xi

Development of a label-free, sensitive gold nanoparticles-poly (adenine)aptasensing platform for colorimetric determination of aflatoxin B1 in corn

Anal. Methods, 2024, Accepted Manuscript
DOI: 10.1039/D4AY00605D, Paper
Omid Heydari Shayesteh, Katayoun Derakhshandeh, Akram Ranjbar, Reza Mahjub, Abbas Farmany
In this work, a sensitive colorimetric bioassay method based on poly (adenine) aptamer (polyA apt) and gold nanoparticles (AuNPs) was developed to the determination of aflatoxin B1 (AFB1). The polyA...
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xi

A three-dimensional network structure of metal-based nanozymes for the construction of colorimetric sensors for the detection of antioxidants

Anal. Methods, 2024, 16,2292-2300
DOI: 10.1039/D3AY02199H, Paper
Shuo Qin, Bin Liu, Yuting Xue, Ruixue Zhao, Guo Wang, Kai Li, Lirong Zheng, Pingyang Wang, Tianhao Tang, Yue Yang, Zhengbo Chen, Xia Zuo
Although many excellent nanozymes have been developed, designing and synthesizing highly active nanozymes is still challenging.
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xi

A reaction based carbazole–indolium conjugate probe for the selective detection of environmentally toxic ions

Anal. Methods, 2024, Advance Article
DOI: 10.1039/D4AY00301B, Paper
Jayasudha Palanisamy, Mansour K. Gatasheh, Ashraf Atef Hatamleh
Carbazole–indolium based colorimetric probe was designed for detecting cyanide ions in various water samples. An outstanding response was shown by paper test strips prepared using the probe for the easy detection of cyanide in real time.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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xi

Proximity hybridization based “turn-on” DNA tweezer for accurate and enzyme-free small extracellular vesicles analysis

Anal. Methods, 2024, Accepted Manuscript
DOI: 10.1039/D4AY00487F, Paper
Jinlin Wu, Xi Mei, Xiaoqin Zhan, Fang Liu, Dongfang Liu
Small extracellular vesicles (sEVs) are a type of extracellular vesicles that carry many types of molecular information. The identification of sEVs is essential for the non-invasive detection and treatment of...
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xi

Novel advanced materials and magnetic solid phase extraction as approaches in sample preparation to enhance the analysis of ochratoxin A in peanuts

Anal. Methods, 2024, Advance Article
DOI: 10.1039/D4AY00246F, Paper
Bingchen Wang, Yifan Wang, Xiuyuan Zhang, Kuo He
In order to improve the detection efficiency of ochratoxin, a superparamagnetic nano-material was synthesized for solid phase extraction of ochratoxin.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




xi

​Beyond intoxication: On alcohol regulation, judicial verdict

Batting for States, the Supreme Court of India holds federal balance on regulating alcohol




xi

Synthesis and cytotoxic activity of madecassic acid–silybin conjugate compounds in liver cancer cells

RSC Med. Chem., 2024, 15,3418-3432
DOI: 10.1039/D4MD00170B, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Chien Van Tran, Thao Thi Phuong Tran, Anh The Nguyen, Loc Van Tran, Ninh Thi Pham, Luu Thi Nguyen, Dung Thi Nguyen, Michelle D. Garrett, Nga Thi Nguyen, Thao Thi Do, Christopher J. Serpell, Sung Van Tran
Madecassic acid and silybin have been conjoined to produce hybrid compounds with improved and different activity against liver cancer cells.
The content of this RSS Feed (c) The Royal Society of Chemistry




xi

A comprehensive apoptotic assessment of niloticin in cervical cancer cells: a tirucallane-type triterpenoid from Aphanamixis polystachya (Wall.) Parker

RSC Med. Chem., 2024, 15,3444-3459
DOI: 10.1039/D4MD00318G, Research Article
Anuja Gracy Joseph, Mohanan Biji, Vishnu Priya Murali, Daisy R. Sherin, Alisha Valsan, Vimalkumar P. Sukumaran, Kokkuvayil Vasu Radhakrishnan, Kaustabh Kumar Maiti
Niloticin, a triterpenoid from Aphanamixis polystachya, induces apoptosis in HeLa cells which is primarily validated through in silico analysis and subsequently in vitro apoptotic evaluation by modulating the apoptotic proteins.
The content of this RSS Feed (c) The Royal Society of Chemistry




xi

Exploring 7β-amino-6-nitrocholestens as COVID-19 antivirals: in silico, synthesis, evaluation, and integration of artificial intelligence (AI) in drug design: assessing the cytotoxicity and antioxidant activity of 3β-acetoxynitrocholestane

RSC Med. Chem., 2024, Advance Article
DOI: 10.1039/D4MD00257A, Research Article
Shahabuddin, Uzma, Mohammad Azam, Mehtab Parveen, Nurul Huda Abd Kadir, Kim Min, Mahboob Alam
In light of the ongoing pandemic caused by SARS-CoV-2, effective and clinically translatable treatments are desperately needed for COVID-19 and its emerging variants.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




xi

Inhibition of monoamine oxidases by heterocyclic derived conjugated dienones: synthesis and in vitro and in silico investigations

RSC Med. Chem., 2024, Advance Article
DOI: 10.1039/D4MD00608A, Research Article
Sunil Kumar, Bishnu Prasad Pandey, Mohamed A. Abdelgawad, Mohammed M. Ghoneim, Rania B. Bakr, Hoon Kim, Bijo Mathew
A total of 18 heterocyclic derived conjugated dienones (CD1–CD18) were evaluated for their potential monoamine oxidase (MAO)-A/-B inhibitory activity.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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xi

Modulating polybasic character of galactose-based glycosylated antitumor ether lipids for enhanced cytotoxic response

RSC Med. Chem., 2024, Advance Article
DOI: 10.1039/D4MD00662C, Research Article
Rajat Arora, Ayan Mukherjee, Gilbert Arthur, Mark W. Nachtigal, Frank Schweizer
We describe the multi-step synthesis of different dibasic and tribasic galactosamine-based glycosylated antitumor ether lipids (GAELs) and their cytotoxic response in comparison to doxorubicin and cisplatin.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




xi

Amides of moronic acid and morolic acid with the tripeptides MAG and GAM targeting antimicrobial, antiviral and cytotoxic effects

RSC Med. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4MD00742E, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Uladzimir Bildziukevich, Lucie Cerna, Jana Trylčová, Marie Kvasnicova, Lucie Rárová, David Šaman, Petra Lovecká, Jan Weber, Zdenek Wimmer
A series of amides of the selected plant triterpenoids, moronic acid and morolic acid, with the tripeptides MAG and GAM was designed and synthesized. Two required tripeptides 5 and 10...
The content of this RSS Feed (c) The Royal Society of Chemistry




xi

meso-Substituted AB3-type phenothiazinyl porphyrins and their indium and zinc complexes photosensitising properties, cytotoxicity and phototoxicity on ovarian cancer cells

RSC Med. Chem., 2024, Advance Article
DOI: 10.1039/D4MD00601A, Research Article
Open Access
Brém Balázs, Bianca Stoean (Vasile), Éva Molnár, Eva Fischer-Fodor, Ovidiu Bălăcescu, Raluca Borlan, Monica Focsan, Adriana Grozav, Patriciu Achimaş-Cadariu, Emese Gál, Luiza Gaina
New meso-substituted AB3-type phenothiazinyl porphyrins and ferrocenylvinyl phenothiazinyl porphyrin were synthesised by Suzuki–Miyaura and Mizoroki–Heck cross-coupling reactions, respectively.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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xi

Light enhanced cytotoxicity and antitumoral effect of a ruthenium-based photosensitizer inspired from natural alkaloids

RSC Med. Chem., 2024, Advance Article
DOI: 10.1039/D4MD00600C, Research Article
Open Access
Gennaro Sanità, Maria Laura Alfieri, Barbara Carrese, Serena Damian, Vincenza Mele, Gaetano Calì, Brigida Silvestri, Sebastiano Marra, Susan Mohammadi, Giuseppina Luciani, Paola Manini, Annalisa Lamberti
Biological assays carried out on melanoma and breast cancer cells highlighted the role of light in boosting the cytotoxic effect of a ruthenium complex featuring a dihydroisoquinoline ligand suggesting applications in photodynamic therapy.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




xi

Adjuvant strategies to tackle mcr-mediated polymyxin resistance

RSC Med. Chem., 2024, Advance Article
DOI: 10.1039/D4MD00654B, Review Article
Madison R. Nuske, Junlang Zhong, Renjie Huang, Vijayalekshmi Sarojini, Jack L. Y. Chen, Christopher J. Squire, Mark A. T. Blaskovich, Ivanhoe K. H. Leung
The emergence of the mobile colistin resistance (mcr) gene is a significant threat contributing to the worldwide antibiotic resistance crisis. This review discusses adjuvant strategies to restore polymyxin sensitivity in these resistant bacteria.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




xi

Flexing it

The Tata Nexon has a wide array of engine and gearbox choices, and the inclusion of a CNG-powered version allows Tata to flaunt its advantage over each of its rivals




xi

Toxic air chokes urban India 

Residents grapple with respiratory, cardiac, and other ailments as the air thickens




xi

Several Delhi govt. schemes to tackle toxic air yet to take off

AAP govt. yet to implement at least 5 programmes it announced over the past two years to curb air pollution; these include using drones to map bad air sources and making PUC mandatory to buy fuel; our plans have been stopped by Centre: AAP




xi

Delhi enveloped in toxic haze, AQI in severe zone in some areas

Data from the CPCB's Sameer app, which provides hourly AQI updates, showed that out of the 38 monitoring stations, 13 were in the severe category with readings above 400




xi

Chhath Puja: Devotees take dip in Yamuna even as toxic foam floats over river  




xi

Yamuna highly toxic, says Delhi HC, bins plea to allow Chhath Puja rituals on riverbanks

Court dismisses petition against order prohibiting Chhath Puja rituals on Yamuna’s banks, says it can’t let devotees fall sick; have made ample arrangements at 1,000 ghats: Delhi govt. counsel; 4-day festival dedicated to Sun God began on Tuesday




xi

DMRC launches bike taxis for last-mile connectivity




xi

Decoding the Xiaomi playbook

A look at the smart strategies that have taken the Chinese ‘internet company’ shooting to the top




xi

RIL exits East Africa petro retail

Sells 76% stake in GAPCO to Total of France; to focus on home market




xi

Axis Bank unveils India’s first certified green bond on LSE




xi

Chain stretching in brushes favors sequence recognition for nucleobase-functionalized flexible precise oligomers

Soft Matter, 2024, 20,8303-8311
DOI: 10.1039/D4SM00866A, Paper
Kseniia Grafskaia, Qian Qin, Jie Li, Delphine Magnin, David Dellemme, Mathieu Surin, Karine Glinel, Alain M. Jonas
Flexible oligomers having precise sequences of nucleobases do not specifically recognize surface-grafted target chains at low grafting density. Moderately higher grafting densities promote sequence-specific recognition thanks to chain stretching.
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xi

Co-encapsulation of organic polymers and inorganic superparamagnetic iron oxide colloidal crystals requires matched diffusion time scales

Soft Matter, 2024, 20,8312-8325
DOI: 10.1039/D4SM00935E, Paper
Open Access
Brian K. Wilson, Robert K. Prud’homme
Composite nanoparticles co-encapsulate organic materials with inorganic primary colloids. Producing “stoichiometric NPs”, where all NPs contain organic and inorganic species at similar ratios, requires matched diffusion-aggregation time scale.
The content of this RSS Feed (c) The Royal Society of Chemistry




xi

Aging iridium oxide catalyst inks: a formulation strategy to enhance ink processability for polymer electrolyte membrane water electrolyzers

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00987H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sunilkumar Khandavalli, Jae Hyung Park, Robin Rice, Diana Y. Zhang, Sarah A. Berlinger, Guido Bender, Deborah J. Myers, Michael Ulsh, Scott A. Mauger
Steady-shear rheology showing evolution of the microstructure of iridium oxide catalyst inks of PEM water electrolyzers with aging time.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




xi

Enhanced chemotaxis efficiency of Escherichia coli in viscoelastic solutions

Soft Matter, 2024, 20,8675-8683
DOI: 10.1039/D4SM01094A, Paper
Shaoying Zhu, Rui He, Caijuan Yue, Rongjing Zhang, Junhua Yuan
E. coli shows enhanced chemotaxis in viscoelastic media, with faster migration and higher accumulation in attractant-rich areas compared to Newtonian conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry




xi

Influence of counterion type on the scattering of a semiflexible polyelectrolyte

Soft Matter, 2024, 20,8610-8620
DOI: 10.1039/D4SM00874J, Paper
Open Access
Anish Gulati, Jack F. Douglas, Olga Matsarskaia, Carlos G. Lopez
Understanding the influence of counterion and backbone solvation on the conformational and thermodynamic properties of polyelectrolytes in solution is one of the main open challenges in polyelectrolyte science.
The content of this RSS Feed (c) The Royal Society of Chemistry




xi

Fibrotaxis: gradient-free, spontaneous and controllable droplet motion on soft solids

Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM01022A, Paper
Open Access
Sthavishtha Bhopalam, Jesus Bueno, Hector Gomez
Most passive droplet transport strategies rely on spatial variations of material properties to drive droplet motion, leading to gradient-based mechanisms with intrinsic length scales that limit the droplet velocity or...
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xi

Flexible Captioned Slanted Images

Eric Meyer gift wraps the most awkwardly shaped of boxes using nothing but CSS, HTML and a little curl of ribbon. No matter how well you plan and how much paper you have at your disposal, sometimes you just need to slant the gift to the side.


We have a lot of new layout tools at our disposal these days—flexbox is finally stable and interoperable, and Grid very much the same, with both technologies having well over 90% support coverage. In that light, we might think there’s no place for old tricks like negative margins, but I recently discovered otherwise.

Over at An Event Apart, we’ve been updating some of our landing pages, and our designer thought it would be interesting to have slanted images of speakers at the tops of pages. The end result looks like this.

The interesting part is the images. I wanted to set up a structure like the following, so that it will be easy to change speakers from time to time while preserving accessible content structures:

<div id="page-top">
  <ul class="monoliths">
    <li>
      <a href="https://aneventapart.com/speakers/rachel-andrew"> 
        <img src="/img/rachel-andrew.jpg" alt=""> 
        <div> 
          <strong>Rachel Andrew</strong> CSS Grid 
        </div> 
      </a>
    </li>
    <li>
      <a href="https://aneventapart.com/speakers/derek-featherstone"> 
        <img src="/img/derek-featherstone.jpg" alt=""> 
        <div> 
          <strong>Derek Featherstone</strong> Accessibility 
        </div> 
      </a>
    </li>
    <li>
      …
    </li>
    <li>
      …
    </li>
  </ul>
</div>

The id value for the div is straightforward enough, and I called the ul element monoliths because it reminded me of the memorial monoliths at the entrance to EPCOT in Florida. I’m also taking advantage of the now-ubiquitous ability to wrap multiple elements, including block elements, in a hyperlink. That way I can shove the image and text structures in there, and make the entire image and text below it one link.

Structure is easy, though. Can we make that layout fully responsive? I wondered. Yes we can. Here’s the target layout, stripped of the navbar and promo copy.

So let’s start from the beginning. The div gets some color and text styling, and the monoliths list is set to flex. The images are in a single line, after all, and I want them to be flexible for responsive reasons, so flexbox is 100% the right tool for this particular job.

#page-top { 
  background: #000; 
  color: #FFF; 
  line-height: 1; 
} 
#page-top .monoliths { 
  display: flex; 
  padding-bottom: 1em; 
  overflow: hidden; 
}

I also figured, let’s give the images a simple basis for sizing, and set up the hyperlink while we’re at it.

#page-top .monoliths li { 
  width: 25%; 
} 
#page-top .monoliths a { 
  color: inherit; 
  text-decoration: inherit; 
  display: block; 
  padding: 1px; 
}

So now the list items are 25% wide—I can say that because I know there will be four of them—and the links pick up the foreground color from their parent element. They’re also set to generate a block box.

At this point, I could concentrate on the images. They need to be as wide as their parent element, but no wider, and also match height. While I was at it, I figured I’d create a little bit of space above and below the captioning text, and make the strong elements containing speakers’ names generate a block box.

#page-top .monoliths img { 
  display: block; 
  height: 33rem; 
  width: 100%; 
} 
#page-top .monoliths div { 
  padding: 0.5em 0; 
} 
#page-top .monoliths strong { 
  display: block; 
  font-weight: 900; 
}

It looks like the speakers were all cast into the Phantom Zone or something, so that needs to be fixed. I can’t physically crop the images to be the “correct” size, because there is no correct size: this needs to work across all screen widths. So rather than try to swap carefully-sized images in and out at various breakpoints, or complicate the structure with a wrapper element set to suppress overflow of resized images, I turned to object-fit.

#page-top .monoliths img { 
  display: block; 
  height: 33rem; 
  width: 100%; 
  object-fit: cover; 
  object-position: 50% 20%; 
}

If you’ve never used object-fit, it’s a bit like background-size. You can use it to resize image content within the image’s element box without creating distortions. Here, I set the fit sizing to cover, which means all of the img element’s element box will be covered by image content. In this case, it’s like zooming in on the image content. I also set a zooming origin with object-position, figuring that 50% across and 20% down would be in the vicinity of a speaker’s face, given the way pictures of people are usually taken.

This is fairly presentable as-is—a little basic, perhaps, but it would be fine to layer the navbar and promo copy back over it with Grid or whatever, and call it a day. But it’s too square and boxy. We must go further!

To make that happen, I’m going to take out the third and fourth images temporarily, so we can see more clearly how the next part works. That will leave us with Rachel and Derek.

The idea here is to clip the images to be slanted, and then pull them close to each other so they have just a little space between them. The first part is managed with clip-path, but we don’t want to pull the images together unless their shapes are being clipped. So we set up a feature query.

@supports (clip-path: polygon(0 0)) or (-webkit-clip-path: polygon(0 0)) { 
  #page-top .monoliths li { 
    width: 37.5%; 
  } 
}

I decided to test for both the un-prefixed and WebKit-prefixed versions of clip-path because Safari still requires the prefix, and I couldn’t think of a good reason to penalize Safari’s users for the slowness of its standards advancement. Then I made the images wider, taking them from 25% to 37.5%, which makes them half again as wide.

Thanks to object fitting, the images don’t distort when I change their parent’s width; they just get wider and scale up the contents to fit. And now, it is time for clipping!

@supports (clip-path: polygon(0 0)) or (-webkit-clip-path: polygon(0 0)) { 
  #page-top .monoliths li { 
    width: 37.5%; 
    -webkit-clip-path: polygon(25% 0, 100% 0, 75% 100%, 0 100%); 
    clip-path: polygon(25% 0, 100% 0, 75% 100%, 0 100%); 
  } 
}

Each coordinate pair in the polygon() is like the position pairs in background-position or object-position: the horizontal distance first, followed by the vertical distance. So the first point in the polygon is 25% 0, which is 25% of the way across the element box, and no distance down, so right at the top edge. 100% 0 is the top right corner. 75% 100% is on the bottom edge, three-quarters of the way across the element, and 0 100% is the bottom left corner. That creates a polygon that’s a strip three-quarters the full width of the element box, and runs from bottom left to top right.

Now we just have to pull them together, and this is where old tricks come back into play: all we need is a negative right margin to bring them closer together.

#page-top .monoliths li { 
  width: 37.5%; 
  margin-right: -7.5%; 
  -webkit-clip-path: polygon(25% 0, 100% 0, 75% 100%, 0 100%); 
  clip-path: polygon(25% 0, 100% 0, 75% 100%, 0 100%); 
}

The separation between them is a little wider than we were originally aiming for, but let’s see what happens when we add the other two images back in and let flexbox do its resizing magic.

Notice how the slants actually change shape as the screen gets narrower or wider. This is because they’re still three-quarters the width of the image element’s box, but the width of that box is changing as the screen width changes. That means at narrow widths, the slant is much steeper, whereas at wide widths, the slant is more shallow. But since the clipping path’s coordinates were all set with percentage distances, they all stay parallel to each other while being completely responsive to changes in screen size. An absolute measure like pixels would have failed.

But how did the images get closer together just by adding in two more? Because the list items’ basic sizing added up to more than 100%, and they’re all set to flex-shrink: 1. No, you didn’t miss a line in the CSS: 1 is the default value for flex-shrink. Flex items will shrink by default, which after all is what we should expect from a flexible element. If you want to know how much they shrunk, and why, here’s what Firefox’s flex inspector reports.

When there were only two list items, there was space enough for both to be at their base size, with no shrinkage. Once we went to four list items, there wasn’t enough space, so they all shrank down. At that point, having a negative right margin of -7.5% was just right to pull them together to act as a unit.

So, now they’re all nicely nestled together, and fully responsive! The captions need a little work, though. Notice how they’re clipped off a bit on the left edge, and can be very much clipped off on the right side at narrower screen widths? This happens because the li elements are being clipped, and that clipping applies to all their contents, images and text alike. And we can’t use overflow to alter this: clipped is clipped, not overflowed.

Fortunately, all we really need to do is push the text over a small amount. Inside the feature query, I added:

#page-top .monoliths div { 
  padding-left: 2%;
  padding-right: 26%; 
}

This shifts the text just a bit rightward, enough to clear the clip path. On the right side, I padded the div boxes so their contents wouldn’t fall outside the clipped area and appear to slide under the next caption. We could also use margins here, but I didn’t for reasons I’ll make clear at the end.

At the last minute, I decided to make the text at least appear to follow the slants of the images. For that, I just needed to shift the first line over a bit, which I did with a bit more padding.

#page-top .monoliths strong { 
  padding-left: 1%; 
}

That’s all to the good, but you may have noticed the captions still overlap at really narrow screen widths. There are a lot of options here, from stacking the images atop one another to reverting to normal flow, but I decided to just hide the captions if things got too narrow. It reduces clutter without sacrificing too much in the way of content, and by leaving them still technically visible, they seem to remain accessible.

@media (max-width: 35rem) { 
  #page-top .monoliths div { 
    opacity: 0.01 
  } 
}

And that, as they say, is that! Fully responsive slanted images with text, in an accessible markup structure. I dig it.

I did fiddle around with the separations a bit, and found that a nice thin separator occurred around margin-right: -8%, whereas beefier ones could be found above -7%. And if you crank the negative margin value to something beyond -8%, you’ll make the images overlap entirely, no visible separation—which can be a useful effect in its own right.

I promised to say why I used padding for the caption text div rather than margins. Here’s why.

#page-top .monoliths div { 
  padding-left: 3%; 
  padding-right: 26%; 
  border-top: 2px solid transparent; 
  background: linear-gradient(100deg,hsl(292deg,50%,50%) 50%, transparent 85%); 
  background-clip: padding-box; 
}

It required a wee bit more padding on the left to look decent, and an alteration to the background clipping box in order to keep the purple from filling the transparent border area, but the end result is pretty nifty, if I do say so myself. Alternatively, we could drop the background gradient on the captions and put one in the background, with a result like this.

I have no doubt this technique could be extended, made more powerful, and generally improved upon. I really wished for subgrid support in Chrome, so that I could put everything on a grid without having to tear the markup structure apart, and there are doubtless even more interesting clipping paths and layout patterns to try out.

I hope these few ideas spark some much better ideas in you, and that you’ll share them with us!


About the author

Eric A. Meyer (@meyerweb) has been a burger flipper, a college webmaster, an early blogger, one of the original CSS Samurai, a member of the CSS Working Group, a consultant and trainer, and a Standards Evangelist for Netscape. Among other things, Eric co-wrote Design For Real Life with Sara Wachter-Boettcher for A Book Apart and CSS: The Definitive Guide with Estelle Weyl for O’Reilly, created the first official W3C test suite, assisted in the creation of microformats, and co-founded An Event Apart with Jeffrey Zeldman. Eric lives with his family in Cleveland, Ohio, which is a much nicer city than you’ve probably heard. He enjoys a good meal whenever he can and considers almost every form of music to be worthwhile.

More articles by Eric




xi

Editorial. Flexible norms will make rights issues attractive

The current norms are too onerous




xi

RBI approves third term for Axis Bank MD, CEO Amitabh Chaudhry

Before joining Axis Bank, Chaudhry was leading HDFC Life



  • Money &amp; Banking

xi

For new players, existing expense of management regulations are a challenge: Zuno General Insurance CEO

Zuno General Insurance continued to grow faster than the industry in the second quarter of this fiscal, says Shanai Ghosh, MD & CEO of the company



  • Money &amp; Banking

xi

Trump’s toxic politics of misinformation

The danger of Donald Trump’s leadership lies in his willingness to exploit and manipulate information to achieve his goals




xi

The history of approximation theory [electronic resource] : from Euler to Bernstein / Karl-Georg Steffens

Boston : Birkhauser, 2006




xi

The maximum principle [electronic resource] / Patrizia Pucci, James Serrin

Basel ; Boston : Birkhauser, 2007




xi

Round 2 in the Trump-vs-Mexico matchup looks ominous for Mexico

Mexico is facing a second Donald Trump presidency, and few countries can match its experience as a target of Trump’s rhetoric: There have been threats to close the border, impose tariffs and even send U.S. forces to fight Mexican drug cartels if the country doesn’t do more to stem the flow of migrants and drugs




xi

Nexus Select Trust in talks to acquire Axis Mall in Kolkata

The acquisition of the mall would require a different structure to be set in place since it does not have a single owner or promoter




xi

A threadbare existence

Artisans and their indigenous crafts are being pushed to the brink due to fierce competition and lack of cohesive government support




xi

Visible-light heterogeneous photocatalysis with an ionic porous organic polymer (IPOP): synthesis of β-keto sulfoxides and benzothiophene diesters by tandem radical addition–oxidation reactions

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01382D, Research Article
Ajay Kumar Sahoo, Parag Tamuly, Jarugu Narasimha Moorthy
An IPOP, constructed constructed from cyanuric chloride and the readily accessible 2,5-di(pyridin-4-yl)thiazolo[5,4-d]thiazole (BpyTzTz), is shown to exhibit excellent visible light absorption and serve as a metal-free heterogeneous photocatalyst.
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xi

Unravelling the different pathways of cyclohexene oxidation via a peroxyl radical generated from tert-butyl hydroperoxide (TBHP) by various metal salts

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01681E, Research Article
Lu-Jian Zhou, Xiao-Hui Liu, Han-Wen Zhang, Can Xue, Han-Kang Zhong, Xian-Tai Zhou
Two different mechanisms were obtained in the selective oxidation of cyclohexene catalyzed by CuCl2 and VCl3 respectively in presence of TBHP. The two opposed mechanisms are mainly caused by the roles of the t-BuOO˙ radical in catalytic oxidations.
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I2-Promoted oxidative annulation of three different amines to access diverse biheteroaryls

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01801J, Research Article
Guangping Fan, Penghui Cao, Fang Bai, Yanyan Yin, Xueyan Hou, Yani Liu, Zhenzhen Xing, Yanhui Wang, Tangqiang Sun, Qinghe Gao
An I2-promoted oxidative annulation of three different amines enables the assembly of nonsymmetrical 2,2'-biquinolines and related bis-azines through a [4π + 2σ] annulation reaction.
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Photoinduced cobaloxime catalysis for allylic mono- and diphosphinylation of alkenes with hydrogen evolution

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01638F, Research Article
Aijun Zhang, Miao-Miao Li, Lei Guo, Huaixiang Yang, Jiefei Guo, Da Xu, Wei Ding
A highly efficient allylic radical mono- and diphosphinylation of alkenes with secondary phosphine oxides is developed, via visible-light-induced cobaloxime catalysis.
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Visible-light excited copper activating unactivated alkyl iodides for radical addition/cyclization to access oxindole derivatives

Org. Chem. Front., 2024, 11,6380-6384
DOI: 10.1039/D4QO01329H, Research Article
Hang Luo, Fangnian Yu, Luqing Lin
The photocopper catalyst facilitates halogen atom transfer to give unactivated alkyl radicals, which is critical for achieving radical cyclization in the absence of an exogenous photocatalyst.
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Iridium/palladium dual photocatalysis for oxidative decarboxylative esterification of alcohols using α-keto acids

Org. Chem. Front., 2024, 11,6367-6379
DOI: 10.1039/D4QO01452A, Research Article
Subal Mondal, Soumya Mondal, Debabrata Halder, Siba P. Midya, Ankan Paul, Pradyut Ghosh
Herein, we report an unprecedented oxidative decarboxylative C–O cross-coupling reaction for the esterification of feedstock α-keto carboxylic acids and alcohols under mild conditions.
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Visible light-induced aerobic photooxidative cleavage of C(sp3)–C(sp2) σ-bonds of allylarenes

Org. Chem. Front., 2024, 11,6385-6392
DOI: 10.1039/D4QO01243G, Research Article
Jinyu Tang, Xi Zhao, Jinxuan Ni, Yanping Huo, Yang Gao, Xianwei Li, Yan Liu, Keiji Maruoka, Qian Chen
A cleavage of C(sp3)–C(sp2) σ-bonds of allylarenes to aromatic aldehydes and ketones has been achieved via a visible light-induced photocatalysis.
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Design, synthesis and application of bipyridine-N,N'-dioxide catalysts in asymmetric synthesis of chiral cyclopropanes

Org. Chem. Front., 2024, 11,6470-6476
DOI: 10.1039/D4QO01532K, Research Article
Xiaoying Cao, Xue Tian, Minmin Liu, Shi-Wu Li
A novel type of highly efficient chiral C2-symmetric bipyridine-N,N'-dioxide ligands was prepared and successfully applied in the synthesis of optically pure 1,2,3-trisubstituted cyclopropanes.
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Visible-light-promoted catalytic epoxidation of alkenes under metal-free conditions

Org. Chem. Front., 2024, 11,6437-6443
DOI: 10.1039/D4QO01265H, Research Article
Dabao Tan, Xiaoyan Cai, Lele Zhang, Boyu Liu, Jianbin Zeng, Feiming Li, Zhixiong Cai, Mingqiang Huang, Xiaoping Chen, Shunyou Cai
In this work, we report a method for the synthesis of functionalized epoxy analogues using the synergistic interaction of 4CzIPN and oxygen under visible light stimulation.
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