gen Selective syntheses of homoleptic Ir(III) complexes bearing di-CF3-functionalized benzoimidazol-2-ylidenes for generation of blue phosphorescence By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2413-2426DOI: 10.1039/D4QI00454J, Research Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jie Yan, Yi Pan, I-Che Peng, Wen-Yi Hung, Bingjie Hu, Guowei Ni, Shek-Man Yiu, Yun Chi, Kai Chung LauDi-CF3-functionalized benzo[d]imidazol-3-ium pro-chelates were employed in the selective syntheses of fac-coordinated Ir(III) carbene emitters for efficient blue electroluminescence and hyperphosphorescence.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Ultrathin 2D–2D NiFe LDH/MOF heterojunction nanosheets: an efficient oxygen evolution reaction catalyst for water oxidation By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2489-2497DOI: 10.1039/D4QI00090K, Research ArticleHaoran Yin, Shibiao Su, Di Yao, Lixia Wang, Xinqiang Liu, Tayirjan Taylor Isimjan, Xiulin Yang, Dandan CaiAn ultrathin NiFe LDH/MOF catalyst is grown on carbon paper by an in situ self-dissociation–assembly strategy. Studies reveal that the strong electronic interaction between Fe and Ni species with rich active sites results in good OER and OWS performance.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Electrochemical frontiers in the nitrogen cycle By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2202-2204DOI: 10.1039/D4QI90016B, EditorialXuping Sun, Jieshan Qiu, Chenghua SunXuping Sun, Jieshan Qiu and Chenghua Sun introduce this Inorganic Chemistry Frontiers themed collection on nitrogen cycle electrocatalysis.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen New Ultraviolet Transparent Rare-Earth Borates with Enhanced Birefringence Induced by Cation Chemical Substitution By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI00840E, Research ArticleGuanglian Sun, xiaofang Qi, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng WuBirefringence determined by optical anisotropy is one of the most pivotal and fundamental performance of optical materials. However, optimizing the birefringence remains a significant challenge. Herein, a simple and effective...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Electrodeposited Superaerophobic Nickel Catalyst on Pencil-Drawn Paper: A Novel Approach for Highly Efficient and Stable Hydrogen Evolution By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI00101J, Research ArticleQian Sun, Xiaoyu Hao, Tianyi Zhang, Zelin Ma, Kui Hu, Ming Yang, Xiaolei Huang, Xuqing LiuElectrocatalytic water splitting stands at the forefront of advancing renewable energy technologies. A critical challenge in this realm is the detrimental effect of gas bubble adhesion on electrode surfaces, which...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Efficient photocatalytic hydrogen evolution of g-C3N4/Vs-SnS2/CdS through a sulfur vacancy-rich SnS2 induced charge storage effect By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00602J, Research ArticleFangyuan Xing, Junyan Li, Chengzhi Wang, Shaohua Jin, Haibo Jin, Jingbo LiPhotocatalytic hydrogen production using semiconductors is one of the most promising routes for sustainable energy production.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Homochiral Dy2 single-molecule magnets with strong magneto-optical Faraday effect and strong third-harmonic generation By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI00691G, Research ArticleCai-Ming Liu, Rong Sun, Xiang Hao, Xi-Li Li, Bingwu WangFour pairs of homochiral Dy2 complexes were directionally prepared using homochiral β-diketone ligands {D-Htfc/L-Htfc = (+)/(−)-3-trifluoroacetyl camphor, D-Hpfc/L-Hpfc = 3-(perfluorobutyryl)-(+)/(−)-camphor} and hydrazone Schiff base bridging ligands {H2L1 = (E)-N'-(2-hydroxy-3-methoxybenzylidene)pyrazine-2-carbohydrazide, H2L2...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Post-synthetic modification of a covalent organic framework via a thiol–ene reaction for improving fluorescence detection and removal of cationic crystal violet carcinogenic dye By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00419A, Research ArticleKe Li, Bing YanBased on a thiol–ene reaction, a covalent organic framework containing olefins (COF-A) is modified with 2-mercaptoacetic acid to prepare COF-S-COOH for the first time, which greatly improves the sensing and adsorption capacity for crystal violet.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Enhanced photocatalytic CO2 reduction by controlled oxygen vacancy generation and co-constructed heterojunction strategy for Pd/CeO2 By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00581C, Research ArticleFanlin Kong, Xiaoyan Lu, Jing Xie, Zhenjiang Lu, Jindou Hu, Yali CaoRational control of Vo concentration and the construction of a heterojunction strategy enable Pd/CeO2-Vo(r) to exhibit excellent photocatalytic CO2RR activity. The presence of COOH* creates favorable conditions for CO formation and desorption.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Incorporation of One-Dimensional Electron-Rich Chain in Viologen-based Coordination Polymers for Super Photochromic Properties and Improved Optical Applications in Polyvinyl Alcohol Film By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI00200H, Research ArticleYong-Sheng Shi, Tong Xiao, Dong-Dong Yang, Xiangjun ZhengA viologen derivative- and a carboxylic acid -based one-dimensional (1D) cocrystal Zn(Ⅱ) coordination polymer, {[Zn(bcbpy)2][Zn(sip)Cl]·4H2O}n (1, bcbpy = 1,1'-bis (3-carboxybenzyl)-4,4'-bipyridinium, sip = 5-Sulfoisophthalate) has been produced solvothermally and structurally characterized....The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Yolk-Shell type Carbon-Silica Nanoarchitecture Dispersed and Stabilized Ru Nanoparticles for Enhanced Hydrogenation of Aromatic Compounds By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI00553H, Research ArticleLu Yan, Yue Shen, Zidan Zou, Xiao Zhang, Zhixin Yu, Guozhong Wang, Chun ChenHydrogenation of aromatic rings can be used not only for synthesis fine chemicals, but also for hydrogen storage and transportation using organic hydride. In this paper, yolk-shell structural SiO2@Ru@NC catalyst,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Unleashing the power of directed electron transfer: unraveling the potential of {PV4}2 in heterogeneous photocatalysis By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00606B, Research ArticleXin Su, Yuzan He, Kunhong Li, Miao Wang, Wei Tang, Shihao Zhang, Pengtao Ma, Jingyang Niu, Jingping Wang{PV4}2 unleash the power of directed electron transfer in heterogeneous photocatalysis reduction.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Application of changing the valence state of metals through the reaction time for efficient oxygen evolution reaction By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00522H, Research ArticleMing Chen, Sha Luo, Zongyan Ma, Fei Yuan, Jing Chen, Linkun Dong, Weiwen Mao, Jiantai MaIn this study, a novel FeNi sulfide catalyst loaded on carbon nanotubes (CNTs) (FeNiS/CNTs) shows excellent OER electrocatalytic performance in alkaline solutions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Solar heating catalytic formic acid dehydrogenation by graphene-porous foam-supported tungsten nitride nanoparticles By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00590B, Research ArticleJiarong Chang, Tianhua Hao, Cuncai Lv, Maoyu Xu, Deyi Zhang, Linjie Gao, Shangbo Ning, Yaguang Li, Jinhua YeWN/Gr PF exhibits significant solar heating catalytic formic acid dehydrogenation and the rate exceeds those of other reported photocatalysts.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen NaVSeO5: Synergistic Combinations to Excellent Birefringent Materials By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI00513A, Research ArticleQiuyuan Feng, Jialong Wang, Changyou Liu, Qun Jing, Xiaoyu DongThe novel NaVSeO5 birefringent crystals were successfully synthesized using a multifunctional group synergistic strategy, which combines a two-dimensional layered structure, consisting of stereochemically active lone pairs [SeO3], and anomalous [VO6]...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Shift toward EVs could disrupt global oil market: International Energy Agency report By www.thehindubusinessline.com Published On :: Wed, 16 Oct 2024 10:09:02 +0530 As China's rapid switch to electricity plays a significant role in disrupting the oil market, oil companies find they can sell more of their product to India Full Article Commodities
gen Weather experts divided over emergence of La Nina By www.thehindubusinessline.com Published On :: Wed, 23 Oct 2024 09:00:00 +0530 APEC Climate Centre predicts the weather event from December Full Article Agri Business
gen Gen AI: Pharma’s new frontier By www.thehindubusinessline.com Published On :: Mon, 04 Mar 2024 08:00:00 +0530 From clinical trials to cures, AI is set to transform lives faster with underutilized health data Full Article Pulse
gen The rising global tide of genomics for public health By www.thehindubusinessline.com Published On :: Sun, 14 Apr 2024 19:05:12 +0530 Genomics is advancing our understanding of the genetic basis of health and disease and shaping strategies to promote population health. Full Article Pulse
gen Syngenta signs MoUs with CSSRI and HAU on crop productivity, sustainable agriculture By www.thehindubusinessline.com Published On :: Wed, 30 Oct 2024 08:53:21 +0530 MoUs aim to implement projects related to capacity building of rural youth in agriculture and allied sciences, safe use of crop protection chemicals and adoption of new technologies, among other things Full Article Agri Business
gen Icrisat DG to take over as WAF Secretary General By www.thehindubusinessline.com Published On :: Fri, 01 Nov 2024 17:59:00 +0530 Jacqueline d’Arros Hughes transitions from Icrisat to World Agriculture Forum, succeeded by Himanshu Pathak in Hyderabad Full Article Agri Business
gen World experienced its second-warmest October last month, says European weather agency By www.thehindubusinessline.com Published On :: Thu, 07 Nov 2024 17:18:28 +0530 2024 “certain” to be the warmest year on record, says Copernicus Climate Change Service Full Article Agri Business
gen Tech Mahindra partners with OxygenForIndia to deploy 3,000 oxygen concentrators and 40,000 oxygen cylinders By www.thehindubusinessline.com Published On :: Mon, 17 May 2021 14:41:37 +0530 The OxygenForIndia campaign is aimed at providing oxygen cylinders to those in need Full Article Announcements
gen PayPoint partners with Digit General Insurance for health insurance to rural areas By www.thehindubusinessline.com Published On :: Tue, 18 May 2021 13:44:12 +0530 The insurance covers pre-hospitalisation and post-hospitalization expenses along with road ambulance charges Full Article Announcements
gen Goldman Sachs invests in Aragen Life Sciences (GVK Bio) By www.thehindubusinessline.com Published On :: Thu, 20 May 2021 08:44:56 +0530 The company has invested more than $3.6 billion in capital since 2006 Full Article Announcements
gen Bridging two genres of music By www.thehindu.com Published On :: Thu, 03 Nov 2016 14:35:20 +0530 Sudha Ranjith hopes to make a mark as a classical singer and also keep singing for films. Full Article Music
gen A melange of genres By www.thehindu.com Published On :: Fri, 04 Nov 2016 14:59:36 +0530 Rang-Sangam brought different forms of dance and music on one stage. Full Article Friday Review
gen Gently flow the notes By www.thehindu.com Published On :: Wed, 09 Nov 2016 19:43:07 +0530 It’s Ustad Bismillah Khan’s birth centenary, and the shehnai is back in focus. The author talks about how the instrument has been an integral part of film music in the South Full Article Metroplus
gen Ghantasala: A legend in his lifetime By www.thehindu.com Published On :: Fri, 02 Dec 2022 12:26:47 +0530 Full Article Friday Review
gen AI agents can handle complex workflows more efficiently than traditional GenAI By www.newkerala.com Published On :: Tue, 12 Nov 2024 17:06:02 +0530 Full Article
gen AI agents can handle complex workflows more efficiently than traditional GenAI By www.newkerala.com Published On :: Tue, 12 Nov 2024 17:08:02 +0530 Full Article
gen Spotting d-band centers of single-atom catalysts by oxygen intermediate-boosted electrochemiluminescence By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18085-18092DOI: 10.1039/D4SC03763D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ruyu Xie, Kaitao Li, Rui Tian, Chao LuWe have proposed an oxygen intermediate-boosted electrochemiluminescence probe for rapid spotting of the d-band centers of single-atom catalysts: the d-band centers closer to the Fermi level contributed to higher luminol ECL intensities.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen A perspective on next-generation hyperfluorescent organic light-emitting diodes By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,17739-17759DOI: 10.1039/D4SC05489J, Perspective Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Upasana Deori, Gyana Prakash Nanda, Caroline Murawski, Pachaiyappan RajamalliThe evolution of next-generation HF-OLED technology and current challenges.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen A critical factor in reactive oxygen species (ROS) studies: the need to understand the chemistry of the solvent used: the case of DMSO By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,17843-17851DOI: 10.1039/D4SC05038J, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Shubham Bansal, Binghe WangReactive oxygen species (ROS) play critical roles in normal physiological processes including cellular signaling and immune responses.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Substituent effect in determining the total structure of an all-alkynyl-protected Ag98 nanocluster for methanol tolerant oxygen reduction reaction By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18161-18169DOI: 10.1039/D4SC04318A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xiaoqin Cui, Xuehuan Zhang, Ting Li, Sheng Zhu, Gaoyi Han, Huan LiA sterically demanding ortho-CF3 substituent defines not only the arrangement of ligands on a Ag98(2-CF3PhCC)48Cl4 nanocluster (Ag98) but also the inter-cluster interactions. Ag98 shows excellent methanol tolerance in the oxygen reduction reaction.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Enhancing hydrogen evolution reaction activity through defects and strain engineering in monolayer MoS2 By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18127-18134DOI: 10.1039/D4SC04874A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Renjith Nadarajan, Sraboni Dey, Arijit Kayal, Joy Mitra, Manikoth M. ShaijumonThe synergistic creation of vacancy defects, along with strain-induced active sites is shown to enhance hydrogen evolution reaction (HER) performance of CVD-grown monolayer MoS2.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen FragGen: towards 3D geometry reliable fragment-based molecular generation By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC04620J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Odin Zhang, Yufei Huang, Shichen Cheng, Mengyao Yu, Xujun Zhang, Haitao Lin, Yundian Zeng, Mingyang Wang, Zhenxing Wu, Huifeng Zhao, Zaixi Zhang, Chenqing Hua, Yu Kang, Sunliang Cui, Peichen Pan, Chang-Yu Hsieh, Tingjun HouFragGen introduces a novel fragment-based AI-based molecular design method. It proposes the geometry handling protocol to improve the generation quality and has been applied to design highly bioactive type II kinase inhibitors.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Double coordination shell modulation of nitrogen-free atomic manganese sites for enhancing oxygen reduction performance By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05998K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xue Bai, Yin Wang, Jingyi Han, Siyu Chen, Xiaodi Niu, Jingqi GuanUtilizing double coordination shell modulation, we construct a novel nitrogen-free single-atom manganese coordination configuration catalyst on graphene oxide (Mn–S1O4G), which exhibits excellent ORR and zinc–air battery performances.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Correction: Second-shell modulation on porphyrin-like Pt single atom catalysts for boosting oxygen reduction reaction By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC90219J, Correction Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Tayyaba Najam, Syed Shoaib Ahmad Shah, Hanqing Yin, Xin Xiao, Shamraiz Talib, Qianqian Ji, Yonggui Deng, Muhammad Sufyan Javed, Jie Hu, Ruo Zhao, Aijun Du, Xingke Cai, Qiang XuTo cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Selective lignin depolymerization via transfer hydrogenolysis using Pd/hydrotalcite catalysts: model compounds to whole biomass By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC03942D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Darren Dolan, Rebekah Brucato, Christopher William Reid, Adam F. Lee, Karen Wilson, Adelina M Voutchkova-KostalCleavage of lignin ether bonds via transfer hydrogenolysis is a promising route to valorize lignin, but processes that use mild reaction conditions and exploit renewable hydrogen donor solvents (rather than...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Phenacylselenoesters allow facile selenium transfer and hydrogen selenide generation By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05788K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Utsav Dey Sarkar, Mahima Rana, Harinath ChakrapaniA new series of phenacylselenoesters that generate hydrogen selenide in the presence of esterase and a biological thiol under ambient conditions is reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen A metabologenomics strategy for rapid discovery of polyketides derived from modular polyketide synthases By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC04174G, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Run-Zhou Liu, Zhihan Zhang, Min Li, Lihan ZhangA metabologenomics workflow using mass defect filtering (MDF) and bioinformatics-based structural prediction was established for rapid screening of modular polyketide natural products, and led to the identification of 22 polyketides.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen M12L24 nanospheres as supramolecular templates for the controlled synthesis of Ir-nanoclusters and their use in the chemo-selective hydrogenation of nitro styrene By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06324D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lotte L. Metz, Rens Ham, Eduard Bobylev, Kelly J. H. Brouwer, Alfons van Blaaderen, Rim van de Poll, Victor Drozhzhin, Emiel J. M. Hensen, Joost N. H. ReekControlled preparation of ultrafine metal nanoclusters (<2 nm) is challenging, yet important as the properties of these clusters are inherently linked to their size and local microenvironment. In the present...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Large second harmonic generation and birefringence from extended octupolar π-conjugated structures By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05756B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Danyang Dou, Bingbing Zhang, Daqing Yang, Ying WangBy adopting an extended octupolar π-conjugation strategy, two excellent optical functional materials with a strong SHG response and large birefringence were prepared.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Analysis of the cryptic biosynthetic gene cluster encoding the RiPP curacozole reveals a phenylalanine-specific peptide hydroxylase By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC02262A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Samantha Hollands, Julia Tasch, David J. Simon, Dimah Wassouf, Isobel Barber, Arne Gessner, Andreas Bechthold, David L. ZechelThe noncanonical biosynthesis of curacozole by Streptomyces curacoi is shown to be dependent on the bldA-encoded Leu-tRNAUUA. The minimal biosynthetic gene cluster is defined, and the functions of key biosynthetic enzymes are established in vitro.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Understanding ketone hydrogenation catalysis with anionic iridium(III) complexes: The crucial role of counterion and solvation By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04629C, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Paven Kisten, Sandrine Vincendeau, Eric Manoury, Jason Martin Lynam, John M. Slattery, Simon B Duckett, Agusti Lledos, Rinaldo PoliThe catalytic asymmetric hydrogenation of ketones reflect an important way to prepare valuable chiral alcohols. Understanding how transition metals promote these reactions is key to the rational design of more...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Simultaneous generation of hydroxyl and hydrogen radicals from H+/OH− pairs caused by water–solid contact electrification By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06227B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Fengjie Chen, Jingde Wu, Dou Wang, Yu Xia, Qingyuan Song, Ying Liang, Pu Wang, Bolei Chen, Yong Liang, Yongguang Yin, Yawei Wang, Maoyong Song, Guibin JiangWater–solid contact electrification is a common physical phenomenon involving interfacial electron and ion transfer, recently discovered to trigger unique redox reactions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Understanding the Formation of Nitrate from Nitrogen at the Interface of Gas-Water Microbubbles By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06989G, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sandeep Bose, Yu Xia, Richard N. ZareUnderstanding the Formation of Nitrate from Nitrogen at the Interface of Gas-Water MicrobubblesWater microbubbles containing Fe2+ ion has been found to efficiently transform nitrogen (N2) to nitrate (NO3-) by initiating...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Electrochemical reconstruction of metal–organic gels into crystalline oxy-hydroxide heterostructures for efficient oxygen evolution electrocatalysis By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05799F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kang Liu, Haikuo Lan, Yuting Chen, Weicheng Tang, Zhenyu Xiao, Yunmei Du, Jun Xing, Zexing Wu, Lei WangAn amorphous MOG electrochemically reconstitutes to a crystalline NiOOH/FeOOH heterostructure with the morphology changed from nanofibers to nanosheets as a high-performance OER electrocatalyst.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
gen Pnictogen-based vanadacyclobutadiene complexes By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05884D, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Mehrafshan G. Jafari, John B. Russell, Hwan Myung, Seongyeon Kwon, Patrick J. Carroll, Michael R. Gau, Mu-Hyun Baik, Daniel J. MindiolaThe reactivity of a [VV] alkylidyne with unsaturated substrates such as NCR (R = Ad or Ph) and PCAd leads to the formation of rare transition metal complexes featuring an α-aza-vanadacyclobutadiene and a β-phospha-vanadacyclobutadiene moieties.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
