A Democratic member of the U.S. Congress is doubling down as he faces calls to resign after expressing concern about trans-identified male athletes competing in female sports. 

The title compound, C14H8Cl2F3NO, was synthesized by the condensation between trifluoromethylaniline and dichlorosalicylaldehyde by nucleophilic addition, forming a hemiaminal, followed by a dehydration to generate an imine. The compound crystallizes in an orthorhombic Pbca (Z = 8) space group with a dihedral angle of 44.70 (5)° between the two aromatic rings. In the crystal, the molecules pack together to form a zigzag pattern along the c axis.

The synthesis, crystal structure, and Hirshfeld surface analysis of N-(4-methoxyphenyl)picolinamide (MPPA), C13H12N2O2, are presented. MPPA crystallizes in the monoclinic space group P21/n, with a single molecule in the asymmetric unit. Structural analysis reveals that all non-hydrogen atoms are nearly coplanar, and the molecule exhibits two intramolecular hydrogen bonds that stabilize its conformation. Supramolecular features include significant intermolecular interactions, primarily C—H...π and various hydrogen bonds, contributing to the overall crystal cohesion, as confirmed by energy framework calculations yielding a total interaction energy of −138.3 kJ mol−1. Hirshfeld surface analysis indicates that H...H interactions dominate, followed by C...H and O...H interactions, highlighting the role of van der Waals forces and hydrogen bonding in crystal packing.

Mid Cities Psychiatry has been awarded The Joint Commission's Gold Seal of Approval® for Behavioral Health Care and Human Services by powering through its performance standards.

Global cotton markets saw slight declines and stabilisation in recent weeks, with NY/ICE December futures trading between 67–75 cents/lb since June, now at 71 cents/lb. The global A Index dipped from 85 to 83 cents, while China's index dropped from 101 to 97 cents due to a weaker yuan. Indian and Pakistani spot prices also declined, but both rupees remained stable against the dollar.

Abelardo Morell
Camera Obscura: Early Morning View of the East Side of Midtown Manhattan, , 2014
Website - AbelardoMorell.net

Abelardo Morell was born in Havana, Cuba in 1948. He immigrated to the United States with his parents in 1962. Morell received his undergraduate degree in 1977 from Bowdoin College and an MFA from The Yale University School of Art in 1981. In 1997 he received an honorary degree from Bowdoin College.

His publications include a photographic illustration of Alice’s Adventures in Wonderland (1998) by Dutton Children’s Books, A Camera in a Room (1995) by Smithsonian Press, A Book of Books (2002) and Camera Obscura (2004) by Bulfinch Press and Abelardo Morell (2005), published by Phaidon Press. Recent publications include a limited edition book by The Museum of Modern Art in New York of his Cliché Verre images with a text by Oliver Sacks.

His work has been collected and shown in many galleries, institutions and museums, including the Museum of Modern Art, The Whitney Museum of American Art, the Metropolitan Art Museum in New York, The Chicago Art Institute, The San Francisco Museum of Modern Art, The Houston Museum of Art, The Boston Museum of Fine Art, The Victoria & Albert Museum and over seventy other museums in the United States and abroad. A retrospective of his work organized jointly by the Art Institute of Chicago, The Getty in Los Angeles and The High Museum in Atlanta closed in May 2014 after a year of travel. Abelardo will be having his first show at the Edwynn Houk Gallery in New York opening October 23, 2014 and will run until December 20, 2014 featuring a selection of new pictures.

Iain Middleton is based in the Learning Technology Unit at the University of Aberdeen where he is currently working on a 3-year JISC-funded project to develop Web teaching and learning packages around the Museums and Special Collections, having previously been Web Editor at The Robert Gordon University where he played a leading role in the comprehensive redevelopment of the institution's Web presence. He holds a degree in Human Computer Interaction from Heriot-Watt University and a Masters in Information Analysis (Distinction) from The Robert Gordon University where he also spent 5 years in research at the School of Information and Media, specialising in help desks, online user support systems and communication on the World Wide Web. He is a member of the Chartered Institute of Library and Information Professionals (CILIP) and maintains his research interest in the co-ordination of Web sites and help desks in user support, and the role of the Web in Higher Education. Iain gave a joint presentation with Mike McConnell on "Centralised Control Or Departmental Freedom?".

Iain Middleton is a lecturer in E-Business and ICT at the Robert Gordon University. He played a co-ordinating role in RGU's 2005 site-wide Web redevelopment - the second time he has done so, having previously been Web Editor when the site moved to a CMS in 2000. In the intervening years he worked at the University of Aberdeen's Learning Technology Unit, developing educational Web sites and project managing the development of staff and student portals. He has also been a researcher and a help desk slave. Iain is a writer for Faulkner Information Services and has published on help desks and user support, Web strategies and educational technology. Iain participated in a debate on "CMS: Challenging the Consensus". Iain can be contacted via http://www.imiddleton.com/?page=contact.

Midsummers Eve by Sally Caldwell Fisher is a(n) Limited Edition. The Edition is Limited to pcs

After Midnight Giclee by Alonzo Adams is a(n) Limited Edition. The Edition is Limited to Limited Edition 500 pcs

The RM85 is the latest in Ebac’s line of rotational molded polyethylene housing dehumidifiers.

• Rate cuts to date are an acknowledgement of growing confidence that inflation is on the path to 2% goal
• Hope productivity growth can outrun the effects of slowing population growth
• Won't let enthusiasm over rising productivity get ahead of data or commitment to reaching Fed goals

There isn't much of a hint on anything here.

Hi Ozbargainers,

I was watching in amazement as the TravelKon sim card deal clocked over 300+ votes, great deal and also indicative of the number of Ozbargainers thinking about taking off overseas in the next 3 months, so on this note being the ambulance chaser entrepreneur that I am, I thought - what a great time for a deal on Diarrhoea relief. I reached out to a new supplier and asked for a deal so I could offer an ATL on diarrhoea relief. Nova Pharma came good and after scouring the web I think I can say, this is by FAR the best price for this item delivered anywhere in Oz - At this price, why risk taking off without a box in your hand luggage.

The box says: "Lorrex acts to restore normal bowel function", and we all want that!

Item: 20x Lorrex Liquicaps, Loperamide Hydrochloride 2mg
Link: https://pharmacysavings.com.au/products/travel-essentials-tr…
Price: $3.99
Code: Not required
Exp: End July 2025
Delivery: FREE

I'm going to give a special shout out to a very Shorted dated product, but I know many of you don't mind buying short dated at the right price:

Item: 70x Fexit 180mg, Fexofenadine Hydrochloride
Price: $4.99
Delivery: FREE
Exp: End November 2024
Link: https://pharmacysavings.com.au/products/trust-fexit-180-fexo…

Ozbargains Favourites have again been restocked:

• 100x Hayfexo @ $19.99: https://www.ozbargain.com.au/node/776153
• 200x Cetirizne 200x Cetirizine @ $19.99: https://www.ozbargain.com.au/node/834351
• 200x Lorazol, Loratadine 10mg @ $19.99 https://www.ozbargain.com.au/node/837337 (RESTOCKED)
• 70x Cetirizine 10mg + 70x Loratadine 10mg + 48x Ibuprofen @ $17.99 https://www.ozbargain.com.au/node/873236
• 70x Trust Fexit 180mg + 70x Cetrine or 70x Lorazol @ $19.99: https://www.ozbargain.com.au/node/858658
• 192x Trust Ibuprofen 200mg, Coated Tablets @ $10.99 now $9.99 https://www.ozbargain.com.au/node/844425

These bulk deals are still powering along as well:
140x Cetirizine + 140x Loratadine + 140x Fexofenadine https://www.ozbargain.com.au/node/866620

First time poster, so please take it easy on me if ive done any mistakes with the post.

Just bought these from WestCoast Hifi & customer service been prompt and awesome. I have put some features below which i pulled from the website but I don’t think you can go wrong.

Key Features

• 2-way 9.2 mm Dynamic Drive Unit with Balanced Armature
• Up to 5 hours battery for earbuds. Additional 16 hours from charging case
• True 24-bit audio connection with Adaptive Active Noise Cancelling
• Bluetooth 5.0 with aptX™ Adaptive technology
• Audio retransmission from charging case

Hay veces que uno no puede guardarse los mejores bares...

Man ploughs car into crowd in southern China, leaving 35 dead amid divorce rage

Latest news bulletin | November 13th – Midday

Operating revenue remained largely unchanged at Rs 1,430 crore compared to Rs 1,426 crore in FY23. The company, which secured its maiden fundraise last year, saw a 40% surge in employee benefit expenses at Rs 71 crore, while finance costs rose nearly 50% to Rs 29.5 crore. Total expenses increased to Rs 1,460 crore from Rs 1,432 crore in FY23.

Broncos return home Sunday after two straight tough losses on the road against the Atlanta Falcons.

Major Asia-Pacific stock exchanges traded mostly lower on Thursday amid more economic data and earnings reports.The Australian Bureau of Statistics revealed that the seasonally adjusted unemployment r...

APNX is thrilled to introduce APNX V1, a mid-tower case designed for customizable cooling precision for both GPU and CPU, housed in a sleek, dual-chamber structure with a panoramic view.

The post APNX Introduces V1 Mid-Tower Case appeared first on ThinkComputers.org.

Spirit Airlines' stock plunged 59% on Wednesday as the budget airline worked with creditors to restructure debt amid reports the company could file for bankruptcy protection within the next few weeks.

Boeing started issuing layoff notices Wednesday to 17,000 employees to cut 10% of its workforce in an effort to shore up the aerospace giant's shaky finances.

Spirit Airlines' stock plunged 59% on Wednesday as the budget airline worked with creditors to restructure debt amid reports the company could file for bankruptcy protection within the next few weeks.

Boeing started issuing layoff notices Wednesday to 17,000 employees to cut 10% of its workforce in an effort to shore up the aerospace giant's shaky finances.

Schmidt has become a stable, steady force along Florida's blueline since signing with the Panthers over the summer

Windsor, Ont.,'s massive electric vehicle battery plant expects to start producing cells by July — amid uncertainty surrounding possible automotive-related tariffs imposed by the U.S., as threatened by Donald Trump during his election campaign.

While SA's commercial property prospects are improving along with renewed interest from investors, Dipula Income Fund says Johannesburg's water crisis is a significant concern for landlords, carrying serious ramifications for fire protection and insurance.

It was also learnt that India A players have reported in Perth and will be part of the intra-squad match.

India conveyed its stance of not travelling to Pakistan for the ICC Champions Trophy, citing security concerns.

The notice claims that The Great Indian Kapil Show allegedly disrespects Rabindranath Tagore's legacy and risks offending cultural and religious sentiments

Maharashtra Chief Minister Eknath Shinde, whose bag check dominated the political discussions on the poll-bound state today, played it down in an interview with NDTV, saying it was a routine matter for him.

The notice claims that The Great Indian Kapil Show allegedly disrespects Rabindranath Tagore's legacy and risks offending cultural and religious sentiments

Rajasthan Candidate Naresh Meena Who Slapped Poll Official Arrested Amid High Drama

[SAnews.gov.za] South Africa has reiterated its call for calm and restraint following post-election protests in Mozambique.

London — Germany's plan to hold a snap election in February has raised uncertainties over the country's military aid program for Ukraine, as the government has not yet approved its 2025 budget. Berlin is the second biggest donor of weapons and equipment to Kyiv, after the United States. The political turmoil in Europe's biggest economy comes as allies prepare for a second term for President-elect Donald Trump in the United States. Trump has repeatedly questioned U.S. support for Ukraine. February vote Germany's main political parties agreed to hold the election on February 23, following the collapse of the ruling three-party coalition government earlier this month. Chancellor Olaf Scholz is due to introduce a confidence motion in parliament next month, which he is expected to lose, paving the way for a general election. Scholz has said he will stand again as the Social Democrats' candidate, although some in the party have questioned whether he is the best choice amid low approval ratings. The chairman of the Social Democrats in the German parliament, Rolf Mützenich, insisted Tuesday that Scholz was the right candidate. "I am firmly convinced that Olaf Scholz has done this country good in the last three years under the most difficult conditions. He has done everything to ensure that the coalition stays together. We have not only experienced the attack by Russian troops on Ukraine, but we have also helped Ukraine. We have also created important economic stabilization effects in Germany," Mützenich told reporters in Berlin. Opposition poll lead However, the main opposition Christian Democrats have a big lead in the polls. The party's leader, Friedrich Merz, argued for a quicker election. "We are basically losing around a month for the election to the next German parliament and thus also for the formation of a government after the next election," Merz told reporters Tuesday. "I just want to remind you that we do not have a federal budget for 2025. We are going into 2025 with this serious omission, with this heavy burden. And that is why it is completely unknown what will become of it," he added. Debt dispute The current government — a coalition between the Social Democrats, the Green party and the Free Democrats — collapsed last week following disagreements over raising new debt to finance the 2025 budget, including the provision of military aid to Ukraine. A so-called debt brake in Germany's constitution restricts the government's ability to take on new loans. Berlin has given Kyiv around $11 billion in weapons and equipment since Russia's February 2022 full-scale invasion. The outgoing government had planned to cut that aid to just over $4 billion next year. "Broadly speaking, there was a consensus that supporting Ukraine remains a priority for Germany. The question was just where and how to get and raise the finances for that," said Mattia Nelles, founder of the German-Ukraine Bureau, a political consultancy based in Düsseldorf, who said the February election was "bad timing for Ukraine, bad timing for Europe." 'Leadership vacuum' "It means Germany will be preoccupied with itself for a few months before we have a new government with a hopefully strong mandate — a coalition that could take literally until next summer, or in the worst case, even until autumn. So that is a leadership vacuum in Europe, and that's bad news for everyone involved," Nelles said. The election is due to take place just weeks after the January 20 inauguration of Donald Trump as the next U.S. president. "The worst case that many fear in Berlin and Kyiv [is] an incoming Trump administration taking power in January then slashing or ending the Ukraine aid, that will force the German government, the lame duck Scholz government with the current parliament, to increase the funding for Ukraine." "It's important to note that there is still a majority in the old parliament, even before the new parliament is elected, to increase the aid, to take new debt and amend the constitution for that, to take new debt to support Ukraine ... but it's going to be difficult politically to implement that," Nelles said. European security Trump's presidency could have wider implications for European security, including the deployment of U.S. forces and equipment, such as long-range missile systems, says analyst Marina Miron, a defense analyst at Kings College, London. "What else might be reversed is the placement of Tomahawk [U.S. missiles] in Germany. So, we have quite a situation where, let's say, Trump might pursue an anti-globalist agenda and push NATO countries to invest more of their GDP into defense," Miron told VOA. Russian assets Europe froze around $200 billion in Russian assets following Moscow's invasion of Ukraine. The interest is being used to help fund weapons for Kyiv, while the G7 group of rich nations has implemented a loan plan for Ukraine using the Russian assets as collateral. At a time of fiscal pressures in Europe, some argue it's time to seize the assets entirely and give them to Ukraine. "Europe is sitting on a war chest of 200 billion U.S. dollars of frozen Russian assets," said analyst Mattia Nelles. "And I think the incoming Trump administration will push the Europeans to go further. And that's welcome news from the Ukrainian side — to not just give loans and credit based on frozen Russian assets, but to move to confiscate the assets themselves. And that's certainly something many in Germany also support," he added. Economic pressures Chancellor Scholz oversaw German efforts to end reliance on cheap Russian energy. However, analysts say that has driven inflation and undermined confidence in Europe's biggest economy. Scholz also was seen as reluctant to make bolder decisions on arming Ukraine, including the supply of long-range Taurus missiles, something Kyiv has repeatedly requested. Ukraine may be hoping that a change in leadership in Berlin could unblock more military aid, said Nelles. "We are looking at a new, potentially stronger government, which, if it's led by [Christian Democrat leader] Friedrich Merz, might be taking some of the bolder decisions which Scholz had hesitated to take, including the delivery of Taurus. But everyone hoping for that, I would urge caution," he said. Germany's economic constraints won't disappear with new leadership, said analyst Marina Miron. "Let's assume, for a moment, there is somebody who would drive this policy forward and who would have much more resolve than Scholz. The problem is the German budget. The problem is also that defense contractors in Europe are now affected, as other companies, by the disruption in the global supply chain," she told VOA. Germany is also struggling to overcome decades of underinvestment in its armed forces, something the next government will have to address, Miron added. "The dictates of German strategic culture just go against the grain of the current threat landscape, when it comes to bigger investment in defense," she said.

Today, Somaliland took a significant step in its democratic journey, holding simultaneous presidential and political party…

The post Somaliland Elections Officially Begin Amid High Turnout and Minor Delays appeared first on Horseed Media.

“The shockwaves from Israel’s ongoing and indiscriminate warfare on Gaza and Lebanon are reverberating across this entire region. Neither the horrific assault on Israeli civilians on 7 October 2023, nor the indiscriminate missiles launched by militant groups from Lebanon, can justify the degree of destruction on civilian lives and infrastructure in the region that I […]

[Capital FM] NAIROBI -- United States Ambassador to Kenya, Meg Whitman has announced her resignation after two years of being stationed in Kenya.

Demi Moore may never forgive Rob Lowe amid Bruce Willis’ health battleDemi Moore not happy with Rob Lowe as he revisits their past fling amid Bruce Willis ongoing health battle.A source spilled to RadarOnline.com, Moore believed it was “mean and even dimwitted” for Lowe as he...