Actor Timothée Chalamet made a surprise appearance at his own look-alike contest in Lower Manhattan on Sunday, a well-attended event that drew an order to disperse from police and at least one arrest

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The incomplete ‘incidental music’ for Alceste, conducted with liveliness and sensitivity.

The tree will be lit during a live TV broadcast on Dec. 4, featuring 50,000 multi-colored lights with a Swarovski star on top and remain on display until mid-January.

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The defunct charity's former digital director wants to set up its digital volunteer recruitment network as a social enterprise

Washington — OSHA has announced the winners of its national competition challenging stakeholders to submit the best tools and resources on the dangers of heat exposure – indoors and outdoors – at work.

Washington — NIOSH has announced winners of the third and final phase of its Respirator Fit Evaluation Challenge.

Orlando, FL — HeroWear and its exoskeleton suit were voted the winner of the National Safety Council’s third annual Safety Innovation Challenge.

The company successfully completed a build-out with employee-centered construction for Crown Bakeries.

According to a 2014 study by the Harvard University Joint Center for Housing, the home improvement industry is expected to see double-digit growth through the end of the year.

Crowne Plaza: London Docklands - As low as 98 GBP or 22,000 IHG points on Nov 17, 21, 22 / Dec 15, 16, 23 Average nightly rate is 210.40 GBP or 51833 IHG points ...

Children's Geographies; 04/01/2023
(AN 163915530); ISSN: 14733285
Academic Search Premier

A performing arts group has found the child who was literally wowed by a recent classical music concert.

CrowdStrike has agreed to acquire SaaS security solutions provider, Adaptive Shield. With this acquisition, CrowdStrike reports that it will be the only cybersecurity vendor to provide unified, end-to-end protection against identity-based attacks across the entire modern cloud ecosystem – from on-premises

In the Chinese city of Zhuhai, a car rammed into a crowd of people near a sports center. The 62-year-old driver fled the scene of the accident but was later detained. The victims were hospitalized, China Daily said with reference to local authorities. WARNING: The videos are extremely graphic! Click here to see more photos and videos from the scene.

The compression behavior of [Rb(18-crown-6)][SbCl6] crystal under pressure up to 2.16 (3) GPa was investigated in a diamond anvil cell (DAC) using a mixture of pentane–iso­pentane (1:4) as the pressure-transmitting fluid. The compound crystallizes in trigonal space group R3 and no phase transition was observed in the indicated pressure range. The low value of pressure bulk modulus [9.1 (5) GPa] found in this crystal is a characteristic of soft materials with predominant dispersive and electrostatic interaction forces. The nonlinear relationship between unit-cell parameters under high pressure is attributed to the influence of reduced intermolecular H⋯Cl contacts under pressure over 0.73 GPa. It also explains the high compression efficiency of [Rb(18-crown-6)][SbCl6] crystals at relatively low pressures, resulting in a significant shift of the Rb atom to the center of the crown ether cavity. At pressures above 0.9 GPa, steric repulsion forces begin to play a remarkable role, since an increasing number of interatomic H⋯Cl and H⋯H contacts become shorter than the sum of their van der Waals (vdW) radii. Below 0.9 GPa, both unit-cell parameter dependences (P–a and P–c) exhibit hysteresis upon pressure release, demonstrating their influence on the disordered model of Rb atoms. The void reduction under pressure also demonstrates two linear sections with the inflection point at 0.9 GPa. Compression of the crystal is accompanied by a significant decrease in the volume of the voids, leading to the rapid approach of Rb atoms to the center of the crown ether cavity. For the Rb atom to penetrate into the center of the crown ether cavity in [Rb(18-crown-6)][SbCl6], it is necessary to apply a pressure of about 2.5 GPa to disrupt the balance of atomic forces in the crystal. This sample serves as a compression model demonstrating the influence of both attractive and repulsive forces on the change in unit-cell parameters under pressure.

The title complex, (1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane-1κ6O)(μ-oxalato-1κ2O1,O2:2κ2O1',O2')triphenyl-2κ3C-potassium(I)tin(IV), [KSn(C6H5)3(C2O4)(C12H24O6)] or K[18-Crown-6][(C6H5)3SnO4C2], was synthesized. The complex consists of a potassium cation coordinated to the six oxygen atoms of a crown ether mol­ecule and the two oxygen atoms of the oxalatotri­phenyl­stannate anion. It crystallizes in the monoclinic crystal system within the space group P21. The tin atom is coordinated by one chelating oxalate ligand and three phenyl groups, forming a cis-trigonal–bipyramidal geometry around the tin atom. The cations and anions form ion pairs, linked through carbonyl coordination to the potassium atoms. The crystal structure features C—H⋯O hydrogen bonds between the oxygen atoms of the oxalate group and the hydrogen atoms of the phenyl groups, resulting in an infinite chain structure extending along a-axis direction. The primary inter-chain inter­actions are van der Waals forces.

The crystal structure of the title compound, hexa­aqua­nickel(II) dichloride–1,4,7,10,13,16-hexa­oxa­cyclo­octa­deca­ne–water (1/2/2), [Ni(H2O)6]Cl2·2C12H24O6·2H2O, is reported. The asymmetric unit contains half of the Ni(OH2)6 moiety with a formula of C12H32ClNi0.50O10 at 105 K and triclinic (P1) symmetry. The [Ni(OH2)6]2+ cation has close to ideal octa­hedral geometry with O—Ni—O bond angles that are within 3° of idealized values. The supra­molecular structure includes hydrogen bonding between the water ligands, 18-crown-6 mol­ecules, Cl− anions, and co-crystallized water solvent. Two crown ether mol­ecules flank the [Ni(OH2)6]2+ mol­ecule at the axial positions in a sandwich-like structure. The relatively symmetric hydrogen-bonding network is enabled by small Cl− counter-ions and likely influences the more idealized octa­hedral geometry of [Ni(OH2)6]2+.

Organizations, including those that weren’t struck by the CrowdStrike incident, should resist the temptation to attribute the IT meltdown to exceptional circumstances

CrowdStrike beat estimates when it reported late on Wednesday that its revenue jumped 37% to $731.6 million while adjusted net income more than doubled to $180 million in the second quarter on strong growth in subscriptions to its cloud-based data and identity protection services.

After acquiring Crown Bakeries and its Smyrna, GA facility, private equity firm Arbor Investments sought the expertise of Stellar’s Food & Beverage team to design and build an upgraded, state-of-the-art 200,000-square-foot processing facility.

The sweet-and-savory snack joins the producer’s Classic Butter and Extra Butter popcorn varieties already on shelves.

Customer segments serviced by Toronto-based Crownhill include public sector agencies, industrial products, consumer goods and e-commerce.

Seagram's 7 Crown, a brand of Diageo North America, New York, is toasting timeless American staples with an icon in America – the 7&7— with the launch of its new ad campaign, Timeless Taste.

Crown Equipment Corp. announced the availability of the Crown SP 1500 Series order picker.

The winners of the 'Gamescom Awards' held at Gamescom, the world's top three game show, held in Cologne, Germany on the 27th were released on IGN's YouTube channel.

Shincheonji Church of Jesus in Cheongju hosted a significant gathering, attracting approximately 80,000 attendees, including members from various regions and 100 Protestant pastors

Bernie Crowl, LMHC, is a licensed mental health counselor and the founder of City Mental Health Counseling

Crow writes meticulously researched, entertaining novels of romance, history, adventure and mystery in an engaging you-are-there style that allows readers to live the history. Reviewers have compared her work with PD James, Dan Brown and Barbara Pym.

Alisha L. Crowley, CPA, is a certified public accountant with CliftonLarsonAllen

IM.FIT endures up to 400lbs and personally curates hundreds of classes!

For more information about the winter wonderlands in Michigan's Upper Peninsula, please visit https://www.uptravel.com/outdoors-recreation/winter-activities-sports/

Classic typewriter with a modern twist! Enjoy the sophisticated design with increased productivity via a 4-device multi-pairing function

Author who is set to air on BRAVO's Millionaire Matchmaker February 5th spoofed a brand new Superbowl Ad, before it airs, to promote her new book crowd funding.

From Facial Exercise to Facialbuilding®

Outstanding Craftsmanship, Service, and Dedication Shine Through

A Family Dentist that Provides Expert Pediatric and Family Dental Care for a Healthier Smile - from teeth cleanings to oral surgery

Role Effective Immediately

"I am grateful for years of support from students, staff, and supporters."

Crow writes meticulously researched, entertaining novels of romance, history, adventure and mystery in an engaging you-are-there style that allows readers to live the history. Reviewers have compared her work with PD James, Dan Brown and Barbara Pym.

Crow writes meticulously researched, entertaining novels of romance, history, adventure and mystery in an engaging you-are-there style that allows readers to live the history. Reviewers have compared her work with PD James, Dan Brown and Barbara Pym.

Crow writes meticulously researched, entertaining novels of romance, history, adventure and mystery in an engaging you-are-there style that allows readers to live the history. Reviewers have compared her work with PD James, Dan Brown and Barbara Pym.

After reconnecting with a childhood friend, who has since become homeless, an anxiety-ridden woman learns how to face her darkest fears.

The 1/350 scale premium diecast U.S.S. Enterprise will showcase unique details and features. The crowd-funding window open for 45 days only.

The CrowPi2 is the most funded Raspberry Pi powered laptop with 2087 backers, and now you can get one at $269 on Elecrow's official website.

The Time Machine car is deemed one of the top three most iconic movie cars. The crowd-funding window will be open for 30 days only.

The Best In The West Showdown is an explosive combination of lightning fast horses and daredevil-skiing taken right to the edge. All held together by rope, guts and grit, and showcased in the town center of beautiful Big Sky, Montana.

Stylist Montina McMorris specializes in the maintenance of healthy hair.