ycl

Convergent Synthetic Approaches to Polycyclic Aromatic Dicarboximides

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01828A, Review Article
Kazutaka Shoyama, Frank Wuerthner
Polycyclic aromatic dicarboximides (PADIs) as represented by naphthalene and perylene bis(dicarboximide) are useful molecules for a variety of functional materials and remain important synthetic targets for organic chemists. In this...
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Intermolecular Defluorinative 1,2-Diamination of Fluoroalkenyl Iodides with Sulfonamides: Synthesis of Acyclic and Cyclic Fluorinated 1,2-Enediamines

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01913J, Research Article
Xue-Qiang Chu, Yu-Lan Chen, Chi Zhang, Xue-Ying Huang, Yu Ding, Danhua Ge, Zhi-Liang Shen
Alkene diamination represents one of the most straightforward strategies for 1,2-diamine derivatives synthesis. However, transition-metal-free 1,2-diamination of fluoroalkenes has been less studied. Here we report an intermolecular defluorinative vicinal diamination...
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

The building and breaching of Fortress India: chronicling a cycle of cricket dominance

India was invincible at home for 12 years, winning 18 consecutive Test series before New Zealand snapped the record streak in a historic clean sweep. What went into the making of the unbeaten run, what are the consequences of defeat and what does the future look like?




ycl

Investigation of the titanium-mediated catalytic enantioselective oxidation of aryl benzyl sulfides containing heterocyclic groups

RSC Adv., 2024, 14,35105-35113
DOI: 10.1039/D4RA07088G, Paper
Open Access
Maria Annunziata M. Capozzi, Angel Alvarez-Larena, Joan F. Piniella Febrer, Cosimo Cardellicchio
Enantiopure benzyl heteroaryl sulfoxides were obtained by asymmetric oxidation. However, two benzimidazolyl sulfoxides were found to be conglomerates.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

DFT investigation of the mechanism and role of N-heterocyclic carbene (NHC) in constructing asymmetric organosilanes using NHC-catalyzed [4+2] cycloaddition reaction

RSC Adv., 2024, 14,35475-35489
DOI: 10.1039/D4RA03676J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Batoul Alipour
The mechanism and origin of stereoselectivity for the synthesis of asymmetric organosilanes using NHC are theoretically investigated.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Synthesis of supramolecular polymers with calix[4]arene and β-cyclodextrin and their application in heavy metal ion absorption

RSC Adv., 2024, 14,35697-35703
DOI: 10.1039/D4RA05559D, Paper
Open Access
Jian-Jian Bian, Shi-Jin Tang, Jiao Miao, Rui Lin, Guo-Li Huang, Ming-Yu Teng, Xiao-Mei Li
Two categories of supramolecular polymer monomers were produced by introducing the ureidopyrimidone quadruple-hydrogen bonding assemblies on the calix[4]arene and the β-cyclodextrin host units, which adsorbed up to 99% of Pb2+ and Cd2+.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Exploring heterocyclic scaffolds in carbonic anhydrase inhibition: a decade of structural and therapeutic insights

RSC Adv., 2024, 14,35769-35970
DOI: 10.1039/D4RA06290F, Review Article
Open Access
Nafeesa Naeem, Amina Sadiq, Gehan Ahmed Othman, Habab M. Yassin, Ehsan Ullah Mughal
Heterocyclic compounds represent a prominent class of molecules with diverse pharmacological activities.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Porous CaMnO3-promoted g-C3N4 as an effective photocatalyst for tetracycline degradation

RSC Adv., 2024, 14,36181-36192
DOI: 10.1039/D4RA06407K, Paper
Open Access
Bo Zhang, Chaoqi Li, Shasha Liu, Lixuan Zhuang, Weiqi Zhang, Limei Huang, Zhenzhen Jia, Dongdong Chen, Xiang Li
Non-expensive CaMnO3 perovskite oxide can assist in developing efficient g-C3N4-based photocatalysts aimed at removing antibiotics from wastewater.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Cyclone Asna leaves no major impact on Gujarat, moves towards Oman

As a precautionary measure, the local administration had shifted nearly 3,500 persons to safer locations and had asked people living in huts and mud houses to take shelter in other buildings




ycl

Trigonal bipyramidal or square planar? Density functional theory calculations of iron bis(dithiolene) N-heterocyclic carbene complexes

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02650K, Communication
Katherine Merkel, Alyssa V. B. Santos, Scott Simpson
DFT calculations of 57 iron bis(dithiolene)-N-heterocyclic carbene adducts were conducted to determine what parameters predict their coordination. The properties were compared via regression models to see which best predict the Addison τ parameter.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Bicyclic (Alkyl)(Amino)Carbenes (BICAACs): Synthesis, Characteristics, and Applications

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02696A, Perspective
Ankita Sharma, Unnikrishnan Nair K, Subrata Kundu
Carbenes in general and isolable NHCs (N-heterocyclic carbenes) in particular have been useful ligands in recent years. The emergence of CAACs [cyclic(alkyl)(amino)carbenes], BICAACs [bicyclic(alkyl)(amino)carbenes], and many other carbenes has marked...
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Stable homogeneous silver(I) catalysts for the highly efficient cycloaddition of azides onto terminal alkynes in water

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02825B, Communication
Meysam Kakavand, Anna Kozakiewicz, Abdollah Neshat
To develop stable and efficient silver(I) catalysts and evaluate the role of sulfur and phosphorus donor ligands in the catalytic cycloaddition of selected organic azides and alkynes (AAC), a series...
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

β-Cyclodextrin and cucurbit[7]uril as protective encapsulation agents of the CO-releasing molecule [CpMo(CO)3Me]

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT01863J, Paper
Rodrigo P. Monteiro, Isabel B. Calhau, Ana C. Gomes, André D. Lopes, José P. Da Silva, Isabel S. Gonçalves, Martyn Pillinger
For inclusion compounds between the complex [CpMo(CO)3Me] (1) and β-cyclodextrin or cucurbit[7]uril, the macrocyclic hosts modulate to different degrees the UV light-mediated CO release from encapsulated 1.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Effect of mono- and dinuclear thiosemicarbazone platinacycles in the proliferation of a colorectal carcinoma cell line

Dalton Trans., 2024, 53,17803-17818
DOI: 10.1039/D4DT01490A, Paper
Open Access
Francisco Reigosa-Chamorro, Sandra Cordeiro, M. Teresa Pereira, Beatriz Filipe, Pedro V. Baptista, Alexandra R. Fernandes, José M. Vila
The study of the antiproliferative activity of thiosemicarbazone platinacycles puts forward their high selectivity and low IC50 values.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Tunability of triplet excited states and photophysical behaviour of bis-cyclometalated iridium(III) complexes with imidazo[4,5-f][1,10]phenanthroline

Dalton Trans., 2024, 53,17934-17947
DOI: 10.1039/D4DT01996B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Katarzyna Choroba, Joanna Palion-Gazda, Mateusz Penkala, Patrycja Rawicka, Barbara Machura
The impact of cyclometalating ligands on the photophysical behaviour of heteroleptic Ir(III) complexes with imidazo[4,5-f][1,10]phenanthroline. [Ir(ppy)2(imphen)]+ is a 3MLLCT emitter, while [Ir(pybzth)2(imphen)]+ has a predominant 3LCN∩C character.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Gold nanoparticle-decorated amorphous carbon for oxidative cyclization of anthranilamide and aryl alcohols

Dalton Trans., 2024, 53,17976-17988
DOI: 10.1039/D4DT02355B, Paper
The Thai Nguyen, Huyen-Tran Thi Nguyen, Thu Anh Nguyen, Khuong Quoc Vo, Phuong Hoang Tran
Various 2-phenylquinazolin-4(3H)-ones were produced in moderate-to-good yields (44–80%) via the oxidative cyclization of anthranilamide and benzyl alcohols using gold nanoparticle-decorated amorphous carbon as an efficient catalyst.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Freewheeling exploration with a bicycle

The machine was a precious possession, a symbol of hard work and determination




ycl

Sprint ace Mark Cavendish ends cycling career in style with Singapore win

Mark Cavendish, one of the best road sprinters in cycling history, retired in style by winning the Tour de France Criterium in Singapore




ycl

Study of advanced treatment of low concentration tetracycline wastewater in two-stage MBBR system

Environ. Sci.: Water Res. Technol., 2024, 10,2688-2697
DOI: 10.1039/D4EW00313F, Paper
Kuaile Zhao, Hanyu Chen, Zhaoran Wang, Baozhong Zhang, Kunfeng Zhang, Huikang Zhang, Wanbin Hong
In this research, a two-stage reaction system was developed, incorporating a moving bed biofilm reactor (MBBR) and a photocatalytic reactor.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Effect of extracellular organic matter (EOM) accumulation on algal proliferation and disinfection by-product precursors during cyclic cultivation

Environ. Sci.: Water Res. Technol., 2024, 10,3024-3034
DOI: 10.1039/D4EW00207E, Paper
Open Access
Jr-Lin Lin, Fahrudin Sidik
Algal blooms, driven by nutrient enrichment from nitrogen and phosphorus, pose significant challenges to water treatment processes, particularly due to the accumulation of extracellular organic matter (EOM).
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

A review of carbon recovery in sewage treatment and analysis of product options for a typical water recycling plant

Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00160E, Critical Review
Arash Mohseni, Linhua Fan, Li Gao, Joel Segal, Felicity Roddick
Reviewed existing and emerging technologies for carbon recovery from WWTPs, best options investigated as case study for typical conventional plant.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Sludge-derived novel Fe3O4–MgO@C composites for tetracycline abatement from wastewater using sustainable bio-electro-Fenton and nutrient recovery with co-precipitation: a waste-to-resource strategy

Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00684D, Paper
Azhan Ahmad, Monali Priyadarshini, Shraddha Yadav, Makarand M. Ghangrekar, Rao Y. Surampalli
Developing efficient Fenton catalysts for the remediation of emerging pollutants is one of the challenges for researchers.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

GoM decides to cut GST on 20-litre water bottles, bicycles to 5%; raise rate on shoes, watches

The Group of Ministers on GST rate on life and health insurance decided to exempt GST on premiums paid for health insurance with coverage of ₹5 lakh for individuals other than senior citizens; final decision to be taken by the GST Council




ycl

Cyclical slowdown? Nomura thinks so

Days after its research report stating ‘the growth glass looks half empty’ for India, Nomura economists signal weak urban demand is unlikely to rebound soon and GDP growth may even slip under 6.7% this year




ycl

A high-entropy cathode catalyst with multiphase catalytic capability of Li2O2 and Li2CO3 enabling ultralong cycle life in Li–air batteries

Energy Environ. Sci., 2024, 17,8198-8208
DOI: 10.1039/D4EE02817A, Paper
Xia Li, Guoliang Zhang, Dongmei Zhang, Ruonan Yang, Han Yu, Xiuqi Zhang, Gang Lian, Hua Hou, Zhanhu Guo, Chuanxin Hou, Xiaoyang Yang, Feng Dang
High entropy design guidance enables a modulated broad d-band of cathode catalyst with efficient d–p coupling for all reactants, realizing multiphasic catalytic capability of Li2O2 and Li2CO3 and ultralong cycle life in Li–air and Li–CO2 batteries.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Electrocatalytic nitrogen cycle: mechanism, materials, and momentum

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03156C, Review Article
Laiquan Li, Linyuan Xu, Hanyun Wang, Haohong Wei, Cheng Tang, Guisheng Li, Yuhai Dou, Hua Kun Liu, Shi Xue Dou
As a self-sustaining cycle, the electrocatalytic nitrogen cycle represents an avenue for rectifying the nitrogen imbalance and for synthesizing value-added chemicals, thereby contributing to a sustainable and carbon-neutral society.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Superhydrophobic and robust hetero-metal-polymer hybrid interphase enables deep-cycling zinc metal anodes

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04122D, Paper
Mengyu Liu, Wentao Yuan, Xinghan Qu, Xianghao Ru, Xiaotong Li, Tingxuan Wang, Xinke Wang, Yuanyuan Wang, Yongchang Liu, Ning Zhang
Realizing stable zinc (Zn) metal anodes under deep cycling conditions is the prerequisite for practical rechargeable Zn batteries but remains a significant challenge, due to severe water erosion and dendrite...
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Achieving high performance triboelectric nanogenerators simultaneously with high-voltage and high-charge energy cycle

Energy Environ. Sci., 2024, 17,8734-8744
DOI: 10.1039/D4EE02447H, Paper
Open Access
Yikui Gao, Jiaqi Liu, Linglin Zhou, Lixia He, Di Liu, Peiyuan Yang, Bingzhe Jin, Zhong Lin Wang, Jie Wang
This work achieves a high-voltage and high-charge energy cycle for TENGs, as well as lossless energy transmission between TENGs and PMCs.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Anti-Freezing Hydrogel Electrolyte with Regulated Hydrogen Bond Network Enables High-Rate and Long Cycling Zinc Batteries

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE02772H, Paper
Shaojie Guo, Mengyu Yan, DongMing Xu, Pan He, Kaijian Yan, Jiexin Zhu, Yongkun Yu, Zeya Peng, Yanzhu Luo, Feifei Cao
Zinc-based batteries, utilizing hydrogel electrolytes, present significant promise as power sources for next-generation flexible devices due to their stretchable nature and enhanced safety features. Nonetheless, the current hydrogel electrolytes require...
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Efficient aqueous-phase hydrogenation of m-xylylenediamine to 1,3-cyclohexandimethylamine over a highly active and stable ruthenium catalyst

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00712J, Paper
Jing Guo, Heng Shao, Le Gao, Wancheng Ma, Wei Zhang, Long Huang, Haibin Chu
The strong interaction between Ru and –NH2 in Ru/NH2–Al2O3 led to the formation of highly dispersed Ru and modification of its electronic properties, and consequently greatly enhanced its performance and stability.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Photochemical organocatalytic heteroarylation of anilines and secondary alicyclic amines in continuous-flow

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00130C, Paper
Egor N. Boronin, Milena M. Svetlakova, Ilya I. Vorobyov, Yulia B. Malysheva, Yuri V. Polushtaytsev, Sergey N. Mensov, Andrey V. Vorotyntsev, Alexey Yu. Fedorov, Timothy Noël, Alexander V. Nyuchev
Photoorganocatalytic arylation of amines in continuous-flow enables scaling up including decreasing of both reaction time and catalyst loading.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

High-efficiency non-thermal plasma synthesis of imine macrocycles

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00061G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Patrycja Roszkowska, Abbie M. Scholes, James L. Walsh, Timothy L. Easun, Anna G. Slater
Non-thermal plasma synthesis offers efficient access to imine macrocycles.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Garden variety recycling

Indukanth Ragade gives you the know-how for this simple, time-tested way of recycling greywater




ycl

Immune-enhancing effect of Weizmannia coagulans BCG44 and its supernatant on cyclophosphamide-induced immunosuppressed mice and RAW264.7 cells via the modulation of the gut microbiota

Food Funct., 2024, 15,10679-10697
DOI: 10.1039/D4FO02452D, Paper
Open Access
Yafang Xu, Yi Wang, Tao Song, Xiaxia Li, Haolin Zhou, Oumarou Zafir Chaibou, Bing Wang, Huajun Li
W. coagulans BCG44 and its supernatant possess potential immunomodulatory activity and modulate gut microbiota dysbiosis in CTX-induced immunosuppression.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

ISRO satellites tracking cyclone Dana since October 20

ISRO says satellite inputs help in better monitoring and mitigation of cyclone threat




ycl

Get on the sunshine cycle

Neha Arora had the time of her life while on a holiday abroad and came back with vivid memories of that experience. She decided others must also be gifted such experiences to remember



  • Money & Careers

ycl

Mechanistic differences between the Ru(II) and Zn(II)-catalyzed cross-coupling of cyclopropenes with diazo compounds: a DFT study

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00995A, Paper
Tiantian Liu, Kang Lv, Xiaoguang Bao
A detailed computational study was performed to shed light on the mechanistic differences between the Ru(II) and Zn(II)-catalyzed cross-coupling of cyclopropenes with diazo compounds.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Cycloaddition of CO2 with epoxides into cyclic carbonates catalyzed by a binary organocatalyst under mild conditions

Catal. Sci. Technol., 2024, 14,6215-6223
DOI: 10.1039/D4CY00639A, Paper
Wen-Wang Yu, Xiang-Guang Meng, Zi-Yu Gan, Wen Li, Yu-Lian Zhang, Jie Zhou
Highly efficient capture and conversion of CO2 into cyclic carbonates from flue gas under atmospheric pressure.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

A metal-free route to substituted imidazolidines via ring-opening cyclization (ROC) of activated aziridines with N-benzylanilines: DA-COP catalyzed photo-oxidative C–H activation

Catal. Sci. Technol., 2024, 14,6411-6419
DOI: 10.1039/D4CY00808A, Paper
Manish Kumar, Bharat Singh, Sugandha Singh, Indresh Verma, Kamal K. Kar, Manas K. Ghorai
A metal-free, conjugated organic polymer (TPA-PQ)-catalyzed intramolecular C–H functionalization strategy for the synthesis of imidazolidines in the presence of light and O2 is reported.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Exploring the impact of abnormal coordination in macrocyclic N-heterocyclic carbene ligands on bio-inspired iron epoxidation catalysis

Catal. Sci. Technol., 2024, 14,6259-6269
DOI: 10.1039/D4CY00992D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Greta G. Zámbó, Carla A. Esslinger, Michael J. Sauer, Isabelle Rüter, Robert M. Reich, Serhiy Demeshko, Franc Meyer, Fritz E. Kühn
Macrocyclic and abnormal NHC iron complexes are characterised, showing high catalytic activity in epoxidation reaction and potential for ligand design.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Bis-thiourea and macrocyclic polyamines as binary organocatalysts for the ROP of lactide

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00952E, Paper
Open Access
Assunta D'Amato, Maria Voccia, Filippo Bruno, Sara D'Aniello, Lucia Caporaso, Francesco De Riccardis, Irene Izzo, Giorgio Della Sala, Mina Mazzeo
New binary catalysts formed by a bis-thiourea and a series of flexible polyaza-macrocycles are revealed to be efficient catalysts for the ring opening polymerization (ROP) of L-lactide.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Green Photocatalytic N-Debenzylations with Molecular Oxygen Catalyzed by Recyclable Metal-free Tubular Carbon Nitride

Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY00981A, Paper
Yufeng Wu, Jiajie Kang, Li Jianing, Mingshu Bi, Qingwei Meng
Debenzylations are widely used in fields such as pharmaceuticals and fine chemicals. In this study, metal-free tubular carbon nitride (CN-T) was prepared and used to the photocatalytic debenzylations with molecular...
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Heterogeneous oxidative upcycling of polystyrene plastics to benzoic acid under air conditions

Catal. Sci. Technol., 2024, 14,6584-6591
DOI: 10.1039/D4CY00970C, Paper
Chengyang Sun, Yong Guo, Xiaohui Liu, Yanqin Wang
A heterogeneous oxidative upcycling strategy converting polystyrene (PS) waste into benzoic acid.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Recyclable copper(I)-catalyzed cascade C–S and C–N bond formation between 2-iodoanilines and 2-bromobenzenethiols towards functionalized phenothiazines

Catal. Sci. Technol., 2024, 14,6561-6572
DOI: 10.1039/D4CY00888J, Paper
Yan Wang, Chengkai Luo, Li Wei, Mingzhong Cai
Heterogeneous copper-catalyzed heterocyclization between 2-iodoanilines and 2-bromothiophenols has been developed for the assembly of substituted phenothiazines.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Boron–pyridine nitrogen cooperative catalytic conversion of carbon dioxide and epoxides to cyclic carbonates

Catal. Sci. Technol., 2024, 14,6692-6700
DOI: 10.1039/D4CY01052C, Paper
Yu-Hui Luo, Sheng Tao, Fei Chen, Zhi-Hong Du, Hao Zhang, Min Li, Ning Liu
A type of N-heterocyclic carbene (NHC)-diboron adduct in combination with tetrabutylammonium iodide (TBAI) was used as a catalyst for the synthesis of cyclic carbonates from CO2 with epoxides.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

IBzH (IBenzhydryl): Sterically-Flexible N-Aliphatic N-Heterocyclic Carbenes (NHC) for Iron-Catalyzed C(sp3)–C(sp2) Cross-Coupling of Unactivated Haloalkanes

Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01315H, Communication
Marlena Kardela, Błażej Dziuk, Roman Szostak, Michal Szostak, Elwira Bisz
Iron-catalyzed cross-coupling has emerged as a pivotal concept for the synthesis of valuable products across various facets of chemical research, including pharmaceuticals, organic materials and biological probes. In this respect,...
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

N-Heterocyclic carbene-stabilized gold–copper nanoclusters: synthesis, bonding and mechanochromism

Nanoscale, 2024, 16,20228-20234
DOI: 10.1039/D4NR03320E, Paper
Dongjie Zuo, Huifang Guo, Qinghua Xu, Ayisha He, Zilin Li, Simin Li, Hui Shen
The first gold–copper alloy cluster protected by both NHC and alkyne ligands was reported. The cluster displays interesting mechanochromic properties, highlighting the bright future of NHC-functionalized metal nanoclusters in materials science.
The content of this RSS Feed (c) The Royal Society of Chemistry




ycl

Upcycled denim and occasion wear highlight  Lakme Fashion Week 2024

Upcycled denim, and creations with discarded material ruled the runway this year




ycl

Smartphone replacement cycle in India increased from 24 months to almost 36 months

The aspiration to own a good device without paying much is making the used smartphones a very attractive choice for consumers wanting to upgrade or even with first-time smartphone users




ycl

New ventures try again to recycle polystyrene

Start-ups link with plastic makers on new recycling techniques