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Cr-mediated Photocatalytic Decarboxylative Coupling of alpha-Oxo Acids with Benzylic Pyridinium Salts

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO00475B, Research Article
Jia Cao, Yan Liu, Zhixiang Wang, Le Liu
Herein, we report the chromium/photoredox dual catalytic synthesis of ketones using α-oxo acids with benzylic pyridinium salts. This reaction proceeded by photocatalytic generation of acyl radical from α-oxo acids and...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Cobalt-catalysed Csp3–Csp3 cross-coupling of benzyl Katritzky pyridinium salts with Callyl–O electrophiles

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00402G, Research Article
Mengyu Gao, Corinne Gosmini
Different allylbenzyl derivatives are synthesized by Co-catalyzed reductive cross-coupling from functionalized benzyl Katritzky pyridinium salts and various allylic acetates, ethers or carbonates in moderate to good yields under mild conditions.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Efficient Synthesis of Benzophosphole Oxides by Ag-Promoted Radical Cycloisomerization

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO00552J, Research Article
Open Access
Liyao Ma, Sonia Mallet-Ladeira, Julien MONOT, Blanca Maria MARTIN VACA, Didier Bourissou
Cycloisomerization reactions involving C–P bond formation have been overlooked to prepare P-heterocycles. We discovered here a simple, efficient and versatile route to benzophosphole oxides by reacting ortho-alkynyl secondary phosphine oxides...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Substituent-controlled divergent cyclization reactions of benzo[c][1,2]dithiol-3-ones and hexahydro-1,3,5-triazines

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00356J, Research Article
Bohao Zhang, Sifan He, Na Dong, Antong Zhu, Haojie Duan, Dunjia Wang, Yao Zhou
An unprecedented metal-free divergent cyclization reaction of benzo[c][1,2]dithiol-3-ones with hexahydro-1,3,5-triazines to assemble six- and eight-membered N-containing heterocycles has been developed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Expedient deaminative phosphorylation and sulfonylation of benzylic tertiary amines enabled by difluorocarbene

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00412D, Research Article
Chengbo Li, Yu Guo, Jianke Su, Xinyuan Hu, Qingqing Xuan, Qiuling Song
A deaminative functionalization of aliphatic tertiary amines via the cleavage of C(sp3)–N bonds under transition metal-free conditions was disclosed, which goes through SN2 reaction with various phosphorus and sulfur nucleophiles.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Porous carbon nitride rods as an efficient photoanode for water splitting and benzylamine oxidation

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00237G, Paper
Sanjit Mondal, Gabriel Mark, Ayelet Tashakory, Michael Volokh, Menny Shalom
A polymeric carbon nitride layer with controlled directionality, morphology, and nitrogen defects serves as a photoanode to allow photoelectrochemical (PEC) water-splitting and benzylamine oxidation.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Correction: Super-adsorbent hydrogel for removal of methylene blue dye from aqueous solution

J. Mater. Chem. A, 2024, 12,9242-9246
DOI: 10.1039/D4TA90061H, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiao-Sai Hu, Rui Liang, Guoxing Sun
The content of this RSS Feed (c) The Royal Society of Chemistry




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Beneficiaries receive ₹22.15 lakh in loans from TAMCO for minority welfare




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Mamata calls for unity of hills and plains; focuses on development in north Bengal

This is her first official visit to Darjeeling in two years; she did not go to the hills even during the 2024 Lok Sabha election campaigns




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Pyridinyl 4-(2-oxoalkylimidazolidin-1-yl)benzenesulfonates and their hydrochloride salts as novel water soluble antimitotic prodrugs bioactivated by cytochrome P450 1A1 in breast cancer cells

RSC Med. Chem., 2024, 15,3728-3745
DOI: 10.1039/D4MD00476K, Research Article
Vincent Ouellette, Chahrazed Bouzriba, Atziri Corin Chavez Alvarez, Quentin Bruxelles, Geneviève Hamel-Côté, Sébastien Fortin
New water soluble antimitotic CYP1A1-activated prodrugs named PYRAIB-SOs and their hydrochlorides targeting breast cancers.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Design and synthesis of novel 8-(azaindolyl)-benzoazepinones as potent and selective ROCK inhibitors

RSC Med. Chem., 2024, 15,3862-3879
DOI: 10.1039/D4MD00313F, Research Article
Daniele Pala, David Clark, Christine Edwards, Elisa Pasqua, Laura Tigli, Barbara Pioselli, Piotr Malysa, Fabrizio Facchinetti, Fabio Rancati, Alessandro Accetta
This study reports a novel, potent and selective series of ROCK inhibitors based on 8-(azaindolyl)-benzoazepinones identified through a core-hopping strategy.
The content of this RSS Feed (c) The Royal Society of Chemistry




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SKDRDP provides desks and benches worth ₹2.75 crore to 507 government primary schools in four districts of Karnataka

Rajya Sabha MP Veerendra Heggade urges parents to get their wards admitted to government schools as they now have better facilities




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Marakumbi atrocity case: 99 persons granted bail by High Court Dharwad Bench




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Comeback man Shami hogs the spotlight as MP takes honours on opening day against Bengal




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Pro Kabaddi League: Gujarat Giants return to winning ways with big win over Bengal Warriorz

In the second match of the night, Haryana Steelers moved to the top of the table and extended their winning run to four games after defeating the Patna Pirates 37-32




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Irregularities emerge in fund disbursements for Bengal government’s ‘tablet scheme’

So far, at least 10 people from Malda and Uttar Dinajpur districts have been arrested on charges of wrongfully siphoning funds allocated for tablets for the State’s higher secondary students




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Minister discusses solutions to traffic bottleneck on Bengaluru’s airport road

One of the proposals involves widening the stretch near the military land




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Playgrounds in Bengaluru: A mixed bag for parents and children




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Trinamool Congress leader killed in West Bengal’s Bhatpara region

The violence occurred at Bhatpara, the area adjoining Naihati Assembly where bypolls are being held on November 13, 2024




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Unrest and allegations of intimidation mar bypolls in six Assembly segments of West Bengal

Elections are being held at Madarihat, Sitai, Taldangra, Medinipur, Naihati, and Haroa. The polling till 5 p.m. was 69.29% on an average across the six constituencies.




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Surficial geology, Camsell Bend, Northwest Territories, NTS 95-J southeast

Duk-Rodkin, A; Huntley, D H. Geological Survey of Canada, Canadian Geoscience Map 296, 2022, 1 sheet, https://doi.org/10.4095/321855
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/gid_321855.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/gid_321855.jpg" title="Geological Survey of Canada, Canadian Geoscience Map 296, 2022, 1 sheet, https://doi.org/10.4095/321855" height="150" border="1" /></a>




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Al bijna 40 jaar lang hebben we een vertekend beeld van de planeet Uranus, en dat door stom toeval - Het Belang van Limburg

  1. Al bijna 40 jaar lang hebben we een vertekend beeld van de planeet Uranus, en dat door stom toeval  Het Belang van Limburg
  2. Waarom wetenschappers al 40 jaar lang fout beeld hebben van planeet door stom toeval  Het Nieuwsblad
  3. Voyager 2 onthult geheimen van het magnetische mysterie van Uranus  Business AM
  4. Mysterie Uranus ontrafeld: al 40 jaar lang hebben we een verkeerd beeld van de planeet  De Morgen





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Benvenuto a Incarnate

OM Arts introduces locals from Isola, Italy to Incarnate - a programme teaching artists to work in cross-cultural missions.





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SC releases cause list for cases to be heard by constitutional bench

The Supreme Court on Wednesday released the cause list of cases which will be heard by the recently established constitutional bench on November 14 and 15.

Earlier, the SC constituted a three-judge committee to fix cases, issue court rosters, form benches, and decide weekly caseload for its recently established constitutional bench.

SC on Tuesday announced that the constitutional bench will start hearing cases on November 14 and 15.

According to the cause list, available on the SC’s website, a six-member bench headed by Justice Aminud Din Khan will hear a total of 34 cases, including 18 cases on Nov 14 and 16 cases on November 15.

On Nov 5, the Judicial Commission of Pakistan (JCP), in its maiden session, had picked Justice Amin as head of the constitutional bench by a seven-to-five majority.

Chaired by Chief Jus­tice of Pakistan (CJP) Jus­tice Yahya Afridi, the reconstituted JCP for­m­ed a seven-member con­stitutional bench, inc­­luding Justices Ami­nud Din Khan, Jamal Khan Mandokhail, Muha­m­mad Ali Mazhar, Ayesha A Malik, Hassan Azhar Rizvi, Musarrat Hilali and Naeem Akhtar Afghan.

Cases related to environmental pollution from 1993, 2003, and 2018 have been scheduled for hearing.

The scheduled cases also include a revision petition against the dismissal of the petition regarding the appointment of Qazi Faez Isa as the chief jus­tice of the Balochistan High Court.

A request for rescheduling the 2024 general elections has also been fixed for hearing where the petition sought to shift the elections from Feb to the first week of March.

According to the cause list, cases related to harassment of women in offices have been fixed. The Ali Zafar and Meesha Shafi harassment case has also been fixed for hearing.

A suo motu notice case on private use of the Islamabad Convention Centre will also be heard by the bench. The convention centre suo motu was taken on the note of former judge Qazi Faiz Isa.

An application filed for the disqualification of the members of the assembly having business and assets abroad has also been scheduled.

Other scheduled cases include a petition for banning the marriage of government officials with foreign nationals, a petition to declare the legislation passed by the Pakistan Democratic Movement (PDM) government as null and void and a suo motu notice case on overseas bank accounts of Pakistanis.

A petition filed by Mohammad Ali Durrani to bring back laundered money from other countries will also be heard.

Moreover, cases related to the jurisdiction of Gilgit-Baltistan courts in Pakistan and various applications of Khawaja Asif regarding energy projects have also been scheduled.




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Singapore actor Chin Han joins cast of Netflix series Avatar: The Last Airbender

Netflix has expanded the cast of live-action series Avatar: The Last Airbender in its second season, with Singapore actor Chin Han one of the latest eight additions. He will play the role of Long Feng — leader of Dai Li, the secret police force of Ba Sing Se, or the capital of the Earth Kingdom. Another new joiner is Taiwanese-American actor Justin Chien, who starred with Malaysian actress Michelle Yeoh in the Netflix series The Brothers Sun (2024) and will play King Kuei, ruler of the Earth Kingdom in Avatar: The Last Airbender. Meanwhile, Vietnamese-Australian actor Hoa Xuande, who starred with American actor Robert Downey Jr in the HBO miniseries The Sympathizer (2024), will play Professor Zei, head of the anthropology department at Ba Sing Se University.  Other actors in the cast are Amanda Zhou as Joo Dee, Crystal Yu as Lady Beifong, Kelemete Misipeka as The Boulder, Lourdes Faberes as General Sung and Rekha Sharma as Amita.




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eBbay India Lays Off 100 Workers At Bengaluru Centre

E-commerce major eBay has laid off about 100 employees at its technology centre in Bengaluru and is shifting work to other global centres.




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Mercedes Benz To Hire 1,000 Engineers For R&D In India

Luxury automotive major Mercedes Benz today said it will hire 1,000 engineers in the country next year for its research and development (R&D) initiatives in India.




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Ben Foster, Laura Prepon to end their marriage after six years, file for divorce citing 'irreconcilable differences'

Hollywood power couple Ben Foster and Laura Prepon have decided to part ways after six years of their marriage and the actor requested that their prenuptial agreement be upheld and that assets and debts be divided equally.




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Experience the mindful art of pottery at Bengaluru’s Ügam festival

At Ügam festival in Indiranagar, Bengaluru, potters celebrate mindfulness, craft, and community




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Indian IT firms key beneficiaries of H-1B visa sponsorship, data shows

In the current fiscal so far, 9,265 Amazon employees have availed of the H-1B visa facility, followed by Infosys (8,140 employees), Cognizant (6,321), Google (5,364) and TCS (5,274)




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‘Not right to take from 1 state to benefit another’: Congress leader T S Singh Deo slams Mahayuti for diverting projects to Gujarat




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TMC worker killed as violence mars bypolls in Bengal

Sporadic incidents of unrest marred the West Bengal bypolls, with a local Trinamool Congress worker Ashok Shaw dying following a crude bomb attack in Bhatpara, an area adjoining Naihati assembly constituency where voting was underway.




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Benefits of Renting a Car

Embarking on a road trip is akin to setting out on a journey of discovery, where every turn of the road brings forth new vistas and experiences. While the destination holds allure, it’s the journey itself that often leaves an indelible mark on our memories. However, to make the most of this journey, one must […]

The post Benefits of Renting a Car appeared first on Roads To Iraq - The Cradle of Mankind.




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Contending for Truth: Exposed: Tim LaHaye, Chuck Missler, Jerry Falwell, Sun Myung Moon, Rick Santorum, Newt Gingrich, Benny Hinn, Kathryn Kuhlman, Paul Crouch, Chuck Smith, Hal Lindsey, Rick Joyner, The Pope, TBN, Calvary Chapel, CNP, Knights of Malta &a

Welcome to the new Contending for Truth website! We are excited to have an opportunity to streamline the site, focusing more on the content and delivering the teachings to you. God Bless you, Dr. Scott Johnson.




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Contending for Truth: Exposed: Tim LaHaye, Chuck Missler, Jerry Falwell, Sun Myung Moon, Rick Santorum, Newt Gingrich, Benny Hinn, Kathryn Kuhlman, Paul Crouch, Chuck Smith, Hal Lindsey, Rick Joyner, The Pope, TBN, Calvary Chapel, CNP, Knights of Malta &a

Welcome to the new Contending for Truth website! We are excited to have an opportunity to streamline the site, focusing more on the content and delivering the teachings to you. God Bless you, Dr. Scott Johnson.




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Contending for Truth: Exposed: Tim LaHaye, Chuck Missler, Jerry Falwell, Sun Myung Moon, Rick Santorum, Newt Gingrich, Benny Hinn, Kathryn Kuhlman, Paul Crouch, Chuck Smith, Hal Lindsey, Rick Joyner, The Pope, TBN, Calvary Chapel, CNP, Knights of Malta &a

Welcome to the new Contending for Truth website! We are excited to have an opportunity to streamline the site, focusing more on the content and delivering the teachings to you. God Bless you, Dr. Scott Johnson.




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Contending for Truth: Exposed: Tim LaHaye, Chuck Missler, Jerry Falwell, Sun Myung Moon, Rick Santorum, Newt Gingrich, Benny Hinn, Kathryn Kuhlman, Paul Crouch, Chuck Smith, Hal Lindsey, Rick Joyner, The Pope, TBN, Calvary Chapel, CNP, Knights of Malta &a

Welcome to the new Contending for Truth website! We are excited to have an opportunity to streamline the site, focusing more on the content and delivering the teachings to you. God Bless you, Dr. Scott Johnson.




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Ein Mann aus dem linken Spektrum soll 2016 eine Polizistin in der Rigaer Straße angepupst haben. Der Gruppenleiter der Einheit zeigte ihn an. Die heiße Luft wurde nun vor Gericht verhandelt

Viel Wirbel um ein wenig Darmwind. Christopher S. stand am Dienstag vor Gericht. Der offizielle Vorwurf: „Beleidigung und Ehrverletzung einer Beamtin durch Flatulenz“. Was war passiert?

bz-berlin.de




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Cannabis-Indoor-Plantagen ausgehoben

Eine serbisch-bosnische Tätergruppe soll zwei Cannabis-Indoor-Plantagen in den Bezirken Gänserndorf und Baden mit mehr als 1.400 Cannabispflanzen betrieben haben. Die Polizei konnte zwölf Personen als mutmaßliche Betreiber ausforschen.


orf.at




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Verstärke das Team als freiberuflicher Webentwickler für Quadro

Entdecke QUADRO, das innovative Klettersystem für individuelle Spielwelten! Eltern erhalten mit QUADRO die Freiheit, fantasievolle Spielstrukturen für ihre Kinder von 6 Monaten bis 8+ Jahren zu schaffen – sei es ein aufregendes Bällebad oder ein herausforderndes Klettergerüst. Das modulare QUADRO PLUG-IN-SYSTEM ermöglicht einen schnellen und sicheren Aufbau, der die Bedürfnisse von Kindern perfekt trifft. Made in Germany und in Kinderzimmern weltweit im Einsatz, fördert QUADRO die Entwicklung durch… | Quadro Der Grossbaukasten GMBH – Hamburg




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Michelle L. Ross Completes the Risk Management, Insurance Planning and Employee Benefits Course

Michelle L. Ross Completes the Risk Management, Insurance Planning and Employee Benefits Course.




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NEA Foundation Recognizes Alabama Educator with Prestigious NEA Member Benefits Award

The NEA Foundation announced today that Kimberly Johnson, an interventionist, resource educator, and teacher lead at Auburn Junior High School in Auburn, Ala., is the recipient of the 2024 NEA Member Benefits Award for Teaching Excellence, one of public education's top honors. Johnson was presented with the award, which comes with $25,000, by NEA Member Benefits President and CEO Leona Lindner at the NEA Foundation Salute to Excellence in Education Gala on Friday, May 3.




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6 Proven Ways Content Marketing Benefits your Small Business

For small and local businesses, it can be hard to stand out against larger nationwide brands. However, content marketing can help your small business attract attention, and for relevant niches in your industry, too.

Content marketing is a marketing approach that involves creating and distributing relevant and valuable content to your prospective audience in the hopes of driving a consumer action, and it has numerous benefits for small businesses. It can give you the opportunity to not only expand your company, but also to build your reputation and establish a place as a trusted leader in the industry.

complete article




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Can Your Small Business Benefit From Pinterest?

How Can Small Business Owners Build their Online Presence Using Pinterest?

Pinterest is not just an image sharing site. Small businesses can take advantage of the platform to market their goods and services to over 100 million online visitors. Here is how.

complete article




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Will Trumps Tax Plan Benefit Small Businesses?

Steven Mnuchin, Trumps candidate to run the Treasury Department, has stated that comprehensive tax reform will be an immediate priority of Trumps administration, and that his focus as Treasury Secretary will be stimulating economic growth and creating jobs through tax reform.

But how will this affect small businesses and their owners?

complete article




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Here is how small businesses can benefit from online marketplaces

The majority of small business owners agree that online marketplaces have positively impacted their sales, according to a poll by Manta.

Nearly 70% of small business owners polled stated that marketplaces like Amazon and eBay have helped them increase sales, while about 30% believe they have had a negative impact. Most small businesses (81%) believe that online sales are critical to their companys success, but most rely on their own websites as an e-commerce channel. Sixty-six percent of small businesses sell products through their own websites, 24% sell on Amazon, and 22% sell on eBay.

complete article




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What is a Micro Influencer and How Can They Benefit Your Small Business?

Micro influencers are social media personalities with anywhere from 2,000-50,000 followers. The numbers vary depending on the source, but their importance is universal. They are a great cost efficient way to provide targeted advertising for small businesses with limited budgets

Here is what you need to know about how these people can benefit your small business.

complete article




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Wasserbomben schlacht!

Die warscheinlich erste Wasserbomben-Simulation.