diy Paper Window Hearts – DIY Valentine Crafts By joyfulabode.com Published On :: Sat, 13 Feb 2021 04:10:08 +0000 How to make folded paper window hearts. This is a step by step tutorial that will have your windows looking full of love in just a few minutes. The post Paper Window Hearts – DIY Valentine Crafts appeared first on Joyful Abode. Full Article Crafts Holidays
diy I Tried the Viral DIY Pool Noodle Decor Hack, and It Couldn't Be Easier By www.apartmenttherapy.com Published On :: Tue, 12 Nov 2024 08:15:00 -0500 I’m definitely going to do this again! READ MORE... Full Article Home Projects Decor & Accessories DIY Joy Issue 2024
diy This “Almost Free” Lowe’s Holiday DIY Is So Cute and Simple (It Hardly Takes Up Any Space!) By www.apartmenttherapy.com Published On :: Tue, 12 Nov 2024 10:15:00 -0500 And endlessly customizable. READ MORE... Full Article Life christmas DIY Lowes News Shopping
diy How a Basic IKEA Table Became a Viral Sensation (So Easy Anyone Can DIY It) By ikeahackers.net Published On :: Thu, 26 Sep 2024 10:00:00 +0000 IKEA hacks that go viral? It’s often the simplest ideas, brilliantly executed, mixed with a healthy dose of “It’s so easy, even you can do it” appeal. The latest sensation comes from Ayse Balci of @interiorundco, whose stylish DIY project has been turning heads on Instagram, amassing an impressive 115,000 likes and counting. Have you seen it yet? It’s a fantastic DIY project that transforms the popular and affordable 13 3/4″ LACK side table into a stylish chrome cube side […] The post How a Basic IKEA Table Became a Viral Sensation (So Easy Anyone Can DIY It) appeared first on IKEA Hackers. Full Article Coffee & Side Tables Lack Latest on IG
diy Elevate Your Curtains Instantly with This Simple Pelmet DIY By ikeahackers.net Published On :: Wed, 09 Oct 2024 10:00:00 +0000 Sometimes the best hacks are the ones hiding in plain sight, just waiting for a bright spark to shine light on it. Süreyya Tuncer of @sues_daily took a simple IKEA MOSSLANDA picture ledge and turned it into an affordable curtain pelmet. I’ve come across lots of picture ledge hacks over the years but this is the first time I’ve seen it used this way. It’s a straightforward repurposing of the ledge yet this simple twist made a stark difference. Süreyya […] The post Elevate Your Curtains Instantly with This Simple Pelmet DIY appeared first on IKEA Hackers. Full Article Curtains Latest on IG Mosslanda
diy This Round Wall Sconce Hack Is Our New Favorite DIY Project By ikeahackers.net Published On :: Thu, 24 Oct 2024 10:00:00 +0000 Norwegian designer Camilla Bakken repurposed the popular SNUDDA lazy susan into a chic, spinning wall sconce! This innovative repurposing might just be the most unexpected use of a turntable yet. The SNUDDA, known for its practicality in the kitchen, has found a new life in Camilla’s hands. By attaching strip LED lights to three SNUDDA units, she created a unique lighting solution that added ambiance and functionality to her space. The lights are controlled via a remote and can be […] The post This Round Wall Sconce Hack Is Our New Favorite DIY Project appeared first on IKEA Hackers. Full Article Wall Latest on IG Snudda
diy The Poopcopter is a DIY autonomous drone that finds and collects dog-doo By boingboing.net Published On :: Tue, 01 Oct 2024 22:27:31 +0000 A Minnessota maker named Caleb Olson built the Poopcopter, an autonomous drone that seeks out dog-doo and retrieves it for disposal. He describes it as the "world's first aerial bound self-guided dog poop removal system." See it in action below. "The Poopcopter is capable of scanning areas defined by a user, your backyard for example, and as it scans it's performing real-time computer vision using the camera which is inside the drone," Olson says. — Read the rest The post The Poopcopter is a DIY autonomous drone that finds and collects dog-doo appeared first on Boing Boing. Full Article Post animals dogs DRONES
diy Shirkadaha diyaaradaha ee Yurub ayaa kordhiyey hakinta duulimaadyadooda Israel By horseedmedia.net Published On :: Mon, 11 Nov 2024 20:21:30 +0000 Isniintii, 3 diyaaradood oo reer Yurub ah ayaa ku dhawaaqay inay kordhiyeen hakinta duullimaadyada ay ku… The post Shirkadaha diyaaradaha ee Yurub ayaa kordhiyey hakinta duulimaadyadooda Israel appeared first on Horseed Media. Full Article World News
diy Press Release: DIY weather stations will aid flood control efforts By www.iwmi.org Published On :: Wed, 04 May 2016 09:56:00 +0000 New mobile connected device can transform data collection say experts. The post Press Release: DIY weather stations will aid flood control efforts first appeared on International Water Management Institute (IWMI). Full Article Press releases floods mobile weather stations water innovation
diy Yediyurappa urges people to ensure NDA candidate's victory in bypolls By www.ibtimes.co.in Published On :: Tue, 12 Nov 2024 13:21:40 +0530 Former Chief Minister and BJP Central Parliamentary Board Member B.S. Yediyurappa urged the people to teach CM Siddaramaiah a befitting lesson by securing victory for the NDA candidate Nikhil Kumaraswamy in the high profile Channapatna Assembly constituency. Full Article
diy Vandana Sishodiya vs Indian Army on 11 November, 2024 By indiankanoon.org Published On :: : The Complainant filed an (offline) RTI application dated 20.05.2023 seeking the following information: "I am enclosing herewith a Photocopy letter dated 25/9/23 regarding Departmental Grocery Card No CAO 5112259933/201N0o., which was not activated by the Aligarh Depot due to which I Could not got my necessary groceries items. Recognizing this I need information & copies of documents as per following points:- 1. Please intimate the date of receipt of aforesaid letter 2. Please provide a certified photocopy of aforesaid letter 3. Please provide the information regarding action taken on my above letter by the appropriate authority since the date of issuing to this date. Full Article
diy Vandana Sishodiya vs Indian Army on 11 November, 2024 By indiankanoon.org Published On :: : The Complainant filed an (offline) RTI application dated 20.05.2023 seeking the following information: "I am enclosing herewith a Photocopy letter dated 25/9/23 regarding Departmental Grocery Card No CAO 5112259933/201N0o., which was not activated by the Aligarh Depot due to which I Could not got my necessary groceries items. Recognizing this I need information & copies of documents as per following points:- 1. Please intimate the date of receipt of aforesaid letter 2. Please provide a certified photocopy of aforesaid letter 3. Please provide the information regarding action taken on my above letter by the appropriate authority since the date of issuing to this date. Full Article
diy Vandana Sishodiya vs Ministry Of Defence on 11 November, 2024 By indiankanoon.org Published On :: : The Complainant filed an (offline) RTI application dated 20.05.2023 seeking the following information: "I am enclosing herewith a Photocopy letter dated 25/9/23 regarding Departmental Grocery Card No CAO 5112259933/201N0o., which was not activated by the Aligarh Depot due to which I Could not got my necessary groceries items. Recognizing this I need information & copies of documents as per following points:- 1. Please intimate the date of receipt of aforesaid letter 2. Please provide a certified photocopy of aforesaid letter 3. Please provide the information regarding action taken on my above letter by the appropriate authority since the date of issuing to this date. Full Article
diy Deepak S. Kavadiya vs Addl. Divisional Commissioner Konkan ... on 12 November, 2024 By indiankanoon.org Published On :: 1. Revision Application is allowed. 2. The order of Competent Authority Konkan Division in case No.178 of 2023 dated 06.08.2024 is set aside. 3. The Parties be informed accordingly. 24) Thus, the Revisional Authority has relied upon Section 55 of the MRC Act for accepting the contention of the licensee that in absence of registration of the licence agreement, her version of ___Page No.19 of 33___ 12 November 2024 Megha 908_wp_14856_2024_fc.docx licence being granted for commercial use would prevail. Section 55 of the Act provides for providing for compulsory registration of tenancy agreement and consequences of non-registration. Section 55 provides as under: Full Article
diy Gudiya Kumari vs The State Of Jharkhand ... ... Opposite ... on 12 November, 2024 By indiankanoon.org Published On :: For the Petitioner : Mr. Subhneet Jha, Advocate For the State : Mr. Ajay Kumar Pathak, A.P.P ----- 04/12.11.2024 The petitioner is apprehending her arrest for the offences punishable under Sections 376/313/323/341/498-A/420/ 494/34 of the Indian Penal Code, Sections 3/4 of the Dowry Prohibition Act and Section 6 of the POCSO Act. 2. Learned counsel for the petitioner submits that the petitioner has been falsely implicated in the present case and has not committed any offence as alleged in the complaint leading to lodging of the present F.I.R. It has been alleged that the petitioner along with co-accused Shivnandan Sahu @ Shivandan Sahu (father- in-law) and Pramila Devi (mother-in-law) was involved in getting pregnancy of the informant terminated and that the main accused Sikandar Sahu performed another marriage with her. In fact, co- accused Sikandar Sahu has not performed any marriage with the petitioner. She is merely a co-villager and she has been implicated in this case by the informant due to personal grudge. Moreover, co- accused Shivnandan Sahu @ Shivandan Sahu, Pramila Devi and Surendra Sahu @ Sulendra Sahu have already been granted anticipatory bail by this Court vide order dated 10.09.2024 passed in A.B.A No. 3816/2024. The petitioner also undertakes to co-operate in the ongoing investigation. Hence, she may be given the privilege of anticipatory bail. Full Article
diy Unlocking Bollywood-Worthy Hair Secrets! 5 DIY Masks For Healthy And Luscious Locks By www.boldsky.com Published On :: Thu, 07 Nov 2024 11:42:55 +0530 Your mane matters! Healthy, happy hair denotes your priorities towards self-care. Bollywood beauties including Ananya Panday, Janhvi Kapoor, Alia Bhatt, and others understand this must-do beauty ritual and ensure to keep their locks in the finest condition. Now, these celebs may Full Article
diy Die politische und soziale Bedeutung der Naqsbandiyya in Mittelasien im 15. Jahrhundert [Electronic book] / Jürgen Paul. By encore.st-andrews.ac.uk Published On :: Berlin ; Boston : Walter De Gruyter, [2010] Full Article
diy Unveiling the potential of aluminum-decorated 3D phosphorus graphdiyne as a catalyst for N2O reduction By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, 26,27677-27683DOI: 10.1039/D4CP02686A, PaperShehzad Ahmed, Adnan Ali Khan, Danish Khan, Awais Ghani, Rashid Ahmad, Tian Xiaoqing, Imran MuhammadThis study reveals the exceptional reactivity and efficiency of 3D-Al/PGDYN catalysts for the reduction of N2O and CO with minimal energy barriers.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
diy DFT rationalization of the mechanism and selectivity in a gold-catalyzed oxidative cyclization of diynones with alcohols By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, Advance ArticleDOI: 10.1039/D4CP01700E, PaperGuowei Yan, Ji Ma, Simeng Qi, Alexander M. Kirillov, Lizi Yang, Ran FangThe mechanism, regioselectivity, and chemoselectivity in a gold-catalyzed oxidative cyclization of diynones with alcohols to give furan-3-carboxylate derivatives were explored by density functional theory (DFT).To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
diy Annealing approach to form a nanotube from graphdiyne ribbon: A theoretical prediction By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, Accepted ManuscriptDOI: 10.1039/D4CP03573A, PaperBo Song, Kun Cai, Jiao Shi, Qinghua QinA precisely controllable heat treatment process is critical for nanofabrication. We developed a two-step method to fabricate a graphdiyne nanotube (GNT) through heat treatment in an argon environment. Initially, we...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
diy Handmade and hand-painted diyas for Deepavali By www.thehindu.com Published On :: Thu, 24 Oct 2024 22:05:04 +0530 Meet these women whose handcrafted and hand-painted diyas will light up homes this Deepavali Full Article Life & Style
diy From balanced meal bowls to DIY kits for parties, these Chennai brands are putting a spin on eating healthy By www.thehindu.com Published On :: Wed, 06 Nov 2024 17:12:37 +0530 Full Article Features
diy Taste dalma at Oddiyana, which serves authentic Odia cuisine with a contemporary twist By www.thehindu.com Published On :: Fri, 23 Jun 2023 18:10:42 +0530 Oddiyana by Mumbai-based cloud kitchen, Rroshashala, presents authentic Odia cuisine in a contemporary setting Full Article Life & Style
diy Rhodium-catalysed homo-coupling of terminal alkynes: divergent synthesis of bioactive 1,3-diynes and conjugated enediynes By pubs.rsc.org Published On :: New J. Chem., 2024, 48,7517-7523DOI: 10.1039/D4NJ00366G, PaperYijie Xiao, Lijie Lv, Nanxuan Luo, Peirui Zhao, Yao Chen, Zhangshun Luo, Houhua Yin, Yi He, Shenyou NieC(sp)–C(sp) cross-coupling of terminal alkynes represents a robust tool for building biologically active 1,3-diynes although confronted with huge challenges regarding selectivity control.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
diy Alia Gives Us Chal Kudiye By www.rediff.com Published On :: Wed, 18 Sep 2024 09:05:14 +0530 Rakul is a denim girl... Raashii in London... Fatima in Amsterdam... Full Article
diy Porphyrin-linked graphdiyne as a substrate for constructing single-atom catalysts with transition metals towards oxygen reduction reactions and oxygen evolution reactions By pubs.rsc.org Published On :: Mater. Chem. Front., 2024, 8,3741-3746DOI: 10.1039/D4QM00555D, Research ArticleJiejie Ping, Mei Wu, Manyu Liu, Yan Jiang, Wenhui Shang, Menggai Jiao, Jiahao Ruan, Nan Wang, Zhiyu JiaPorphyrin-linked graphdiyne anchored with transition metals exhibits outstanding electrochemical performance, attributed to the modifications in the coordination environment.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
diy Autocomplete Interview - LaurDIY Answers the Web's Most Searched Questions By www.wired.com Published On :: Fri, 09 Dec 2022 17:00:00 +0000 LaurDIY answers the web's most searched questions about herself! What's LaurDIY's real name? What was her first viral video? What kind of camera does she use? How many tattoos does she have? Is she actually leaving YouTube? LaurDIY answers all these questions and much, much more! Check out LaurDIY's channel here: https://www.youtube.com/@LaurDIY Director: Katherine Wzorek Director of Photography: Matt Krueger Editor: Alex Mechanik Talent: LaurDIY Talent Booker: Mica Medoff Line Producer: Joseph Buscemi Associate Producer: Melissa Cho Production Managers: Peter Brunette, Andressa Pelachi Audio: Mike Faner Cam Op/Gaffer: Nate Cornett Production Assistant: Ariel Labasan Post Production Supervisor: Alexa Deutsch Post Production Coordinator: Ian Bryant Supervising Editor: Doug Larsen Assistant Editor: Diego Rentsch Full Article
diy Ayodhya Deepotsav sets two Guinness World Records with 25 lakh diyas and mass aarti By www.thehindubusinessline.com Published On :: Thu, 31 Oct 2024 08:53:45 +0530 Held along the Saryu River’s 55 ghats, including Ram ki Paidi, over 25.12 lakh diyas were lit, with 1,121 participants performing ‘aarti’ in unison Full Article Variety
diy Pronounced Electronic Modulation of Geometrically-Regulated Metalloenediyne Cyclization By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05396F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sarah E. Lindahl, Erin M. Metzger, Chun-Hsing Chen, Maren Pink, Jeff ZaleskiUsing a diverse array of thermally robust phosphine enediyne ligands (dxpeb, X = Ph, Ph-pOCH3, Ph-pCF3, Ph-m2CH3, Ph-m2CF3, iPr, Cy, and tBu) a novel suite of cisplatin-like Pt(II) metalloenediynes (3,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
diy B.S. Yediyurappa says he will respond to allegations of corruption after bypolls By www.thehindu.com Published On :: Mon, 11 Nov 2024 07:00:00 +0530 Full Article Karnataka
diy Dharavi lights up Diwali with 1 million handcrafted diyas By www.newkerala.com Published On :: Fri, 25 Oct 2024 22:00:02 +0530 Full Article
diy Dharavi lights up Diwali with a million handcrafted diyas By www.newkerala.com Published On :: Fri, 25 Oct 2024 23:30:03 +0530 Full Article
diy Jiri Privratsky beats Smit Moradiya by 0.1 point for air rifle gold By www.thehindu.com Published On :: Mon, 11 Nov 2024 18:56:41 +0530 Well-known shooters Umamahesh Maddineni and Aishwary Pratap Singh Tomar were pushed out of the medals table, the little-known Smit shot brilliantly in the climax Full Article Sport
diy WATCH | It was easy for me to come out of the palace and be with people like anybody else: Yaduveer Krishnadatta Chamaraja Wadiyar By www.thehindu.com Published On :: Sat, 20 Apr 2024 19:35:47 +0530 People look up to us for the principles of leadership going forward. The bond we share with people is because of good work and not due to the royal background, says Yaduveer Krishnadatta Chamaraja Wadiyar, the BJP candidate, Mysuru Lok Sabha constituency Full Article Lok Sabha Elections
diy Graphdiyne (CnH2n−2) based copper(I) bromide dual S-scheme heterojunction with AX2O8 type compounds induced electron directional migration By pubs.rsc.org Published On :: Catal. Sci. Technol., 2024, Advance ArticleDOI: 10.1039/D4CY01031K, PaperXinwan Zhao, Minjun Lei, Guangbo Liu, Zhiliang Jin, Noritatsu TsubakiA fundamental strategy for enhancing the performance of photocatalytic water-splitting catalysts is to facilitate the efficient migration of photogenerated charge carriers to establish a heterojunction.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
diy By Hand from the Heart brings custom apparel, teak furniture, and DIY art kits By www.thehindu.com Published On :: Thu, 25 Jul 2024 09:15:04 +0530 The upcoming edition of By Hand from the Heart promises custom apparel, DIY stationery, and more Full Article Fashion
diy Dandiya and garbha workshops mark Navrati celebrations in Visakhapatnam By www.thehindu.com Published On :: Mon, 03 Oct 2022 12:40:58 +0530 The festivities include colourful decor, fusion wear and elaborate satvik food spreads Full Article Society
diy DIY (Development Impact and You) By www.iriss.org.uk Published On :: Mon, 05 Jan 2015 15:02:31 +0000 Full Article Webwatch ideas improvement innovation and improvement toolkit Institute for Research and Innovation in Social Services (IRISS) innovation
diy Pergolas, patios, paint? We've all gone DIY daft By www.heraldscotland.com Published On :: Sun, 10 May 2020 05:03:52 +0100 THERE is a new altar to worship at: all hail the mighty god of DIY. If you're not sitting down to a Zoom call on Monday morning with plaster-streaked hair, singed eyebrows and muscles aching from hard graft, what on earth have you been doing with your weekend? Full Article
diy How Much is DIY Worth to You? By feedproxy.google.com Published On :: Sat, 09 May 2020 14:00:00 +0000 It all started with an article about Wink Labs putting a monthly fee on their previously free service. It wasn’t so much the amount they were asking ($5 / month) that raised my hackles, but rather the fact that they would essentially render a device that you ostensibly bought worthless …read more Full Article Hackaday Columns diy culture IoT newsletter time value of money wages
diy Ramkaran Fagediya S/O Shri ... vs State Of Rajasthan on 8 May, 2020 By indiankanoon.org Published On :: Fri, 08 May 2020 00:00:00 +0530 For State : Mr. S.K. Mahala, PP. HON'BLE MR. JUSTICE PANKAJ BHANDARI Order 08/05/2020 1. Heard counsel for the petitioners through video conferencing. Learned Public Prosecutor is present in person in the Court. 2. Counsel for the complainant has not given his detail, hence, could not be connected. 3. Petitioner has filed this bail application under Section 439 of Cr.P.C. 4. F.I.R. No.343/2019 was registered at Police Station Kotwali, Jhunjhunu for offence under Sections 323, 365, 201, 302/34 of I.P.C. (FIR has been lodged for offence under Section 302 of IPC.) 5. It is contended by counsel for the petitioner that eye witnesses have turned hostile. As per the FSL report, cause of death is inconclusive. There was only a bruise on the person of the prosecutrix. Full Article
diy Manish @ Ratanbhai Simadiyabhai ... vs State Of Gujarat on 8 May, 2020 By indiankanoon.org Published On :: Fri, 08 May 2020 00:00:00 +0530 2. Learned advocate Mr. Karia for the applicant submits that the applicant is arrested on the basis of statement of co-accused. Learned Advocate further submits that considering the nature of the offence, the applicant may be enlarged on regular bail by imposing suitable conditions. 3. Learned Additional Public Prosecutor appearing on behalf of the respondent-State has opposed grant of regular bail looking to the nature and gravity of the offence. He further submits that the applicant has two past criminal antecedents. 4. Learned Advocates appearing on behalf of the respective parties do Page 1 of 3 Downloaded on : Fri May 08 22:29:40 IST 2020 R/CR.MA/6081/2020 ORDER not press for further reasoned order. Full Article
diy Gudiya's choice By indiatogether.org Published On :: Fri, 01 Oct 2004 00:00:00 +0000 The recent controversy over a soldier returning after four years to 'claim' his wife is telling. It illustrates that where women are concerned, everyone has an agenda: the panchayat, the media and the media-consuming middle class says Kalpana Sharma. Full Article
diy Mother’s Day 2020: 5 Easy DIY Gift Ideas to Make Your Mom Smile By www.news18.com Published On :: Sun, 10 May 2020 07:24:15 +0530 Here are 5 easy Do-It-Yourself gift ideas to make your mom's day special on Mother's Day 2020 (May 10th) in the middle of a global pandemic. Full Article
diy Hugs and dandiya: Modi welcomes Trump to India By www.rediff.com Published On :: Mon, 24 Feb 2020 15:17:51 +0530 Prime Minister Narendra Modi, who reached Ahmedabad over an hour before Trump did, was present at the airport to welcome the US president at the airport. Full Article Narendra Modi Trump Sardar Vallabhbhai Patel Ahmedabad United States NAMASTE Air Force Melania India
diy 3,3'-[(1E,1'E)-Hydrazine-1,2-diylidenebis(ethan-1-yl-1-ylidene)]bis(4-hydroxy-6-methyl-2H-pyran-2-one) By scripts.iucr.org Published On :: 2019-10-03 The title compound, C16H16N2O6, lies about an inversion centre at the mid-point of the N—N bond. The molecule features two intramolecular O—H⋯N and two C—H⋯O hydrogen bonds, each of which forms an S(6) ring motif. In the crystal, molecules are linked by C—H⋯O hydrogen bonds into infinite zigzag chains propagating along the c-axis direction. π–π stacking interactions between the pyrone rings [centroid–centroid distances = 3.975 (2) Å] stack the molecules along b. Full Article text
diy Crystal structure of butane-1,4-diyl bis(furan-2-carboxylate) By scripts.iucr.org Published On :: 2019-05-24 The asymmetric unit of the title compound, C14H14O6, a monomeric compound of poly(butylene 2,5-furandicarboxylate), consists of one half-molecule, the whole all-trans molecule being generated by an inversion centre. In the crystal, the molecules are interconnected via C—H⋯O interactions, forming a molecular sheet parallel to (10overline{2}). The molecular sheets are further linked by C—H⋯π interactions. Full Article text
diy Crystal structure of (15,20-bis(2,3,4,5,6-pentafluorophenyl)-5,10-{(pyridine-3,5-diyl)bis[(sulfanediylmethylene)[1,1'-biphenyl]-4',2-diyl]}porphyrinato)nickel(II) dichloro By scripts.iucr.org Published On :: 2019-07-12 The crystal structure of the title compound, [Ni(C63H31F10N5S2)]·xCH2Cl2 (x > 1/2), consists of Ni–porphyrin complexes that are located in general positions and dichloromethane solvent molecules that are disordered around centers of inversion. The NiII ions are in a square-pyramidal (CN5) coordination, with four porphyrin N atoms in the equatorial and a pyridine N atom in the apical position and are shifted out of the porphyrine N4 plane towards the coordinating pyridine N atom. The pyridine substituent is not exactly perpendicular to the N4 plane with an angle of intersection between the planes planes of 80.48 (6)°. The dichloromethane solvent molecules are hydrogen bonded to one of the four porphyrine N atoms. Two complexes are linked into dimers by two symmetry-equivalent C—H⋯S hydrogen bonds. These dimers are closely packed, leading to cavities in which additional dichloromethane solvent molecules are embedded. These solvent molecules are disordered and because no reasonable split model was found, the data were corrected for disordered solvent using the PLATON SQUEEZE routine [Spek (2015). Acta Cryst. C71, 9–18]. Full Article text
diy Crystal structure of (15,20-bis(2,3,4,5,6-pentafluorophenyl)-5,10-{(4-methylpyridine-3,5-diyl)bis[(sulfanediylmethylene)[1,1'-biphenyl]-4',2-diyl]}porphyrinato)nickel(II) dichloro By scripts.iucr.org Published On :: 2019-09-27 The title compound, [Ni(C64H33F10N5S2)]·xCH2Cl2, consists of discrete NiII porphyrin complexes, in which the five-coordinate NiII cations are in a distorted square-pyramidal coordination geometry. The four porphyrin nitrogen atoms are located in the basal plane of the pyramid, whereas the pyridine N atom is in the apical position. The porphyrin plane is strongly distorted and the NiII cation is located above this plane by 0.241 (3) Å and shifted in the direction of the coordinating pyridine nitrogen atom. The pyridine ring is not perpendicular to the N4 plane of the porphyrin moiety, as observed for related compounds. In the crystal, the complexes are linked via weak C—H⋯F hydrogen bonds into zigzag chains propagating in the [001] direction. Within this arrangement cavities are formed, in which highly disordered dichloromethane solvate molecules are located. No reasonable structural model could be found to describe this disorder and therefore the contribution of the solvent to the electron density was removed using the SQUEEZE option in PLATON [Spek (2015). Acta Cryst. C71, 9–18]. Full Article text
diy Crystal structure and Hirshfeld surface analysis of 2,2'-{(1E,1'E)-[ethane-1,2-diylbis(azanylylidene)]bis(methanylylidene)}bis[4-(trifluoromethoxy)phenol]copper(II) hydroquinone hemisolvate By scripts.iucr.org Published On :: 2019-10-29 In the title complex, [Cu(C18H12F6N2O4)]·0.5C6H6O2, the CuII ion has a square-planar coordination geometry, being ligated by two N and two O atoms of the tetradentate open-chain Schiff base ligand 6,6'-{(1E,1'E)-[ethane-1,2-diylbis(azanylylidene)]bis(methanylylidene)}bis[2-(trifluoromethoxy)phenol]. The crystal packing is stabilized by intramolecular O—H⋯O and intermolecular C—H⋯F, C—H⋯O and C—H⋯π hydrogen bonds. In addition, weak π–π interactions form a three-dimensional structure. Hirshfeld surface analysis and two-dimensional fingerprint plots were performed and created to analyze the intermolecular interactions present in the crystal, indicating that the most important contributions for the crystal packing are from F⋯H/H⋯F (25.7%), H⋯H (23.5%) and C⋯H/H⋯C (12.6%) interactions. Full Article text