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Large enhancement of electrochemical biomass oxidation by optimizing the competitive adsorption of HMF and OH− on doped CoOx

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00519H, Research Article
Tianqi Nie, Guihao Liu, Ziheng Song, Tianyang Shen, Xiaoliang Sun, Tianrui Yu, Sha Bai, Lirong Zheng, Yu-Fei Song
By doping transition metals into CoOx, we can regulate the deintercalation capacity of OH. The CoCuOx with enriched oxygen vacancies allowed the optimization of the competitive adsorption between HMF and OH, and accelerated the kinetics of HMFOR.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Disruption of lipid metabolism to induce ferroptosis using multifunctional fibrate-Pt(IV) prodrugs for cancer treatment

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00386A, Research Article
Peng Sun, Jia-Qian Wang, Qiang Xie, Xuan-Lin Ren, Xin Qiao, Jing-Yuan Xu
Two multifunctional fibrate-Pt(IV) prodrugs, 1 and 3, bearing lipid-modulating agents, exhibited impressive anticancer activity by triggering ferroptosis and apoptosis.
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Enhanced photocatalytic CO2 reduction by controlled oxygen vacancy generation and co-constructed heterojunction strategy for Pd/CeO2

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00581C, Research Article
Fanlin Kong, Xiaoyan Lu, Jing Xie, Zhenjiang Lu, Jindou Hu, Yali Cao
Rational control of Vo concentration and the construction of a heterojunction strategy enable Pd/CeO2-Vo(r) to exhibit excellent photocatalytic CO2RR activity. The presence of COOHcreates favorable conditions for CO formation and desorption.
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Yolk-Shell type Carbon-Silica Nanoarchitecture Dispersed and Stabilized Ru Nanoparticles for Enhanced Hydrogenation of Aromatic Compounds

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00553H, Research Article
Lu Yan, Yue Shen, Zidan Zou, Xiao Zhang, Zhixin Yu, Guozhong Wang, Chun Chen
Hydrogenation of aromatic rings can be used not only for synthesis fine chemicals, but also for hydrogen storage and transportation using organic hydride. In this paper, yolk-shell structural SiO2@Ru@NC catalyst,...
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Anisotropic ZSM-5 nanorod assemblies: facile synthesis, epitaxial growth, and strikingly enhanced stability in benzene alkylation

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00287C, Research Article
Peng Zhu, Yiren Yu, Guoshu Gao, Yumeng Zhao, Yuting Jiao, Haiou Liu, Guodong Liu, Xiongfu Zhang, Guohui Yang
A novel bundle-like ZSM-5 nanorod assembly was facilely synthesized by adopting a CTAB-aided seed-induced strategy for highly efficient alkylation of benzene with ethanol.
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Advances in technical strategies for monitoring the reduction of platinum(IV) complexes

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00459K, Review Article
Open Access
Shu Chen, Qiyuan Zhou, Ka-Yan Ng, Zoufeng Xu, Weikang Xu, Guangyu Zhu
The reduction of Pt(IV) complexes can be monitored by various analytical techniques. These techniques hold significant promise in elucidating the mechanisms of Pt(IV) prodrug activation, aiding in the rational design of novel Pt(IV) prodrugs.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Not much relevance of windfall tax on crude now: Advisor to PM

Windfall Tax is to counterbalance the unusually high profits earned by oil and gas companies from high global crude oil prices




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Crude Check: At a resistance level

Traders can go short




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Golden morning, balanced diet & tennis




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Balancing innovation and access to healthcare

The draft Patent (Amendment) Rules, 2023, have prompted extensive discussion and debate, drawing attention to India’s pivotal role in providing affordable medicines, especially to those in need




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Health insurance no longer a no-go zone for the elderly

As IRDAI lifts the age cap for seniors, the focus shifts to overcoming operational barriers




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Boosting health insurance coverage

In a landmark move, the IRDAI’s recent guidelines aim to streamline and enhance the health insurance claims process. Groundbreaking among them is setting the three-hour timeline on cashless claims. 




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Lung cancer, in need of local research

Lung cancer in India presents unique challenges, with different patterns, genetics, and treatment options compared to the western world.




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Centre launches mobile app for grievance redressal of rice millers

Move to enchance transparency, accountability




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Arya.ag bags $19.8 million from US International Development Finance Corporation

These funds will be utilised to connect farmers and FPOs with buyers across the country




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Farmers’ reliance on paddy and maize threaten pulses, oilseeds crops

The shifting from pulses and cash crops towards stable paddy and maize has thrown challenges before policy makers on how to align the crop pattern as per the country’s needs




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Time window for advance ticket booking reduced to 60 days: Railways

Bookings done up to October 31, 2024 under the ARP of 120 days will remain intact




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Airlines, insurance companies may relook at disruption cover

Over the last seven days nearly 100 flights operated by Indian carriers have received bomb threats posted on social media resulting in flight disruptions, diversions and scrambling of fighter jets




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GMR group raises ₹6,300 crore to refinance promoter entity debt

GMR group will use the proceeds to refinance all external debt of GMR Enterprise Private Limited, the promoter of GMR Airports Limited




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MHI to consult with Ministry of Health again for guidelines on e-ambulances

Ministry says companies like Force Motors, Maruti Suzuki, Tata Motors and Toyota ready to manufacture e-ambulances under the Scheme




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Government moots ₹2,000 crore funding for Pawan Hans to revive operations, enhance capacity

Proposed fund infusion to help Pawan Hans provide consultation services for heliport construction, introduce seaplane services as well as add new choppers to its fleet




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ESAF Bank opens 500th branch in Ahmadabad




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Fino Payments Bank goes live with enhanced deposit limit of ₹2 lakh

Move in line with the revised guidelines announced by RBI




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PayPoint partners with Digit General Insurance for health insurance to rural areas

The insurance covers pre-hospitalisation and post-hospitalization expenses along with road ambulance charges




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Infosys beats market estimates; profit up 12%, raises guidance

It raised guidance to 19.5-20 per cent growth compared to the 16.5-17.5 per cent growth it had indicated earlier




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Reliance acquire Lithium Werks for $61 million




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Dance from within

Performances by Kathak prodigy Protyasha and Manipuri by Sudip Ghosh impressed, writes Gudipoodi Srihari.




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Brilliance of nadaswaram

A nadaswaram concert by ‘Bejawada Brothers’ enthralled the audience.




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Significance of the kriti

Radha Bhaskar talks about the various aspects of kriti




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How T.V. Sankaranarayanan’s music combined style and substance

T.V. Sankaranarayanan, who passed away recently, held aloft the Madurai Mani Iyer bani and great musical values




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A captivating Bharatanatyam performance on the shores of Visakhapatnam

Aayana Dance Company’s hour-long Bharatanatyam dance presentation captivates the audience in Visakhapatnam. The event was an initiative of Paramparaa Foundation




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Union Finance Minister Nirmala Sitharaman meets AIIB Board of Directors in Delhi




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Donor-modified asymmetric N/B/O multi-resonance TADF emitters for high-performance deep-blue OLEDs with the BT.2020 color gamut

Chem. Sci., 2024, 15,18135-18145
DOI: 10.1039/D4SC04896B, Edge Article
Open Access
Jing Jin, Zhaolong He, Di Liu, Yongqiang Mei, Jiahui Wang, Huihui Wan, Jiuyan Li
Spiro-acridine modified N/B/O type MR-TADF emitters realized deep blue fluorescence with an EQEmax of 20.5% and CIE (0.147, 0.048), which is state-of-the-art efficiency for N/B/O type deep-blue MR emitters with CIEy approaching the BT.2020 standard.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Enhancing the performance of molecule-based piezoelectric sensors by optimizing their microstructures

Chem. Sci., 2024, 15,18060-18066
DOI: 10.1039/D4SC05442C, Edge Article
Open Access
Zheng-Xiao Tang, Bin Wang, Zhi-Rui Li, Zhuo Huang, Hai-Xia Zhao, La-Sheng Long, Lan-Sun Zheng
A molecule-based ferroelectric [(CH3)3NCH2CH2Br][GaBr4] (1), with a d33 value of 331 pC N−1, was synthesized. The power density of the 1@S-PDMS piezoelectric sensor, featuring optimized microstructures, is up to 490 μW cm−2.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Recent advances in hydrogel-based flexible strain sensors for harsh environment applications

Chem. Sci., 2024, 15,17799-17822
DOI: 10.1039/D4SC05295A, Review Article
Open Access
Miaoyu Li, Jie Pu, Qinghe Cao, Wenbo Zhao, Yong Gao, Ting Meng, Jipeng Chen, Cao Guan
The application of hydrogel-based flexible strain sensors in harsh environments, including extreme temperatures, humidity, high mechanical strain, and strong corrosion, is investigated.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Enhancing hydrogen evolution reaction activity through defects and strain engineering in monolayer MoS2

Chem. Sci., 2024, 15,18127-18134
DOI: 10.1039/D4SC04874A, Edge Article
Open Access
Renjith Nadarajan, Sraboni Dey, Arijit Kayal, Joy Mitra, Manikoth M. Shaijumon
The synergistic creation of vacancy defects, along with strain-induced active sites is shown to enhance hydrogen evolution reaction (HER) performance of CVD-grown monolayer MoS2.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Two in one: merging photoactivated chemotherapy and photodynamic therapy to fight cancer

Chem. Sci., 2024, 15,17760-17780
DOI: 10.1039/D4SC04608K, Perspective
Open Access
Kirill M. Kuznetsov, Kevin Cariou, Gilles Gasser
Combining photodynamic therapy (PDT) and photoactivated chemotherapy (PACT) into one single compound allows to achieve more efficient light-induced therapy.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Double coordination shell modulation of nitrogen-free atomic manganese sites for enhancing oxygen reduction performance

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05998K, Edge Article
Open Access
Xue Bai, Yin Wang, Jingyi Han, Siyu Chen, Xiaodi Niu, Jingqi Guan
Utilizing double coordination shell modulation, we construct a novel nitrogen-free single-atom manganese coordination configuration catalyst on graphene oxide (Mn–S1O4G), which exhibits excellent ORR and zinc–air battery performances.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Enhanced efficiency in plastic waste upcycling: the role of mesoporosity and acidity in zeolites

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05121A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Saideep Singh, Joaquín Martínez-Ortigosa, Nuria Ortuño, Vivek Polshettiwar, Javier García-Martínez
By optimizing zeolite pore confinement, polymer diffusion and up-cycling efficiency in hierarchical catalysts are significantly enhanced, reducing plastic degradation temperatures and providing a suitable route to sustainable plastic-to-fuel pathways.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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From small changes to big gains: pyridinium-based tetralactam macrocycle for enhanced sugar recognition in water

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06190J, Edge Article
Open Access
Canjia Zhai, Ethan Cross Zulueta, Alexander Mariscal, Chengkai Xu, Yunpeng Cui, Xudong Wang, Huang Wu, Carson Doan, Lukasz Wojtas, Haixin Zhang, Jianfeng Cai, Libin Ye, Kun Wang, Wenqi Liu
Incorporating pyridinium into an anthracene-based macrocycle significantly enhances its sugar binding affinity by increasing hydrogen bonding and expanding the contact surface area.
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Resonance Plasmonic Coupling: Selective Enhancement of Band Edge Emission over Trap State Emission of CdSe Quantum Dots

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04960H, Edge Article
Open Access
Livin Paul, Elizabeth Mariam Thomas, Akshaya Chemmangat, Stephen Gray, K. George Thomas
The photoluminescence properties of quantum dots (QDs) are often enhanced by eliminating surface trap states through chemical methods. Alternatively, a physical approach is presented here for improving photoluminescence purity in...
The content of this RSS Feed (c) The Royal Society of Chemistry




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An interactive dual energy storage mechanism boosts high-performance aqueous zinc-ion batteries

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05710D, Edge Article
Open Access
Shengen Gong, Meihua Zhu, Yan Zhou, Runan Li, Jianhua Zhang, Xiaoteng Jia, Danming Chao, Caiyun Wang
A conductive polymer cathode with high redox potential is realized by pre-doping Mn2+ into PANI, which demonstrates an interactive dual energy storage mechanism of reversible doping of multiple cations and dissolution–deposition of Mn2+.
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Shape-shifting with dance

Sanjukta Sinha dwells on belonging and relationships in Kin , her new contemporary Kathak production




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Eat, drink, dance Greek

Mariketty Grana is back in the city with a permanent spot for her Greek restaurant, Thalassa




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Why this balanced advantage fund is a useful addition amidst rough markets

ICICI Prudential Balanced Advantage juggles stocks, bonds and derivatives smartly for optimal returns




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Past performance not a guarantee for future returns

Sectoral funds usually are cyclical, which means their performance can swing significantly




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Markets correlate with economic performance, not political dispensation: Ashish Somaiyaa, CEO, WhiteOak Capital AMC

Ashish Somaiyaa, CEO, WhiteOak Capital AMC, on the impact of elections on the market and more




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Insurance of bank balance: some useful perspectives

The basis of safety or comfort with a bank should not be DICGC cover but overall fundamental quality of the bank; preferably bank with institutions where you would not require this coverage




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Mutual Funds: Does past performance indicate how they’ll perform in the future?

An analysis on if and how historical outperformance of mutual funds foretell their future returns




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Why balanced advantage fund may help tide over volatile markets

Balanced advantage funds are seen as attractive in the current market as they tend to generate risk-adjusted returns and insulate investor portfolios from stiff corrections