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Morphology-dependent Li+ ion dynamics in X-ray amorphous and crystalline Li3PS4 prepared by solvent-assisted synthesis

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02636E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jonas Spychala, Christoph Mandl, Katharina Hogrefe, H. Martin R. Wilkening, Bernhard Gadermaier
Ionic conductivity of Li3PS4 if synthesized by a solvent-assisted method strongly depends on overall and surface morphology. Amorphous Li3PS4 shows a rather high conductivity which is only slightly enhanced when going to the (nano-)crystalline form.
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Highly selective organo-gallium hydroxamate mediated inhibition of antibiotic resistant Klebsiella pneumoniae

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02440K, Paper
Rebekah N. Duffin, Jenisi Kelderman, Megan Herdman, Philip Craig Andrews
Five complexes of gallium derived from hydroxamic acids have been synthesised, characterised, and their anti-bacterial activity and mammalian cell toxicity established. These are three metal-organic complexes; [Ga(BPHA]3 1, [Ga(BHA-H]3 2,...
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Heavy fog affects 21 flights at Kempegowda International Airport in Devanahalli in Bengaluru

There were more than 15 delays, and six flights diverted




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People have seen our work... Devendra Fadnavis exudes confidence in Mahayuti alliance retaining power in Maharashtra




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L&T, E2E Network form alliance for deployment of Gen AI solutions in India

“The partnership is a significant step towards adoption of GenAI solutions in India to foster a fundamental shift in the way Accelerated Computing on Cloud is used by Indian organisations,” the companies said




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China's economy grew 4.6% in July-September quarter, falling short of 5% target

The latest data show the world's second largest economy slowing from 4.7% annual growth in the previous quarter and falling short of the official target of “about 5%” growth for 2024,




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It is an illusion to say that the DMK alliance looks stronger: Palaniswami

Asserting that “the ground realities are different”, AIADMK general secretary Edappadi K. Palaniswami said “we will emerge victorious with the support of the people”



  • Lok Sabha Elections

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BJP can’t be trusted, its manifesto is just a pack of lies: Mallikarjun Kharge

Criticising the Modi-led government for its failure to fulfil past poll promises such as providing two crore jobs annually and doubling the income of farmers, the Congress chief says the BJP’s manifesto is silent on issues such as rising food prices and unemployment; he also asserts the INDIA bloc’s main aim is to safeguard the Constitution and democracy



  • Lok Sabha Elections

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Eknath Shinde interview | ‘Our candidates are very good, and we have good coordination among allies’

The Maharashtra Chief Minister says industry was spooked after a bomb was placed outside Mukesh Ambani’s home during previous MVA regime’s tenure; adds that Uddhav Thackeray’s betrayal of Shiv Sena ideology will not win him sympathy



  • Lok Sabha Elections

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De-templated crystallization in 2D perovskites for enhanced photovoltaic efficiency

Energy Environ. Sci., 2024, 17,8284-8292
DOI: 10.1039/D4EE03272A, Paper
Fang Zeng, Zhenhuang Su, Weiyu Kong, Feng Li, Yuhang Liang, Xingmo Zhang, Tao Wang, Lin Zhang, Yuze Lvtao, Runkai Liu, Xingyu Gao, Jun Huang, Xudong Yang, Rongkun Zheng
A de-templated crystallization strategy using a stable intermediate to promote out-of-plane crystallization of layered 2D perovskites was proposed, in favor of highly efficient and stable perovskite solar cells.
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Quantitatively detecting and characterizing metallic lithium in lithium-based batteries

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03468F, Review Article
Zhi Zheng, Xue Fang, Wei Deng, Peng Li, Xiaobo Zheng, Hang Zhang, Lin Li, Shulei Chou, Yuan Chen, Yongbing Tang, Jiazhao Wang
Quantitative detection and characterization methods for analysis of metallic Li and related inactive components of Li batteries and their related characteristics are discussed.
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Regulating the Crystallization of Mixed-Halide Perovskites by Cation Alloying for Perovskite-Organic Tandem Solar Cells

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03045A, Paper
Mingqian Chen, Yanxun Li, Zixin Zeng, Ming Liu, Tao Du, Xiaofeng Huang, Leyu Bi, Jiarong Wang, Wenlin Jiang, Yidan An, Sai Wing Tsang, Jun Yin, Shengfan Wu, Alex K. Y. Jen
Halide segregation and energy loss pose significant challenges for wide-bandgap perovskite solar cells, impairing their photovoltage and device stability. These issues are often exacerbated by inferior film quality and inhomogeneous...
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Self-assembled porous salt crystals for solar-powered crystallization

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04741A, Paper
Jie Yu, Lenan Zhang, Jintong Gao, Wenyu Han, Ruzhu Wang, Zhenyuan Xu
Thermally localized solar evaporation has been recognized as an efficient and suitable pathway for desalination and brine treatment. However, the annoying salt crystallization inside the porous evaporator brings challenges for...
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Calling out exploitative labour dynamics on platforms

India’s first nationwide digital strike that was organised by women gig workers is an attempt to mainstream their work issues




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Selective aerobic oxidative C–C bond cleavage using a high-entropy oxide-derived multimetallic catalyst

React. Chem. Eng., 2024, 9,967-973
DOI: 10.1039/D3RE00525A, Paper
Shaoyuan Guo, Xinli Tong, Jipeng Wang, Hang Tang
A stable and efficient high entropy catalyst is developed for the selective oxidative C–C bond cleavage in the presence of O2.
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Merging inline crystallization and pulsed flow operation to enable enantiospecific solid state photodecarbonylation

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00058G, Paper
Open Access
Bavo Vandekerckhove, Bart Ruttens, Bert Metten, Christian V. Stevens, Thomas S. A. Heugebaert
Photoelimination of α-chiral ketones in the solid state results in highly regio- and enantiospecific C–C bond formation. By combining inline crystallisation and pulsatile flow, the photochemistry of these slurries can now be run fully continuously.
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Selective hydrogenation of 5-hydroxymethylfurfural to 2,5-bis(hydroxymethyl)furan over Ni–Ga intermetallic catalysts and its kinetic studies

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00129J, Paper
Weixiao Sun, Fuzeyu Zhong, Xiaohu Ge, Wenyao Chen, Gang Qian, Yueqiang Cao, Xuezhi Duan, Xinggui Zhou, Jing Zhang
5-Hydroxymethylfurfural (HMF) has been listed as the “TOP 14” most important biomass-derived platform molecules, which can be converted into 2,5-bis(hydroxymethyl)furan (BHF) via selective hydrogenation of the carbonyl group on HMF.
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India Cements’ Q2 loss widens on falling cement prices despite eased cost pressures

India Cements reports a sharp increase in its net loss to ₹240 crore




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Editorial. FMCG firms should look within for falling performance

FMCG multinationals seem to be hurt more by sector-specific disruptions that they have failed to foresee, than any economy-wide distress




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Karmma Calling Review

Despite its flaws, you can watch Karmma Calling if you like the glitz and drama of the ultra-rich, notes Mohnish Singh.




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Congress-led alliance conspiring with divisive elements in Muslim communities for electoral gains, alleges BJP

BJP’s Ravi Shankar Prasad accuses Muslim NGOs of raising support for Congress and its allies in Maharashtra, Jharkhand; says BJP will oppose any efforts to extend OBC, SC quota benefits to Muslims




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Remembering Suryakumari, the woman who immortalised ‘Ma Telugu Thalli ki’ with her voice

The neice of Tanguturi Prakasam Pantulu brought much popularity to the song written by Sankarambadi Sundarachari




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Goods train derails in Telangana's Peddapalli; 20 trains cancelled, 10 diverted

Eleven wagons of the goods train carrying iron ore derailed between Raghavapuram and Ramagundam





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What sending Jallikattu to the Oscars means

To an award show that's famous for honouring artists belatedly, we have sent as our official entry one of our major film-makers's weakest work yet, feels Sreehari Nair.




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Oscar nod or not, Jallikattu's selection is a win-win

The Oscars is prestigious and all artists covet it but ultimately, the business of winning is ruthless and political. And India has seldom risen to the challenge, argues Sukanya Verma.




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Look, who's calling the shots!

An inspiring story of three women who've taken advantage of changing technology and attitudes to occupy top corporate jobs




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Allied Digital Services Ltd. - Board Meeting Intimation for Approval Of Un-Audited Standalone And Consolidated Financial Results Of The Company.




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Omni Axs Software Ltd. - Board Meeting Intimation for Notice Calling The Board Meeting For The Consideration Of Unaudited Financial Results For The Quarter Ended June 30, 2019




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Synergy of Ag and Pd in bimetallic catalysts for the selective oxidation of 5-(hydroxymethyl)furfural

Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01028K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Dominik Neukum, Maya Eyleen Ludwig, Georgios Uzunidis, Ajai Raj Lakshmi Nilayam, Baerbel Krause, Silke Behrens, Jan-Dierk Grunwaldt, Erisa Saraçi
The synthesis of renewable bio-based monomers, like 2,5-furandicarboxylic acid (FDCA), is of high interest in the shift toward a circular economy. Bimetallic catalysts offer the variation of different properties, enabling...
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Single-step in situ synthesis of bimetallic catalysts via a gas-phase route: the case of PdZn–ZnO

Catal. Sci. Technol., 2024, 14,6321-6330
DOI: 10.1039/D4CY00807C, Paper
Andrija Kokanović, Dunja Pupavac, Stéphane Chenot, Stéphane Guilet, Igor M. Opsenica, Slavica Stankic
In this study, we explore the catalytic activity of highly pure PdZn–ZnO nanopowder, synthesized via an innovative metal–organic chemical vapor synthesis (MOCVS) method.
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Effect of metal loading sequences in CO2 methanation activity on samarium-doped ceria supported bimetallic catalysts

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01007H, Paper
Andrew C. Chien, Corinna C. Chi
The La/Ni/SDC catalyst from one pot microwave-heating gives higher methanation activity than La–Ni/SDC and Ni–La/SDC from stepwise heating.
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Deciphering the role of chemisorbed CO in CO2 methanation: kinetic and mechanistic investigation over monometallic (Ru) and bimetallic (Ru–Ni) catalysts

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01004C, Paper
Pavan Dongapure, Jyoti Tekawadia, V. Satyam Naidu, R. Nandini Devi
Supported metal catalysts have made prominent contributions to CO2 mitigation through conversion into useful chemicals.
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Active site engineering of intermetallic nanoparticles by the vapour–solid synthesis: carbon black supported nickel tellurides for hydrogen evolution

Nanoscale, 2024, 16,20168-20181
DOI: 10.1039/D4NR03397C, Paper
Open Access
Daniel Garstenauer, Patrick Guggenberger, Ondřej Zobač, Franz Jirsa, Klaus W. Richter
The intermetallic phases Ni3Te2, NiTe, NiTe2−x & NiTe2 were synthesized as carbon-black supported nanoparticles using the vapour–solid synthesis approach and were characterized for their performance in electrocatalytic hydrogen evolution.
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Dual metal centers within a water-stable Co/Ni bimetallic metal-triazolate framework contribute to durable photocatalysis for water treatment

Nanoscale, 2024, 16,20082-20088
DOI: 10.1039/D4NR03940H, Communication
Minling Zheng, Yubo Liu, Qifu Zhang, Wenjing Li, Yong Zhang, Guangxue Feng, Yating Hu, Shaoming Huang
A bimetallic CoNi-MET with fixed metal occupancy combines the strong water resistance of Co-MET with the high porosity of a Ni-MET.
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Exploring size-dependent optical property alterations in fine-tuning intermetallic PdCd nanocube sizes

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03640A, Paper
Jia-Lin Li, Ting-Yu Tien, Hung-Chun Liao, Hsin-Lun Wu
Size-tuned intermetallic PdCd nanocubes, synthesized via a quantum dot-like method, reveal novel size-dependent optical properties.
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HKUST-1 MOF Nanoparticles: Non-classical Crystallization Route in Supercritical CO2

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03070B, Communication
Ji Feng, Almond Lau, Igor V. Novosselov
Reducing MOF particles to the nanoscale size range is beneficial due to their increased surface-to-volume ratio, higher defects exposing metals and ligands, and short diffusion path. While great efforts have...
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Mixed phase Ti3+-rich TiO2 thin films by oxide defect engineered crystallization

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03545C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lauri Palmolahti, Harri Ali-Löytty, Markku Hannula, Tuomas Tinus, Kalle Lehtola, Antti Tukiainen, Jarno Reuna, Mika Valden
Amorphous TiO2 has insufficient chemical stability that can be enhanced with annealing induced crystallization. However, the crystalline structure is already predetermined by the defect composition of the amorphous phase. In...
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Preceramic polymer hybridized phenolic aerogels and the derived ZrC/SiC/C ceramic aerogels with ultrafine nanocrystallines

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03470H, Paper
Ding Nie, Hangyu Zhong, Hongli Hu, Zhenhua Luo, Boxing Zhang
Phenolic and carbon aerogels have important applications for thermal insulation and ablative resistance materials in aerospace areas. However, their antioxidant ability in long-term and high-temperature aerobic environments is facing serious...
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Electrical transport phenomena in two-dimensional metallic 2H-NbSe2: an experimental and theoretical study

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03369H, Paper
Jeongmin Kim, Seonhye Youn, Damin Lee, Chan Woong Kim, Hongjae Moon, Seok-Hwan Chung, Hoyoung Kim, Dong Hwan Kim, Sumin Kim, Jong Wook Roh, Joonho Bang, Wooyoung Lee
Two-dimensional (2D) metallic transition metal dichalcogenides (TMDCs) have attracted extensive interest in various fields owing to their unique electronic properties.
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Constructing Nickel Complex/Crystalline Carbon Nitride Hybrid with a Built-in Electric Field for Boosting CO2 Photoreduction

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03586K, Paper
Yanrui Li, Linda Wang, Bo Zhan, Liangqing Zhang, Xiaolin Zhu, Xiang Gao
Sluggish charge separation dynamics resulting from the amorphous structure and the lack of driving force for graphitic carbon nitride (GCN) limits its highly effective CO2 photoreduction performance. Herein, a built-in...
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Discover your calling

Uncertain about your career options? Low on self-confidence? This career counselling column may help




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Career as an allied health professional

Allied health professionals are the crucial link between medical professionals and patients and encompass a diverse array of roles within healthcare




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Andhra CM Chandrabu Naidu to virtually lay stone for 220KV sub-station in Anakapalli district




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Need to acquire technical knowledge to handle cybercrime cases, says Anakapalli SP




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Anakapalli police create 30-member SWAT team to provide help during natural calamities and industrial accidents

Anakapalli SP urges the personnel to upgrade their skills to perform better at the valedictory of training programme




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Will film on Jallikattu protests be released?

'The biggest agitation in Tamil Nadu -- after the anti-Hindi agitation in 1965 -- were the Jallikattu protests. The anti-Hindi agitations had the backing of a political party but this one does not. No famous actor is involved in it either. It was an incredible agitation.'




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Chennai| Thamalli, a newly launched bespoke jewellery brand features rare gemstones from around the world

Young entrepreneur Adithi Ganeshan speaks about her newly launched jewellery brand Thamalli, the design process, and working with rare gemstones



  • Life & Style

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Allies turn more saffron than BJP; DMK turns to Lord Murugan




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Trump turns to allies on capitol hill to fill top cabinet posts

Trump will also reach into the the Senate, with the expected appointment of Marco Rubio of Florida as secretary of State, according to a person familiar with the matter