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Peptide-linked perylenebisimide and ferrocene dicarboxylic acid conjugates with tunable optoelectronic properties

New J. Chem., 2024, 48,7225-7234
DOI: 10.1039/D3NJ05809C, Paper
Biswanath Hansda, Soumyajit Hazra, Niladri Hazra, Purnadas Ghosh, Arindam Banerjee
Peptide linked perylenebisimide and ferrocene dicarboxylic acid conjugates display wonderful and tunable optoelectronic properties.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Self-assembled superstructures derived from suitably substituted phenanthro[9,10-d] imidazole-based Zn(II)/Cd(II) complexes for selective detection of acetone

New J. Chem., 2024, 48,7456-7468
DOI: 10.1039/D4NJ00450G, Paper
Mallayasamy Siva, Sheethal Sasi, Priya Rana, Raj Kumar Bera, Yuvaraj Sivalingam, Priyadip Das
Newly synthesized (L1)2M, (L2)2M, and (L3)2M (M = Zn(II)/Cd(II)) self-assembled into well-ordered superstructures and exhibited promising potential for developing a new class of sensor devices for human health monitoring and environmental safety measurements.
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Nanopolyhedral Zn/Fe-NC derived from bimetallic zeolitic imidazole frameworks as an efficient catalyst for the oxygen reduction reaction in an air-cathode microbial fuel cell

New J. Chem., 2024, 48,7092-7101
DOI: 10.1039/D3NJ05279F, Paper
Qianwu Wang, Jingzhao Lu, Songlin Liu, Boqu Yu, Bolong Liang
The synergistic effect of Zn, N and moderate Fe doping enhances the ORR performance. The maximum power density of the Zn/Fe-NC-0.5 MFC is 1954 ± 20 mW m−2.
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Persulfate promoted regioselective C-1 thiocyanation of imidazo[1,5-a]pyridines under visible light irradiation in water

New J. Chem., 2024, 48,7041-7044
DOI: 10.1039/D4NJ00327F, Communication
Pallavi Saha, Samarpita Das, Harish K. Indurthi, Rohit Kumar, Deepak K Sharma
A visible light-mediated, photocatalyst-free, persulfate-promoted approach has been explored for regioselective C-1 thiocyanation of imidazo[1,5-a]pyridines.
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1-Butyl-3-methylimidazolium hydrogen sulfate-induced structure modification and reconstruction of nickel foams for oxygen evolution reactions

New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ05752F, Paper
Huamei Yang, Ziqin Chen, Kai Luo, Mengjun Yu, Yao Zhang
Surface chemical etching for the in situ growth of metal–organic materials and electrochemical reconstruction are expected to efficiently improve the catalytic performance of oxygen evolution reactions (OERs).
To cite this article before page numbers are assigned, use the DOI form of citation above.
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KOH-mediated synthesis of amides from azides and 1,3-dicarbonyl compounds

New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ05813A, Paper
Zhuoran Yang, Yao Xu, Xiaoming Liao, Wenjun Wang, Chang Lyu, Xiaoxiang Zhang
Aryl amides were prepared through KOH-mediated [3+2] cycloaddition/Wolff rearrangement from organic azides and 1,3-dicarbonyl compounds.
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Consequences of twisting of the flexible arms of imidazole-derived urea in zinc-dicarboxylate coordination polymers

CrystEngComm, 2024, 26,1976-1985
DOI: 10.1039/D4CE00005F, Paper
Satyendra Verma, Rinki Brahma, Jubaraj B. Baruah
A semi-flexible imidazole-based urea ligand, 1-(3-(1H-imidazol-1-yl)propyl)-3-phenylurea, and three zinc-dicarboxylate coordination polymers possessing the ligand were synthesized and characterized.
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Study on growth technology and optical properties of large size and high quality methylamine lead bromide single crystals

CrystEngComm, 2024, 26,2003-2008
DOI: 10.1039/D4CE00028E, Paper
Yuanlong Sun, Yundong Ma, Xiangting Li, Ziyu Hu, Guozong Zheng
As a new generation of photoelectric materials, organic–inorganic halide perovskites have been widely used in photodetectors, solar cells and other fields, but most of the current mainstream applications are thin film materials.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Koo, rival to X, to shut down amid failed acquisition talks

After struggling to secure new funding and exploring mergers with various platforms, Koo faced insurmountable challenges




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Govt prepares draft to use Middleware for broadcasting TV channel content without Internet

Middleware can be used to deliver broadcast content to portable devices through Wireless LAN/WiFi




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A dawn-to-midnight guide to celebrating New Year’s in Chennai

Bored of the usual plans and want to try something different to usher the new year in? We have got you covered from dawn to midnight



  • Life & Style

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How Will the Prabowo Administration Shape Indonesia’s Foreign Policy as a Middle Power?

How Will the Prabowo Administration Shape Indonesia’s Foreign Policy as a Middle Power? How Will the Prabowo Administration Shape Indonesia’s Foreign Policy as a Middle Power?

jacksonl




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US-Japan Alliance Resiliency Amid Risks

US-Japan Alliance Resiliency Amid Risks US-Japan Alliance Resiliency Amid Risks

jacksonl




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Aviation giant Boeing to cut 10 pc of its workforce amid rough path ahead




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Community Voices Unite: Tackling Bengaluru's Infrastructure Crisis Amid Heavy Rains




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Hungary's Finance Minister submits 2025 'peace budget' amid recession concerns




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Japan's Nikkei falls amid US trade policy concerns




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Posidex Technologies eyes US, Middle-East, APAC expansion

“This strategic rebrand aligns with our target to bring our solutions to high-growth international markets, strengthening its position as a leader in customer data management and technology innovation”




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Indian IT industry confident amid potential Trump return, sees reduced H1B visa dependency

 The U.S. remains the largest market for India’s IT exports, contributing 55% of its $200 billion in IT-BPM exports.




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Stone in the middle

With Anshar and Ninsar safe in the bullock cart, their mother takes them to a safer place…far, far away.




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Use of ionic liquids in amidation reactions for proteolysis targeting chimera synthesis

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00304G, Paper
Michela Eleuteri, Jenny Desantis, Gabriele Cruciani, Raimondo Germani, Laura Goracci
Selective degradation of disease-causing proteins using proteolysis targeting chimeras (PROTACs) has gained great attention, thanks to its several advantages over traditional therapeutic modalities.
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An efficient synthesis of mono-, di-, and tri-substituted 1,3-thiazoles employing functionalized thioamides as thiocarbonyl precursors

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00229F, Paper
Kalleshappa Sheela, Chikkappaiahnayaka Santhosh, Krishna Ravi Singh, Kalleshappa Sharath, Maralinganadoddi P. Sadashiva
Herein, we report an efficient strategy to synthesize functionalized 1,3-thiazoles using alkyl 2-amino-2-thioxoacetates.
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Correction: Recent progress of core-substituted naphthalenediimides: highlights from 2010

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB90045F, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sheshanath V. Bhosale, Sidhanath V. Bhosale, Suresh K. Bhargava
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Synthesis of fluorescent 5-heteroarylpyrimidine-containing oligonucleotides via post-synthetic trifluoromethyl conversion

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00402G, Paper
Yuta Ito, Hisato Tanaka, Ayana Murakami, Yasufumi Fuchi, Yoshiyuki Hari
5-(Benzimidazol-2-yl)- and 5-(benzothiazol-2-yl)-pyrimidine bases-modified oligonucleotides were prepared by post-synthetic trifluoromethyl conversion and their fluorescence properties were measured.
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The synthesis of alk-2-ynl Weinreb amides via Pd/Cu-catalysed oxidative carbonylation of terminal alkynes

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00290C, Paper
Bharati Mourya, Sandip T. Gadge, Bhalchandra M. Bhanage
Synthesis of alk-2-ynl-Weinreb amides via Pd-catalyzed oxidative carbonylation of terminal alkynes and N,O-dimethylhydroxylamine hydrochloride at room temperature under low CO/O2 pressure is reported for the first time.
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DMSO promoted catalyst-free oxidative C–N/C–O couplings towards synthesis of imidazoles and oxazoles

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00383G, Paper
Debasish Bera, Rajib Sarkar, Tiyasa Dhar, Pinaki Saha, Prasanta Ghosh, Chhanda Mukhopadhyay
Dimethyl sulfoxide (DMSO)-promoted catalyst-free oxidative C–N coupling and C–O coupling under oxidant-free conditions are outlined.
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Synthesis of Asp-based lactam cyclic peptides using an amide-bonded diaminodiacid to prevent aspartimide formation

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00472H, Communication
Wen-Jie Li, Jun-You Chen, Hui-Xia Zhu, Yi-Ming Li, Yang Xu
A diaminodiacid (DADA) containing an amide bond can be used in Fmoc solid-phase peptide synthesis (SPPS) of an Asp-based lactam cyclic peptide with no aspartimide formation.
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Recent advances in spirocyclization of maleimides via transition-metal catalyzed C–H activation

Org. Biomol. Chem., 2024, 22,2916-2947
DOI: 10.1039/D3OB01904G, Review Article
Swadhin Swaraj Acharya, Sagarika Patra, Rojalini Maharana, Manaswini Dash, Liza Mama Barad, Bibhuti Bhusan Parida
In recent years, the maleimide scaffold has received a great deal of attention in C–H activation.
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Hydrosilylation of nitriles and tertiary amides using a zinc precursor

Org. Biomol. Chem., 2024, 22,3053-3058
DOI: 10.1039/D4OB00161C, Paper
Ravi Kumar, Rohan Kumar Meher, Himadri Karmakar, Tarun K. Panda
A competent and selective hydrosilylation of nitriles and tertiary amides catalyzed by zinc bis(hexamethyldisilazide) [Zn(HMDS)2] under solvent-free and mild conditions are reported, as a sustainable and desirable alternative to existing methods.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A phosphamide nucleotide analog: a substrate for polymerase synthesis of DNA

Org. Biomol. Chem., 2024, 22,2963-2967
DOI: 10.1039/D4OB00089G, Communication
Jiong Meng, Qiaqia Guo, Xiaona Zhai, Song Yang, Shuai Wang, Pengcheng Wang, Debin Ji
A phosphamide nucleotide analog (dNTPγNH2) exhibited higher stability than dNTPs and can be recognized by DNA polymerases in PCR.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Why opening the emergency door mid-flight is not possible




mid

Crypto firm Consensys to cut 20% of workforce amid macroeconomic, regulatory headwinds

The crypto firm added that elevated interest rates, inflationary pressures, and tightening liquidity have created a more “cautious macroeconomic environment”




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Perplexity AI CEO says “still haven’t gotten” a green card amid immigration debate ahead of U.S. Presidential Election 2024

Srinivas went on to work with OpenAI for a year before co-founding Perplexity AI in 2022




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Can mid-level healthcare providers compensate for physician shortages in rural India?

To make up for doctor shortages, several countries around the world have introduced a cadre of MLHPs into their health systems; however, in India, mainstreaming of MLHPs has time and again been met with resistance from organised medicine 




mid

Govt hopeful of 'bountiful harvest' amid food inflation headwinds

The government subsidised the sale of a few commodities to improve domestic supply and arrest the sharp spikes in retail prices of wheat, rice, edible oils, pulses, tomato, and onion




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‘Migration will become a human right’ – interview with Mohsin Hamid

The author of The Reluctant Fundamentalist talks to Graeme Green about extremism, the refugee crisis and feeling at home in the past.




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How to read Middle English poetry / Daniel Sawyer.

Oxford : Oxford University Press, [2024]




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Anthology of Japanese literature from the earliest era to the mid-nineteenth century / compiled and edited by Donald Keene.

New York : Grove Press, 1960.




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Tailoring the adsorption properties of imidazole-based halogen bonded organic frameworks for anionic dye removal

Mater. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QM00735B, Research Article
Shumeng Wang, Hongqiang Dong, Guanfei Gong, Siyi Lin, Jiahao Zhao, Zhennan Tian, Ya Lu, Xuguan Bai, Meimei Zhang, Lu Wang, Kang-Da Zhang, Shigui Chen
A novel class of [N⋯I⋯N]+ halogen-bonded XOFs were synthesized using imidazole ligands. XOF-TIB showed strong adsorption capacity and selectivity for anionic dyes, with excellent stability and reusability for environmental remediation.
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(WO + ICG)@PLGA@lipid/plasmid DNA nanocomplexes as core–shell vectors for synergistic genetic/photothermal therapy

Mater. Chem. Front., 2024, 8,3747-3757
DOI: 10.1039/D4QM00330F, Research Article
Yang Bai, Guoqing Feng, Qingbin Yang, Tingting Hua, Bowen Li, Hao-Lin Guo, Yuan Liu, Qing Yuan, Niansong Qian, Bin Zheng
(WO + ICG)@PLGA@PL could not only achieve a synergistic therapy effect of gene delivery and photothermal effect but also effectively inhibit tumor growth.
The content of this RSS Feed (c) The Royal Society of Chemistry




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“Delocalized π-bond” guided pyramidal nanocrystal superstructures for excellent light trapping in SERS

Mater. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QM00576G, Research Article
Yang Shang, Bo Ren, Xiaotian Wang, Jie Lin
A 2D CuI pyramidal superstructure is self-assembled in a manner similar to a delocalized π-bond, which effectively traps light and exhibits a remarkable SERS performance.
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A smart spiropyran-containing cellulose material for photopatterning, temperature and humidity sensing

Mater. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QM00773E, Research Article
Xue Zhou, Jishuai Liu, Congxia Xie, Zhongtao Wu, Lei Zhang, Xiliang Luo
A smart cellulose material can respond to light, heat and humidity. This study provides a design strategy for fabricating multiple stimuli-responsive materials.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Maharashtra’s Political Turmoil: Voters head to polls amid uncertain alliances and shifting loyalties

The last five years of the state’s political landscape, marked by defections and power struggles, have left voters wary. The roller-coaster twists in Maharashtra’s politics have sparked both intrigue and doubt, with alliances hanging by a thread and loyalties as uncertain as ever.




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Out-of-pocket expenditure in India decreasing amid govt's healthcare push




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R is for remote: The clash for control in the middle-class melodrama

The remote is one of the most symbolic objects for today’s generation of armchair activists, epitomising our yearning for change while exerting minimal physical effort to attain it.




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S is for Suitcase: Revolutionising middle-class travel 

No destination is too far, and no possibility far-fetched with the right luggage




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Mideast (India) Ltd. - Board Meeting Intimation for Intimation Of Board Meeting Under Regulation 29 (1) (A) Of SEBI (Listing Obligations And Disclosures Requirements) Regulations, 2015 For Consideration Of Un-Audited Financial Results For The Quarter Ende




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A doubly interpenetrated perylene diimide-based zirconium metal–organic framework for selective oxidation of sulfides powered by blue light

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06294A, Paper
Chao Wei, Ming Lu, Jing-Jing Li, Ze-Jiu Diao, Guoliang Liu, Xiao-Qin Liu, Lin-Bing Sun
A doubly interpenetrated perylene diimide-based zirconium metal–organic framework is developed as a heterogeneous photocatalyst for selective photocatalytic oxidation of organic sulfides powered by blue light.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Vertical Macroporous Chitosan Aerogel Adsorbents for Simple and Efficient Enhancement of Atmospheric Water Harvesting and Air Dehumidification

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA07005D, Paper
Zhiguang Guo, Changhui Fu, Yuxuan He, Anhui Yu, Guangyi Tian, Danyan Zhan, Huimin Zhang
Adsorption-based atmospheric water harvesting (SAWH) has become one of the effective methods to extract water from the air in arid regions due to its high efficiency and low energy consumption....
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NFL midseason special: best rookies, true Super Bowl contenders, surprises/disappointments & more | Football 301

The three man weave returns, as Nate Tice is joined by Matt Harmon & Charles McDonald for a special midseason awards show. The trio check in on their preseason takes, predict true Super Bowl contenders, give their biggest surprises & disappointments so far this season and much more.