Five months after Jewish graves were vandalised in St. Louis, questions remain.

Also: a resolution condemning racism causes chaos at the Southern Baptist Convention; why refugees from Myanmar draw inspiration from the action movie, Rambo; the story of a murder that got manipulated to serve more than one political agenda; why a hate crime survivor tried to save the life of his attacker; plus Renee Goust has something to say to people who thinks she’s a “feminazi” and it comes in the form of a song.

(Image: Karen Aroesty is the regional director of the Anti-Defamation League. Credit: Daniel A. Gross)

This is not about promoting a song, but a posture of the heart…Let the church rise up and say “Whatever You Want”. 

Whatever You Want
Written by Michael Farren and Josh Alltop
Recorded by CHURCHOUSE - Gateway Franklin Church

Lyric Video: https://youtu.be/SDJcMAsmi_w
Free Chord Charts: https://www.weareworship.com/us/songs-2/song-library/showsong/7420
Get Song on iTunes: https://itunes.apple.com/us/album/whatever-you-want-live/id1098023380

Prayon, a world leader in phosphate chemistry, will build a new factory and boost the company’s production of food grade sodium hexametaphosphate (SHMP). This project is part of Prayon's growth strategy in several sectors (food additives, water treatment, industrial applications), and it will support the group's development worldwide. 

Florida Food Products, LLC (“FFP”), a leading innovator, formulator, and producer of natural, clean label ingredient solutions, announced the issuance of a new patent granted by the United States Patent and Trademark Office (USPTO) for its rice bran extract marketed under the VegStable® Plus brand.

Duchateau adds two colors, Aether and Solstice, to its Atelier engineered hardwood collection.

Volume 34, Issue 5, September-October 2024, Page 306-322. Read the full article ›

The post “I Don’t Just Take Whatever They Hand to Me”: How Women Recently Released from Incarceration Access Internet Health Information was curated by information for practice.

Nancy O'Brien Simpson I've been on a hiatus, however, the hubris of the USA and its self-righteous bullshit burns through me.  Writing is a catharsis to prevent my soul from being scorched by our hypocrisy.   Where to begin?  The USA loves to throw stones, we love to hate.  Russia is "our enemy" is blasted throughout our media.  Why Russia is our enemy is never revealed.  It is inferred they are commies and want to somehow harm us.  So we have to fear them, nuke up against them and sanction them.  

Craw-Dadding. Actually, Craw-Daddin'. The first time I used it the blonde with me had no conception.

Dr. Neil Johnson, a physics professor at George Washington University, explores unconventional areas within physics, focusing on complex, "taboo" problems not traditionally tackled by physicists, like online hate networks.

On this week's episode of I Feel You, DJ Hyerim and NVee dive into their fitness routines, sharing the secrets behind staying in shape and the complicated relationships with personal trainers....

[more...]

In the title compound, the symmetric phosphate derived from para-chloro­phenol and phospho­ric acid, two of the three aromatic moieties adopt syn-orientation towards the P&z-dbnd;O bond while the last chloro­phenol ring is pointing away from this bond. In the extended structure, C—H⋯O bonds connect the individual mol­ecules into sheets lying perpendicular to the crystallographic b axis.

Glucose-6-phosphate dehydrogenase (G6PD) is the first enzyme in the pentose phosphate pathway. It has been extensively studied by biochemical and structural techniques. 13 X-ray crystal structures and five electron cryo-microscopy structures in the PDB are focused on in this topical review. Two F420-dependent glucose-6-phosphate dehydrogenase (FGD) structures are also reported. The significant differences between human and parasite G6PDs can be exploited to find selective drugs against infections such as malaria and leishmaniasis. Furthermore, G6PD is a prognostic marker in several cancer types and is also considered to be a tumour target. On the other hand, FGD is considered to be a target against Mycobacterium tuberculosis and possesses a high biotechnological potential in biocatalysis and bioremediation.

Guanosine 5'-monophosphate (GMP) synthetase (GuaA) catalyzes the last step of GMP synthesis in the purine nucleotide biosynthetic pathway. This enzyme catalyzes a reaction in which xanthine 5'-monophosphate (XMP) is converted to GMP in the presence of Gln and ATP through an adenyl-XMP intermediate. A structure of an XMP-bound form of GuaA from the domain Bacteria has not yet been determined. In this study, the crystal structure of an XMP-bound form of GuaA from the thermophilic bacterium Thermus thermophilus HB8 (TtGuaA) was determined at a resolution of 2.20 Å and that of an apo form of TtGuaA was determined at 2.10 Å resolution. TtGuaA forms a homodimer, and the monomer is composed of three domains, which is a typical structure for GuaA. Disordered regions in the crystal structure were obtained from the AlphaFold2-predicted model structure, and a model with substrates (Gln, XMP and ATP) was constructed for molecular-dynamics (MD) simulations. The structural fluctuations of the TtGuaA dimer as well as the interactions between the active-site residues were analyzed by MD simulations.

Structures of tetra­pyridine­silver(I) hexa­fluoro­phosphate and tetra­pyridine silver(I) hexa­fluoro­anti­monate are reported from data collected at 300 K and 100 K.

The title compound, [Ru(C19H13N5)2](PF6)2·3C4H10O, was obtained from the reaction of Ru(bimpy)Cl3 [bimpy is 2,6-bis­(1H-benzimidazol-2-yl)pyridine] and bimpy in refluxing ethanol followed by recrystallization from diethyl ether/aceto­nitrile. At 125 K the complex has ortho­rhom­bic (Pca21) symmetry. It is remarkable that the structure is almost centrosymmetric. However, refinement in space group Pbcn leads to disorder and definitely worse results. It is of inter­est with respect to potential catalytic reduction of CO2. The structure displays N—H⋯O, N—H⋯F hydrogen bonding and significant π–π stacking and C—H⋯π stacking inter­actions.

The title compound, [Ir(C15H10N)2(C19H12N4)]PF6·CH3OH, crystallizes in the C2/c space group with one monocationic iridium complex, one hexa­fluorido­phosphate anion, and one methanol solvent mol­ecule of crystallization in the asymmetric unit, all in general positions. The anion and solvent are linked to the iridium complex cation via hydrogen bonding. All bond lengths and angles fall into expected ranges compared to similar compounds.

The title compound, [Ru(C12H14NO2)2(C12H8N2)]PF6 crystallizes in the tetra­gonal Sohnke space group P41212. The two bidentate chiral salicyloxazoline ligands and the phenanthroline co-ligand coordinate to the central RuIII atom through N,O and N,N atom pairs to form bite angles of 89.76 (15) and 79.0 (2)°, respectively. The octa­hedral coordination of the bidentate ligands leads to a propeller-like shape, which induces metal-centered chirality onto the complex, with a right-handed (Δ) absolute configuration [the Flack parameter value is −0.003 (14)]. Both the complex cation and the disordered PF6− counter-anion are located on twofold rotation axes. Apart from Coulombic forces, the crystal cohesion is ensured by non-classical C—H⋯O and C—H⋯F inter­actions.

The title compound, C18H12Cl3O4P, is the symmetric phosphate derived from para-chloro­phenol and phospho­ric acid. Two of the three aromatic moieties adopt syn-orientation towards the P=O bond while the last chloro­phenol ring is pointing away from this bond. In the extended structure, C—H⋯O bonds connect the individual mol­ecules into sheets lying perpendicular to the crystallographic b axis.

Single crystals of tricadmium orthophosphate, Cd3(PO4)2, have been synthesized successfully by the hydro­thermal route, while its powder form was obtained by a solid-solid process. The corresponding crystal structure was determined using X-ray diffraction data in the monoclinic space group P21/n. The crystal structure consists of Cd2O8 or Cd2O10 dimers linked together by PO4 tetra­hedra through sharing vertices or edges. Scanning electron microscopy (SEM) was used to investigate the morphology and to confirm the chemical composition of the synthesized powder. Infrared analysis corroborates the presence of isolated phosphate tetra­hedrons in the structure. UV–Visible studies showed an absorbance peak at 289 nm and a band gap energy of 3.85 eV, as determined by the Kubelka–Munk model.

The tetra­kis complex of neodymium(III), tetra­kis­{μ-N-[bis­(pyrrolidin-1-yl)phos­phor­yl]acet­am­id­ato}bis(pro­pan-2-ol)neodymiumsodium pro­pan-2-ol monosol­vate, [NaNd(C10H16Cl3N3O2)4(C3H8O)2]·C3H8O or NaNdPyr4(i-PrOH)2·i-PrOH, with the amide type CAPh ligand bis(N,N-tetra­methylene)(tri­chloro­acetyl)phos­phoric acid tri­amide (HPyr), has been synthesized, crystallized and characterized by X-ray diffraction. The complex does not have the tetra­kis­(CAPh)lanthanide anion, which is typical for ester-type CAPh-based coordin­ation compounds. Instead, the NdO8 polyhedron is formed by one oxygen atom of a 2-propanol mol­ecule and seven oxygen atoms of CAPh ligands in the title compound. Three CAPh ligands are coordinated in a bidentate chelating manner to the NdIII ion and simultaneously binding the sodium cation by μ2-bridging PO and CO groups while the fourth CAPh ligand is coordinated to the sodium cation in a bidentate chelating manner and, due to the μ2-bridging function of the PO group, also binds the neodymium ion.

Syntheses of the acyclic amidinium salts, morpholino­formamidinium hexa­fluorido­phosphate [OC4H8N—CH=NH2]PF6 or C5H11N2O+·PF6−, 1, and pyrrolidinoformamidinium hexa­fluorido­phosphate [C4H8N—CH= NH2]PF6 or C5H11N2+·PF6−, 2, were carried out by heating either morpholine or pyrrolidine with triethyl orthoformate and ammonium hexa­fluorido­phosphate. Crystals of 1 obtained directly from the reaction mixture contain one cation and one anion in the asymmetric unit. The structure involves cations linked in chains parallel to the b axis by N—H⋯O hydrogen bonds in space group Pbca, with glide-related chains pointing in opposite directions. Crystals of 1 obtained by recrystallization from ethanol, however, showed a similar unit cell and the same basic structure, but unexpectedly, there was positional disorder [occupancy ratio 0.639 (4):0.361 (4)] in one of the cation chains, which lowered the crystal symmetry to the non-centrosymmetric space group Pca21, with two cations and anions in the asymmetric unit. In the pyrrolidino compound, 2, cations and anions are ordered and are stacked separately, with zigzag N—H⋯F hydrogen-bonding between stacks, forming ribbons parallel to (101), extended along the b-axis direction. Slight differences in the delocalized C=N distances between the two cations may reflect the inductive effect of the oxygen atom in the morpholino compound.

The title compound dipotassium gadolinium(III) phosphate(V) molybdate(VI), K2Gd(PO4)(MoO4), was synthesized from a high-temperature melt starting from GdF3 as a source of gadolinium. Its structure is isotypic with other MI2MIII(MVIO4)(PO4) compounds, where MI = Na, K or Cs, and MIII = rare-earth cation, MVI = Mo or W. The three-dimensional framework is built up from [Gd(PO4)(MoO4)] anionic sheets, which are organized by adhesion of [GdPO4] layers and [MoO4] tetra­hedra stacked above and below these layers. The inter­stitial space is occupied by K cations having eightfold oxygen coordination. The polyhedron of GdO8 was estimated to be a triangular dodeca­hedron by the continuous shape measurement method.

Single crystals of two basic cadmium phosphates, dicadmium orthophosphate hydroxide, Cd2(PO4)OH, and penta­cadmium bis­(orthophosphate) tetra­kis­(hydroxide), Cd5(PO4)2(OH)4, were obtained under hydro­thermal conditions. Cd2(PO4)OH adopts the triplite [(Mn,Fe)2(PO4)F] structure type. Its asymmetric unit comprises two Cd, one P and five O sites, all situated at the general Wyckoff position 8 f of space group I2/a; two of the O atoms are positionally disordered over two sites, and the H atom could not be localized. Disregarding the disorder, distorted [CdO6] polyhedra form a tri-periodic network by edge-sharing with neighbouring [CdO6] units and by vertex-sharing with [PO4] units. The site associated with the OH group is coordinated by four Cd atoms in a distorted tetra­hedral manner forming 1∞[(OH)Cd4/2] chains parallel to [001]. The oxygen environment around the OH site suggests multiple acceptor atoms for possible O—H⋯O hydrogen-bonding inter­actions and is the putative reason for the disorder. Cd5(PO4)2(OH)4 adopts the arsenoclasite [Mn5(AsO4)2(OH)4] structure type. Its asymmetric unit comprises five Cd, two P, and twelve O sites all located at the general Wyckoff position 4 a of space group P212121; the H atoms could not be localized. The crystal structure of Cd5(PO4)2(OH)4 can be subdivided into two main sub-units. One consists of three edge-sharing [CdO6] octa­hedra, and the other of two edge- and vertex-sharing [CdO6] octa­hedra. Each sub-unit forms corrugated ribbons extending parallel to [100]. The two types of ribbons are linked into the tri-periodic arrangement through vertex-sharing and through common [PO4] tetra­hedra. Qu­anti­tative structure comparisons are made with isotypic M5(XO4)2(OH)4 crystal structures (M = Cd, Mn, Co; X = P, As, V).

A lutetium(III) complex based on the anion of the ligand dimethyl (2,2,2-tri­chloro­acet­yl)phospho­ramidate (HL) and tetra­phenylphosphonium, of composition PPh4[LuL4] (L = CAPh = carbacyl­amido­phosphate), or (C24H20)[Lu(C4H6Cl3NO4P)4], has been synthesized and structurally characterized. The X-ray diffraction study of the compound revealed that the lutetium ion is surrounded by four bis-chelating CAPh ligands, forming the complex anion [LuL4]− with a coordination number of 8[O] for LuIII, while PPh4+ serves as a counter-ion. The coordination geometry around the Lu3+ ion was determined to be a nearly perfect triangular dodeca­hedron. The complex crystallizes in the monoclinic crystal system, space group P21/c, with four mol­ecules in the unit cell. Weak hydrogen bonds O⋯HC(Ph), Cl⋯HC(Ph) and N⋯HC(Ph) are formed between the cations and anions. For a comparative study, HL-based structures were retrieved from the Cambridge Structural Database (CSD) and their geometries and conformations are discussed. A Hirshfeld surface analysis was also performed.

In the title salt, C6H16N22+ ·H2P2O72−, the complete dication is generated by a crystallographic centre of symmetry with the methyl groups in equatorial orientations. The complete dianion is generated by a crystallographic twofold axis with the central O atom lying on the axis: the P—O—P bond angle is 135.50 (12)°. In the crystal, the di­hydrogen diphosphate anions are linked by O—H⋯O hydrogen bonds, generating (001) layers. The organic cations bond to the inorganic layers by way of N—H⋯O and C—H⋯O hydrogen bonds. A Hirshfeld surface analysis shows that the most important contributions for the crystal packing are from O⋯H/H⋯O (60.5%) and H⋯H (39.4%) contacts.

Amazon CEO Andy Jassy, in a recent internal meeting, outlined the company's strategy to reduce management layers, aiming to eliminate bureaucracy and foster a more agile and innovative culture. Citing the rapidly evolving tech landscape, Jassy emphasized the need for faster decision-making and increased individual ownership.

Save Big on LiFePO4 Batteries from Powerwin During spring sale (MAR.5TH-26TH)

Le Chateau Giclee On Canvas by Arian is a(n) Limited Edition. The Edition is Limited to Limited Edition of 175 pcs

This episode is an introduction to user interface design with Joachim Machate of UID. We talk about the importance of user interface design, about its relationship to the overall software engineering process, as well as about UID's process for systematic user interface design.

Manufacturing

Transport / Logistic issues / Storage capacity issues

The OSCE Mission to Skopje organized a workshop on 23 June 2016 for 35 police managers from the Sector of Internal Affairs on identification, prevention and investigation of hate crimes.

The aim of the workshop was to strengthen the capacity of police officers to identify hate crimes and provide responses in line with democratic policing principles and international human rights standards. 

This workshop complemented other previous and ongoing activities of the Mission in this area which are implemented in co-operation with national authorities.

The event was the first in a series of eight workshops which will be held in each sector for internal affairs in the country.

Related Stories

• OSCE Mission to Skopje organizes two-day workshop on multi-ethnic policing
• OSCE Mission to Skopje organizes workshop for national Police Union on countering gender-based discrimination
• OSCE Mission to Skopje supports face recognition on-site training for border police officers

A two-day workshop on  ways to improve the recording of hate crimes  was organized on 11 and 12 July in Prishtinë/Priština by the OSCE Office for Democratic Institutions and Human Rights (ODIHR), the OSCE Mission in Kosovo and the Kosovo Police.

In addition to reinforcing their understanding of the OSCE’s approach to hate crime, workshop participants identified a series of additional improvements in the way local authorities monitor and record hate crimes. Participants also agreed to establish a permanent national mechanism to co-ordinate hate crime data collection.

"Police recording is the key point of entry for information about hate crimes into the criminal justice system. But, the police cannot operate alone," said Ales Giao Hanek, ODIHR Hate Crime Officer. "Co-ordination between all the agencies concerned is crucial, and political support will be required to make the changes identified and agreed upon by participants."

Workshop participants included Kosovo Police specialists responsible for recording and managing crime statistics from all eight policing districts. Police and Prosecution Service focal points on hate crimes took part, as well as representatives from the Kosovo Judicial Institute.

This workshop follows up on an event held in May 2015, which mapped hate crime data collection in Kosovo.

Related Stories

• OSCE/ODIHR final report on the former Yugoslav Republic of Macedonia’s postponed early parliamentary elections recommends continuing electoral reform process
• OSCE/ODIHR final report on early parliamentary elections in Serbia recommends comprehensive review of legislation and ensuring the level playing field for contestants
• OSCE/ODIHR event in Kyiv supports dialogue platform in Verkhovna Rada on parliamentary ethics

Heba Kanso, Reporter for CBSNews.com, discusses how a symbol of hate used by ISIS to target Christians in Iraq has become a rallying cry for the global Christian community.

By Glen McCarty, Director of Velocity Consulting.

For those of us who still work in an office regularly, you cannot underestimate the absolute necessity of reliable IT infrastructure to make sure business operations aren’t interrupted.

By Stephen Dombroski, Director of Food and Beverage Markets, QAD.

For many business organizations, internal departments working independently of one another is the norm. This norm creates siloed day-to-day functions and rigid disconnects in processes. This is especially true when it comes to sales and operations planning (S&OP).

Facebook profits off hate and that's why it won't change, says whistleblower Frances Haugen

762: The Islamic Caliphate Moves to Baghdad

Chaldean Patriarchate to restore ancient manuscripts, rebuild Christian future

Meanwhile, Byron locals are not happy with the docusoap as they reportedly paddle out into the ocean to protest the show in addition to launching a petition against the new project.

https://www.youtube.com/watch?v=kFYXOgXqoe4 Elections aren't exactly cozy, even in the best of times. This one, though, felt worse for a lot of people. No matter where your allegiances lie, 2016 has been the emotional equivalent of a dumpster fire. But it wasn't all unbearable. Here and there, lighter moments emerged to provide comic relief — or even a small burst of joy. Here are 10 of them, in no particular order. 1. Bill Clinton at the DNC balloon drop When the balloons fell from the rafters on the final night of the Democratic National Convention, Hillary Clinton and her running mate Tim Kaine had a lot to feel triumphant about. The Democratic Party seemed to be uniting around Clinton as its candidate. But as the Philadelphia arena filled with red, white and blue globes, no one seemed to enjoy it quite as much as Bill Clinton, who looked up with childlike wonder. 2. Trump's "Hotline Bling" Back in November 2015, when Donald Trump was still in his campaign's relative infancy, he

Facebook faces a $2 billion lawsuit over hate speech; Expanse co-author Ty Franck on the role of nuclear fusion in sci-fi universes and the real world; making sense of the connection between respiratory virus outbreaks and invasive Strep A bacterial infections; a theatre director's bid to bring British holiday 'pantos' to Canada; Israeli documentary Tantura confronts an alleged massacre in a Palestinian village; and more.

Dear Eric: I am newly in love and engaged. My fiancé and I are both in our early 70s. Quite a few of my friends (not my close friends but others) have responded to the news with: how cute! Somehow the fact that we have fallen in love and plan to marry is "cute."

Pretty valid reasons, honestly.

They don't, because haters gon' hate.

When you hate your friend rsquo s new friend



View Comic!

HATERS GONNA HATE

"We Must Do Whatever It Takes!" - Netherlands Reinstates Temporary Border Controls To Curve Illegal Immigration Authored by Thomas Brooke via Remix News, The Netherlands has announced it will reintroduce internal border checks starting Dec. 9 in fresh efforts to manage illegal immigration. The…