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Rare-earth metal complexes bearing electrophilic and nucleophilic carbon centres and their unique reactivity patterns towards pyridine derivatives

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04197F, Edge Article
Open Access
weikang Wu, Thayalan Rajeshkumar, Shan Zhu, Fuxiang Chai, Dongjing Hong, ZeMing Huang, Qingbing Yuan, Laurent Maron, Shaowu Wang
The rare-earth metal dialkyl complexes (κ2-L1)RE(CH2SiMe3)2(THF)2 [RE = Lu(1a), Yb(1b), Er(1c), Y(1d), Dy(1e)] (L1 = 1-(2-N-C5H10NCH2CH2)-3-(2,6-iPr2C6H3N=CH)-C8H4N) and the rare-earth metal monoalkyl complexes (κ2-L1)2RE(CH2SiMe3)(THF)n [n = 0, RE = Lu(2a), Yb(2b);...
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Pronounced Electronic Modulation of Geometrically-Regulated Metalloenediyne Cyclization

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05396F, Edge Article
Open Access
Sarah E. Lindahl, Erin M. Metzger, Chun-Hsing Chen, Maren Pink, Jeff Zaleski
Using a diverse array of thermally robust phosphine enediyne ligands (dxpeb, X = Ph, Ph-pOCH3, Ph-pCF3, Ph-m2CH3, Ph-m2CF3, iPr, Cy, and tBu) a novel suite of cisplatin-like Pt(II) metalloenediynes (3,...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Carnatic music at an eclectic festival

For the first time, the Celebrate Bandra fest will have a classicalmusic concert featuring vocalist Vasumathi Badrinathan




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Still classy after all these years

Meet the team that ensures that the taste of your favourite paneer makhanwala, murg makhani and au Gratin remains unchanged at Churchgate’s beloved Gaylord




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Classical constellations

Two dancers collaborate to use the Odissi form as a language to interpret folkloric myths from across the world




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A new asset class?

SEBI’s proposal to introduce an investment product that fits between MFs and PMS is an investment vehicle that could invest in asset classes such as equity and bonds and their derivatives




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Edelweiss Business Cycle NFO: Should you invest?

The new fund seeks to combine multiple factors to make the most of business cycles




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Bandhan Business Cycle Fund: Should you invest in the NFO?

The fund will follow a top-down approach to sector selection and bottom-up process to zero-in on stocks




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Car walkers' club

Breed of morning walkers. They drive to park for walk, but what else they do?




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NHRC conclave to boost human rights in Global South




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Baku climate talks: India not attending World Leaders Climate Action Summit




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Inertial co-focusing of heterogeneous particles in hybrid microfluidic channels with constantly variable cross-sections

Lab Chip, 2024, 24,5032-5042
DOI: 10.1039/D4LC00479E, Paper
Tianwei Zhao, Peng Zeng, Yuanting Zhang, Jinxia Li, Hui Sun, Imrich Gablech, Honglong Chang, Xichen Yuan, Pavel Neužil, Jianguo Feng
Inertial focusing chips based on hybrid microfluidic channels were presented for high-efficiency heterogeneous particle co-focusing, offering significant applications in microfluidic flow cytometry and single-cell analysis.
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Self-actuated microfluidic chiplet for two-stage multiplex nucleic acid amplification assay

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00752B, Paper
Open Access
Felix Ansah, Marziyeh Hajialyani, Fatemeh Ahmadi, Yuming Gu, Ergün Alperay Tarım, Michael G. Mauk, Gordon A. Awandare, Haim H. Bau
Self-actuated chiplet for Penn-RAMP assay.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Real-time impedance-activated dielectrophoretic actuation for reconfigurable manipulation of single flowing particles

Lab Chip, 2024, 24,5145-5154
DOI: 10.1039/D4LC00622D, Paper
Alexis Lefevre, Cristian Brandi, Adele De Ninno, Filippo Ruggiero, Enrico Verona, Michaël Gauthier, Paolo Bisegna, Aude Bolopion, Federica Caselli
We present an original all-electrical platform that combines MIC-sensing and DEP-actuation for precise and selective trajectory control of single flowing particles.
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Integrated device for plasma separation and nucleic acid extraction from whole blood toward point-of-care detection of bloodborne pathogens

Lab Chip, 2024, 24,5124-5136
DOI: 10.1039/D4LC00571F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Abigail G. Ayers, Christia M. Victoriano, Samuel K. Sia
This work presents PRECISE, a device that integrates plasma separation and nucleic acid extraction, enabling streamlined sample preparation of whole blood for point-of-care diagnostics without external equipment or electricity.
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Optical tweezer-assisted cell pairing and fusion for somatic cell nuclear transfer within an open microchannel

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00561A, Paper
Yidi Zhang, Han Zhao, Zhenlin Chen, Zhen Liu, Hanjin Huang, Yun Qu, Yaowei Liu, Mingzhu Sun, Dong Sun, Xin Zhao
We developed a somatic cell nuclear transfer-electrofusion system for pairing and fusing oocytes and somatic cells with a thousand-fold volume difference. The system showed a 90.56% pairing efficiency, potentially boosting batch cloning efficiency.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Dual-drive acoustic micromixer for rapid nucleation and ultrafast growth of perovskite nanoparticles

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00721B, Paper
Zhifang Liu, Yuwen Lu, Wei Tan, Guorui Zhu
An acoustic micromixer driven by bubbles and sharp edges, controlling the nucleation and growth of perovskite nanoparticles.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Road safety class mandatory for driving licence applicants in Ernakulam from Dec. 2

“The sessions will include new road safety guidelines in keeping with advancements in automobiles and road construction and also amendments made to the Motor Vehicles Act in the recent past”




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CKCL, private players help fill gaps in non-biodegradable waste management in Ernakulam




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HC declines former Chief Secretary’s plea seeking exemption from personal appearance

Court exempts Palakkad Collector from personal appearance on condition that she will appear through virtual mode




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Boxing competition disrupted by man claiming to be YouTuber in Kerala




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HC flays police inaction in clearing blockade to Thiruvananthapuram Corporation office




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PDP declares support to LDF in forthcoming byelections

Decision assumes significance in the wake of a controversy over a reference in CPI(M) leader P. Jayarajan’s book that PDP supremo Abdul Nasir Maudany had a role in radicalising the Muslim youth in the State




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1,000 consumer clubs to be formed on campuses, says Kerala Minister




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Illegally mined sand, vehicles seized in Ernakulam




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Kerala School Sports & Games: Govt. determined to reclaim Kerala’s lost glory in sports, says CM Pinarayi Vijayan

‘Kerala could attract investments worth ₹5,050 crore to the sports sector by becoming the first State to hold a sports summit’




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No separate categories of schools in adjudging winners, clarifies Minister




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Chief Minister’s Trophy declared null and void due to false start




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Magneto claims the Suresh Mahindra Trophy




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Redefined upstages Santissimo to claim the HPSL Pune Derby




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Nightmare claims Raja Mahboob Karan Memorial Cup




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Neziah for the Madras Race Club Trophy




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Mandarino claims the Cubic Mysore Derby 2024




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Yukan claims the Rajyotsava Trophy




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Knotty Legend claims the General Rajendrasinhji Million




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FAME-III scheme unlikely to extend benefits to hybrid vehicles as govt focuses on EVs, cabinet note ready

Maruti Suzuki India, Toyota and Hyundai Motor have been lobbying for tax cuts on hybrid vehicles




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MoS Kirti Vardhan Singh heads to Kuwait amid fire tragedy, expects clarity upon arrival

The Indian Embassy in Kuwait has set up a helpline for family members, and Prime Minister Modi has announced an ex-gratia relief of ₹2 lakh for the families of deceased Indian nationals




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Cabinet clears ₹2,254 crore for national forensic infra enhancement scheme

Under this scheme, the MHA will establish campuses of the National Forensic Sciences University and central forensic science laboratories in the country




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Self-declaration for advertisers limited to food, health sectors

I&B Ministry stated that advertisements issued for products related to food and health sectors will be required to upload an annual self-certificate on the Broadcast Seva Portal and Press Council of India portal.  




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Govt issues fifth draft notification to declare Western Ghats as ecologically sensitive area

The notification aims to safeguard the region by prohibiting activities such as mining, quarrying, sand mining, and new thermal power projects, while also restricting large-scale construction projects and townships




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Entering a decade of financial inclusion: PMJDY reaches 53 crore beneficiaries and ₹2.28 lakh crore in deposits

The scheme has largely been women-centric with 29.48 crore beneficiaries while 35.27 crore of total accounts are from rural and semi-urban branches




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Need clear laws, standard operating procedures to protect workers, manufacturers' interests: GTRI

Amid the ongoing Samsung workers’ strike in Tamil Nadu, economic think tank GTRI suggests seven-step strategy to foster a more stable industrial environment in the country




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Govt may bring flex fuel vehicles on a par with EVs

Mulls reducing GST, offering support to crops to boost ethanol output




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Vehicle scrappage policy receives lukewarm response: Auto dealers

State incentives boost scrappage uptake, but space limitations hinder progress




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Bentley Bentayga EWB: First Class

The Bentley Bentayga pretty much kickstarted the luxury SUV trend. How good is it nearly a decade later?




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Mercedes-Benz G-Class updated

The model line has for now been updated with new features and suspension tech.




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A Class Act

As the entry point to the once highly popular luxury sedan segment, the Mercedes-Benz A-Class has its work cut out for itself




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Mercedes-Benz GLE 450: Milestone-Class

More than 25 years after it was introduced as the M-Class, the GLE still looks pretty promising in its latest avatar




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Close call 

Commuter friendly: Stylish and sporting, but easy on the pocket, both the Hero Xtreme 125R and TVS Raider 125 put their best foot forward 




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Top (of the) Class

With more than seven lakh units sold since its launch, the Tata Nexon shows what’s behind its unabated success