threads with 15 million users. Like Threads, it also currently has no advertising and the company has said it plans to experiment with subscription-based features.

Update November 13, 2024, 2 PM ET: Added a statement from a Meta spokesperson. 

This article originally appeared on Engadget at https://www.engadget.com/social-media/meta-will-reportedly-bring-ads-to-threads-as-soon-as-january-183044211.html?src=rss




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DCGI calls for meeting with stakeholders of cosmetics industry to discuss issues

The Drugs Controller General of India (DCGI) will be meeting the stakeholders in the cosmetics industry in the country to discuss the issues relating to the regulatory provisions of the cosmetics sector.




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India celebrates joining Square Kilometre Array Observatory as member country, to set up regional data centre - The Indian Express

  1. India celebrates joining Square Kilometre Array Observatory as member country, to set up regional data centre  The Indian Express
  2. India becomes full member of SKA, aims to build world’s most sensitive radio telescope  Deccan Herald
  3. India to host regional centre for world’s biggest radio telescope  The Times of India
  4. India set to contribute Rs 1,250 crore for construction of Square Kilometre Array Observatory  Telegraph India
  5. India celebrates joining SKAO as member country  Hindustan Times




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Lalit Kumar vs Delhi Metro Rail Corporation on 13 November, 2024

:

The Appellant filed an (online) RTI application dated 23.03.2023 seeking the following information:

Page 1 of 5

"In continuation to RTI Application No- DMRCP/R/E/22/00489, received to you dated 15-11-2022 please provide some more details which were not given, related to the same points mentioned below:

1. My policy number of superannuation (GSPS) is 321581 and my LIC ID is 1779. Please provide my annuity number for the same.

2. In my last application number stated above I desired for DMRC pay scale comparison with the CDA pay scale which was denied to me. As an exemployee of your prestigious organization, I can help, it is available at D2 in the HR Manual- A Compendium of service rules in DMRC. Kindly provide.




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Publicitarul Bogdan Naumovici lansează lungmetrajul „Țăndări” în ianuarie 2025

Bogdan Naumovici, om de publicitate, își lansează lungmetrajul de debut pe 28 ianuarie 2025. Comedia „Țăndări”, distribuită de Forum Film, are în distribuție actori precum Alin Florea, Constantin Florescu, Cristian Bota, Nicodim Ungureanu, Cătălin Neamțu, Carmen Tănase, Dan Badea, Alex Conovaru, Sergiu Costache, Robert Tudor, Andreea Samson, și Gabriel Spahiu. De la spoturi publicitare pentru ...

The post Publicitarul Bogdan Naumovici lansează lungmetrajul „Țăndări” în ianuarie 2025 appeared first on Forbes Romania.




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A Mn(III)-catalyzed arylboronic acid-based cascade reaction via a nonclassical organometallic-radical mechanism

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00244J, Research Article
Hui-Min Qian, Jian-Dong Zhang, Shun-Jun Ji, Xiao-Ping Xu
An efficient Mn(III)-catalyzed cascade reaction of arylboronic acids, o-cyanoaryl isocyanides, and indoles was developed. The mechanism was fully investigated and elucidated.
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Diazenylation of active methyne compounds via arylazo sulfones

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00343H, Research Article
Ruiqing Wang, Lingkai Kong, Xinyu Zong, Minghui Zhang, Wenyi Chen, Yaxin Liu, Lingjuan Ma, Yulei Zhao
An interesting diazenylation reaction is demonstrated, which enables the efficient synthesis of hydrazones using active methyne compounds and arylazo sulfones.
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Highly selective separation of toluene/methylcyclohexane based on pagoda[5]arene nonporous adaptive crystals

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00364K, Research Article
Zhongwen Liu, Ming Li, Shuai Fang, Li Shao, Bin Hua, Feihe Huang
Herein the selective separation of toluene/methylcyclohexane based on pagoda[5]arene nonporous adaptive crystals is investigated.
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Recent advances in the metal-catalyzed asymmetric alkene hydrogenation of cyclic conjugated carbonyl compounds

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00227J, Review Article
Min Tan, Bram B. C. Peters, Pher G. Andersson, Taigang Zhou
This review summarizes the recent advances (2016–2023) in the stereoselective metal-catalyzed hydrogenation of cyclic α,β-unsaturated ketones, lactams and lactones since considerable developments were made. Where possible the application of these methodologies in synthesis is outlined.
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Modular synthesis of C2-symmetric nitrogen-containing polyaromatics via visible light-enabled reductive aza-6π electrocyclization

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00140K, Research Article
Qun-Liang Zhang, Qing-Tian Fan, Yirong Zhou, Jingli Zhang, Fang-Lin Zhang
Here, an unprecedented one-step modular construction of C2-symmetric N-PACs through  reduction/aza-6π electrocyclization was reported and the resultant C2-symmetric N-PAC could be  converted into  a powerful organic photocatalyst.
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Palladium-catalyzed [4 + 4] cycloaddition of 2-pyrones with 2-alkylidenetrimethylene carbonates: access to bridged eight-membered oxygen heterocycles

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00329B, Research Article
Huawei Lin, Biming Mao, Bing Han, Jiayi Luo, Yanqing Ge, Xuerui Zhang, Chang Wang, Hongchao Guo, Chunhao Yuan
A novel palladium-catalyzed [4 + 4] cycloaddition of 2-pyrones with 2-alkylidenetrimethylene carbonates has been developed for the synthesis of bridged eight-membered oxygen heterocycles in good yields and with excellent stereoselectivities.
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Neighboring group-directed asymmetric [2 + 2 + 2] cycloaddition to access C–N axially chiral indoles

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00042K, Research Article
Xuan Zhang, Qi Teng, Yanru Ren, Baitong Wei, Chen-Ho Tung, Zhenghu Xu
A Rh-catalyzed neighboring group-directed asymmetric [2 + 2 + 2] cycloaddition of 1,6-diynes and ynamides to generate C–N axially chiral indole derivatives has been developed.
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Sustainable synthesis of long-acting local anesthetics ropivacaine and levobupivacaine under batch and continuous flow via asymmetric hydrogenation

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00072B, Research Article
Zhi Yang, Hanlin Chen, Linxi Wan, Xinyi Feng, Lingshuang Ma, Pei Tang, Fen-Er Chen
A sustainable synthesis method was developed for long-acting local anesthetics, ropivacaine and levobupivacaine, using both batch and continuous flow processes via asymmetric hydrogenation.
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Review of application of the I2 and dimethyl sulfoxide combined reagent system to aryl methyl ketones for diverse transformations

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00396A, Review Article
Dong-Sheng Yang, Xiang-Long Chen, An-Xin Wu
The synthesis of small molecules and complex scaffolds is one of the most important topics in organic synthesis.
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Asymmetric [3 + 2] cycloaddition of donor–acceptor cyclopropanes with azadienes enabled by Brønsted base catalysis

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00002A, Research Article
Shu Li, Zhi-Hong Dong, Si-Yu Dan, Mei-Jun Zheng, Teng Long, Jie Zhan, Qing Zhou, Wen-Dao Chu, Quan-Zhong Liu
A chiral bifunctional Brønsted base-catalyzed enantioselective [3 + 2] cycloaddition of D–A cyclopropanes and azadienes is reported. The protocol features broad substrate scope, mild reaction conditions and high functional group tolerance.
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Organocatalytic formal [4 + 2] cycloaddition of o-quinone-methyl derivatives and 2-isocyanatomalonate diesters for the construction of chroman derivatives with adjacent quaternary chiral centers

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00141A, Research Article
Tong Xiong, Yi-Zhao Xu, Yao Wang, You-Cai Xiao, Fen-Er Chen
An asymmetric organocatalytic formal [4 + 2] cycloaddition/annulation cascade of ortho-quinone methides with 2-isocyanatomalonate diesters has been reported.
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Stereodivergent synthesis of chiral spiropyrazolones through Pd-catalyzed asymmetric sequential hydroalkylation of 1,3-enynes: unusual solvent effects on the enantioselectivity

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00358F, Research Article
Shan Wang, Long Li, Yifei Zheng, Luqing Li, Yingcheng Wang, Fangzhi Peng, Zhihui Shao
Chiral spiropyrazolones were constructed through Pd-catalyzed asymmetric sequential hydroalkylation of 1,3-enynes. Four stereoisomers could be obtained through substrate control and chiral ligand control.
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Nickel metallaphotoredox-catalyzed C–O bond activation/Csp2–Csp3 coupling enabled by phosphine

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00310A, Research Article
Jiaxi Fang, Ziheng Jian, Huan Liu, Yuting Wang, Xianbo Yu, Zehuai Mou, Huifei Wang
A novel and general nickel/photoredox dual catalysis platform for benzyl alcohol C–O bond activation/Csp2–Csp3 cross coupling of benzothiazolyl bromide and free alcohol, enabled by the catalytic generation of an alkyl radical, is reported.
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Metal-Free Cascade O-H Double Insertion Between I(III)/S(VI)-Ylides, Carboxylic Acids, and Alcohols: Modular Access to Unsymmetrical α,α-O,O-Substituted Ketones

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO00453A, Research Article
Shang-Shi Zhang, Jiaohang Wei, Wen-Xuan Zou, Qiong Hu, Mei-Zhu Bao, Dan-Ting Shen, Lin Xiao, Jia-Lin Song, Xiang Liu
The synthesis of unsymmetrical α,α-O,O-substituted ketones via O-H double insertion is appealing but remains constrained due to the lack of compatible coupling partners or uncontrollable selectivity. Herein, we present a...
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Visible-light-mediated catalyst-free synthesis of trifluoromethyl(spiro)-epoxides bearing contiguous quaternary centers

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00184B, Research Article
Jingchuan Lin, Yu Zhang, Jinxin Wang, Xinyu Han, Shenglan Zhu, Tong Li, Yanping Zhu, Wei-Dong Zhang
Herein, we describe a non-covalent complex-mediated epoxidation strategy that can yield highly selective central spiro-epoxides by irradiation with visible light without the need for catalyst addition.
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Dynamic kinetic resolution of α-F-β-ketone amides (esters) via Ir/f-diaphos-catalyzed asymmetric hydrogenation

Org. Chem. Front., 2024, 11,2201-2207
DOI: 10.1039/D4QO00125G, Research Article
Pengtao Yang, Dingguo Song, Lingxin Chen, Xianghua Zhao, Yirui Chen, Feiyang Shen, Fei Ling, Weihui Zhong
Highly reactive and highly stereoselective asymmetric hydrogenation of α-F-β-ketone amides (esters) via Ir/f-diaphos-catalyzed dynamic kinetic resolution is reported.
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Selective photochemical synthesis of primary arylamines and symmetric diarylamines via amination of aryl bromides using Ni(NH3)6Cl2 as a nitrogen source and catalyst

Org. Chem. Front., 2024, 11,2313-2318
DOI: 10.1039/D4QO00116H, Research Article
Zhehui Xu, Jianyang Dong, Geyang Song, Fuqiang Kong, Gang Li, Dong Xue
The selective synthesis of primary arylamines and diarylamines via coupling reactions with ammonia as a nitrogen source is still challenging.
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Palladium-catalyzed asymmetric [4 + 3] cycloaddition of acyclic α,β-unsaturated imines with trimethylenemethane donors: access to chiral non-fused azepines

Org. Chem. Front., 2024, 11,2326-2331
DOI: 10.1039/D4QO00064A, Research Article
Ting-Peng Li, Shuixiu Su, Jia-Huan Shen, Meng Zang, Yang-Zi Liu, Quannan Wang, Wei-Ping Deng
An efficient approach for the construction of non-fused azepines in good yields with high enantioselectivity via Pd-catalyzed asymmetric [4 + 3] cycloaddition was developed.
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Advancement in the C–H bond alkylation of (hetero)arenes catalyzed by the most abundant transition metal–iron

Org. Chem. Front., 2024, 11,2397-2417
DOI: 10.1039/D4QO00063C, Review Article
Chandini Pradhan, Benudhar Punji
Advancement in the direct C–H bond alkylation of arenes and heteroarenes using the catalysts based on the most abundant transition metal, iron, is summarized.
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NHC and photoredox catalysis dual-catalyzed 1,4-mono-/di-fluoromethylative acylation of 1,3-enynes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00372A, Research Article
Jiuli Xia, Ruiyang Ma, Lihong Wang, Jiaqiong Sun, Guangfan Zheng, Qian Zhang
NHC and photocatalysis dual-catalyzed mono/difluoromethylative acylation of 1,3-enynes was realized, providing fluormethyl-substituted allenyl ketones. SO2 might play a critical role in achieving high reactivity and selectivity.
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Visible-light Induced [1, 3]-Brook Rearrangements of α-Ketoacylsilanes and Its Subsequent Trapping in a Tandem Annulation with 1, 3, 5-Triazinanes and Azomethine Imines

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO00463A, Research Article
Zhong Zhang, Sirui Wu, Yuqiao Zhou, Bao-Lin Li, Siyue Xiao, Xiaohu Zhao, Zhipeng Yu
An unusual visible light-induced [1, 3]-Brook rearrangement of α-ketoacylsilanes for cascade cyclization with 1,3,5-triazinanes and C,N-cyclic azomethine imines has been developed under catalyst-free and mild reaction conditions. The strategy offers...
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Metal-free photoinduced denitrogenative alkylation of vinyl azides with alkyl radicals toward ketones

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00280F, Research Article
Hui Yin, Siqi Jian, Xiujuan Feng, Ming Bao, Xuan Zhang
A metal-free method for the synthesis of ketones via a visible-light induced denitrogenative alkylation of vinyl azides with alkyl radicals is presented.
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Base- and metal-free visible-light driven site-selective α-C(sp3)–H functionalization reaction of glycine derivatives with hydroxamic acid derivatives

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00425F, Research Article
Shiyun He, Hongying Fan, Xue Zhang, Meiling Ye, Jian Chen, Jinyu Hou, Tianle Huang, Li Guo, Guanghui Lv, Yong Wu
A visible-light-mediated radical–radical cross-coupling reaction between hydroxamic acid and N-phenyl glycine derivatives under base and metal free conditions is reported. A series of unnatural amino acids and peptides were obtained in good to excellent yields with good chemo-selectivity.
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Development of a photoenzymatic one-pot hybrid system for the direct synthesis of 3,3-disubstituted indole-2-ketones from N-methyl indoles

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00371C, Research Article
Yao Yao, Yuan Yu, Ming-Liang Shi, Xin-Yue Fan, Ru-De Lin, Kun Li, Wen-Dian Li, Fei-Yan Tao, Na Wang
The effective combination of photocatalysis and enzyme catalysis has been widely utilized for the synthesis of high-value-added products.
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