synthesis

[ASAP] From Industrial Method to the Use of Silylated P(III) Reagents for the Synthesis of Relevant Phosphonylated Molecules

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00490




synthesis

[ASAP] Total Synthesis of (+)-Oxo-tomaymycin

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00009




synthesis

[ASAP] Synthesis of 5-Substituted 1<italic toggle="yes">H</italic>-Tetrazoles from Nitriles by Continuous Flow: Application to the Synthesis of Valsartan

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00526




synthesis

[ASAP] Scalable Synthesis of Esp and Rhodium(II) Carboxylates from Acetylacetone and RhCl<sub>3</sub>·<italic toggle="yes">x</italic>H<sub>2</sub>O

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00164




synthesis

[ASAP] Photo-oxidation of Cyclopentadiene Using Continuous Processing: Application to the Synthesis of (1<italic toggle="yes">R</italic>,4<italic toggle="yes">S</italic>)-4-Hydroxycyclopent-2-en-1-yl Acetate

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00066




synthesis

[ASAP] Process Development and Large-Scale Synthesis of BTK Inhibitor BIIB068

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00087




synthesis

[ASAP] Improved Synthesis of 6-Chloro-5-methylpyridin-2-amine: A Key Intermediate for Making Lumacaftor

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00556




synthesis

[ASAP] <italic toggle="yes">N</italic>-Acyl-5,5-Dimethylhydantoins: Mild Acyl-Transfer Reagents for the Synthesis of Ketones Using Pd–PEPPSI or Pd/Phosphine Catalysts

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00054




synthesis

[ASAP] Scalable Synthesis of <italic toggle="yes">S</italic>-Fluoromethyl Benzenesulfonothioate

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00101




synthesis

[ASAP] Optimized Synthesis of 7-Azaindazole by a Diels–Alder Cascade and Associated Process Safety

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00184




synthesis

[ASAP] Continuous Process for Preparing the Difluoromethylating Reagent [(DMPU)<sub>2</sub>Zn(CF<sub>2</sub>H)<sub>2</sub>] and Improved Synthesis of the ICHF<sub>2</sub> Precursor

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00089




synthesis

[ASAP] Development and Production of an Enantioselective Tetrahydroisoquinoline Synthesis Enabled by Continuous Cryogenic Lithium–Halogen Exchange

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00141




synthesis

Synthesis and characterization of a supported Pd complex on carbon nanofibers for the selective decarbonylation of stearic acid to 1-heptadecene: the importance of subnanometric Pd dispersion

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00322K, Paper
Open Access
Elba Ochoa, Wilson Henao, Sara Fuertes, Daniel Torres, Tomas van Haasterecht, Elinor Scott, Harry Bitter, Isabel Suelves, Jose Luis Pinilla
Evaluation of the dispersion of Pd active sites on the catalyst performance during fatty acids decarbonylation to α-olefins was explored in this work. Pd subnanometric particles, clusters and aggregates were found to modulate the catalyst activity.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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synthesis

Development of an engineered thermostable amine dehydrogenase for the synthesis of structurally diverse chiral amines

Catal. Sci. Technol., 2020, 10,2353-2358
DOI: 10.1039/D0CY00071J, Paper
Lei Liu, Dong-Hao Wang, Fei-Fei Chen, Zhi-Jun Zhang, Qi Chen, Jian-He Xu, Zhi-Long Wang, Gao-Wei Zheng
Structurally diverse chiral amines and amino alcohols were synthesized using an engineered thermostable amine dehydrogenase, demonstrating its extensive synthesis potential.
The content of this RSS Feed (c) The Royal Society of Chemistry




synthesis

Direct synthesis of hydrogen peroxide without the use of acids or halide promoters in dissolution

Catal. Sci. Technol., 2020, 10,2333-2336
DOI: 10.1039/D0CY00416B, Communication
Open Access
G. Blanco-Brieva, F. Desmedt, P. Miquel, J. M. Campos-Martin, J. L. G. Fierro
We show the first catalyst family able to produce hydrogen peroxide at concentrations higher than 5 wt% in the absence of any promoter or stabilizing agent in dissolution.
The content of this RSS Feed (c) The Royal Society of Chemistry




synthesis

Synthesis and molecular structure of model silica-supported tungsten oxide catalysts for oxidative coupling of methane (OCM)

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00289E, Paper
Daniyal Kiani, Sagar Sourav, Israel E. Wachs, Jonas Baltrusaitis
Catalysts with only dispersed phase Na–WO4 sites where Na/W < 2 are slightly less active but significantly more C2 selective than the traditional Na2WO4/SiO2 catalysts that contain a crystalline phase where Na/W = 2.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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synthesis

Facile synthesis of oxygen-deficient nano-TiO2 coordinated by acetate ligands for enhanced visible-light photocatalytic performance

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00592D, Paper
Shaohua Pang, Yunfei Lu, Lin Cheng, Juming Liu, Huiyan Ma, Jucai Yang, Qiancheng Zhang
To date, various methods have been adopted to enhance the visible-light photocatalytic activity of nano-TiO2. However, a more facile and moderate method is still highly desirable. In this work, a...
The content of this RSS Feed (c) The Royal Society of Chemistry




synthesis

Bifunctional rhenium-copper nanostructures for intensified and stable ethanol synthesis via hydrogenation of dimethyl oxalate

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00579G, Communication
Zhongnan Du, Meng Chen, Xuepeng Wang, Xingkun Chen, Xiaolin Mou, Yuan Tan, Wenshao Yang, Chuanqi Huang, Hejun Zhu, Ronghe Lin, Yunjie Ding
Decorating small copper nanoparticles with isolated and/or clusted oxophilic rhenium species enables the first low-copper catalytic technology for intensified and stable ethanol production under mild conditions in dimethyl oxalate hydrogenation....
The content of this RSS Feed (c) The Royal Society of Chemistry




synthesis

Synthesis of vinyl chloride monomer by acetylene hydrochlorination with a ruthenium-based N-heterocyclic carbene complex catalyst

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00512F, Paper
Ming Cai, Haiyang Zhang, Baochang Man, Jian Li, Linfeng Li, Yanqin Li, Dongyang Xie, Renpan Deng, Jinli Zhang
With the implementation of Minamata Convention and the urgent demand for green, and efficient mercury-free catalysts, the carbon-supported IPr-(Ru)/AC catalyst was synthesized and assessed for its successful application in acetylene...
The content of this RSS Feed (c) The Royal Society of Chemistry




synthesis

Synthesis of FeCo-N@N-doped carbon oxygen reduction catalysts via microwave-assisted ammoxidation

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00376J, Paper
Hung-Chih Kuo, Shou-Heng Liu, Yan-Gu Lin, Chao-Lung Chiang, Dan CW Tsang
A core-shell structured FeCo-N@N-doped carbon derived from biomass wastes (sugarcane and palm kernel shell) is facilely prepared by hydrothermal carbonization and NH3 microwave ammoxidation method. The fabricated carbons are thoroughly...
The content of this RSS Feed (c) The Royal Society of Chemistry




synthesis

Selective synthesis of α-olefins by dehydration of fatty alcohols over alumina–thoria mixed catalysts

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00551G, Paper
Arif Ali, Chen Zhao
The selective and high-yield production of α-olefins by alcohol dehydration is challenging because the isomerization and polymerization olefin products are more thermodynamically stable. In this study, we prepared a physical...
The content of this RSS Feed (c) The Royal Society of Chemistry




synthesis

Eco-friendly synthesis of glutathione-capped CdTe/CdSe/ZnSe core/double shell quantum dots: their cytotoxicity and genotoxicity effects on Chinese hamster ovary cells

Toxicol. Res., 2019, 8,868-874
DOI: 10.1039/C9TX00113A, Paper
Neo Mervyn Monaheng, Sundararajan Parani, Mary Gulumian, Oluwatobi Samuel Oluwafemi
In this work, we report green one-pot synthesis, cytotoxicity and genotoxicity of glutathione-capped CdTe/CdSe/ZnSe heterostructured quantum dots (QDs) using a label-free xCELLigence RTCA system as well as the Cytokinesis Blocked Micronucleus assay.
The content of this RSS Feed (c) The Royal Society of Chemistry




synthesis

Tin thiocarbonohydrazone complexes: synthesis, crystal structures and biological evaluation

Toxicol. Res., 2019, 8,862-867
DOI: 10.1039/C9TX00109C, Paper
Jin Wang, Yu-Ting Wang, Yan Fang, Yan-Li Lu, Ming-Xue Li
Three organotin thiocarbonohydrazone complexes have been synthesized, and growth inhibition assays indicated that complex 3 has the highest tumor cell selectivity.
The content of this RSS Feed (c) The Royal Society of Chemistry




synthesis

Facile synthesis of core–shell structured Si@graphene balls as a high-performance anode for lithium-ion batteries

Nanoscale, 2020, 12,9616-9627
DOI: 10.1039/D0NR01346C, Paper
Anif Jamaluddin, Bharath Umesh, Fuming Chen, Jeng-Kuei Chang, Ching-Yuan Su
Encapsulating silicon (Si) nanoparticles with graphene nanosheets in a microspherical structure is proposed to increase electrical conductivity and solve stability issues when using Si as an anode material in lithium-ion batteries (LIBs).
The content of this RSS Feed (c) The Royal Society of Chemistry




synthesis

Exploring the direct synthesis of exchange-spring nanocomposites by reduction of CoFe2O4 spinel nanoparticles using in situ neutron diffraction

Nanoscale, 2020, 12,9440-9451
DOI: 10.1039/D0NR00912A, Paper
Jakob Voldum Ahlburg, Cecilia Granados-Miralles, Frederik Holm Gjørup, Henrik Lyder Andersen, Mogens Christensen
In situ neutron powder diffraction (NPD) was employed for investigating gram-scale reduction of hard magnetic CoFe2O4 (spinel) nanoparticles into CoFe2O4/CoFe2 exchange-spring nanocomposites via H2 partial reduction.
The content of this RSS Feed (c) The Royal Society of Chemistry




synthesis

Triplet photosensitizer-nanotube conjugates: synthesis, characterization and photochemistry of charge stabilizing, palladium porphyrin/carbon nanotube conjugates

Nanoscale, 2020, 12,9890-9898
DOI: 10.1039/D0NR02136A, Paper
Luis M. Arellano, Habtom B. Gobeze, María J. Gómez-Escalonilla, José Luis G. Fierro, Francis D'Souza, Fernando Langa
SWCNTs covalently modified with a triplet photosensitizer, palladium porphyrin, have been newly prepared and photoinduced charge separation is reported.
The content of this RSS Feed (c) The Royal Society of Chemistry




synthesis

A unique synthesis of rare-earth-Co-based single crystal particles by “self-aligned” Co nano-arrays

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR00490A, Paper
Qiong Wu, Liying Cong, Yue Ming, Chenglin Li, Zhenhui Ma, Xiangyu Ma, Yatao Wang
In this study, anisotropic SmCo5 magnets were prepared by a distinctive method, which is the high-temperature reductive annealing of Co@Sm2O3 with specially designed nanostructure. High resolution transmission electron microscope and...
The content of this RSS Feed (c) The Royal Society of Chemistry




synthesis

Synthesis of monodisperse water-stable surface Pb-rich CsPbCl3 nanocrystals for efficient photocatalytic CO2 reduction

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR02917C, Communication
Jingrun Zhu, Yihua Zhu, Jianfei Huang, Lu Hou, Jianhua Shen, Chunzhong Li
Surface Pb-rich lead halide perovskite nanocrystals (NCs) with high stability and monodispersity in water have been synthesized using a general and convenient liquid-solid-interpenetration (LSI) method. In this process, water molecules...
The content of this RSS Feed (c) The Royal Society of Chemistry




synthesis

Energy and transient power minimization during behavioral synthesis




synthesis

FPGA-based implementation of concatenative speech synthesis algorithm




synthesis

Efforts toward the first enantioselective total synthesis of praziquantel and synthetic model studies on ecteinascidin 743 by novel aromatic C-H insertion methodology




synthesis

Synthesis and characterization of potential drug delivery systems using nonionic surfactant "niosome"




synthesis

Synthesis of nanostructures in single crystal silicon carbide by electron beam lithography




synthesis

High level synthesis of an image processing algorithm for cancer detection




synthesis

Synthesis and magnetic properties of polymer nanocomposites




synthesis

Studies in rhodium catalyzed intramolecular C-H insertion of amino acid derived α-diazo-β-(substituted)acetamides and its application to the total synthesis of clasto-lactacystin β-lactone




synthesis

The utilization of enzymes in the synthesis and modification of natural and non-natural compounds




synthesis

Characterization of preliminary breast tomosynthesis data




synthesis

Photosynthesis and respiration in five species of benthic foraminifera that host algal symbionts




synthesis

VHDL coding style guidelines and synthesis




synthesis

Effects of hydrodynamic regime on photosynthesis in the green alga Caulerpa




synthesis

Leakage power driven behavioral synthesis of pipelined asics




synthesis

Heme biosynthesis: structure-activity studies of murine ferrochelatase




synthesis

Mode of action and structure-activity studies of N-alkylthio beta-lactams and N-alkylthio-2-oxazolidinones, and synthesis of second-generation disulfide Inhibitors of beta-Ketoacyl-Acyl Carrer Protein Synthase III (FabH) as potent antibacterial agents




synthesis

Design and synthesis of core structural intermediates for novel HIV-1 protease inhibitors & synthesis, biological activity and molecular modeling of novel 20S proteasome inhibitors




synthesis

The theoretical modeling, design, and synthesis of key structural units for novel molecular clamps and pro-apoptotic alpha helix peptidomimetics




synthesis

Chemo-enzymatic route to synthesis of biodegradable polymers and glycolipid analogs




synthesis

Synthesis and characterization of type II silicon and germanium clathrates




synthesis

Assessing the role of filler atoms in skutterudites and synthesis and characterization of new filled skutterudites




synthesis

Zeolite synthesis from municipal solid waste ash using fusion and hydrothermal treatment