The Slovak Republic is one of the most dynamic economies in the euro area. The country has continued to converge rapidly towards the living standards of advanced OECD economies. However, the Slovak Republic should continue on its path of reform to achieve balanced, fair and sustainable growth, according to a new OECD report.

The webinars enabled serious discussion on the concept of ‘local economic resilience’ in an informal setting that facilitates interaction and questions. The format featured presentations from policy experts and a roundtable discussion with the audience.

The webinars will enable serious discussion on the concept of ‘local economic resilience’ in an informal setting that facilitates interaction and questions. The format will feature presentations from policy experts and a roundtable discussion with the audience.

How are countries around the world helping youth stay in school, build skills and careers? What are they doing about youth unemployment? These case studies provide a starting point for those looking not only to learn about the problems facing youth today, but how to solve them.

The webinars enabled serious discussion on the concept of ‘local economic resilience’ in an informal setting that facilitates interaction and questions. The format featured presentations from policy experts and a roundtable discussion with the audience.

The webinars will enable serious discussion on the concept of ‘local economic resilience’ in an informal setting that facilitates interaction and questions. The format will feature presentations from policy experts and a roundtable discussion with the audience.

This seminar series is part of the OECD project, Supporting Decentralisation in Ukraine.

This new council act recommends that Member countries take steps to establish, as appropriate, implement and make publicly available a pollutant release and transfer register (PRTR) system using the principles and information set forth in the OECD Guidance Documents on PRTRs.

This document aims to assist government and industry assessors involved in the registration of microbial pesticides in the determination of whether microbial pesticides could be associated with known or as yet uncharacterised ‘new’ secondary metabolites. A background document that was also published as Annex to the main document aims to provide clarity on issues and terminology related to microbial secondary metabolites.

On 11 February 2019, the OECD organised a webinar to learn and discuss new methodologies on liver models for induction, clearance and toxicity. The speakers presented the benefits compared to existing methods in place, the types of chemicals tested, the results obtained, the transferability and economic aspects for routine testing, and any known limitation to the technologies and their applications.

Nanomaterials have unique physical and chemical features. OECD's Decision Framework and Guiding Principles tools fill data gaps in the hazard characterisation by identifying the most useful parameters and best available methods for a given type of nanomaterial.

The purpose of this document is to give guidance to Receiving Authorities on the evaluation of the GLP compliance status of nonclinical safety studies submitted for regulatory purposes. This guidance does not address the scientific evaluation and interpretation of the submitted data or the risk assessment based on these data.

On 27 September 2019, Anne Gourmelon of the Environment Directorate presented an overview of the various alternative test methods developed as OECD Test Guidelines and relevant guidance material to address eye irritation and serious eye damage for hazard classification of chemicals.

This document is intended to provide universal Guiding Principles that should be considered when developing or augmenting systematic approaches to Weight of Evidence (WoE) for chemical evaluation and Key Elements to formulating a systematic approach to WoE. The ultimate goal is to facilitate that regulators follow a consistent, clear and transparent delivery of evidence using the Principles and Elements described in this document.

Given that Series 1 E-Types - especially this model - are by far the most valuable, the cost associated with bringing the Jag back from the dead makes financial as well as sentimental sense.

There is cause for concern following the news that Love Island will not go ahead this summer as well as rumours circulating Strictly Come Dancing.

बीएमडब्ल्यू इंडिया (BMW INDIA) ने हाल ही में अपने भारतीय वेबसाईट में 8 सीरिज को शामिल किया था तथा इसके मॉडलों की झलक भी कम्पनी के प्लांट में देखने को मिली थी। अब भारत में एम8 कूपे व ग्रैन कूपे को

Director: Sahir RazaCast: Piyush Mishra, Neha Sharma, Akshay Oberoi, Satyadeep Mishra, Kubbra SaitAvailable On: Voot SelectDuration: 35 minutes/ 10 episodesLanguage: Hindi, English Story: Illegal is a courtroom drama, that explores the roles of media and politics in corruption crime and

Amidst the lockdown, when the whole world has come to a halt, Eros Now has come up with a unique concept for a one of a kind web series that starts streaming today on the platform.   A Viral Wedding is

BMW has launched its most luxurious models in the Indian market, the 8 Series Gran Coupe and the M8 Coupe. The new BMW 8 Series Gran Coupe is offered in two variants: 840i Gran Coupe and 840i Gran Coupe ‘M Sport' Edition.

The four-wheeler space in India has received new models at the higher and lower end of the pricing scale. The demand for performance variants of normal SUVs and hatchback have increased substantially. As a result, more manufacturers are either developing or

Director: Sahir RazaCast: Piyush Mishra, Neha Sharma, Akshay Oberoi, Satyadeep Mishra, Kubbra SaitAvailable On: Voot SelectDuration: 35 minutes/ 10 episodesLanguage: Hindi, English Story: Illegal is a courtroom drama, that explores the roles of media and politics in corruption crime and

Amidst the lockdown, when the whole world has come to a halt, Eros Now has come up with a unique concept for a one of a kind web series that starts streaming today on the platform.   A Viral Wedding is

Over the past couple of weeks, the PFTPM podcast has generated extended interviews with various team decision-makers in the wake of the 2020 draft. If you've missed them, here's your chance to catch up. Just click the link and click the accompanying videos to see (via Zoom) and hear from the likes of: Cowboys COO [more]

The synthesis and crystal structures of a series of 6-aryl­fuvlenes (fulvene is 5-methyl­idene­cyclo­penta-1,3-diene) with varying methyl­ation patterns on the 6-phenyl substituent are reported, namely 6-(3-methyl­phen­yl)-1,3-di­phenyl­fulvene (C25H20), 6-(4-methyl­phen­yl)-1,3-di­phenyl­fulvene (C25H20), 6-mesityl-3-di­phenyl­fulvene (C27H24) and 6-(2,3,4,5,6-penta­methyl­phen­yl)-1,3-di­phenyl­fulvene (C29H28). The bond lengths are typical of those observed in related fulvenes. A network of C—H⋯π ring inter­actions consolidates the packing in each structure.

Five new crystal structures of perfluoro­pyridine substituted in the 4-position with phen­oxy, 4-bromo­phen­oxy, naphthalen-2-yl­oxy, 6-bromo­naphthalen-2-yl­oxy, and 4,4'-biphen­oxy are reported, viz. 2,3,5,6-tetra­fluoro-4-phen­oxy­pyridine, C11H5F4NO (I), 4-(4-bromo­phen­oxy)-2,3,5,6-tetra­fluoro­pyridine, C11H4BrF4NO (II), 2,3,5,6-tetra­fluoro-4-[(naphthalen-2-yl)­oxy]pyridine, C15H7F4NO (III), 4-[(6-bromo­naphthalen-2-yl)­oxy]-2,3,5,6-tetra­fluoropyridine, C15H6BrF4NO (IV), and 2,2'-bis­[(perfluoro­pyridin-4-yl)­oxy]-1,1'-biphenyl, C22H8F8N2O2 (V). The dihedral angles between the aromatic ring systems in I–IV are 78.74 (8), 56.35 (8), 74.30 (7), and 64.34 (19)°, respectively. The complete mol­ecule of V is generated by a crystallographic twofold axis: the dihedral angle between the pyridine ring and adjacent phenyl ring is 80.89 (5)° and the equivalent angle between the biphenyl rings is 27.30 (5)°. In each crystal, the packing is driven by C—H⋯F inter­actions, along with a variety of C—F⋯π, C—H⋯π, C—Br⋯N, C—H⋯N, and C—Br⋯π contacts. Hirshfeld surface analysis was conducted to aid in the visualization of these various influences on the packing.

Charge-assisted hydrogen bonding plays a significant role in the crystal structures of solvates of ionic com­pounds, especially when the cation or cations are primary ammonium salts. We report the crystal structures of four ammonium salts of molybdenum halide cluster solvates where we observe significant hydrogen bonding between the solvent molecules and cations. The crystal structures of bis­(anilinium) octa-μ3-chlorido-hexa­chlorido-octa­hedro-hexa­molybdate N,N-di­­methyl­formamide tetra­solvate, (C6H8N)2[Mo6Cl8Cl6]·4C3H7NO, (I), p-phenyl­enedi­ammonium octa-μ3-chlorido-hexa­chlorido-octa­hedro-hexa­mol­yb­date N,N-di­methyl­formamide hexa­solvate, (C6H10N2)[Mo6Cl8Cl6]·6C3H7NO, (II), N,N'-(1,4-phenyl­ene)bis­(propan-2-iminium) octa-μ3-chlorido-hexa­chlo­rido-octa­hedro-hexa­molybdate acetone tris­olvate, (C12H18N2)[Mo6Cl8Cl6]·3C3H6O, (III), and 1,1'-dimethyl-4,4'-bipyridinium octa-μ3-chlo­rido-hexa­chlorido-octa­hedro-hexa­molybdate N,N-di­methyl­formamide tetra­solvate, (C12H14N2)[Mo6Cl8Cl6]·4C3H7NO, (IV), are reported and described. In (I), the anilinium cations and N,N-di­methyl­formamide (DMF) solvent mol­ecules form a cyclic R42(8) hydrogen-bonded motif centered on a crystallographic inversion center with an additional DMF mol­ecule forming a D(2) inter­action. The p-phenyl­enedi­ammonium cation in (II) forms three D(2) inter­actions between the three N—H bonds and three independent N,N-di­methyl­formamide mol­ecules. The dication in (III) is a protonated Schiff base solvated by acetone mol­ecules. Compound (IV) contains a methyl viologen dication with N,N-di­methyl­formamide mol­ecules forming close contacts with both aromatic and methyl H atoms.

Herein the nucleation pathway of conformational polymorphs was revealed by studying the relationships and distinctions among a series of α,ω-alkanedicarboxylic acids [HOOC–(CH2)n−2–COOH, named DAn, where n = 5, 7, 9, 11, 13, 15] in the solid state and in solution. Their polymorphic outcomes, with the exception of DA5, show solvent dependence: form I with conformation I crystallizes from solvents with hydrogen-bond donating (HBD) ability, whereas form II with conformation II crystallizes preferentially from solvents with no HBD ability. In contrast, form II of DA5 does not crystallize in any of the solvents used. Quantum mechanical computation showed that there is no direct conformational link between the solvents and the resultant polymorphic outcomes. Surprisingly, solute aggregates were found in no-HBD solvents by Fourier transform infrared spectroscopy, and only monomers could be detected in HBD solvents, suggesting stronger solvation. Furthermore, it was found that all six compounds including DA5 followed the same pattern in solution. Moreover, crystal-packing efficiency calculations and stability tests stated that dimorphs of DA5 bear a greater stability difference than others. These suggest that the rearrangement from conformation II to I could not be limited by hard desolvation in HBD solvents, where form I was also obtained. In other systems, metastable II was produced in the same solvents, probably as a result of the rearrangement being limited by hard desolvation. In this work, a comparative study uncovers the proposed nucleation pathway: difficulty in desolvation has a remarkable effect on the result of rearrangement and nucleation outcome.

Smithsonian Tropical Research Institute community ecologist Sunshine Van Bael primarily examines the relationship between leaf cutter ants–the world’s first farmers–and the fungi that they cultivate.

The post New online video series to feature Tropical Research Institute scientists appeared first on Smithsonian Insider.

Office of Public Affairs videographers Johnny Gibbons and Brian Ireley recently headed down to the Punta Culebra Nature Center on the edge of Panama City […]

The post New online video series to feature Tropical Research Institute scientists appeared first on Smithsonian Insider.

There’s something exciting and strange about having an idea. It can come suddenly. Unexpectedly. Randomly. Intensely. Ideas can uninvitingly appear full-forced and bright—like the cliché […]

The post Making the Smithsonian’s New “Sidedoor” podcast series a reality appeared first on Smithsonian Insider.

Smithsonian Institution Libraries has recently acquired a rare first edition of Darwin's Geological Observations on the Volcanic Islands, Visited During the Voyage of the H.M.S. Beagle.

The post With 1844 first edition, Smithsonian Libraries completes its collection of Charles Darwin’s three-volume geology series appeared first on Smithsonian Insider.

In the first reported crystal structure involving the potential ligand N,N',N''-tris­(2-pyridin­yl)-1,3,5-benzene­tricarboxamide, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules via their amide groups into slanted ladder-like chains. Only two of the three amide groups in the mol­ecule are involved in hydrogen bonding, which influences the degree of out-of-plane twisting at each amide group.

In the first reported crystal structure involving the potential ligand N,N',N''-tris(pyridin-2-yl)benzene-1,3,5-tricarboxamide, C24H18N6O3, intermolecular N—H...O hydrogen bonds link the molecules via their amide groups into slanted ladder-like chains, in which the uprights of the ladder are formed by the hydrogen-bonding interactions and the benzene ring cores of the molecules act as the rungs of the ladder. Only two of the three amide groups in the molecule are involved in hydrogen bonding and this influences the degree of out-of-plane twisting at each amide group, with the twist being more significant for those amide groups participating in hydrogen bonds.

Director Michael Apted (L) with Larry Mantle in the AirTalk studio.

This past Wednesday on "AirTalk," film director Michael Apted came in to talk with us about his eighth documentary in the series that's followed the lives of 13 people, beginning in 1964 when the kids were seven.  They've shared their stories with Apted every seven years, and he's clearly invested a lot of emotion into this project.

"56 Up" is wonderful for how it shows the mid-life evolution of the participants.  Apted includes scenes from earlier interviews, so that we see what aspects of today's 56-year-olds were present in childhood and what turns their lives have made over these years. 

"56 Up" is showing at the Nuart in West Los Angeles, and Apted will be doing Q-and-A at some of the screenings.

This content is from Southern California Public Radio. View the original story at SCPR.org.

The last two decades have seen a series of new construction waste policies management in Hong Kong. One of the most significant is an offsite construction waste sorting (CWS) programme which, since its implementation in 2006, has separated 5.11 million tonnes of construction waste into different materials. The researchers suggest that the study provides an important reference for other countries working to minimise construction waste.

The post Flying car race series attracts investment appeared first on The Lead SA.

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Prof Subra Suresh, a Distinguished University Professor and President of NTU Singapore, was honoured by his alma mater, the Indian Institute of Technology Madras, which launched the Prof Subra Suresh Institute Lecture Series....

Finally, it appears that the networks' love affair with the Palin family is coming to a merciful end.

Former governor hopes new show will inspire young women to get out and enjoy the great outdoors.

LivingHomes once again teams up with manufactured home heavyweight Cavco for a trio of low-ish-cost, high-quality green prefabs that have nothing to do with Mar

Photographer Elena Shumilova creates timeless images of childhood that touch people all around the world.

In less than 2 minutes a day, you'll learn 101 (no, make that 202) things about Philadelphia that the tourism company wishes you knew.