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Prochem Introduces the Crew Chief


The Crew Chief is the center of the Prochem restoration product line. The built in advanced power management can balance the equipment which optimizes the job site drying conditions.




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Prochem’s Aqua Helix: Deep extraction in a portable tool

Prochem says that the tool’s advanced design speeds jobs and all at a cost that’s 75% less than a traditional ride-on extractor.




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Knit and Crochet Club

11/17/2024 - 1:30 PM - Venue: Rawlings Library





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University of Rochester investigates 'Wanted' posters accusing staff of Gaza war crimes

The posters, which appeared across campus, accuse university faculty of being complicit in war crimes against Palestinians in Gaza. The university president condemned the posters as antisemitic.




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Electrochemically dehydrogenative C(sp2)–H/S–H cross-coupling: efficient synthesis of ortho-aminophenyl thioglycoside derivatives

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00171K, Research Article
Li-Yan Hu, Li Zhu, Shen-Yuan Zhang, Yu-Xin Guo, Yuan Li, Jie Zhu, Lei Wu
A method has been reported for synthesizing aryl thioglycosides through direct electrocatalytic dehydrogenative C(sp2)–H/S–H cross-coupling.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Electrochemical switching in mechanically interlocked molecules (MIMs)

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00061G, Review Article
Ayush Bhadani, Murugavel Kathiresan
Mechanically interlocked molecules (MIMs) which include rotaxanes and catenanes are formed by the mechanical linking of two or more components and has the ability to switch between different states in the presence of an external stimuli.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Regioselective electrochemical cascade C–H sulfonylation–bromination of indolizines to access difunctionalized indolizines

Org. Chem. Front., 2024, 11,2306-2312
DOI: 10.1039/D4QO00035H, Research Article
Wenxuan Jiang, Xiang Liu, Chuanying Zhu, Meiyi Chen, Weidan Li, Hua Cao
Regioselective electrochemical C–H sulfonylation–bromination between indolizines, sodium sulfinates, and KBr has been established in an undivided cell, in which KBr serves as both the brominating agent and electrolyte.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Electrochemical remote C(sp3)–H thiocyanation

Org. Chem. Front., 2024, 11,2283-2288
DOI: 10.1039/D4QO00032C, Research Article
Xinyu Pang, Hui He, Xiangrui Meng, Linbao Zhang, Shaofei Ni, Ming Li, Weisi Guo
An electrochemical thiocyanation of distal C(sp3)–H bonds based on amidyl radical-mediated 1,5-HAT has been developed. The transformation is highly site-selective and compatible with primary, secondary, and tertiary sulfonamides, and bioactive derivatives.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Electrochemical nitrate reduction for ammonia production: amorphous or crystalline oxidized copper catalyst?

J. Mater. Chem. A, 2024, 12,8689-8693
DOI: 10.1039/D3TA07506K, Communication
Quanxiao Peng, Dandan Xing, Liuqi Dong, Yuhan Fu, Jixue Lu, Xiaoyu Wang, Changhong Wang, Chunxian Guo
An amorphous oxidized copper (a-O–Cu) is designed to investigate for electrochemical nitrate reduction to ammonia. It is found that a-O–Cu has high capability for water dissociation and amorphous structure-enabled high catalytic activity.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Development of diverse aluminium concentration gradient profiles in Ni-rich layered cathodes for enhanced electrochemical and thermal performances

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00433G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xinwei Jiao, Junwei Yap, Junbin Choi, Mengyuan Chen, Devendrasinh Darbar, Gongshin Qi, Xiaosong Huang, Jung-Hyun Kim
Nickel (Ni)-rich cathodes with elemental concentration gradients within particles have attracted great interest due to their considerably enhanced interfacial stability and electrochemical performance for advanced Li-ion batteries.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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In situ analysis of the oxygen evolution reaction on the CuO film in alkaline solution by surface interrogation scanning electrochemical microscopy: investigating active sites (CuIII) and kinetics

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00628C, Paper
Seokjun Han, Jinoh Yoo, Won Tae Choi
Surface interrogation scanning electrochemical microscopy was employed to assess the electrocatalytic activity of CuO films for the oxygen evolution reaction in an alkaline solution.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Plasticity tunable artificial synapses based on organic electrochemical transistors with aqueous electrolytes

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03569K, Paper
Ruhua Wu, Miao Xie, Yuhua Cheng, Dan Zhao, Liang-Wen Feng, Jianhua Chen, Wei Huang
By regulating ion transporting kinetics and ion diffusion distances in organic mixed ionic–electronic conductor channels, highly tunable short- and long-term plasticity are obtained in vOECTs with aqueous electrolytes.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of MOF-supported Pt catalyst with high electrochemical oxidation activity for methanol oxidation

RSC Adv., 2024, 14,36370-36377
DOI: 10.1039/D4RA06393G, Paper
Open Access
Merve Akin, Hatice Kars, Muhammed Bekmezci, Aysenur Aygun, Mert Gul, Guray Kaya, Fatih Sen
In this study, Pt and Pt@Ti-MOF NPs catalysts were synthesized by chemical reduction method. Ti-MOF structure was synthesized using the solvothermal method, and the effect of Ti-MOF on methanol oxidation was investigated.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Tuktut Nogait : rivières et roches

Rainbird, R. 1, 2020, 90 pages, https://doi.org/10.4095/326138
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/gid_326138.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/gid_326138.jpg" title=" 1, 2020, 90 pages, https://doi.org/10.4095/326138" height="150" border="1" /></a>




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Rochester, MN Author Publishes Poetry Collection

Life Is Something We All Go Through And Humanity Is Something We All Have.




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Yves-Rocher

Yves-Rocher Cosmetics




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Guest Co-Host Fr. Gabriel Rochelle

Fr. Evan welcomes Fr. Gabriel Rochelle to join him as co-host as they tackle questions together ranging from missions in the early Church compared to today, leavened bread in the Eucharist, and humility.






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A Somerville teen crocheted her prom dress in three days. Her video of the design process went viral.

Sarah Akinbuwa remembers the days when she was bullied over her love of crocheting, a hobby she picked up with her circle of schoolmates as a 12-year-old in Nigeria. Now living in Somerville and devoted to the craft, the 18-year-old is winning acclaim for one of her latest creations: a bright pink, floor-length prom dress […]

The post A Somerville teen crocheted her prom dress in three days. Her video of the design process went viral. appeared first on Boston.com.




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Why Garrett Crochet makes sense as a Red Sox trade target

With Garrett Crochet linked to the Red Sox as a potential trade candidate, John Tomase explains why the White Sox pitcher would be a great fit in Boston.




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Open-source electrochemical cell for in situ X-ray absorption spectroscopy in transmission and fluorescence modes

X-ray spectroscopy is a valuable technique for the study of many materials systems. Characterizing reactions in situ and operando can reveal complex reaction kinetics, which is crucial to understanding active site composition and reaction mechanisms. In this project, the design, fabrication and testing of an open-source and easy-to-fabricate electrochemical cell for in situ electrochemistry compatible with X-ray absorption spectroscopy in both transmission and fluorescence modes are accomplished via windows with large opening angles on both the upstream and downstream sides of the cell. Using a hobbyist computer numerical control machine and free 3D CAD software, anyone can make a reliable electrochemical cell using this design. Onion-like carbon nanoparticles, with a 1:3 iron-to-cobalt ratio, were drop-coated onto carbon paper for testing in situ X-ray absorption spectroscopy. Cyclic voltammetry of the carbon paper showed the expected behavior, with no increased ohmic drop, even in sandwiched cells. Chronoamperometry was used to apply 0.4 V versus reversible hydrogen electrode, with and without 15 min of oxygen purging to ensure that the electrochemical cell does not provide any artefacts due to gas purging. The XANES and EXAFS spectra showed no differences with and without oxygen, as expected at 0.4 V, without any artefacts due to gas purging. The development of this open-source electrochemical cell design allows for improved collection of in situ X-ray absorption spectroscopy data and enables researchers to perform both transmission and fluorescence simultaneously. It additionally addresses key practical considerations including gas purging, reduced ionic resistance and leak prevention.




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Electrochemical cell for synchrotron nuclear resonance techniques

Developing new materials for Li-ion and Na-ion batteries is a high priority in materials science. Such development always includes performance tests and scientific research. Synchrotron radiation techniques provide unique abilities to study batteries. Electrochemical cell design should be optimized for synchrotron studies without losing electrochemical performance. Such design should also be compatible with operando measurement, which is the most appropriate approach to study batteries and provides the most reliable results. The more experimental setups a cell can be adjusted for, the easier and faster the experiments are to carry out and the more reliable the results will be. This requires optimization of window materials and sizes, cell topology, pressure distribution on electrodes etc. to reach a higher efficiency of measurement without losing stability and reproducibility in electrochemical cycling. Here, we present a cell design optimized for nuclear resonance techniques, tested using nuclear forward scattering, synchrotron Mössbauer source and nuclear inelastic scattering.




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New copper carboxyl­ate pyrene dimers: synthesis, crystal structure, Hirshfeld surface analysis and electrochemical characterization

Two new copper dimers, namely, bis­(dimethyl sulfoxide)­tetra­kis­(μ-pyrene-1-carboxyl­ato)dicopper(Cu—Cu), [Cu2(C17H9O2)4(C2H6OS)2] or [Cu2(pyr-COO−)4(DMSO)2] (1), and bis­(di­methyl­formamide)­tetra­kis­(μ-pyrene-1-carboxyl­ato)dicopper(Cu—Cu), [Cu2(C17H9O2)4(C3H7NO)2] or [Cu2(pyr-COO−)4(DMF)2] (2) (pyr = pyrene), were synthesized from the reaction of pyrene-1-carb­oxy­lic acid, copper(II) nitrate and tri­ethyl­amine from solvents DMSO and DMF, respectively. While 1 crystallized in the space group Poverline{1}, the crystal structure of 2 is in space group P21/n. The Cu atoms have octa­hedral geometries, with four oxygen atoms from carboxyl­ate pyrene ligands occupying the equatorial positions, a solvent mol­ecule coordinating at one of the axial positions, and a Cu⋯Cu contact in the opposite position. The packing in the crystal structures exhibits π–π stacking inter­actions and short contacts through the solvent mol­ecules. The Hirshfeld surfaces and two-dimensional fingerprint plots were generated for both compounds to better understand the inter­molecular inter­actions and the contribution of heteroatoms from the solvent ligands to the crystal packing. In addition, a Cu2+/Cu1+ quasi-reversible redox process was identified for compound 2 using cyclic voltammetry that accounts for a diffusion-controlled electron-donation process to the Cu dimer.




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Crystal structure of a water oxidation catalyst solvate with composition (NH4)2[FeIV(L-6H)]·3CH3COOH (L = clathrochelate ligand)

The synthetic availability of mol­ecular water oxidation catalysts containing high-valent ions of 3d metals in the active site is a prerequisite to enabling photo- and electrochemical water splitting on a large scale. Herein, the synthesis and crystal structure of di­ammonium {μ-1,3,4,7,8,10,12,13,16,17,19,22-dodeca­aza­tetra­cyclo­[8.8.4.13,17.18,12]tetra­cosane-5,6,14,15,20,21-hexa­onato}ferrate(IV) acetic acid tris­olvate, (NH4)2[FeIV(C12H12N12O6)]·3CH3COOH or (NH4)2[FeIV(L–6H)]·3CH3COOH is reported. The FeIV ion is encapsulated by the macropolycyclic ligand, which can be described as a dodeca-aza-quadricyclic cage with two capping tri­aza­cyclo­hexane fragments making three five- and six six-membered alternating chelate rings with the central FeIV ion. The local coord­ination environment of FeIV is formed by six deprotonated hydrazide nitro­gen atoms, which stabilize the unusual oxidation state. The FeIV ion lies on a twofold rotation axis (multiplicity 4, Wyckoff letter e) of the space group C2/c. Its coordination geometry is inter­mediate between a trigonal prism (distortion angle φ = 0°) and an anti­prism (φ = 60°) with φ = 31.1°. The Fe—N bond lengths lie in the range 1.9376 (13)–1.9617 (13) Å, as expected for tetra­valent iron. Structure analysis revealed that three acetic acid mol­ecules additionally co-crystallize per one iron(IV) complex, and one of them is positionally disordered over four positions. In the crystal structure, the ammonium cations, complex dianions and acetic acid mol­ecules are inter­connected by an intricate system of hydrogen bonds, mainly via the oxamide oxygen atoms acting as acceptors.




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2-Cyano-2-iso­nitro­soacetamide–3,4-di­methylpyrazole (1/1): a co-crystal of two mol­ecules with agrochemical activities

In the structure of the title co-crystal, C3H3N3O2·C5H8N2, the components are linked by a set of directional O—H⋯N, N—H⋯O, N—H⋯N and C—H⋯O hydrogen bonds to yield a two-dimensional mono-periodic arrangement. The structure propagates in the third dimension by extensive π–π stacking inter­actions of nearly parallel mol­ecules of the two components, following an alternating sequence. The primary structure-defining inter­action is very strong oxime-OH donor to pyrazole-N acceptor hydrogen bond [O⋯N = 2.587 (2) Å], while the significance of weaker hydrogen bonds and π–π stacking inter­actions is comparable. The distinct structural roles of different kinds of inter­actions agree with the results of a Hirshfeld surface analysis and calculated inter­action energies. The title compound provides insights into co-crystals of active agrochemical mol­ecules and features the rational integration in one structure of a fungicide, C3H3N3O2, and a second active component, C5H8N2, known for alleviation the toxic effects of fungicides on plants. The material appears to be well suited for practical uses, being non-volatile, air-stable, water-soluble, but neither hygroscopic nor efflorescent.




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The AUREX cell: a versatile operando electrochemical cell for studying catalytic materials using X-ray diffraction, total scattering and X-ray absorption spectroscopy under working conditions

Understanding the structure–property relationship in electrocatalysts under working conditions is crucial for the rational design of novel and improved catalytic materials. This paper presents the Aarhus University reactor for electrochemical studies using X-rays (AUREX) operando electrocatalytic flow cell, designed as an easy-to-use versatile setup with a minimal background contribution and a uniform flow field to limit concentration polarization and handle gas formation. The cell has been employed to measure operando total scattering, diffraction and absorption spectroscopy as well as simultaneous combinations thereof on a commercial silver electrocatalyst for proof of concept. This combination of operando techniques allows for monitoring of the short-, medium- and long-range structure under working conditions, including an applied potential, liquid electrolyte and local reaction environment. The structural transformations of the Ag electrocatalyst are monitored with non-negative matrix factorization, linear combination analysis, the Pearson correlation coefficient matrix, and refinements in both real and reciprocal space. Upon application of an oxidative potential in an Ar-saturated aqueous 0.1 M KHCO3/K2CO3 electrolyte, the face-centered cubic (f.c.c.) Ag gradually transforms first to a trigonal Ag2CO3 phase, followed by the formation of a monoclinic Ag2CO3 phase. A reducing potential immediately reverts the structure to the Ag (f.c.c.) phase. Following the electrochemical-reaction-induced phase transitions is of fundamental interest and necessary for understanding and improving the stability of electrocatalysts, and the operando cell proves a versatile setup for probing this. In addition, it is demonstrated that, when studying electrochemical reactions, a high energy or short exposure time is needed to circumvent beam-induced effects.




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International Artist Publishing names Rochelle Belsito as Executive Editor of Three Titles

www.internationalartist.com * www.americanartcollector.com * www.westernartcollector.com www.nativeamericanartmagazine.com * www.americanfineartmagazine.com




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UNION BETWEEN VILLA CURA BROCHERO, CORDOBA, ARGENTINA AND THE CULTURAL ASSOCIATION THE WAY OF THE HOLY GRAIL

The foundations are laid for a union between Villa Cura Brochero, Córdoba, Argentina and the Cultural Association El Camino del Santo Grial during the VIII Cultural Week in Massamagrell.




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Local Agrochemical Supplier Council-Oxford Inc. Rebrands

Council-Oxford Inc, a local supplier of agrochemicals and crop protection products, has announced the launch of their new brand identity. The company has unveiled a new logo and website, which better reflects their position as a local supplier.




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Rochers à l’Île Boudreau

Sous un ciel partiellement voilé, des rochers le long de l’Île Boudreau se dressent majestueusement au-dessus des eaux calmes et claires. Le rouge profond des formations rocheuses contraste magnifiquement avec le bleu apaisant de la mer, créant une palette de couleurs vibrantes et naturelles. L’érosion a sculpté ces pierres en des formes uniques, témoignant du...




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Rochers des Iles de la Madeleine

Les rochers des Îles de la Madeleine se dressent, imposants et majestueux, sous un ciel parsemé de nuages légers. Leur teinte rouge vibrante, sculptée par les vents marins et l’érosion, crée un contraste saisissant avec le bleu infini de la mer à l’horizon. Une arche naturelle, formée au fil du temps, ajoute une dimension presque...




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Workshop: Community Crocheting

Dec 8, 2024, 2pm EST

Join the TUAG Student Programming Committee for a crochet workshop with Leslie Rogers, SMFA at Tufts professor of the practice in sculpture. Taking inspiration from Tomashi Jackson’s use of fibers, knitwear, and woven elements in Across the Universe, Rogers will teach participants some basic techniques. Together, we can knit community via shared artmaking.

BuildingAidekman Arts Center
Campus Location: Medford/Somerville campus
City: Medford, MA 02155
Campus: Medford/Somerville campus
Location Details: Tufts Art Galleries, Aidekman Arts Center, Medford
Wheelchair Accessible (for in-person events): Yes
Open to Public: Yes
Primary Audience(s): Alumni and Friends, Faculty, Parents, Postdoctoral Fellows, Staff, Students (Graduate), Students (Undergraduate)
Event Type: Community Engagement, Exhibition, Lecture/Presentation/Seminar/Talk
Subject: Arts/Media, Education, Humanities
Event Sponsor: Tufts University Art Galleries
Event Sponsor Details: Generous support for Tufts University Art Galleries programming is provided by The Andy Warhol Foundation for the Visual Arts.
RSVP Information: Event is free and open to all. Please register here: www.eventbrite.com…
More infoartgalleries.tufts.edu…



  • 2024/12/08 (Sun)

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2016 Employee Benefits Update - Rochester





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Creating Thermal Energy Networks in Rochester, Minnesota

As Rochester city leaders set the ambitious goal of reducing greenhouse gas emissions by 50% by 2030 and 100% by 2050, the challenge is now how to follow through.




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Pogacar busca en Zúrich la triple corona que sólo alcanzaron Merckx y Roche

El esloveno, tras ganar Giro y Tour en el mismo año, busca el oro en un Mundial en el que las opciones españolas pasan Ayuso, Pello Bilbao y Castrillo Leer




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Pogacar y el broche a un año descomunal: arrasa en Lombardía e iguala a Coppi

El esloveno domina la Clásica de las hojas muertas con una superioridad abrumadora para sumar su cuarto triunfo consecutivo. Atacó sin respuesta a falta de 50 kilómetros. Evenepoel segundo e Izagirre cuarto Leer




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Dr. Rochelle Walensky has made a mockery of the CDC

It cannot be easy to lead the agency that handles infectious diseases in the midst of an international pandemic. Still, the director of the Centers for Disease Control and Prevention should at least be able to prove she is up to the task. Dr. Rochelle Walensky has repeatedly proved herself unfit and unreliable. She needs to go.




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New collection: Crochet Spaghetti Straps Bodystocking

A new collection of Body Stockings by MusicLegs®.

Crochet bodystocking with sexy spaghetti straps. Open crotch for convenience. Perfect to be worn under sexy evening dress with high heels shoes!




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New collection: Crochet Thigh High With Vinyl Top

A new collection of crochet thigh highs with vinyl top, by MusicLegs®.

Unstretch pothole size 14x14mm.




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New collection: Mesh Pantyhose With Side Crochet

A new collection of meshed pantyhose by MusicLegs®.

Fishnet pantyhose with side crocheted. Seamless fine fishnet mesh. Sexy pantyhose that is perfect for your favorite dress.




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New collection: Side Crochet Opaque Crotchless Bodystocking

A new collection of bodystockings by MusicLegs®.

Lycra opaque sleeveless bodystocking with side crochet potholes and sexy spaghetti straps. Enhanced with precious Lycra for durability and elasticity.




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New collection: Opaque Bodystocking With Side Crochet

A new collection of bodystockings by MusicLegs®.

Crotchless opaque bodystocking with side crochet design.

Onesize (5'~5'10", 100~175lbs).




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New collection: Music Legs Spandex Tights with Crochet

Patterned pantyhose from Music Legs®. With crochet at ankle level. High spandex content for greater elasticity.

Onesize (5'~5'10", 100~175lbs).




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Especiales Hora20: Serge Haroche, premio Nobel de Física

Durante el Hay Festival el premio Nobel de Física en 2012, Serge Haroche, habló sobre sus investigaciones, desarrollo científico y de los avances y desafíos que tiene la ciencia en la actualidad




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Reclutamiento de menores, derroche min salud y caracol número uno

Escuche el programa de este miércoles 13 de marzo. La Luciérnaga, un espacio de humor y opinión de Caracol Radio que desde hace 31 años acompaña a sus oyentes en su regreso casa.




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Petro insiste en constituyente, escándalos en gestión del riesgo y derroche en embajadas

Escuche el programa de este lunes 27 de mayo. La Luciérnaga, un espacio de humor y opinión de Caracol Radio que desde hace 31 años acompaña a sus oyentes en su regreso casa.




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Para Petro todo es golpe de Estado, aquí toca hacer reformas para sostener el gasto y el derroche y ahora juega Colombia y los recibimos has

Escuche el programa de este lunes 9 de septiembre . La Luciérnaga, un espacio de humor y opinión de Caracol Radio que desde hace 31 años acompaña a sus oyentes en su regreso casa.