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New Study Examines How Extraterrestrial Civilizations Could Become “Stellarvores.”

One of the most challenging aspects of astrobiology and the Search for Extraterrestrial Intelligence (SETI) is anticipating what life and extraterrestrial civilizations will look like. Invariably, we have only one example of a planet that supports life (Earth) and one example of a technologically advanced civilization (humanity) upon which to base our theories. As for …

The post New Study Examines How Extraterrestrial Civilizations Could Become “Stellarvores.” appeared first on Universe Today.




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New Species of Bioluminescent Sea Slug Discovered

Named Bathydevius caudactylus, the new species is bioluminescent and represents the third independent origin of bioluminescence among sea slugs.

The post New Species of Bioluminescent Sea Slug Discovered appeared first on Sci.News: Breaking Science News.




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New docuseries examines 2010 murder of Laura Letts Beckett near Revelstoke, B.C.

Peter Beckett was found guilty of first-degree murder in 2017, but his conviction was overturned in 2020.



  • News/Canada/British Columbia

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Synthesis of multisubstituted carbazol-4-amines from tetrahydrocarbazol-4-one oximes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00386A, Research Article
Jiahua Wang, Dandan Gao, Aanuoluwapo O. Oyejobi, Na Ji, Xiang-Ying Tang, Long Wang
A sequential synthetic method toward 1,3-disubstituted carbazol-4-amines is reported and an interesting C–S metathesis process is disclosed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Rhodium-catalyzed C–C bond alkenylation and arylation of α-branched N-sulfonyl amines

Org. Chem. Front., 2024, 11,2182-2188
DOI: 10.1039/D3QO02140H, Research Article
Lun Xu, Yucheng Liu, Hang Shi, Lun Li
In this work, we described a rhodium-catalyzed C–C bond cleavage of α-branched amines via β-carbon elimination, then formed a five-membered rhodacycle intermediate, which can be captured by styrene(alkenylation) or silane(arylation).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Selective photochemical synthesis of primary arylamines and symmetric diarylamines via amination of aryl bromides using Ni(NH3)6Cl2 as a nitrogen source and catalyst

Org. Chem. Front., 2024, 11,2313-2318
DOI: 10.1039/D4QO00116H, Research Article
Zhehui Xu, Jianyang Dong, Geyang Song, Fuqiang Kong, Gang Li, Dong Xue
The selective synthesis of primary arylamines and diarylamines via coupling reactions with ammonia as a nitrogen source is still challenging.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Palladium-catalyzed asymmetric [4 + 3] cycloaddition of acyclic α,β-unsaturated imines with trimethylenemethane donors: access to chiral non-fused azepines

Org. Chem. Front., 2024, 11,2326-2331
DOI: 10.1039/D4QO00064A, Research Article
Ting-Peng Li, Shuixiu Su, Jia-Huan Shen, Meng Zang, Yang-Zi Liu, Quannan Wang, Wei-Ping Deng
An efficient approach for the construction of non-fused azepines in good yields with high enantioselectivity via Pd-catalyzed asymmetric [4 + 3] cycloaddition was developed.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Visible-light Induced [1, 3]-Brook Rearrangements of α-Ketoacylsilanes and Its Subsequent Trapping in a Tandem Annulation with 1, 3, 5-Triazinanes and Azomethine Imines

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO00463A, Research Article
Zhong Zhang, Sirui Wu, Yuqiao Zhou, Bao-Lin Li, Siyue Xiao, Xiaohu Zhao, Zhipeng Yu
An unusual visible light-induced [1, 3]-Brook rearrangement of α-ketoacylsilanes for cascade cyclization with 1,3,5-triazinanes and C,N-cyclic azomethine imines has been developed under catalyst-free and mild reaction conditions. The strategy offers...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Expedient deaminative phosphorylation and sulfonylation of benzylic tertiary amines enabled by difluorocarbene

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00412D, Research Article
Chengbo Li, Yu Guo, Jianke Su, Xinyuan Hu, Qingqing Xuan, Qiuling Song
A deaminative functionalization of aliphatic tertiary amines via the cleavage of C(sp3)–N bonds under transition metal-free conditions was disclosed, which goes through SN2 reaction with various phosphorus and sulfur nucleophiles.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Study examines journalistic stress in covering election

Here's a new phenomenon to consider: "Post-election season stress." This term comes to us from the University of Southern California's Center for Health Journalism, which released on Wednesday a brief study titled "Reflecting on the Election's Toll on Journalists."




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The ups and downs of the Canadian Shield: 3 - additional apatite fission-track analyses from the Musselwhite, Roberto, Meadowbank and Raglan mines, Ontario, Quebec, and Nunavut

Pinet, N; McDannell, K. Geological Survey of Canada, Open File 8706, 2020, 49 pages, https://doi.org/10.4095/321845
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/of8706.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/of8706.jpg" title="Geological Survey of Canada, Open File 8706, 2020, 49 pages, https://doi.org/10.4095/321845" height="150" border="1" /></a>




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Aliphatic Amines Market Expands Due to Demand in Agriculture and Chemical Manufacturing, as per Maximize Market Research

(EMAILWIRE.COM, November 03, 2024 ) Aliphatic Amines Market are substances created through displacement reaction within an ammonia molecule. Monovalent hydrocarbon radicals replaced the hydrogen atoms in ammonia in Aliphatic Amines. The analysis in the report examines how the COVID-19 pandemic...




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Your Attitude Determines Your Altitude

Jesus refuses to allow the lack of faith of His disciples to send the crowd away. He tells them, commands them "You feed them!"




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Landmines in Your Business Exit

Part one of a two part series that outlines some occupational hazards before selling the business.




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Report examines work-related asthma in California

Sacramento, CA – Almost 1 million people in California have work-related asthma, according to a new surveillance report from the California Department of Public Health.




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Research project seeks better dust control in underground mines

Blacksburg, VA — Researchers at Virginia Tech have launched a project aimed at boosting the effectiveness of dust scrubbers in underground mining to enhance dust control and improve miner safety.




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No changes to training requirements for refuge alternatives in coal mines, MSHA says

Washington — The Mine Safety and Health Administration has determined that the annual training requirements outlined in its Refuge Alternatives for Underground Coal Mines rule supply “an experience sufficient to enable miners to apply their knowledge, other training and available written instruction to effectively use the refuge alternative in an emergency.”




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Study examines role of metabolism in night shift worker health

Spokane, WA — Individual organs in the digestive system contain separate biological clocks that may influence the metabolism of people who work the night shift and help explain a link to shift worker health problems such as obesity and diabetes, a recent study from researchers at Washington State University suggests.




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Study examines frailty among female shift workers

Toronto — Middle-aged and older shift workers are more likely to be considered frail – particularly women who work rotating shifts, a recent study out of Canada suggests.




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Report examines cause of Chevron hydrocarbon release

Washington – The ruptured steel pipe at the center of the 2012 hydrocarbon release and fire at the Chevron U.S.A. Inc. refinery in Richmond, CA, was corroded and should have been replaced, concludes a report released by the Chemical Safety Board and the California Division of Occupational Safety and Health.




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Latest ‘Fatal Facts’ examines fall from forklift-elevated pallet

Washington – OSHA is warning employees and employers about the dangers of falling from pallets raised by forklifts in its latest edition of Fatal Facts.




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Smart Phones: Pocket Landmines?

With more smart phones in use than PCs today, they are especially vulnerable to hackers, especially through QR codes.




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New tool helps track corrective action at mines

Arlington – The Mine Safety and Health Administration on Aug. 14 issued a new online tool to help mine operators track their record of correcting violations.




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MSHA issues alerts on hazards at metal, non-metal mines

Washington – The Mine Safety and Health Administration has published a pair of hazard alerts in response to an increase in fatalities at metal and non-metal mines.




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MSHA releases final rule on examinations in metal, non-metal mines

Arlington, VA – The Mine Safety and Health Administration has issued a final rule intended to improve pre-shift examinations of metal and non-metal mines.




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MSHA seeks to amend, delay final rule on examinations in metal, non-metal mines

Arlington, VA – The Mine Safety and Health Administration is proposing to amend a final rule intended to improve pre-shift examinations of metal and non-metal mines, as well as delay its effective date until March 2, according to separate notices published in the Sept. 12 Federal Register.




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MSHA clarifies escapeway requirements for underground mines

Washington — In response to recent questions from the mining community, the Mine Safety and Health Administration has issued a program policy letter intended to clarify requirements for providing emergency escapeways for underground metal and nonmetal miners.




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Escapeway requirements for underground mines: MSHA schedules meeting, extends comment period on clarification letter

Washington — The Mine Safety and Health Administration has scheduled a public meeting and extended the comment period on a program policy letter intended to clarify requirements for providing emergency escapeways for underground metal and nonmetal miners, in response to stakeholder requests.




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MSHA: Final rule on electronic detonators in metal and nonmetal mines now in effect

Washington — The Mine Safety and Health Administration’s direct final rule concerning advances in electronic detonators in metal and nonmetal mines has gone into effect, the agency announced March 18.




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MSHA cancels clarification letter on escapeway requirements for underground mines

Washington — After weighing public and stakeholder input, the Mine Safety and Health Administration has rescinded a program policy letter intended to clarify requirements for providing emergency escapeways for underground metal and nonmetal miners, determining that the clarification “is not needed.”




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Institute of Medicine examines health effects of combat blasts

Washington – Although blast trauma among soldiers can be proven to cause serious eye injuries and may be linked to post-traumatic stress disorder, insufficient evidence exists showing a relationship to tinnitus, vertigo and cardiovascular issues, according to a new report from the Institute of Medicine.




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CPWR report examines causes of death for current, retired and former construction workers

Silver Spring, MD — Of the nearly 225,000 construction worker deaths recorded in 2020, 60% of those workers were at least 65 years old, according to a new report from CPWR – The Center for Construction Research and Training.




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NIOSH study examines workplace hearing loss trends over 30 years

Washington – The risk of work-induced hearing loss http://www.cdc.gov/niosh/topics/ohl/ may be declining, but efforts are still needed in industries such as mining, construction and health care, according to a new NIOSH study.




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Guide examines safety of work zone plans

Washington — The National Cooperative Highway Research Program has released a guidebook that “provides practitioners who develop phasing and staging plans for temporary traffic control through work zones with guidance to evaluate the safety impacts of their plan decisions.”




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Abuse or ‘tough love’? Study examines why some bad bosses get a pass

Columbus, Ohio — Do some bosses who are abusive toward employees get away with it simply because they’re “high performers?” A recent pair of studies took a look.




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NIOSH study examines hearing loss in mining, oil and gas

Washington — Nearly 1 out of 4 mining workers experience job-related hearing loss, and more than 1 out of 3 employees in one industry subgroup are affected, according to a recent NIOSH study.




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MSHA inspection blitz finds violations at 25 mines

Washington — The Mine Safety and Health Administration uncovered hundreds of violations at mines with concerning compliance histories during recent impact inspections.




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New report examines construction fatalities

Silver Spring, MD — Nearly 1,100 construction workers died in 2022, according to a recent data bulletin published by CPWR – The Center for Construction Research and Training.




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Two emergency medical techs is too many for small coal mines, Kentucky lawmaker says

Frankfort, KY — A bill that would reduce – to one from two – the number of mine emergency technicians required during each shift at small underground coal mines is advancing in the Kentucky Legislature.






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The Discovery Institute Quote Mines Judge Jones

Added September 28, 2006: The Discovery Institute selectively quotes Judge Jones' decision in Kitzmiller v. Dover Area School District in aid of its "bait and switch" claim of scientific evidence in support of intelligent design.




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The Discovery Institute Quote Mines Stephen Jay Gould

Added October 9, 2006: The newest addition to the Quote Mine Project shows how Casey Luskin of Discovery Institute misrepresents what Gould and others wrote in a brief for Daubert v. Merrell Dow Pharmaceuticals.




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Crystal structures of two unexpected products of vicinal di­amines left to crystallize in acetone

Herein we report the crystal structures of two ben­zo­di­az­e­pines obtained by reacting N,N'-(4,5-di­amino-1,2-phenyl­ene)bis­(4-methyl­ben­zene­sul­fon­am­ide) (1) or 4,5-(4-methyl­ben­zene­sul­fon­am­ido)­ben­zene-1,2-diaminium dichloride (1·2HCl) with acetone, giving 2,2,4-trimethyl-8,9-bis­(4-methyl­ben­zene­sul­fon­am­ido)-2,3-di­hydro-5H-1,5-ben­zo­di­az­e­pine, C26H30N4O4S2 (2), and 2,2,4-tri­methyl-8,9-bis­(4-methyl­ben­zene­sul­fon­am­ido)-2,3-di­hydro-5H-1,5-ben­zo­di­az­e­pin-1-ium chloride 0.3-hydrate, C26H31N4O4S2+·Cl−·0.3H2O (3). Compounds 2 and 3 were first obtained in attempts to recrystallize 1 and 1·2HCl using acetone as solvent. This solvent reacted with the vicinal di­amines present in the mol­ecular structures, forming a 5H-1,5-ben­zo­di­az­e­pine ring. In the crystal structure of 2, the seven-membered ring of ben­zo­di­az­e­pine adopts a boat-like conformation, while upon protonation, observed in the crystal structure of 3, it adopts an envelope-like conformation. In both crystalline com­pounds, the tosyl­amide N atoms are not in resonance with the arene ring, mainly due to hy­dro­gen bonds and steric hindrance caused by the large vicinal groups in the aromatic ring. At a supra­molecular level, the crystal structure is maintained by a combination of hy­dro­gen bonds and hydro­phobic inter­actions. In 2, amine-to-tosyl N—H⋯O and amide-to-imine N—H⋯N hy­dro­gen bonds can be observed. In contrast, in 3, the chloride counter-ion and water mol­ecule result in most of the hy­dro­gen bonds being of the amide-to-chloride and ammonium-to-chloride N—H⋯Cl types, while the amine inter­acts with the tosyl group, as seen in 2. In conclusion, we report the synthesis of 1, 1·2HCl and 2, as well as their chemical characterization. For 2, two synthetic methods are described, i.e. solvent-mediated crystallization and synthesis via a more efficient and cleaner route as a polycrystalline material. Salt 3 was only obtained as presented, with only a few crystals being formed.




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Chromic soft crystals based on luminescent platinum(II) complexes

Platinum(II) complexes of square-planar geometry are interesting from a crystal engineering viewpoint because they exhibit strong luminescence based on the self-assembly of molecular units. The luminescence color changes in response to gentle stimuli, such as vapor exposure or weak mechanical forces. Both the molecular and the crystal designs for soft crystals are critical to effectively generate the chromic luminescence phenomenon of Pt(II) complexes. In this topical review, strategies for fabricating chromic luminescent Pt(II) complexes are described from a crystal design perspective, focusing on the structural regulation of Pt(II) complexes that exhibit assembly-induced luminescence via metal–metal interactions and structural control of anionic Pt(II) complexes using cations. The research progress on the evolution of various chromic luminescence properties of Pt(II) complexes, including the studies conducted by our group, are presented here along with the latest research outcomes, and an overview of the frontiers and future potential of this research field is provided.




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Structure–property relationship of a complex photoluminescent arylacetylide-gold(I) compound. I: a pressure-induced phase transformation caught in the act

A pressure-induced triclinic-to-monoclinic phase transition has been caught `in the act' over a wider series of high-pressure synchrotron diffraction experiments conducted on a large, photoluminescent organo-gold(I) compound. Here, we describe the mechanism of this single-crystal-to-single-crystal phase transition, the onset of which occurs at ∼0.6 GPa, and we report a high-quality structure of the new monoclinic phase, refined using aspherical atomic scattering factors. Our case illustrates how conducting a fast series of diffraction experiments, enabled by modern equipment at synchrotron facilities, can lead to overestimation of the actual pressure of a phase transition due to slow transformation kinetics.




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Report Examines Hidden Costs of Energy Production and Use

A new report from the National Research Council examines and, when possible, estimates hidden costs of energy production and use.




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Report Examines Options for Detecting and Countering Near-Earth Objects

A new report from the National Research Council lays out options NASA could follow to detect more near-Earth objects (NEOs) – asteroids and comets that could pose a hazard if they cross Earths orbit.




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New Report Examines Implications of Growing Gap in Life Span by Income for Entitlement Programs

As the gap in life expectancy between the highest and lowest earners in the U.S. has widened over time, high earners have disproportionately received larger lifetime benefits from government programs such as Social Security and Medicare, says a new congressionally mandated report from the National Academies of Sciences, Engineering, and Medicine.




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New Report Examines Molybdenum-99 Production and Use

Although the current supply of molybdenum-99 and technetium-99m – isotopes used worldwide in medical diagnostic imaging – is sufficient to meet domestic and global demand, changes to the supply chain before year-end could lead to severe shortages and impact the delivery of medical care, says a new report by the National Academies of Sciences, Engineering, and Medicine.