The title compound, di­aqua­[tris­(2-amino­eth­yl)amine]­nickel(II) hexa­aqua­nickel(II) bis­(sulfate), [Ni(C6H18N4)(H2O)2][Ni(H2O)6](SO4)2 or [Ni(tren)(H2O)2][Ni(H2O)6](SO4)2, consists of two octa­hedral nickel complexes within the same unit cell. These metal complexes are formed from the reaction of [Ni(H2O)6](SO4) and the ligand tris­(2-amino­eth­yl)amine (tren). The crystals of the title compound are purple, different from those of the starting complex [Ni(H2O)6](SO4), which are turquoise. The reaction was performed both in a 1:1 and 1:2 metal–ligand molar ratio, always yielding the co-precipitation of the two types of crystals. The asymmetric unit of the title compound, which crystallizes in the space group Pnma, consists of two half NiII complexes and a sulfate counter-anion. The mononuclear cationic complex [Ni(tren)(H2O)2]2+ comprises an Ni ion, the tren ligand and two water mol­ecules, while the mononuclear complex [Ni(H2O)6]2+ consists of another Ni ion surrounded by six coordinated water mol­ecules. The [Ni(tren)(H2O)2] and [Ni(H2O)6] subunits are connected to the SO42− counter-anions through hydrogen bonding, thus consolidating the crystal structure.

For serial femtosecond crystallography at X-ray free-electron lasers, which entails collection of single-pulse diffraction patterns from a constantly refreshed supply of microcrystalline sample, delivery of the sample into the X-ray beam path while maintaining low background remains a technical challenge for some experiments, especially where this methodology is applied to relatively low-ordered samples or those difficult to purify and crystallize in large quantities. This work demonstrates a scheme to encapsulate biological samples using polymer thin films and graphene to maintain sample hydration in vacuum conditions. The encapsulated sample is delivered into the X-ray beam on fixed targets for rapid scanning using the Roadrunner fixed-target system towards a long-term goal of low-background measurements on weakly diffracting samples. As a proof of principle, we used microcrystals of the 24 kDa rapid encystment protein (REP24) to provide a benchmark for polymer/graphene sandwich performance. The REP24 microcrystal unit cell obtained from our sandwiched in-vacuum sample was consistent with previously established unit-cell parameters and with those measured by us without encapsulation in humidified helium, indicating that the platform is robust against evaporative losses. While significant scattering from water was observed because of the sample-deposition method, the polymer/graphene sandwich itself was shown to contribute minimally to background scattering.

Based on decades of cutting-edge research, the 15,000-square-foot Hall of Human Origins offers visitors an immersive, interactive journey through 6 million years of human evolution spelling out how defining characteristics of the human species have evolved during millions of years in response to a changing world.

The post New Hall of Human Origins points to environmental change as major force in evolution of hominins appeared first on Smithsonian Insider.

A research team from The Smithsonian Environmental Research Center and Virginia's Old Dominion University will be awarded $110,999 to develop a tool to help seagrass restorers predict which places will be the best for planting seagrasses, the Virginia Sea Grant has announced.

The post Environmental Research Center to help with Chesapeake Bay seagrass restoration appeared first on Smithsonian Insider.

The expanded and remodeled Mathias Laboratory, named in honor of U.S. Senator Charles "Mac" Mathias Jr. (1922-2010) (R-Md.) will have a low environmental impact on all fronts, from where it gets its power to where it gets its materials.

The post New Mathias Lab at Environmental Research Center will have low environmental impact appeared first on Smithsonian Insider.

The new research reveals that from the period between 1100-1600 small agricultural settlements up and down the Delaware River Valley caused a 50-percent increase in sediment runoff into the Delaware River.

The post Study reveals environmental impact of American Indian farms centuries before Europeans arrived in North America appeared first on Smithsonian Insider.

The world’s coasts are home to more than 70 percent of the human population and experience intense development as a result. The rate of environmental […]

The post Smithsonian Environmental Research Center Marks 50 Years of Making a Difference appeared first on Smithsonian Insider.

Here’s some good news that should hit you in the gut. A team of scientists searching thousands of environments for bacteria that produce the deadly […]

The post Survey pinpoints where toxic mercury accumulates in world environments appeared first on Smithsonian Insider.

Like many predators, the fringe-lipped bat primarily uses its hearing to find its prey, but with human-generated noise on the rise, scientists are examining how […]

The post Bats Use Second Sense to Hunt Prey in Noisy Environments appeared first on Smithsonian Insider.

Odile Madden knows a lot about plastic. A materials scientist with the Smithsonian Museum Conservation Institute, she has spent the past eight years studying plastics […]

The post Microplastics in our environment: A conversation with Odile Madden, Smithsonian plastics scientist appeared first on Smithsonian Insider.

The post Device at the Smithsonian Environmental Research Center examines how phytoplankton would react if the ozone layer vanished appeared first on Smithsonian Insider.

The post How do paleontologists reconstruct environments from the ancient past? appeared first on Smithsonian Insider.

Meet Amy Homma, the Director of Digital Learning at Art Lab+. Learn how Smithsonian’s Hirshhorn Museum and Sculpture Garden has created a dynamic program to […]

The post An Active Environment With Smithsonian Educator: Amy Homma appeared first on Smithsonian Insider.

Follow botanist Candy Feller of the Smithsonian Environmental Research Center as she conducts field work on mangrove ecosystems at Carrie Bow Cay, a Smithsonian field research station in the Caribbean.

The post Mangroves research by Candy Feller, Smithsonian Environmental Research Center botanist appeared first on Smithsonian Insider.

On crime scene investigation shows, forensic scientists use remnants of genetic material to solve mysteries in a matter of hours. Researchers at the Smithsonian Environmental […]

The post Environmental “Forensics” Pieces Together Mysterious Plant Invasion appeared first on Smithsonian Insider.

Is it foolish to be optimistic about our environment and its future prospects? Every day, we hear dire warnings about the health of the planet […]

The post The Argument for Environmental Optimism: Opinion by Smithsonian Secretary David J. Skorton appeared first on Smithsonian Insider.

A tiny invasive insect from Asia might have an effect on Chesapeake Bay waters. The emerald ash borer is killing millions of ash trees in […]

The post Invasive ash borer found in Smithsonian Environmental Research Center forest; ash deaths may impact Chesapeake waters appeared first on Smithsonian Insider.

Although there is evidence of harmful health and ecological effects associated with exposure to high doses of chemicals known as hormonally active agents – or endocrine disrupters – little is understood about the harm posed by exposure to the substances at low concentrations, such as those that typically exist in the environment, says a new report from a National Research Council committee.

The environmental effects of oil and gas exploration and production on Alaska s North Slope have been accumulating for more than three decades, says a new report from the National Academies National Research Council.

Weather and environmental forecasts made several weeks to months in advance can someday be as widely used and essential as current predictions of tomorrow’s weather are, but first more research and sustained investment are needed, says a new report from the National Academies of Sciences, Engineering, and Medicine.

The emerging science of gene drives has the potential to address environmental and public health challenges, but gene-drive modified organisms are not ready to be released into the environment and require more research in laboratories and highly controlled field trials, says a new report from the National Academies of Sciences, Engineering, and Medicine.

New Report Outlines Research Agenda to Better Understand the Relationship Among Microbiomes, Indoor Environments, and Human Health

The Gulf Research Program (GRP) of the National Academies of Sciences, Engineering, and Medicine today announced grant awards for seven new projects totaling $5.3 million.

The National Academies of Sciences, Engineering, and Medicine are launching an Academies-wide initiative to transform how the nation addresses the complex issues associated with environmental health—a field that examines how the environment affects human health.

The Gulf Research Program (GRP) of the National Academies of Sciences, Engineering, and Medicine today announced awards for nine new grant projects totaling $3.2 million.

If the dilute and dispose approach for disposing of the surplus plutonium in the Waste Isolation Pilot Plant (WIPP) is fully implemented, the U.S. Department of Energy (DOE) should use two independent review teams to develop public trust in and improve its decisions, says a new interim report by the National Academies of Sciences, Engineering, and Medicine.

Over the next several decades as the global population grows, society will be faced with pressing challenges such as providing reliable supplies of food and water, diminishing climate change and adapting to its impacts, and building healthy, resilient cities.

Representatives from the national academies of sciences of the G20 countries handed over recommendations for improving marine conservation to the Japanese Prime Minister Shinzo Abe.

Coral reefs around the world face growing danger from a changing climate, on top of the historic threats from local pollution and habitat destruction.

Between one-third and one-half of U.S. clinicians experience burnout and addressing the epidemic requires systemic changes by health care organizations, educational institutions, and all levels of government, says a new report from the National Academy of Medicine.

NASA should collaborate with the Federal Aviation Administration (FAA), industry, academia to research the full effects that increased unpiloted air vehicle traffic would have on society, including ramifications to sound, privacy, environmental matters, and cybersecurity, says a new report from the National Academies of Sciences, Engineering, and Medicine.

On Broad Beach in Malibu, high tide not only wets sand but also retaining walls and broken down rock revetments. What happens next in homeowners' efforts to get sand trucked in here will go to the State Lands Commission - and the next Controller likely will weigh in on the problem. ; Credit: Molly Peterson/KPCC

The most common question I’ve been asked about the statewide Controller race this election year is the same question I get every four years. “Wait, we have one?”

The inevitable follow-up question: “What does this person do?” Down-ballot races in California’s state election can seem like a tedious part of a the voting process. Most of us just don't take the time to research them. In 2010, the last time we elected statewide executives, 435,308 of those people who voted for Governor just didn’t bother to vote for anybody in the Controller race. 

But in addition to being the chief fiscal officer of the 8th-largest economy in the world, the Controller sits on something like 80 state commissions and boards. And if you’re interested in California’s environment, a biggie there is the State Lands Commission.

The State Lands Commission oversees roughly 4 million acres of submerged land and tidelands, holding them in trust for the public. Right now it's looking at policy alternatives to respond to sea level rise. It manage the state's offshore oil-drilling leases. It even gets authority over historical shipwrecks! 

Three issues coming before to the Lands Commission mean the Controller matters:  

• Coastal Access and Martin’s Beach: At the end of September, Governor Jerry Brown signed a law requiring the State Lands Commission to negotiate with Vinod Khlosa, a private property owner who famously shut down coastal access over his land this year. The commission has all of next year to negotiate with Khlosa. If no deal is reached, it can use eminent domain authority to force public access – something that would represent a big break in historical practice, because that authority hasn’t ever been used in the 76 years that the commission has existed.
• Malibu’s Broad Beach has been rapidly eroding under pressure of waves and storms worsened by climate change, and very rich homeowners there have been seeking to add sand in front of their houses to combat the risk of damage to very expensive properties. Earlier this year, those homeowners successfully completed an application to the State Lands Commission, and the commission was expected to decide on it in October. The decision’s been put over till after the election.
• Fracking: Offshore oil made news late last year and earlier this year when some operators didn’t report that they were using drilling and production techniques collectively referred to as hydraulic fracturing. The news prompted the EPA to require chemical disclosures for drilling operations it oversees.  The state agencies that should be overseeing these issues – the Coastal Commission and the Lands Commission – are considering their next moves too.

Positions on these issues don’t really come up when it comes to the Controller race, though both Betty Yee and Ashley Swearengin have gone on the record to say they’re against fracking. 

This content is from Southern California Public Radio. View the original story at SCPR.org.

Science for Environment Policy are very pleased to announce the launch of a new series of policy briefs. Entitled 'Future Briefs', these will explore emerging areas of research with implications for environmental policy.'Plastic Waste: redesign and biodegradability' is the first Future Brief, which will be published week commencing 27 June. Future Briefs will be available to download free from our website: http://ec.europa.eu/environment/integration/research/newsalert/index_en.htm

Scientists involved in a pan-European project to develop better methods of risk assessment say maps that show such cumulative risks geographically are easy to interpret and should be considered as practical tools for conveying risk information to decision makers and the general public.

A recent study has assessed the lifecycle environmental impact during the production and use phase of three battery types for plug-in hybrid (PHEV) and full performance battery electric vehicles (BEV). The study indicates that newer lithium-ion (Li-ion) technologies outperform current nickel-metal hydride (NiMH) batteries and identifies processes contributing to 13 environmental impacts

A new analysis of how to encourage pro-environmental behaviour highlights four effective techniques: goal-setting, prompts or reminders, witnessing the behaviour of others and introducing new behaviours that correspond with existing beliefs.

A new German study suggests that residents??? level of satisfaction with their urban neighbourhood can be predicted from their perceptions of multiple and co-occurring burdens, such as poor air quality, lack of green space, noise and low cleanliness.

Citizen science is not only a tool for collecting valuable scientific data, it can also enable participants to reconnect with nature and encourage pro-conservation behaviour, new research has shown. Participants in a French butterfly monitoring programme reported making wildlife-friendly changes to their gardens as a result of taking part in the initiative.

A recent study has investigated how waste disposal sites in southern Italy have affected residents living nearby. Villagers reported being annoyed by odours, but the perceptions of residents living in the village closest to the facilities were possibly influenced by receiving financial compensation for the presence of the facilities.

International agreements to reduce plastic use are needed to address plastic litter in the marine environment, as well as increased public awareness of the problem, according to scientists at a workshop on the EU Marine Strategy Framework Directive held in Italy in 2013. The issues discussed at the workshop have been summarised in a recent research paper.

The global production, trade and use of goods and services has a significant impact on the environment — and rates of consumption are rising. A new study combines two assessment methods to quantify the impact of European trade on the environment. It finds that, overall, the EU was a net importer of environmental impact from 2000 to 2010, that machinery, equipment and vehicles contributed most to the EU’s export impacts and that the EU’s trade balance (import impact minus export impact) is increasing over time. The two assessment methods complement one another well and could form the basis for future country or region-wide studies, suggest the researchers, by enabling a detailed analysis of individual steps within a product’s trade flow, while also providing a larger picture of the overall process.

As 3D printing, also known as additive manufacturing (AM), begins to replace conventional manufacturing, the environmental impacts of its implementation must be assessed. This study conducted a life cycle assessment (LCA) to investigate the environmental and resource implications of using AM to manufacture the metal parts of an engine in a light distribution truck. In the LCA, the impacts of both present and possible future states of AM technology were compared with current conventional manufacturing. The results suggest that there are potential environmental and resource benefits1 to AM technologies, but that these benefits rely on the achievement of a clean energy source and further technological development.

Approximately 88 megatonnes (Mt) of food are wasted every year in the European Union, causing 186 metric tons (Mt) carbon dioxide equivalent (CO2-eq) — a universal measure for all greenhouse gases. The impact of food waste on the climate, acidification and eutrophication is around 15–16% of the environmental impact of the entire food chain. In developed countries, food waste is high at the point of consumption— so significantly reducing food losses would require a food-waste reduction in households and the food-services sector.

New research has compared the environmental impact of four alternative methods of water supply in Copenhagen. Results indicated that rain and stormwater harvesting is the most environmentally sound approach, whilst desalination currently has a large environmental impact, mainly due to electricity use. However, if freshwater extraction is included as an impact, the environmental credibility of desalination is improved.

A recent study has compared the environmental impact of a range of building materials. Energy consumption, carbon dioxide emissions and water demand can all be reduced by switching to renewable sources of energy, improving technologies and promoting eco-friendly alternative materials.

Environmentally responsible attitudes and behaviour do not necessarily translate into real benefits for the environment, according to the results of a new study. The study shows that people who think they are environmentally aware – and even those who, in some respects, seem to behave in an environmentally friendly way – actually have just as large an impact on the environment as other consumers.

New research has assessed the environmental impact of gold production using life cycle assessment and estimated embodied energy and greenhouse gases, embodied water and solid waste burden that each tonne of gold produces, using various processes.

Using high-strength concrete in construction could help to reduce its impact on the environment, according to a study by French researchers. The researchers compared the environmental impacts of bridges built from ordinary and high-strength concrete and found that the high-strength solution had a lower impact on the environment overall.

A new concrete-reinforcement system, used by the LIFE INSU-SHELL1 project, replaces steel rods with non-corrosive textile structures to reduce the amount of concrete needed in construction. This nearly halves the global warming potential of traditional steel-reinforced concrete which is the largest producer of CO2 emissions in the building industry.

Staff in buildings that have been certified as ‘green’ under the LEED scheme are just as satisfied with their indoor working environment as people working in non-LEED buildings, according to research on commercial buildings. The study suggests that investment in the thermal and acoustic aspects of buildings, however, would further improve occupant satisfaction.