xi Catalyst and solvent switched divergent C–H functionalization: oxidative annulation of N-aryl substituted quinazolin-4-amine with alkynes By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3032-3037DOI: 10.1039/D0OB00318B, CommunicationSiddi Ramulu Meesa, Praveen Kumar Naikawadi, Kishan Gugulothu, K. Shiva KumarCatalyst and solvent controlled ortho/peri site-selective oxidative annulation of C–H bonds of N-aryl substituted quinazolin-4-amines with internal alkynes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi Construction of pH sensitive smart glutathione peroxidase (GPx) mimics based on pH responsive pseudorotaxanes By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3125-3134DOI: 10.1039/D0OB00122H, PaperJiaxi Li, Wenlong Jia, Ganghui Ma, Xiaoyin Zhang, Shaojie An, Tao Wang, Shan ShiTwo pH-sensitive smart glutathione peroxidase (GPx) mimics were developed by using pH-responsive pseudorotaxanes based on cucurbit[6]uril and organoselenium compounds.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi Acylation of oxindoles using methyl/phenyl esters via mixed Claisen condensation – An access to 3-alkylideneoxindoles By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Accepted ManuscriptDOI: 10.1039/D0OB00789G, CommunicationRamdas Sreedharan, Purushothaman Rajeshwaran, Pradeep Kumar Reddy Panyam, Saurabh Yadav, C. M. Nagaraja, THIRUMANAVELAN GANDHIPredominantly, aggressive acid chlorides and stoichiometric coupling reagents are employed in the acylating process for synthesizing carbonyl tethered heterocycles. Herein, we report simple acyl sources, viz. methyl and phenyl esters...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi A silver-catalyzed radical ring-opening reaction of cyclopropanols with sulfonyl oxime ethers By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Advance ArticleDOI: 10.1039/D0OB00055H, PaperXiaobao Zeng, Xin Wang, Yanan Zhang, Li Zhu, Yu ZhaoA simple and efficient method for the radical ring-opening reaction of cyclopropanols with sulfonyl oxime ethers catalyzed by AgNO3 is developed, affording γ-keto oxime ethers in moderate to good yields.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi Rhodium-Catalyzed ortho-Acrylation of Aryl Ketone O-Methyl Oximes with Cyclopropenones By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Accepted ManuscriptDOI: 10.1039/D0OB00064G, CommunicationYafeng Liu, Yuan Tian, Kexin Su, Xin Guo, Baohua ChenAn efficient Rh-catalyzed ortho-acrylation reaction for the synthesis of chalcones from O-methyl ketoximes and cyclopropenones via C–H bond activation has been described. This cross-coupling reaction exhibits high functional group tolerance...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi Synthesis of Glycosyl Sulfoximines by a Highly Chemo- and Stereoselective NH- and O-Transfer to Thioglycosides By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Accepted ManuscriptDOI: 10.1039/D0OB00647E, PaperArianna Tota, Claudia Carlucci, Luisa Pisano, Giuliano Cutolo, Guy James Clarkson, Giuseppe Romanazzi, Leonardo Degennaro, James A Bull, Patrick Rollin, Renzo LuisiA synthesis of unprecedented and stable glycosyl sulfoximines is reported. The developed strategies represent the first examples of highly stereoselective sulfoximine formation directly from thioglycosides. X-ray analysis confirmed the structure...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi Synthesis of unsymmetrical benzils via palladium-catalysed α-arylation–oxidation of 2-hydroxyacetophenones with aryl bromides By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Advance ArticleDOI: 10.1039/D0OB00575D, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Takanori Matsuda, Souta OyamaUnsymmetrical benzils are synthesised by a one-pot tandem palladium-catalysed α-arylation and oxidation of 2-hydroxyacetophenones with aryl bromides.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi Copper(I)/Ganphos catalysis: enantioselective synthesis of diverse spirooxindoles using iminoesters and alkyl substituted methyleneindolinones By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Advance ArticleDOI: 10.1039/D0OB00546K, PaperHao Cui, Ke Li, Yue Wang, Manman Song, Congcong Wang, Donghui Wei, Er-Qing Li, Zheng Duan, François MatheyA copper/Ganphos-catalyzed asymmetric 1,3-dipolar cycloaddition of glycine iminoesters with alkyl substituted 3-methylene-2-oxindoles is described, producing the spiro[pyrrolidin-3,3'-oxindole]s in good yields with high ee.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi A Selectfluor-promoted oxidative reaction of disulfides and amines: access to sulfinamides By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Advance ArticleDOI: 10.1039/D0OB00720J, PaperHaibo Mei, Jiang Liu, Romana Pajkert, Gerd-Volker Röschenthaler, Jianlin HanAn unprecedented metal-free oxidative reaction of disulfides and amines with Selectfluor as a mild oxidant under aerobic conditions was developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi Dienaminodioate based multicomponent reactions with post-benzylic oxidative transformations mediated by DDQ By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Accepted ManuscriptDOI: 10.1039/D0OB00721H, PaperJaice Ravindran, Velickakathu Yadhukrishnan, Reghuvaran Asha , Ravi Shankar LankalapalliMulticomponent reactions (MCRs) using dienaminodioate with post-benzylic oxidative transformation by DDQ that afforded a diverse array of products is described. An unprecedented rearrangement of 1,2-dihydropyridines (1,2-DHPs), 3CR products, to 2-pyridones...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi Synthesis of gem-difluoroalkenes via nickel-catalyzed allylic defluorinative reductive cross-coupling of trifluoromethyl alkenes with epoxides By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Advance ArticleDOI: 10.1039/D0OB00535E, CommunicationXiao-Yu Lu, Run-Chuang Jiang, Jia-Mei Li, Chuang-Chuang Liu, Qing-Qing Wang, Hai-Pin ZhouA nickel-catalyzed defluorinative reductive cross-coupling of trifluoromethyl alkenes with epoxides has been developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi Xiaomi launches Mi Box 4K streaming device in India, here's are the features, price By www.dnaindia.com Published On :: Fri, 08 May 2020 10:53:00 GMT With the Mi Box 4K, Xiaomi is venturing into a segment dominated by Amazon with its Fire TV Stick. Full Article Technology
xi [ASAP] Controlling Surface Phase Transition and Chemical Reactivity of O3-Layered Metal Oxide Cathodes for High-Performance Na-Ion Batteries By dx.doi.org Published On :: Fri, 01 May 2020 04:00:00 GMT ACS Energy LettersDOI: 10.1021/acsenergylett.0c00700 Full Article
xi Concrete and durability of concrete structures: August 11-15, 2013, Cancun, Mexico / editors, L. E. Rendon Diaz Miron, N. Ramirez Salinas, B. Martinez Sanchez By library.mit.edu Published On :: Sun, 6 Dec 2015 06:11:13 EST Barker Library - TA439.S96 2013 Full Article
xi Recent advances in concrete technology and sustainability issues: proceedings of the fourteenth international conference, Beijing, China, October-November 2018 / [edited by] Tongbo Sui, Terence C. Holland, Ziming Wang, Xiaolong Zhao By library.mit.edu Published On :: Sun, 23 Feb 2020 06:28:52 EST Barker Library - TA439.I584 2018 Full Article
xi Big data in omics and imaging. Momiao Xiong By library.mit.edu Published On :: Sun, 21 Apr 2019 07:26:01 EDT Online Resource Full Article
xi Analysis and design of delayed genetic regulatory networks / Xian Zhang, Yantao Wang, Ligang Wu By library.mit.edu Published On :: Sun, 19 May 2019 07:20:37 EDT Online Resource Full Article
xi Peroxisomes: Biogenesis, Function, and Role in Human Disease / edited by Tsuneo Imanaka, Nobuyuki Shimozawa By library.mit.edu Published On :: Sun, 16 Feb 2020 07:32:02 EST Online Resource Full Article
xi An Event Apart: Slow Design for an Anxious World By feedproxy.google.com Published On :: Mon, 28 Oct 2019 00:00:00 +0000 In his Slow Design for an Anxious World presentation at An Event Apart in Denver, Jeffrey Zeldman espoused the benefits of design that aims to increase comprehension and intentional use. Here's my notes from his talk: We live in fast times and care a lot about making things faster for people. In this world, "slow" is often associated with friction. But some things are better slow. Fast is best for transactional customer-service designs. We optimize our checkout flows for efficiency and our code for performance. Likewise, service-oriented content must be designed for speed of relevancy. Getting to content like driving directions, return policies, and more should be quick and easy for customers. Slow is best for comprehension. Reading slowly helps us understand more of what we read and even transactional sites have some content that we want people to understand more deeply. There's lots of resources for site optimization but few for slowing people down so they appreciate and understand our content. Legibility means you can read what's on the page. Readability is where the art comes in. You don't need to be a graphic designer to improve readability. When focusing on readability you're focusing on absorption not conversion. Improving readability means putting the focus on content and removing distractions. The service Readability optimized Web pages for this by removing ads, third party widgets, and more. Considering different reading modes like in bed, at breakfast, on your lap, etc. can trigger ideas for layout and type for sites. For example, big fonts can help you lean back and take in content vs. leaning in and squinting. Big type used to be a controversial design choice on the Web but now has been adopted by a number of sites like Medium, Pro Publica, and the New Yorker. To be readable: use big type (16px should be your smallest size); use effective hierarchy for type; remove all extraneous elements in your layout; art direction helps you call attention to important content; make effective use of whitespace. Art direction can bring unique emotion and resonance to articles online. In a world of templates and scalability, distinct art direction can help people take notice of intentional high value content. Macro-whitespace is the bigger columns and padding around content we often associate with high-end luxury brands. Micro-whitespace is the space in between letter forms and between the lines of type. Consider both in your designs Ensure your content is branded so it stands out. When all content looks like the same it all appears to have equal value. Have a brand that sticks out to be more trusted. With all these techniques we're trying to get people to lean back and have a good "readable" experience on the Web. Full Article
xi Lost in exile: The forgotten Chagos Islanders of West Sussex By feedproxy.google.com Published On :: 2017-06-22T04:21:57-07:00 A group of Indian Ocean islanders, forcibly removed from their homes 50+ years ago and deported to England, are still fighting for recognition and basic rights. By Alexi Demetriadi. Full Article
xi The day Colombia’s FARC guerrilla ceases to exist as an armed group By feedproxy.google.com Published On :: 2017-06-27T06:31:23-07:00 The guerrillas are handing weapons over to the UN, but they are in fear. Thomas Mortensen reports from Urabá. Full Article
xi Axis Bank to report Q4 earnings today; here's what analysts expect By www.business-standard.com Published On :: Mon, 27 Apr 2020 14:25:00 +0530 Analysts at MOFSL believe the Mumbai-based bank's credit cost may stay elevated led by higher slippages. Besides, asset quality could witness some pressure along with modest loan growth. Full Article
xi Axis Bank reports net loss of Rs 1,388 cr in Q4FY20; NII at Rs 6,808 cr By www.business-standard.com Published On :: Tue, 28 Apr 2020 17:47:00 +0530 The private lender's net interest income (NII) came in at Rs 6,808 crore for the period under review Full Article
xi Axis Bank reports Rs 1,878-crore pre-tax loss in Q4 on Covid-19 provisions By www.business-standard.com Published On :: Tue, 28 Apr 2020 20:01:00 +0530 the bank reported a 17 per cent increase in its operating profit at Rs 5,851 crore in the March quarter Full Article
xi [ASAP] Carbon Nanotubes Modulate Activity of Cytotoxic Compounds via a Trojan Horse Mechanism By feedproxy.google.com Published On :: Mon, 10 Feb 2020 05:00:00 GMT Chemical Research in ToxicologyDOI: 10.1021/acs.chemrestox.9b00370 Full Article
xi [ASAP] Identifying Cysteine, <italic toggle="yes">N</italic>-Acetylcysteine, and Glutathione Conjugates as Novel Metabolites of Aristolochic Acid I: Emergence of a New Detoxification Pathway By feedproxy.google.com Published On :: Tue, 25 Feb 2020 05:00:00 GMT Chemical Research in ToxicologyDOI: 10.1021/acs.chemrestox.9b00488 Full Article
xi [ASAP] Computational Approaches to Identify Structural Alerts and Their Applications in Environmental Toxicology and Drug Discovery By feedproxy.google.com Published On :: Thu, 05 Mar 2020 05:00:00 GMT Chemical Research in ToxicologyDOI: 10.1021/acs.chemrestox.0c00006 Full Article
xi [ASAP] The Role of Cyclooxygenases-2 in Benzo(<italic toggle="yes">a</italic>)pyrene-Induced Neurotoxicity of Cortical Neurons By feedproxy.google.com Published On :: Wed, 11 Mar 2020 04:00:00 GMT Chemical Research in ToxicologyDOI: 10.1021/acs.chemrestox.9b00451 Full Article
xi [ASAP] Surface Functionalization of Pegylated Gold Nanoparticles with Antioxidants Suppresses Nanoparticle-Induced Oxidative Stress and Neurotoxicity By feedproxy.google.com Published On :: Fri, 13 Mar 2020 04:00:00 GMT Chemical Research in ToxicologyDOI: 10.1021/acs.chemrestox.9b00368 Full Article
xi [ASAP] Systems Toxicology Approaches Reveal the Mechanisms of Hepatotoxicity Induced by Diosbulbin B in Male Mice By feedproxy.google.com Published On :: Wed, 18 Mar 2020 04:00:00 GMT Chemical Research in ToxicologyDOI: 10.1021/acs.chemrestox.9b00503 Full Article
xi [ASAP] Triiodothyronine Attenuates Silica-Induced Oxidative Stress, Inflammation, and Apoptosis via Thyroid Hormone Receptor a in Differentiated THP-1 Macrophages By feedproxy.google.com Published On :: Fri, 03 Apr 2020 04:00:00 GMT Chemical Research in ToxicologyDOI: 10.1021/acs.chemrestox.0c00018 Full Article
xi [ASAP] Synergy between Experiments and Computations: A Green Channel for Revealing Metabolic Mechanism of Xenobiotics in Chemical Toxicology By feedproxy.google.com Published On :: Fri, 10 Apr 2020 04:00:00 GMT Chemical Research in ToxicologyDOI: 10.1021/acs.chemrestox.9b00448 Full Article
xi [ASAP] <italic toggle="yes">In Vitro</italic> Toxicity and Chemical Characterization of Aerosol Derived from Electronic Cigarette Humectants Using a Newly Developed Exposure System By feedproxy.google.com Published On :: Mon, 13 Apr 2020 04:00:00 GMT Chemical Research in ToxicologyDOI: 10.1021/acs.chemrestox.9b00490 Full Article
xi [ASAP] Neurotoxicology of Nanomaterials By feedproxy.google.com Published On :: Tue, 14 Apr 2020 04:00:00 GMT Chemical Research in ToxicologyDOI: 10.1021/acs.chemrestox.0c00050 Full Article
xi [ASAP] Interindividual Differences in DNA Adduct Formation and Detoxification of 1,3-Butadiene-Derived Epoxide in Human HapMap Cell Lines By feedproxy.google.com Published On :: Wed, 15 Apr 2020 04:00:00 GMT Chemical Research in ToxicologyDOI: 10.1021/acs.chemrestox.9b00517 Full Article
xi [ASAP] The Urine Proteome in Toxicology By feedproxy.google.com Published On :: Fri, 24 Apr 2020 04:00:00 GMT Chemical Research in ToxicologyDOI: 10.1021/acs.chemrestox.0c00126 Full Article
xi [ASAP] Toxicity and Gene Expression Profiling of Copper- and Titanium-Based Nanoparticles Using Air–Liquid Interface Exposure By feedproxy.google.com Published On :: Tue, 28 Apr 2020 04:00:00 GMT Chemical Research in ToxicologyDOI: 10.1021/acs.chemrestox.9b00489 Full Article
xi [ASAP] Thioproline Serves as an Efficient Antioxidant Protecting Human Cells from Oxidative Stress and Improves Cell Viability By feedproxy.google.com Published On :: Thu, 30 Apr 2020 04:00:00 GMT Chemical Research in ToxicologyDOI: 10.1021/acs.chemrestox.0c00055 Full Article
xi [ASAP] Particulate Matter Toxicity Is Nrf2 and Mitochondria Dependent: The Roles of Metals and Polycyclic Aromatic Hydrocarbons By feedproxy.google.com Published On :: Thu, 30 Apr 2020 04:00:00 GMT Chemical Research in ToxicologyDOI: 10.1021/acs.chemrestox.0c00007 Full Article
xi [ASAP] Unexpected Observations: Probiotic Administration Greatly Aggravates the Reproductive Toxicity of Perfluorobutanesulfonate in Zebrafish By feedproxy.google.com Published On :: Fri, 08 May 2020 04:00:00 GMT Chemical Research in ToxicologyDOI: 10.1021/acs.chemrestox.0c00139 Full Article
xi [ASAP] Most Influential Physicochemical and In Vitro Assay Descriptors for Hepatotoxicity and Nephrotoxicity Prediction By feedproxy.google.com Published On :: Fri, 08 May 2020 04:00:00 GMT Chemical Research in ToxicologyDOI: 10.1021/acs.chemrestox.0c00040 Full Article
xi The Toxic Cloud-Emitting Portable Dry Ice Maker By www.wired.com Published On :: Wed, 11 Feb 2009 00:00:00 +0000 The Toxic Cloud-Emitting Portable Dry Ice Maker in action. Full Article
xi Tesla Taxi By www.wired.com Published On :: Wed, 05 Dec 2012 00:00:00 +0000 Damon Lavrinc and Tesla Model S owner Konstantin Othmer are using the Sidecar App to pick up passengers around San Francisco and get their first impressions of the car. Full Article
xi Calexico - Station to Station By www.wired.com Published On :: Fri, 13 Sep 2013 18:00:00 +0000 Members of the band Calexico play an acoustic version of Crystal Frontier in Frank Lloyd Wright’s Taliesin West. Full Article
xi Gadget Lab - PlayStation 4: Unboxing the New Game Console By www.wired.com Published On :: Thu, 07 Nov 2013 11:30:00 +0000 We got the PlayStation 4! Sony’s new console comes out on November 15 in the US, but we went to Sony’s Tokyo HQ and asked engineering director Yasuhiro Ootori to give WIRED an exclusive look inside the new system—literally. Like, he takes it apart piece by piece and explains what all the parts do, and how they fit together. Full Article
xi Think Like a Tree - How Coral Reefs and Carbon Dioxide Can Change the Future By www.wired.com Published On :: Tue, 08 Sep 2015 13:00:00 +0000 Most people think of carbon dioxide as a poison, but in nature it’s a building block. Find out how we can imitate coral reef by using CO2 as a raw material for the creation of concrete. Full Article
xi Hacker Lexicon: A Guide to Ransomware, the Scary Hack That’s on the Rise By www.wired.com Published On :: Thu, 04 Feb 2016 11:00:00 +0000 Ransomware is a rising type of malware that locks your keyboard or computer until you pay a ransom, typically in Bitcoin. Find out how the sophisticated hacks happen and learn what you can do to avoid falling victim to them. Full Article
xi Absurd Creatures | The Fennec Fox and Its Giant Ears Are Too Cute to Possibly Exist By www.wired.com Published On :: Mon, 04 Apr 2016 10:30:00 +0000 The Fennec fox is the smallest, and arguably the cutest, fox on earth. Its enormous ears make it look like a cartoon character and help it hear prey and keep cool. Full Article
xi We Drive an All-Electric Ferrari, the Car that Shouldn’t Exist By www.wired.com Published On :: Tue, 24 May 2016 10:00:00 +0000 Ferrari boss Sergio Marchionne is on record as saying an electric Ferrari is an obscene concept, but that didn't stop a group of guys in California from turning the 308 GT into an EV. Full Article
xi Explore a Mysterious Deep Reef That Shouldn’t Exist By www.wired.com Published On :: Wed, 08 Jun 2016 10:00:00 +0000 A new exhibit shows off the undersea creatures who populate one of the most mysterious, poorly understood parts of the ocean. Full Article