The title compound, [Ni(NCS)2(C6H7N)2]n, was prepared by the reaction of Ni(NCS)2 with 4-methyl­pyridine in water. Its asymmetric unit consists of two crystallographically independent NiII cations, of which one is located on a twofold rotational axis whereas the second occupies a center of inversion, two independent thio­cyanate anions and two independent 4-methyl­pyridine co­ligands in general positions. Each NiII cation is octa­hedrally coordinated by two 4-methyl­pyridine coligands as well as two N- and two S-bonded thio­cyanate anions. One of the cations shows an all-trans, the other a cis–cis–trans configuration. The metal centers are linked by pairs of μ-1,3-bridging thio­cyanate anions into [101] chains. X-ray powder diffraction shows that a pure crystalline phase has been obtained and thermogravimetry coupled to differential thermoanalysis reveals that the title compound loses half of the 4-methyl­pyridine coligands and transforms into Ni(NCS)2(C6H7N). Nearly pure samples of this compound can be obtained by thermal annealing and a Rietveld refinement demonstrated that it is isotypic to its recently reported Cd analog [Neumann et al., (2020). CrystEngComm. 22, 184–194] In its crystal structure, the metal cations are linked by one μ-1,3(N,S)- and one μ-1,3,3(N,S,S)-bridging thio­cyanate anion into single chains that condense via the μ-1,3,3(N,S,S)-bridging anionic ligands into double chains.

The mol­ecule of the title compound, [Ni(C5H7O2)2(C8H9N3)(H2O)]·C2H5OH, has triclinic (Poverline{1}) symmetry. This compound is of inter­est for its anti­microbial properties. The asymmetric unit comprises two independent complex mol­ecules, which are linked by N—H⋯O and O—H⋯O hydrogen bonds along [111]. Hirshfeld surface analysis indicates that 71.7% of inter­mol­ecular inter­actions come from H⋯H contacts, 17.7% from C⋯H/H⋯C contacts and 7.6% from O⋯H/H⋯O contacts, with the remaining contribution coming from N⋯H/H⋯N, C⋯N/N⋯C, C⋯C and O⋯O contacts.

The crystal structure of the title compound, [Ni(C8H20N4)(NO3)]NO3, at room temperature, has monoclinic (P21/n) symmetry. The structure displays inter­molecular hydrogen bonding. The nickel displays a distorted bipyramidal geometry with the symmetric bidentate bonded nitrate occupying an equatorial site. The 1,4,7,10-tetra­aza­cyclo­dodecane (cyclen) backbone has the [4,8] configuration, with three nitro­gen-bound H atoms directed above the plane of the nitro­gen atoms towards the offset nickel atom with the fourth nitro­gen-bound hydrogen directed below from the plane of the nitro­gen atoms. The nitrate anion O atoms are seen to hydrogen bond to the H atoms bound to the N atoms of the ligand.

The unit cell of the title compound, [Ni(C16H10ClN6)2]·2CH3OH, consists of a neutral complex and two methanol mol­ecules. In the complex, the two tridentate 2-(3-(4-chloro­phen­yl)-1H-1,2,4-triazol-5-yl)-6-(1H-pyrazol-1-yl)pyridine ligands coordinate to the central NiII ion through the N atoms of the pyrazole, pyridine and triazole groups, forming a pseudo­octa­hedral coordination sphere. Neighbouring tapered mol­ecules are linked through weak C—H(pz)⋯π(ph) inter­actions into monoperiodic chains, which are further linked through weak C—H⋯N/C inter­actions into diperiodic layers. The inter­molecular contacts were qu­anti­fied using Hirshfeld surface analysis and two-dimensional fingerprint plots, revealing the relative contributions of the contacts to the crystal packing to be H⋯H 32.8%, C⋯H/H⋯C 27.5%, N⋯H/H⋯N 15.1%, and Cl⋯H/H⋯Cl 14.0%. The average Ni—N bond distance is 2.095 Å. Energy framework analysis at the HF/3–21 G theory level was performed to qu­antify the inter­action energies in the crystal structure.

Lenny & Larry’s Snickerdoodle Complete Cookie is made with ground cinnamon and sugar, plus “a little twist.”

A devoted teacher and head baseball coach, Mr. Sorrell led an AA baseball team to Idaho's state title in 2020

Adam Jonathan Skolnick is lauded for his career in college sports as a leading head men's and women's soccer coach

Scott Mitnick celebrated for over 35 years of success in local government management and public service

Nick Singleton, MBA, is a seasoned leadership and business strategy expert in his leading role at Integra Connect LLC

Sounick Haldar is recognized for his expertise as a primary care physician at Cooper Green Mercy Health Services Authority (CGMHSA), an affiliate of University of Alabama at Birmingham (UAB) Health System.

Michael G. Botwinick, CFP, is lauded for his contributions to the financial sector as a distinguished wealth advisor

Theresa A. Nicklas is an expert with more than 40 years of experience in nutrition and public health

Heartwarming Holiday Film to Screen in Florida and California

Catch the Award-Winning Saint Nick on September 29th at the Palm Springs International Comedy Festival!

This will be the last episode of the Livecast posted to Metal Injection, get future episodes at ripalivecast.com Skoly-D himself, Alex Skolnick sits in with us to chat about our […]

Nick is an Information Systems developer based in the Faculty of Economic and Social Studies in the University of Manchester. His role is to develop (mostly Web) applications to support teaching and administration. Nick gave a talk entitled "'He left the course 3 months ago?' - Web front-ends to student databases".

"Giant, sprawling future Gotham City is under martial law, protected and regulated by a private security force led by the infamous Peacekeepers. Their mandate is to maintain the safety of the citizens of Gotham, regardless of any Constitutional rights, and to hunt down, incarcerate, or kill all masked vigilantes, villains, and criminals in the city limits. It's a dangerous and violent look at a possible future Gotham City and the heroes and villains who live there!" -- Provided by publisher.

The Australian musician talks about the motivation and meaning behind Wild God, a new album with his band The Bad Seeds.

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Nick Tune and Jean-Georges Perrin join host Giovanni Asproni to talk about their proposed approach to modernizing legacy systems. The episode starts with some high-level perspective to set context for the approach described in their book, Architecture Modernization (Manning, 2024). From there, the discussion turns to important details, including criteria for deciding which aspects to revisit; some of the activities, processes, and tools; and the importance of data engineering in modernization efforts. Nick and Jean-Georges describe how to successfully implement an architecture-modernization effort, and how to fit that work with the teams' other priorities. The episode finishes with some warnings about the typical risks associated with modernizing a legacy system, and suggestions on how to mitigate them.

This episode is sponsored by QA Wolf.

Mike and Ike is making NY Knicks star Josh Hart's dreams come true, by putting his face on one of its boxes.

WASHINGTON, D.C. -- Multi-hyphenate entertainer and media mogul Nick Cannon will host the 2022 Marconi Radio Awards Dinner on October 19 during NAB Show New York. Record producer and radio host DJ Scratch will provide live music during the ceremony, which celebrates excellence in radio and is returning in person after a two-year hiatus.

Brawl it out as your favorite Nickelodeon characters in bombastic platform battles! With a power-packed cast of heroes from the Nickelodeon universe, face-off with all-stars from SpongeBob Squarepants, Teenage Mutant Ninja Turtles, The Loud House, Danny Phantom, Aaahh!!! Real Monsters, The Wild Thornberrys, Hey Arnold!, Rugrats, and more to determine ultimate animation dominance.

With unique move sets and attacks inspired by their personalities, each character has an individual style of play enabling endless action for Nickelodeon’s legion of fans. Select your favorite and then let the intense brawls begin with online and local multiplayer action.

Tyler Herro may never be missed more than in the Eastern Conference semifinals against the New York Knicks. But there still is a way for the Miami Heat to keep it rolling in the NBA playoffs.

Miami Heat again steal homecourt advantage in a playoff road opener, this time pushing past the New York Knick at Madison Square Garden.

Location: Sciences Library Library- TC824.M9P4 no.7

The British model, who shot to fame for starring in an iconic commercial for Levi's jeans in the 1980s before launching his music career, has passed away at the age of 59.

Wednesday MidDay Medley Produced and Hosted by Mark Manning Wednesday, November 13, 2024 Brock Wilbur & Nick Spacek of The Pitch + Damron Russel Armstrong of The Black Repertory Theatre […]

The post WMM presents Brock Wilbur & Nick Spacek of The Pitch + Damron Russel Armstrong of The Black Repertory Theatre of Kansas City appeared first on KKFI.

Kid Rock and Nickelback have announced that they will be rocking the country next spring and summer with a new touring festival

In the latest edition of the Kickin' it with Kiz podcast, sports columnist Mark Kiszla reflects on a pair of coaching legends calling it quits in the same week.

She has been struggling with her health.

Aby byla vzpoura povýšena na revoluci, musí nejdříve zvítězit. Extremista, který ve svém boji uspěl, se může stát bojovníkem za svobodu – aspoň pro dějepravu vlastního národa. Základním problémem každé definice je, že se politické pojmosloví zpravidla nepoužívá ve svém normativním významu. Ještě donedávna se výstižně vtipkovalo, že rozdíl mezi demokracií obecně a demokracií socialistickou je zhruba stejný jako mezi křeslem a elektrickým křeslem.

  With just a few simple ingredients and a little bit of time, you can make these delicious Snickerdoodle Cookies to share with your family and friends for Christmas, other seasonal holidays, or anytime for that matter. Snickerdoodle Cookies have the delicious flavor of cinnamon, sweet sugar taste, and the velvety butter mouth feel.  If …

Every Canadian of my generation knows the line, “I told him, Julie, don’t go!” It was said by Sylvia Lennick, the mother of my dear friend, the great Canadian filmmaker and special-effects expert Michael Lennick. Michael passed away ten years ago today, on November 7, 2014, at just 61 years of age. He’d been admitted […]

Prisons are in the news again, following recent outbreaks of disorder. This is an excellent piece from the Telegraph

I have been to Hollesley Bay a couple of times; it had a completely different culture from closed prisons such as the Scrubs, with a target of getting inmates ready for work on release.

"I use music as a way into writing; it's a bit of Pavlovian self-programming, and particularly handy if you've got a full day and only narrow windows in which to write. You teach yourself that a particular piece of music means work, and your brain will generally go along. It makes the transition from shopping list to fiction much faster and smoother, at least for me."

I do in-house design work for my boss. I’ve worked with her for ten years and she swings wildly back and forth from being surprisingly design-savvy (not for a literal decade of trying on my part) and being a client from Hell. Today, she swung somewhere in the middle.

I have spent the entire time I’ve known her explaining how you cannot just pull photos from Google; I’ve explained copyright, public domain, etc. She refuses to buy photos 99% of the time, so I usually use free stock photos when possible. When she absolutely needs to buy a photo, she emails our web guy and has him buy one for her and add it to her next bill.

Me: “I see you got [Web Guy] to purchase the photo for the ad and forwarded me the email with the file. Unfortunately, the file is too small. Unless he sent you a separate email with a larger file, I will just email him for the correct one.”

Boss: “Maybe it’s how I sent it. I’ll try again.”

She forwards me the same email.

Me: “No, no, it’s not you. The file he sent you is labelled “thumbnail,” which is a preview file. He probably just sent the wrong one by accident. I have emailed him.”

Boss: “What about this one?”

She sends an email with the same photo attached.

Me: “That’s the same one. I have emailed [Web Guy]. Don’t worry about it. You don’t have the correct file.”

She forwards the same original email from [Web Guy].

Boss: “What about now?”

Me: “No, boss, I’ll get it from [Web Guy].”

She forwards the individual email she sent me.

Boss: “How about now?”

Me: “Boss, no.”

Closure: She now has a stock photo account that I have access to.

Simon Morrison, author of the new musical biography "Mirror in the Sky,” is a professor of music and Slavic languages and literatures, and a sought-after lecturer in the humanities.

America has been chipping away at China's huge lead in the global cleantech race. Trump's return will see the US all but drop out. Bad news for the US, worse for the climate. But there are silver linings for the rest of the world, says Nick Hedley.

There's a simple way to increase your cat's happiness, says animal behaviorist Nicky Trevorrow. She explains the importance of play for our feline friends — and for basically any species (looking at you, dog lovers!) — and shares specific, actionable strategies to boost your cat's mental and physical health.

While the Lady Vols volunteered at the Girls Inc. basketball clinic, they reminded Nicky Anosike of her own Tennessee teammates

The last time a snowfall was recorded at the Winnipeg airport was on April 19, making it 206 days without any snow. Normally, Winnipeggers would see the first snowfall in October.

In South Africa, an astounding 81% of Grade 4 pupils can't read for meaning. It's time we looked at approaches in other markets that have clearly delivered results, says Nick Hedley.

Penn State Brandywine’s Student Spotlight series highlights the remarkable work being done by students in leadership, academics, service, athletics and more.

The pace of the energy transition has accelerated exponentially in recent years and South Africa has failed to keep pace. But there is hope with legislative changes paving the way for a more competitive electricity market, says Nick Hedley.

Nick Jonas even grooved a bit with his mother-in-law, Madhu Chopra at Priyanka Chopra’s cousin’s wedding