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Amber Ruffin reacts to the U.S. election by leaning on Instagram quotes

Amber Ruffin wrote an "Amber Says What" segment for "Late Night with Seth Meyers" before the election. Now, she's leaning on "inspirational Instagram quotes" to get through it.




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Stephen Colbert Reacts to Matt Gaetz and Tulsi Gabbard’s Cabinet Appointments: This Wasn’t the ‘Outrageous, Stupefying Story That I Thought I’d Be Leading’ With Tonight

Stephen Colbert spent the majority of his opening monologue on Wednesday night’s “Late Show” talking about President-elect Donald Trump’s Cabinet choices so far, including Rep. Matt Gaetz of Florida as attorney general and Tulsi Gabbard as director of national intelligence. “Almost eight years ago, we all saw [Trump] saunter down those Capitol steps, put his […]




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S. Korea allegedly to react to North joining Kursk fights

South Korea is planning to make an "effective and phased" response to North Korea supposedly deploying its troops to fight Ukraine alongside Russia in the latter's Kursk region, Yonhap reported on Thu...




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'We Don't Want You': MAGA Reacts to John Thune Becoming Senate Majority Leader, and He Won't Like What They're Saying

President-elect Donald Trump’s landslide victory in the 2024 election has given his MAGA supporters eight straight days of euphoria. In a secret-ballot vote conducted Wednesday, however, Republicans in the U.S. […]

The post 'We Don't Want You': MAGA Reacts to John Thune Becoming Senate Majority Leader, and He Won't Like What They're Saying appeared first on The Western Journal.




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Justice Department officials react to Trump picking Matt Gaetz for attorney general

President-elect Donald Trump's pick of Rep. Matt Gaetz as his future attorney general has sent shockwaves through the Justice Department.




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Eve Hewson reacts to fans recreating viral dance moves

Eve Hewson expressed she is hesitant to reprise her role for a potential new season. Eve Hewson, Irish actress, has finally voiced her opinion on the famous dance montage from the hit Netflix show The Perfect Couple. In her Byrdie cover story, the 33-year-old revealed that the cast was...




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Rob Lowe reacts to Golden Bachelorette Joan Vassos' 'crush' confession

Rob Lowe responds to Joan Vassos' confessionRob Lowe wants to be Golden Bachelorette Joan Vassos' Golden Bachelor.During an October 16 appearance on Jimmy Kimmel Live, The Golden Bachelorette star Joan Vassos shared that she had been an extra in the 1985 film St. Elmo’s Fire and hinted...




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'I was shocked': Lawmakers react to Gaetz pick to be Trump's attorney general

Trump intends to nominate Rep. Matt Gaetz as attorney general and former Democratic Rep. Tulsi Gabbard as director of national intelligence, surprising many lawmakers who will have to confirm them.






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A Mn(III)-catalyzed arylboronic acid-based cascade reaction via a nonclassical organometallic-radical mechanism

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00244J, Research Article
Hui-Min Qian, Jian-Dong Zhang, Shun-Jun Ji, Xiao-Ping Xu
An efficient Mn(III)-catalyzed cascade reaction of arylboronic acids, o-cyanoaryl isocyanides, and indoles was developed. The mechanism was fully investigated and elucidated.
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A Pd(II)-catalyzed denitrative alkyne annulation reaction for the synthesis of cyclopenta[b]chromanes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00344F, Research Article
Pratiksha Bhorali, Deep J. Kalita, Babulal Das, Sanjib Gogoi
The first denitrative Pd(II)-catalyzed alkyne annulation reaction is reported for the synthesis of cyclopenta[b]chromanes.
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Organocatalyzed double dearomatization reaction of non-functionalized phenols and propargylic alcohols: the important regulating effect of steric hindrance

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00103F, Research Article
Xihong Liu, Boyan Zhu, Panpan Zhou, Jingying Zhang, Anqi Chu, Rui Wang
Steric hindrance-regulated double dearomatization reaction of non-functionalized phenols and propargylic alcohols for the efficient synthesis of polycyclic diketones is reported.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Chiral guanidine catalyzed cyclization reactions of 1,3-enynes for lactone synthesis: switchable H-bond catalysis

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00374H, Research Article
Yongyan Zhang, Lichao Ning, Tianxin Zhu, Zheng Xie, Shunxi Dong, Xiaoming Feng, Xiaohua Liu
Cyclization and 1,4-conjugate addition/cyclization between 2-activated 1,3-enynes and azlactones were achieved with chiral guanidine-amides for enol-type activation to yield a range of δ-lactone derivatives.
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Enantioselective synthesis of 8-membered lactone derivatives via organocatalytic cascade reactions

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00148F, Research Article
Dong-Sheng Ji, Rui Zhang, Xu-Yan Han, Hai-Long Chai, Yucheng Gu, Xiu-Qin Hu, Peng-Fei Xu
The challenging 8-membered lactone derivatives bearing two vicinal chiral stereocenters were synthesized via a cascade reaction mediated by the chiral squaramide.
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Blue light-mediated carbene transfer reaction of thioesters with diazoesters: efficient synthesis of tetrasubstituted Z-enol esters

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00265B, Research Article
Shuncheng Wang, Hua Zhang, Jin Yang, Dongfang Zhang, Xin-Ping Hui
An efficient metal-free, blue light-mediated carbene transfer reaction of thioesters with diazoesters has been achieved. This protocol produced tetrasubstituted Z-enol esters containing arylsulfur groups in good yields under mild conditions.
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Cyclization reactions of 1,6-dienes and 1,6-enynes by dual cobalt photocatalysis

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00311J, Research Article
Pei-Ting Li, Zi-Fa Shi, Wei Yu
Two triphenylamine-derived organophotocatalysts were developed. Their photocatalytic capacity was exploited to enable the [CoIII]-H-mediated cycloisomerization of 1,6-dienes and reductive cyclization of 1,6-enynes under visible light irradiation.
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Sulfamide instead of urea in Biginelli reaction: from black box to reality

Org. Chem. Front., 2024, 11,2155-2160
DOI: 10.1039/D3QO01926H, Research Article
Alexander Yu. Lyapunov, Andriy V. Tarnovskiy, Sergey Yu. Boron, Eduard B. Rusanov, Galyna P. Grabchuk, Dmytro M. Volochnyuk, Serhiy V. Ryabukhin
The scope and limitations of the classical Biginelli reaction have been expanded to principally novel substrates: sulfamide and its monosubstituted analogues.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Unprecedented single-electron-transfer reduction-based N → C acyl migration reactions of imides enabled by redox-neutral photocatalysis

Org. Chem. Front., 2024, 11,2344-2350
DOI: 10.1039/D3QO01955A, Research Article
Linge Huai, Li Zhang, Zhentao Wang, Yewen Fang
N → C acyl migration: in the absence of a base, redox-neutral photocatalyzed acyl migration reactions have been realized via the reaction of N-vinylimides with alkyl radicals derived from alkyl silicates.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Iron(III)/quinoxaline-derived N,N-ligand catalyzed oxygen transfer reaction of N-vinyl nitrones through selective 4π-electrocyclization and N–O bond cleavage

Org. Chem. Front., 2024, 11,2277-2282
DOI: 10.1039/D3QO01999C, Research Article
Yan-Jiao Lu, Feng-Lan Lu, Jin-Qi Zhang, Chun-Hua Chen, Cui Liang, Xiao-Pan Ma, Dong-Liang Mo
We describe an iron(III)/quinoxaline-derived N,N-ligand promoted O-transfer reaction of N-vinyl nitrones through selective O-4π-electrocyclization and N–O bond cleavage to prepare a variety of 2,5-dihydrooxazoles in good yields.
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Fe-catalyzed B–H and Si–H insertion reactions of gem-dihaloalkanes

Org. Chem. Front., 2024, 11,2241-2248
DOI: 10.1039/D4QO00136B, Research Article
Xinyu Wang, Zhaobin Wang
We present an approach involving Fe-catalyzed B–H and Si–H insertion of gem-dichloroalkanes. In contrast to previous strategies, our method uses gem-dihaloalkanes as non-stabilized carbene precursors and operates through a radical reaction pathway.
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Selective deletion of one carbon atom from C60 through benzylamine mediated reactions

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00449C, Research Article
Yaqiong Wang, Yiran Wu, Yuming Yu, Jie Su, Yi Qiu, Liangbing Gan
Benzylamine selectively adds to one of the two carbonyl groups on the 9-membered orifice to form an N,O-aminal moiety. Subsequent oxidation and hydrogen atom transfer lead to a decarboxylation process and formation of a nor [59]fullerene derivative.
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Base- and metal-free visible-light driven site-selective α-C(sp3)–H functionalization reaction of glycine derivatives with hydroxamic acid derivatives

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00425F, Research Article
Shiyun He, Hongying Fan, Xue Zhang, Meiling Ye, Jian Chen, Jinyu Hou, Tianle Huang, Li Guo, Guanghui Lv, Yong Wu
A visible-light-mediated radical–radical cross-coupling reaction between hydroxamic acid and N-phenyl glycine derivatives under base and metal free conditions is reported. A series of unnatural amino acids and peptides were obtained in good to excellent yields with good chemo-selectivity.
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Substituent-controlled divergent cyclization reactions of benzo[c][1,2]dithiol-3-ones and hexahydro-1,3,5-triazines

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00356J, Research Article
Bohao Zhang, Sifan He, Na Dong, Antong Zhu, Haojie Duan, Dunjia Wang, Yao Zhou
An unprecedented metal-free divergent cyclization reaction of benzo[c][1,2]dithiol-3-ones with hexahydro-1,3,5-triazines to assemble six- and eight-membered N-containing heterocycles has been developed.
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Diverting the Mannich reaction to access 2,2-disubstituted indolin-3-ones by merging 1,2-aryl migration and copper-catalyzed aerobic oxidation

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00481G, Research Article
Jia-Chen Xiang, Yu-Die Wang, Peng Yuan, Hui-Min Zhu, Tong Lei, An-Xin Wu, Zhixin Liao
Three typical substrates for the Mannich reaction, p-anisidine, aldehyde, and a nucleophile, did not afford the predictable linear Mannich base under an aerobic copper oxidation condition, but rendering a 2,2-disubstituted indolin-3-one product.
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Integrating continuous flow reaction and work-up: chiral amine resolution, separation and purification using a novel coalescing filter system

React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00442F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bethan May Rowley, Lisa Alice Thompson, Luke Power, James Daglish, Emma Parks, James Birbeck, Stephen P Marsden, Nikil Kapur, John Blacker
To maximize the benefits of a continuous flow reaction, a continuous work-up is also needed. Herein, we present a process design and novel equipment for a continuous amine resolution reaction,...
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A Hierarchical Surrogate Approach to Biomass Ethanolysis Reaction Kinetic Modelling

React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00378K, Paper
Ailís O'Shea, Conall McNamara, Prajwal Rao, Mícheál Séamus Howard, Mohammad Reza Ghaani, Stephen Dooley
The reaction mechanism and kinetics of the sulfuric acid catalysed ethanolysis of glucose, cellulose, xylan, and corncob was investigated using a combination of experiments and empirical reaction mechanism modelling. The...
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Contribution of an instructional module incorporating PhET simulations to Rwandan students' knowledge of chemical reactions, acids, and bases through social interactions

Chem. Educ. Res. Pract., 2024, Advance Article
DOI: 10.1039/D4RP00105B, Paper
Jean-Baptiste Ndagijimana, Jeannette Musengimana, Henriette Mushimiyimana, Evode Mukama, Olivier Habimana, Paulin Manirakiza, Jean Claude Dushimimana, Jean Pierre Alpha Munyaruhengeri, Samia Khan, Elizabeth Lakin
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Oxygen vacancy-induced efficient hydrogen spillover in Ni17W3/WO3−x/MoO3−x for a superior pH-universal hydrogen evolution reaction

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00729H, Paper
Open Access
Yiqing Sun, Yiwei Bao, Di Yin, Xiuming Bu, Yuxuan Zhang, Kaihang Yue, Xiaoshuang Qi, Ziyan Cai, Yongqiang Li, Xiulan Hu, Johnny C. Ho, Xianying Wang
By regulating the oxygen vacancy in the WO3−x/MoO3−x support synergistically, the active phase transition can be accomplished at low voltage, resulting in fast intermediate hydrogen uptake/transfer/desorption kinetics on the prepared catalyst surface and interface.
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Atomically Dispersed Ru Sites on MOF-derived NC-ZnO for Efficient Oxygen Evolution Reaction in Acid Media

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00586D, Paper
Sagar Varangane, Ragunath Madhu, Saad Mehmood, Bhavya Jaksani, Vidha Bhasin, Moses Abraham Abraham Bokinala, Ammavasi Nagaraj, Chandra Shobha Vennapoosa, Venkata Subba Reddy Basireddy, Subrata Kundu, Ujjwal Pal
Developing acid-stable oxygen evolution/reduction reaction (OER/ORR) electrocatalysts is essential for high-performance water splitting. Still, the slow kinetics of the ORR and OER during the discharge and charge processes seriously impede...
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Boosting reaction kinetics of polycrystalline phase Fe7S8/FeS2 heterostructures encapsulated in hollow carbon nanofiber for superior fast sodium storage

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01241K, Paper
Hui Cai, Fei Wang, Huiyan Feng, Zhendong Liu, Chengzhi Zhang, Anbang Lu, Xi Zhao, Qiuhong Lu, Quanbing Liu, Jun Tan
Metal sulfides have been regarded as highly competitive anode materials for fast sodium storage due to the excellent redox reversibility and comparatively great electron properties. Nevertheless, metal sulfides suffer from...
The content of this RSS Feed (c) The Royal Society of Chemistry




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NiFeCo–OH/NiTe nanoarrays with amorphous/crystalline interfaces for highly efficient oxygen evolution reaction

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00772G, Paper
Jing Liu, Da Liu, Xiaoxiao Yan, Peifang Guo, Hongbin Xu, Peng Chen, Renbing Wu
One-dimensional heterostructured NiFeCo–OH/NiTe nanorod arrays with amorphous/crystalline interfaces have been rationally synthesized, exhibiting an excellent OER electrocatalytic performance.
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In situ analysis of the oxygen evolution reaction on the CuO film in alkaline solution by surface interrogation scanning electrochemical microscopy: investigating active sites (CuIII) and kinetics

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00628C, Paper
Seokjun Han, Jinoh Yoo, Won Tae Choi
Surface interrogation scanning electrochemical microscopy was employed to assess the electrocatalytic activity of CuO films for the oxygen evolution reaction in an alkaline solution.
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Gaining the Molecular Design Principles for Efficient Diarylethene Photoacid and Photohydride Generators Based on Photochemical Reaction Mechanism

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06202G, Edge Article
Open Access
Yifan Su, Dexin Zheng, Lingfeng Ge, Le Yu, David Lee Phillips, Jiani Ma, Yu Fang
Abstract: Photoacid generators (PAGs) and photohydride generators (PHGs) are specific photolabile protecting groups that release acid and hydride, respectively. Over the past decade, great efforts have been devoted to developing...
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Synthesis of highly condensed phospholes by Lewis acid-assisted dehydrogenative Mallory reaction under visible light irradiation

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05657D, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ikki Kamiyoshi, Yuki Kojima, Shibo Xu, Kosuke Yasui, Yuji Nishii, Koji Hirano
A photo-promoted oxidative cyclization, that is, Mallory reaction of 2,3-diarylbenzophopholes has been developed. With an assistance of Bi(OTf)3 Lewis acid, the reaction proceeds smoothly under visible light irradiation even without...
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29th Climate Conference (COP) tracker | Day 2 LIVE: Key speeches, UK NDC, and India’s reaction at 5 p.m. on November 13

Vibhuti Garg, an Associate and Senior Energy Specialist with over 13 years of experience in the energy sector, will guide us through the implications of these financial negotiations and the potential impacts on global energy transitions and climate commitments at 5 p.m. on November 13




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Muscovite dehydration melting; reaction mechanisms, microstructures, and implications for anatexis

Dyck, B; Waters, D J; St-Onge, M R; Searle, M P. Journal of Metamorphic Geology 2019 p. 1-24, https://doi.org/10.1111/jmg.12511
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/20160157.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/20160157.jpg" title="Journal of Metamorphic Geology 2019 p. 1-24, https://doi.org/10.1111/jmg.12511" height="150" border="1" /></a>





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When This British Cafe Got a 1-Star Review They Reacted Brilliantly






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Surprising danger, quick reaction, God's protection

Faith is strengthened when OMers learn how the Lord watches over them, not allowing harm to come to the people or the ministry.




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Bizarre: Flying Ants 'Attack' Stops Ind vs SA T20I. Internet Reacts - Watch

After India had set hosts South Africa a target of 220,Ryan Rickelton and Reeza Hendricks scored seven in one over when play had to be stopped as insects caused the play to stop





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The Great Indian Kapil Show receives legal notice for this reason, Salman Khan reacts: 'We are not...'

The Bongo Bhashi Mahasabha Foundation (BBMF) has sent a legal notice to The Great Indian Kapil Show team for allegedly tarnishing Rabindranath Tagore's legacy.




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Karan Oberoi, Sudhanshu Pandey react to reunion A Band of Boys, revival of albums: 'Even in bad phase..' | Exclusive

Karan Oberoi, Sudhanshu Pandey and other band members of A Band of Boys talk about the inspiration behind the reunion of the boys' band after decades, and the revival of albums with it.




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Ananya Panday sets Instagram on fire in sizzling bikini; BFF Suhana Khan, mom Bhavana Pandey react

Ananya Panday shared a set of photos from her recent Dubai vacation on her Instagram on Wednesday.




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'Vivian Dsena you are an...': Ravi Dubey reacts after Madhubala star calls him his favourite TV actor in Bigg Boss 18

Vivian Dsena called Ravi Dubey his favourite actor. Vivian even called Ravi far better than him and lauded his achievement of breaking the world record for delivering the longest monologue.




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How Will the Market React?




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Build a cross-platform mobile app using React Native

As part of my developer advocacy efforts at IBM, I often build and share demos to showcase our products and how developers can integrate them into their own applications. The IBM Developer site provides a wealth of resources for developers with a focus on code, content, and community. And code patterns are our way of […]

The post Build a cross-platform mobile app using React Native first appeared on Tom Markiewicz.