xi Baidu Unveils Xiaodu AI Glasses With 16-Megapixel Ultra-Wide-Angle Camera By www.gadgets360.com Published On :: Wed, 13 Nov 2024 17:54:43 +0530 Baidu, the Chinese tech giant, reportedly unveiled the Xiaodu AI Glasses on Tuesday. The company introduced the AI-integrated smart glasses in China and it reportedly comes with an AI assistant that can perform several tasks for users. The Xiaodu AI Glasses are said to weigh 45 grams and feature a 16-megapixel ultra-wide-angle camera and a four-microphone array. Full Article
xi Perplexity AI Begins Experimenting With Ads on Its Search Platform By www.gadgets360.com Published On :: Wed, 13 Nov 2024 18:57:54 +0530 Perplexity AI, the company behind the eponymous artificial intelligence (AI) search platform, announced on Tuesday that it will begin experimenting with ads this week. An earlier report in August highlighted the company’s intentions of incorporating ads by the end of the year to boost its revenue. The AI firm highlighted that ads will be shown in a format that does not clutter or ruins the user experience of the platform. Full Article
xi Biden, Xi To Meet In Peru This Week As World Leaders Shift Focus To Trump By www.ndtv.com Published On :: Thu, 14 Nov 2024 11:38:04 +0530 US President Joe Biden will meet his Chinese counterpart, Xi Jinping, in Peru on Saturday for the last of three in-person sit-downs between the leaders during the US president's term in office. Full Article
xi Joe Biden, Chinese President Xi Jinping To Meet In Peru On Saturday By www.ndtv.com Published On :: Thu, 14 Nov 2024 05:09:37 +0530 US President Joe Biden and Chinese President Xi Jinping will meet Saturday at the APEC summit in Peru, in what will likely be their last encounter before Donald Trump returns to the White House, US officials said. Full Article
xi Delhi Covered In Toxic Smog, Visibility Low At Airports Across North India By www.ndtv.com Published On :: Thu, 14 Nov 2024 11:20:06 +0530 Delhi-NCR Air Pollution: A sharp spike in Delhi's air pollution was witnessed in the past 24 hours with 30 out of 36 monitoring stations reporting a severe air quality index. Full Article
xi Biden, Xi To Meet In Peru This Week As World Leaders Shift Focus To Trump By www.ndtv.com Published On :: Thu, 14 Nov 2024 11:38:04 +0530 US President Joe Biden will meet his Chinese counterpart, Xi Jinping, in Peru on Saturday for the last of three in-person sit-downs between the leaders during the US president's term in office. Full Article
xi Delhi Covered In Toxic Smog, Visibility Low At Airports Across North India By www.ndtv.com Published On :: Thu, 14 Nov 2024 06:59:34 +0530 Delhi-NCR Air Pollution: A sharp spike in Delhi's air pollution was witnessed in the past 24 hours with 30 out of 36 monitoring stations reporting a severe air quality index. Full Article
xi Xiaomi Finally Hits a Major EV Sales Milestone By phandroid.com Published On :: Wed, 13 Nov 2024 19:14:04 +0000 The company's EV has become one of the most talked-about electric cars this year. The post Xiaomi Finally Hits a Major EV Sales Milestone appeared first on Phandroid. Full Article automotive News electric vehicles su7 Xiaomi
xi Russian exiles plan massive anti-Putin march in Berlin By www.voanews.com Published On :: Wed, 13 Nov 2024 18:56:29 -0500 Russian exiles plan a march Sunday in Berlin demanding the withdrawal of Russian troops from Ukraine, the prosecution of Russian President Vladimir Putin as a war criminal, and the release of all political prisoners. Ricardo Marquina reports. Narrator: Elizabeth Cherneff. Full Article Ukraine Europe
xi Codbixinta doorashada Somaliland oo si rasmi ah u bilaamatey By horseedmedia.net Published On :: Wed, 13 Nov 2024 08:08:41 +0000 Maanata oo taariikhdu tahay 13 Nofeembar 2024 waxaa deegaanada Somaliland ka bilowdey Doorashooyinka isku idkan ee… The post Codbixinta doorashada Somaliland oo si rasmi ah u bilaamatey appeared first on Horseed Media. Full Article Somaliland
xi Biden, Xi to meet in Lima on sidelines of APEC summit in Peru By www.voanews.com Published On :: Wed, 13 Nov 2024 12:30:00 -0500 U.S. President Joe Biden and Chinese President Xi Jinping will meet November 16 on the sidelines of the 2024 Asia Pacific Economic Cooperation, or APEC summit in Lima, Peru, the White House announced Wednesday. The meeting follows the leaders' last in-person engagement a year ago on the sidelines of the APEC summit in California, and their 2022 meeting in Bali on the sidelines of the G20 summit. Biden and Xi are expected to revisit areas of cooperation, particularly the resumption of military-to-military contacts, efforts to combat the global fentanyl crisis and nascent work to deal with the risks of Artificial Intelligence, or AI, a senior administration said in a briefing with reporters Wednesday. The U.S. president will also express "deep concern" over Beijing's support for Moscow's war against Ukraine, and the deployment of North Korean troops to aid Russia, said the official, who requested anonymity to speak on the upcoming meeting. The official said Biden will also reiterate his "longstanding concern" over China's "unfair trade policies and non-market economic practices" that hurt American workers. The official added Biden will raise Chinese cyber-attack efforts on U.S. civilian critical infrastructure as well as Beijing's increased military activities around Taiwan and the South China Sea while also underscoring the importance of respect for human rights. The meeting is likely to be the last between Biden and Xi ahead of the incoming administration of Donald Trump in January. The president-elect has appointed ardent China critics in key foreign policy positions that could lead to a more confrontational U.S. posture toward Beijing. They include Republican Congressman Mike Waltz as Trump's pick for national security adviser and Senator Marco Rubio as secretary of state. Whatever the next administration decides, they're going to need to find ways to manage the "tough, complicated relationship" between the U.S. and China, the official said in response to a question from VOA. "Russia, cross-strait issues, the South China Sea and cyber are areas the next administration is going to need to think about carefully, because those are areas of deep policy difference with China, and I don't expect that will disappear," the official said. Xi is also likely anticipating what the Trump administration plans to do about global trade, particularly whether he will enact promises to impose steep tariffs on all Chinese goods. Full Article USA East Asia China News
xi China looks to expand global influence with Xi’s Latin America tour By www.voanews.com Published On :: Wed, 13 Nov 2024 10:39:38 -0500 Taipei, Taiwan — Chinese President Xi Jinping departs on a nine-day diplomatic tour to Latin America on Wednesday, during which he will inaugurate a Chinese-financed megaport in Peru and attend the Asia-Pacific Economic Cooperation Summit in Lima and the G20 Summit in Brazil. Analysts say the trip is part of China’s attempt to expand its global influence and present itself as “a responsible global power” at a time when countries around the world brace for uncertainties following U.S. President-elect Donald Trump’s victory on November 5. “The trip is especially significant since Latin America is viewed as ‘the backyard’ of the United States; and [since] the next U.S. president is likely to return to a unilateral approach in world affairs, it provides China with the opportunity to expand its influence around the world as a champion for global development and multilateral cooperation,” said Zhiqun Zhu, an expert on Chinese foreign policy at Bucknell University. During his state visit to Peru, Xi will inaugurate the $3.5 billion Chancay port with his Peruvian counterpart Dina Boluarte on Thursday. Situated 80 kilometers north of the Peruvian capital Lima, the port has a maximum depth of 17.8 meters and is expected to become a major trading hub between Latin America and China. “The port will become the largest deep-water port in South America and it will drastically reduce the time needed to ship products from Peru to China,” Leland Lazarus, associate director of national security at Florida International University, told VOA in a video interview. China’s state-run Cosco Shipping Corporation has a majority 60% stake in the port and a 30-year concession to operate the terminal. According to China’s official data, the port can handle up to one million containers and 160,000 vehicles in the first year of operation. The port is among 17 ports globally where China holds a majority stake, according to the Council on Foreign Relations and is one of more than 100 port projects built globally under China’s flagship Belt and Road Initiative. The port is expected to become a major hub for exporting critical commodities such as lithium, copper, iron and soybeans to China more efficiently. Latin American countries including Peru, Chile, Brazil, Colombia, and Ecuador, which had a combined export of $135 billion to China in 2023, could all benefit from the launch of the Chancay Port. “There is a huge gap in infrastructure development in Global South countries and Western powers are not active in helping [to] fill the gap. [As a result,] China’s investments in such large infrastructure projects are welcomed by host countries,” Zhu at Bucknell University told VOA in a written response. While Latin American countries will likely welcome the inauguration of the Chancay Port, the U.S. has warned about the potential for the port to be used for military purposes by China. That Washington claims could threaten its interests in Latin America. “It could be used as a dual-use facility, it’s a deepwater port,” said Laura Richardson, the outgoing chief of the U.S. Southern Command told the Financial Times in a recent interview, adding that the Chinese navy could use the port in a scenario that, she said, fits “Beijing’s playbook.” Some experts say it’s difficult for China to deploy its naval vessels to Latin America in the near future and that Peru is unlikely to let Beijing militarize the Chancay port. “Currently, the Chinese navy is not capable of projecting its power across the Pacific, and since Peru still needs to maintain its relationship with the U.S., Peruvian authorities won’t allow the port to be militarized,” Kung Kwo-Wei, an expert of Latin American affairs at Tamkang University in Taiwan, told VOA by phone. However, Lazarus told VOA that Beijing’s activities in other ports around the world suggest it could still use the Chancay port for military purposes in the future. “When looking at Chinese behaviors [at other ports around the world], such as the Port of Bata in Equatorial Guinea and the Ream Naval Base in Cambodia, Chinese state-owned enterprises would promise to expand the ports for commercial purposes, yet there have been allegations that there’s been construction for what looks like military purposes on these areas,” said Lazarus. In addition to the Chancay Port, Peruvian Foreign Minister Elmer Schialer told Reuters news agency in an exclusive interview that Beijing and Lima plan to sign around 30 agreements, including an updated free trade agreement, during Xi’s visit. Kung in Taiwan said these developments show that China’s investment in Latin America is now focusing on logistical infrastructure and access to minerals from Latin America. “China relies heavily on ports and logistical infrastructure to ensure it can export and import commodities at a steady pace, and as Beijing continues to expand its renewable energy industries, its appetite for minerals from Latin America will also grow,” Kung told VOA. As the U.S. could possibly adopt a more isolationist foreign policy approach during Trump’s second term, Lazarus said Xi will use the upcoming APEC and G20 summits to amplify the message that China is a more consistent global power than the U.S. “While the U.S. is going to potentially look inward with another Trump administration, [the summits] are Xi’s big opportunities to show that China is playing a much more global role,” he told VOA. However, some experts say it remains unclear whether China will achieve its intended goals. “Beijing will double down on the image of being the leader of the Global South and some countries will be attracted by that message,” said Ian Chong, a political scientist at the National University of Singapore. “But others who are more clear-eyed and who have followed developments from the Belt and Road Initiative and other Chinese projects will recognize that China is just another great power,” he told VOA in a phone interview. Full Article East Asia Americas China News
xi Mexican lawmakers reelect human rights agency leader criticized for not addressing abuses By www.voanews.com Published On :: Wed, 13 Nov 2024 14:55:36 -0500 mexico city — Legislators from Mexico's ruling party reelected the head of the National Human Rights Commission on Wednesday despite widespread opposition and her failure to call out the government for abuses. The reelection of Rosario Piedra Ibarra in a party-line Senate vote appeared to be another example of the ruling Morena party's attempts to weaken independent oversight bodies. Morena has proposed eliminating a host of other oversight, transparency and freedom-of-information agencies, claiming they cost too much to run. Mexico's civic and nonprofit rights groups have been almost unanimous in their criticism of Piedra's reelection. "This is an undeserved prize for a career marked by inaction, the loss of independence and the weakening of the institution," the Miguel Agustin Pro Juarez human rights center wrote on social media. Piedra is a committed supporter of former President Andres Manuel Lopez Obrador, who left office on September 30. She once affirmed that none of the deaths caused by the armed forces under his administration were illegal or unjustified, and she shared the former president's delight in attacking and criticizing other independent human rights groups. Commission issues few recommendations Since her first election in 2019, Piedra has done little to investigate allegations of massacres or extrajudicial killings by soldiers and members of the militarized National Guard, to whom Lopez Obrador gave sweeping powers. Despite receiving over 1,800 citizen complaints against the armed forces between 2020 and 2023, her commission issued only 39 recommendations, and most of the few military cases her commission did follow up on involved abuses committed under previous administrations. The rights commission has the power to make non-binding recommendations to government agencies. If they do not agree to follow the recommendations, they are at least required by law to explain why. Piedra has almost exclusively focused the commission's work on issuing recommendations in cases where people have not received proper health care at government-run hospitals. Those recommendations accomplish little, because they don't address the underlying problem of underfunded, poorly equipped hospitals forced to handle too many patients. At times Piedra acted as if human rights violations no longer existed under Lopez Obrador. In 2019, she expressed disbelief when asked about the killing of journalists, despite the fact that almost a dozen were killed in Lopez Obrador's first year in office. "Are they killing journalists?" she said with an expression of disbelief. 'Her actions appear to support impunity ' Piedra comes from a well-known activist family: Her mother founded one of Mexico's first groups to demand answers for families whose relatives had been abducted and disappeared by the government in the 1960s and '70s. But even her mother's group, the Eureka Committee, did not support Piedra's reelection. "Her actions appear to support impunity for the perpetrators of governmental terrorism, and the government's line of obedience and forgetting" rights abuses, the committee wrote in a statement. Piedra broke with two important traditions: she was a member of the ruling party up until she was elected to her first term in 2019. The job has usually gone to nonpartisan human rights experts. And she has openly endorsed and supported government policies and actions. Previous heads of the commission had a more critical relationship with the government. Piedra also failed to make the final cut for candidates for the post this year in a congressional examination of their qualifications, but was put on the ballot anyway. That's important because similar evaluation committees will decide who gets on the ballot in judicial reforms that make federal judges stand for election next year. Activists worry that the same kind of favoritism will come into play in the election of judges. "This decision comes after a selection process in which she (Piedra) wasn't found to be the most qualified," a coalition of rights groups said in a statement. "That reveals the political, partisan considerations that put her onto the ballot." She also apparently falsified a letter of recommendation; a bishop and human rights activist said a letter she presented to support her reelection had not been signed by him. Piedra will serve under new President Claudia Sheinbaum, another devoted follower of Lopez Obrador, who took office October 1. On Sheinbaum's first day in office, the army killed six migrants near the Guatemalan border; 10 days later, soldiers and National Guard killed three bystanders in the northern border city of Nuevo Laredo while chasing suspects. Sheinbaum's third week in office was capped by the killing of a crusading Catholic priest who had been threatened by gangs, and a lopsided encounter in northern Sinaloa state in which soldiers killed 19 drug cartel suspects, but suffered not a scratch themselves. That awakened memories of past human rights abuses, like a 2014 incident in which soldiers killed about a dozen cartel suspects after they had surrendered. The purportedly leftist government has been quick to criticize human rights groups and activists who expose abuses. In June, an outspoken volunteer advocate for missing people found an apparent body dumping ground with human remains in Mexico City, embarrassing ruling party officials who had done little to look for such clandestine grave sites. City prosecutors lashed out at her, claiming "the chain of custody" of the evidence had been manipulated, which could lead to charges. Full Article Americas
xi John Krasinski being named Sexiest Man Alive sparks surprising fan theory By www.thenews.com.pk Published On :: Thu, 14 Nov 2024 00:09:00 +0500 John Krasinski reportedly could not believe being named the Sexiest Man AliveJohn Krasinski as 2024’s Sexiest Man Alive invoked a mixed reaction from social media, pleasing some fans while leaving the others disappointed. Meanwhile some social media users have found an interesting link... Full Article
xi Department of Government Efficiency social media channel goes live on X for 'maximum transparency' By www.foxnews.com Published On :: Wed, 13 Nov 2024 16:30:35 -0500 The Department of Government Efficiency (DOGE) went live on X Wednesday, giving the public a way to question and see how tax dollars are being spent. Full Article 492e68a6-52d7-599d-99db-462074d5a2ea fnc Fox News fox-news/politics/elections/presidential/trump-transition fox-news/person/elon-musk fox-news/person/donald-trump fox-news/tech/companies/twitter fox-news/politics article
xi GOP Rep. Michael McCaul 'briefly detained' by police at airport for 'appearing intoxicated' By www.foxnews.com Published On :: Wed, 13 Nov 2024 17:15:59 -0500 GOP Rep. Michael McCaul of Texas said he was detained by police at Dulles International Airport after he became disoriented from mixing Ambien with alcohol. Full Article aa96f254-fd1a-532f-a679-851e94001433 fnc Fox News fox-news/politics fox-news/us/crime/police-and-law-enforcement fox-news/us/washington-dc fox-news/politics article
xi Canada shares U.S. concern over Mexico’s trade practices, Freeland says By financialpost.com Published On :: Wed, 13 Nov 2024 23:03:06 +0000 Mexico has been criticized for being a backdoor for cheap Chinese imports to the U.S. market Full Article Economy News
xi 3 men arrested in B.C. have ties to Mexican drug cartels, RCMP say By www.cbc.ca Published On :: Wed, 13 Nov 2024 15:09:52 EST Mounties say they've arrested three men in Surrey, B.C., believed to be tied to a transnational organized crime group connected to Mexican drug cartels, while four others suspected of trafficking large quantities of drugs were arrested in Burnaby, B.C. Full Article News/Canada/British Columbia
xi Mysterious Ultra-Massive Galaxies Spotted in Early Universe By www.sci.news Published On :: Wed, 13 Nov 2024 23:42:08 +0000 Astronomers using the NASA/ESA/CSA James Webb Space Telescope have discovered three ultra-massive galaxies -- nearly as massive as our own Milky Way Galaxy -- already in place within the first billion years after the Big Bang. The post Mysterious Ultra-Massive Galaxies Spotted in Early Universe appeared first on Sci.News: Breaking Science News. Full Article Astronomy Big Bang CSA Dark matter Dark matter halo Early Universe ESA Galaxy Galaxy formation NASA Red monster galaxy Star formation Universe Webb
xi 'Red Monster' galaxies in early universe challenge current models of galaxy formation - Nanowerk By news.google.com Published On :: Wed, 13 Nov 2024 17:18:33 GMT 'Red Monster' galaxies in early universe challenge current models of galaxy formation NanowerkJames Webb Space Telescope’s data unveils galaxies that could lead to a dark matter revolution The Times of IndiaNASA James Webb Telescope Data Points to Dark Matter Alternative: 10 Key Insights Moneycontrol‘Red Monster’: Scientists discover three ultra-massive galaxies, challenging previous formation theories Business TodayJames Webb Space Telescope finds galaxies pointing toward a dark matter alternative Space.com Full Article
xi Biden and Xi will meet on Saturday, the 3rd and likely final time during Biden's term By www.npr.org Published On :: Wed, 13 Nov 2024 12:30:00 -0500 President Biden plans to tell China's Xi Jinping that communication channels between the two governments need to remain open — no matter who is in the White House. Full Article
xi Deputy PM Freeland says she shares American trade concerns about Mexico, China By www.cbc.ca Published On :: Wed, 13 Nov 2024 17:18:57 EST Deputy Prime Minister and Finance Minister Chrystia Freeland says she shares Washington's concerns about whether Mexico is "aligned" with Canada and the U.S. on trade policy — specifically when it comes to China. Full Article News/Politics
xi Biden and Xi to meet in Peru, US officials say By www.asiaone.com Published On :: Thu, 14 Nov 2024 10:49:11 +0800 WASHINGTON — US President Joe Biden will meet Chinese counterpart Xi Jinping for likely the final time on Saturday (Nov 16), senior administration officials said, as Beijing prepares for a potentially more confrontational period with Washington under Donald Trump. The two leaders are expected to hold talks spanning a range of global hot spots, including heightened tensions between Washington and Beijing, on the sidelines of the Asia-Pacific Economic Cooperation forum in Lima, Peru, US national security adviser Jake Sullivan told reporters. He did not confirm the date of the meeting. It will be Biden and Xi's first known interaction since an April phone call. The two leaders have tried to keep tensions at bay over issues ranging from Taiwan to the South China Sea and Russia, and American demands for more Chinese help to stem the flow of the ingredients for fentanyl, the leading cause of US drug overdoses. Biden will raise concerns over a Chinese-linked group that recently hacked into private telecommunications of prominent US officials, Sullivan said. Full Article
xi Using phone? Jaywalker hit and sent flying by taxi in Orchard By www.asiaone.com Published On :: Thu, 14 Nov 2024 11:57:33 +0800 A woman was sent flying after she was hit by a car on Wednesday (Nov 13) morning. The incident occurred at the junction of Orchard Road and Handy Road. In a video posted to the SG Kaypoh Facebook group, the woman is seen crossing the road while the traffic light was not in her favour. She appears to be looking down at her phone. The driver involved in the accident did not notice her till it was too late and collided with her head-on. In the video, the woman is sent flying and lands several metres in front of the car upon impact. She manages to sit up after landing, and looks stunned from the impact. The driver and his passenger also rush out of the vehicle to assist. Speaking to AsiaOne, the Singapore Civil Defence Force said that the female pedestrian was conveyed conscious to Tan Tock Seng Hospital. When contacted, the police said they were alerted to an accident involving a taxi and a pedestrian at the junction of Orchard Road and Handy Road on Nov 13 at about 3.15am. Full Article
xi Mexican city's security chief held over mayor's beheading By www.bbc.com Published On :: Wed, 13 Nov 2024 13:16:15 GMT The mayor of Chilpancingo, Alejandro Arcos, was murdered just days after taking office last month. Full Article
xi Can GABA and L-Theanine Supplements Together Help With Stress and Anxiety? By www.medindia.net Published On :: Highlights: GABA and L-theanine are popular supplements for stress relief L-theanine may help reduce stress, whi Full Article
xi Growing Threat of Nitrous Oxide to Public Health and Climate By www.medindia.net Published On :: Rising Nitrous Oxide emissions pose serious risks to public health and climate, contributing to respiratory issues and global warming. Immediate action is crucial. Full Article
xi Can GABA and L-Theanine Supplements Together Help With Stress and Anxiety? By www.medindia.net Published On :: GABA and L-theanine are often used to reduce stress. While promising, there's limited research on their combined use, making healthcare consultation essential. Full Article
xi Marketing masterclass: How to maximize your hotel’s seasonal digital marketing By www.hospitalitynet.org Published On :: Wed, 13 Nov 2024 07:47:00 +0200 Q4 is a crucial time for hotels, and we’re here to help you capture more business this holiday season. Tune in for an expert-led webinar to explore the latest trends and strategies for boosting bookings and transitioning smoothly into the New Year. Full Article
xi Shocking: 86% diabetics in India facing anxiety, depression; women more affected: Report By www.ibtimes.co.in Published On :: Wed, 13 Nov 2024 18:08:00 +0530 More than 4 in 5 Indians, or 86 per cent of Indians living with diabetes have experienced anxiety, depression, or another mental health condition as a result of their diabetes, according to a report, ahead of World Diabetes Day. Full Article
xi Actor John Krasinski named 'Sexiest Man Alive 2024' by People magazine By www.dnaindia.com Published On :: Wed, 13 Nov 2024 16:05:00 GMT Krasinski's win adds him to an esteemed group of past honourees like George Clooney, Brad Pitt, Idris Elba, and Michael B. Jordan. Full Article Entertainment
xi Synthesis of multisubstituted carbazol-4-amines from tetrahydrocarbazol-4-one oximes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00386A, Research ArticleJiahua Wang, Dandan Gao, Aanuoluwapo O. Oyejobi, Na Ji, Xiang-Ying Tang, Long WangA sequential synthetic method toward 1,3-disubstituted carbazol-4-amines is reported and an interesting C–S metathesis process is disclosed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi DNA-compatible functional group transformations via K2RuO4-mediated oxidation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00203B, Research ArticlePengyang He, Guixian Zhao, Mengping Zhu, Yangfeng Li, Gong Zhang, Yizhou LiK2RuO4-mediated oxidation offers a DNA-compatible method for functional group transformations, enabling alcohol-to-carboxylic acid and amine-to-nitrile conversions valuable for DNA-encoded library synthesis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi Neighboring group-directed asymmetric [2 + 2 + 2] cycloaddition to access C–N axially chiral indoles By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00042K, Research ArticleXuan Zhang, Qi Teng, Yanru Ren, Baitong Wei, Chen-Ho Tung, Zhenghu XuA Rh-catalyzed neighboring group-directed asymmetric [2 + 2 + 2] cycloaddition of 1,6-diynes and ynamides to generate C–N axially chiral indole derivatives has been developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi Review of application of the I2 and dimethyl sulfoxide combined reagent system to aryl methyl ketones for diverse transformations By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00396A, Review ArticleDong-Sheng Yang, Xiang-Long Chen, An-Xin WuThe synthesis of small molecules and complex scaffolds is one of the most important topics in organic synthesis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi Vaska's complex–PMHS combination enabled mild and chemoselective reduction of sulfoxides to sulfides with low catalyst loading By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00312H, Research ArticleFang-Fang Xu, Zhong-Lei Ruan, Pei-Qiang HuangWe report a highly efficient, versatile, and chemoselective method for the catalytic reduction of sulfoxides to sulfides under mild conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi Visible-light-mediated catalyst-free synthesis of trifluoromethyl(spiro)-epoxides bearing contiguous quaternary centers By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00184B, Research ArticleJingchuan Lin, Yu Zhang, Jinxin Wang, Xinyu Han, Shenglan Zhu, Tong Li, Yanping Zhu, Wei-Dong ZhangHerein, we describe a non-covalent complex-mediated epoxidation strategy that can yield highly selective central spiro-epoxides by irradiation with visible light without the need for catalyst addition.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi Synthesis of benzothiophenes via sulfonium-[3,3]-rearrangement of aryl sulfoxides with allenenitriles By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2208-2214DOI: 10.1039/D4QO00121D, Research ArticleLei Zhang, Kun Wan, Huanhuan Wang, Mengyao Wang, Ao Cui, Xin Huang, Bo PengA facile synthesis of benzothiophenes from readily available aryl sulfoxides and allenenitriles has been established through sulfonium-rearrangement triggered cyclization.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi Deoxygenation of N-heterocyclic N-oxides using isopropanol as a recyclable reductant By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2249-2268DOI: 10.1039/D4QO00208C, Research ArticleHo Kyeong Ryu, Yun Do Song, Jun Hee LeeAn organic photoredox-based recyclable strategy that facilitates the chemoselective deoxygenation of various functionalised N-heterocyclic N-oxides is presented.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi A formal (3 + 2) annulation–Cannizzaro cascade of bifunctional peroxides for the synthesis of dihydrofurans By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2215-2219DOI: 10.1039/D4QO00215F, Research ArticleYiwei Chen, Min Gao, Qianlan Xu, Jiumeng Zhang, Lin HuTunable tandem processes of bifunctional peroxides allow the divergent construction of functionalized dihydrofurans and epoxides by simply changing the basic conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi Prins cyclization of 1,3-dioxinone: synthesis of 11-epi-badkhysin By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2332-2338DOI: 10.1039/D4QO00162A, Research ArticleXiaoliang Xu, Ping Hua, Yiren Xu, Baoqing He, Jingfeng Zhao, Liang Li, Wen Chen, Hongbin ZhangThe asymmetric synthesis of highly functional 11-epi-badkhysin has been accomplished using a structure-unit based approach.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi Copper-catalyzed oxidative sulfenylation and alkylation of indolin-2-ones for direct construction of sulfur-substituted quaternary carbons By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00491D, Research ArticleYun-Hao Zhang, Yi-Nuo Wang, Zi-Yu Liu, Si-Han Zheng, Guang-Lin Li, Dexin Feng, Da-Zhen XuA rapid and green one-pot access to S-substituted quaternary carbon centers from commercially available feedstock chemicals has been established, providing complex molecules with high chemoselectivity by the use of air as the terminal oxidant.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi Efficient Synthesis of Benzophosphole Oxides by Ag-Promoted Radical Cycloisomerization By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO00552J, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Liyao Ma, Sonia Mallet-Ladeira, Julien MONOT, Blanca Maria MARTIN VACA, Didier BourissouCycloisomerization reactions involving C–P bond formation have been overlooked to prepare P-heterocycles. We discovered here a simple, efficient and versatile route to benzophosphole oxides by reacting ortho-alkynyl secondary phosphine oxides...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi Regioselective Oxidative Cleavage of Conjugated Dienes to Access α,β–Unsaturated Nitriles By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D3QO02101G, Research ArticleYuqing Fu, Yijia Leng, Haotong Bai, Jiaxi Xu, Ning ChenA highly regioselective oxidative cleavage method has been developed for the synthesis of α,β-unsaturated nitriles from unsymmetric conjugated dienes. This transformation selectively cleaved the terminal C=C double bond, providing moderate...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi Synthesis of oxindole fused 1,3-oxazepanes via hydride transfer initiated ring expansion of pyrrolidine By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00474D, Research ArticlePeng He, Zongkang Wang, Qiongwen Kang, Nana Fei, Chengyu Wang, Yanzhong LiAn efficient B(C6F5)3 catalyzed protocol for the synthesis of oxindole fused 1,3-oxazepanes from pyrrolidine substituted aryl alkynones has been developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi NHC-Catalyzed Stereoselective Synthesis of Spirooxindole Lactones by in situ Generated Oxindole-embedded o-Quinone Methides and Aldehydes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO00347K, Research ArticleZhengqiang Cao, Fang Hu, Yunpeng Chu, Jiaxue Pei, Xin-Ping HuiA novel N-heterocyclic carbene-catalyzed asymmetric [4 + 2] annulation of in situ generated oxindole-embedded o-quinone methides with aldehydes has been developed for the assembly of complicated spirooxindoles. The methodology provides...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi Diverting the Mannich reaction to access 2,2-disubstituted indolin-3-ones by merging 1,2-aryl migration and copper-catalyzed aerobic oxidation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00481G, Research ArticleJia-Chen Xiang, Yu-Die Wang, Peng Yuan, Hui-Min Zhu, Tong Lei, An-Xin Wu, Zhixin LiaoThree typical substrates for the Mannich reaction, p-anisidine, aldehyde, and a nucleophile, did not afford the predictable linear Mannich base under an aerobic copper oxidation condition, but rendering a 2,2-disubstituted indolin-3-one product.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi Thiourea as a precatalyst for the electron donor–acceptor complex photoactivation platform of oxime esters By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00424H, Research ArticleHaichen Mao, Yuting Zhang, Hengrong Cao, Qianqian Shi, Yu Lan, Junbiao Chang, Bo ZhuA novel electron donor–acceptor (EDA) complex catalysis strategy has been developed using thiourea as a precatalyst under blue LED irradiation. Using 2–5 mol% of thiourea, various nitrogen-containing compounds were successfully synthesized.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
xi UN report warns nitrous oxide emissions impact public health By www.newkerala.com Published On :: Wed, 13 Nov 2024 12:08:01 +0530 Full Article
xi Non-classical electrostriction in calcium-doped cerium oxide ceramics By pubs.rsc.org Published On :: J. Mater. Chem. A, 2024, 12,9173-9183DOI: 10.1039/D3TA07512E, PaperAhsanul Kabir, Victor Buratto Tinti, Simone Santucci, Maxim Varenik, Samuel Griffiths, Sebastian Molin, Igor Lubomirsky, Vincenzo EspositoOxygen-defective metal oxides, e.g., acceptor-doped CeO2, demonstrate exceptionally large electrostrictive responses compared to state-of-the-art electromechanically active ceramic materials.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article