The synthesis, crystal structure, and Hirshfeld surface analysis of N-(4-methoxyphenyl)picolinamide (MPPA), C13H12N2O2, are presented. MPPA crystallizes in the monoclinic space group P21/n, with a single molecule in the asymmetric unit. Structural analysis reveals that all non-hydrogen atoms are nearly coplanar, and the molecule exhibits two intramolecular hydrogen bonds that stabilize its conformation. Supramolecular features include significant intermolecular interactions, primarily C—H...π and various hydrogen bonds, contributing to the overall crystal cohesion, as confirmed by energy framework calculations yielding a total interaction energy of −138.3 kJ mol−1. Hirshfeld surface analysis indicates that H...H interactions dominate, followed by C...H and O...H interactions, highlighting the role of van der Waals forces and hydrogen bonding in crystal packing.

TASHKENT, 15 October 2015 – An OSCE-supported roundtable discussion introducing representatives of local law enforcement bodies to the methodology of a national assessment of money-laundering and terrorism-financing risks in Uzbekistan was held today in Tashkent.

International experts invited by the OSCE Project Co-ordinator in Uzbekistan presented the results of their work on devising a comprehensive and tailored methodology for conducting a national risk assessment in the country.

“The OSCE continues to support international efforts that have made national risk assessment the standard in the fight against money laundering and the financing of terrorism,” said the OSCE Project Co-ordinator in Uzbekistan Gyorgy Szabo. “We see this as an essential step on the road to eliminating money laundering and terrorism financing in Uzbekistan.”

The discussion is part of a wider process of consultations with representatives of Uzbek law-enforcement agencies and the private sector to implement a national risk assessment on money laundering and the financing of terrorism.

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Between this blog, my podcast, MicroConf and the TinySeed, I’ve had the privilege of watching hundreds of entrepreneurs launch products over the past decade (even into the thousands, depending on how you count). After a while, I started to notice a pattern emerging among the pool of bootstrappers who were able to successfully replace their income, buy back their time,Read More →

The post The Stair Step Method of Bootstrapping first appeared on Rob Walling - Serial Entrepreneur.

Mottram, C M; Kellett, D A; Barresi, T; Zwingmann, H; Friend, M; Todd, A; Percival, J B. Geology vol. 48, no. 12, 2020 p. 1179-1183, https://doi.org/10.1130/G47778.1
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/20200143.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/20200143.jpg" title="Geology vol. 48, no. 12, 2020 p. 1179-1183, https://doi.org/10.1130/G47778.1" height="150" border="1" /></a>

My entryway has never looked better. READ MORE...

A MDT trainee puts what she has learned into practice as she teaches German to an Egyptian immigrant in Switzerland.

1. Don’t follow self-healing methods to control diabetes, says diabetologists  The Hindu
2. Study: 100mn Indians have diabetes  The Times of India
3. The Hindu webinar on diabetes management to be held on November 13  The Hindu
4. Combat diabetes with urgent lifestyle changes: Experts  The Times of India
5. Rice University’s ROGUE device implants a ‘living pharmacy’ to combat diabetes and obesity  Express Pharma

Doctrines and theology: The 20th century Wesley scholar Albert Outler argued in his introduction to the 1964 collection John Wesley that Wesley developed his theology by using a method that Outler termed the Wesleyan Quadrilateral. In this method, Wesley believed that the living core of the Christian faith was revealed in Scripture; and the Bible was the sole foundational source of theological or doctrinal development. The centrality of Scripture was so important for Wesley that he called himself "a man of one book"-meaning the Bible-although he was well-read for his day. However, he believed that doctrine had to be in keeping with Christian orthodox tradition. So, tradition was considered the second aspect of the Quadrilateral. -- Wesley contended that a part of the theological method would involve experiential faith. In other words, truth would be vivified in personal experience of Christians (overall, not individually), if it were really truth. And every doctrine must be able to be defended rationally. He did not divorce faith from reason. Tradition, experience and reason, however, were subject always to Scripture, Wesley argued, because only there is the Word of God revealed "so far as it is necessary for our salvation." -- The doctrines which Wesley emphasised in his sermons and writings are prevenient grace, present personal salvation by faith, the witness of the Spirit, and sanctification. Prevenient grace was the theological underpinning of his belief that all persons were capable of being saved by faith in Christ. Unlike the Calvinists of his day, Wesley did not believe in predestination, that is, that some persons had been elected by God for salvation and others for damnation. He understood that Christian orthodoxy insisted that salvation was only possible by the sovereign grace of God. He expressed his understanding of humanity's relationship to God as utter dependence upon God's grace. God was at work to enable all people to be capable of coming to faith by empowering humans to have actual existential freedom of response to God. -- Wesley defined the witness of the Spirit as: "an inward impression on the soul of believers, whereby the Spirit of God directly testifies to their spirit that they are the children of God." He based this doctrine upon certain Biblical passages (see Romans 8:15-16 as an example). This doctrine was closely related to his belief that salvation had to be "personal." In his view, a person must ultimately believe the Good News for himself or herself; no one could be in relation to God for another. -- Sanctification he described in 1790 as the "grand depositum which God has lodged with the people called `Methodists'." Wesley taught that sanctification was obtainable after justification by faith, between justification and death. He did not contend for "sinless perfection"; rather, he contended that a Christian could be made "perfect in love". (Wesley studied Eastern Orthodoxy and particularly the doctrine of Theosis). This love would mean, first of all, that a believer's motives, rather than being self-centred, would be guided by the deep desire to please God. One would be able to keep from committing what Wesley called, "sin rightly so-called." By this he meant a conscious or intentional breach of God's will or laws. A person could still be able to sin, but intentional or wilful sin could be avoided. -- Secondly, to be made perfect in love meant, for Wesley, that a Christian could live with a primary guiding regard for others and their welfare. He based this on Christ's quote that the second great command is "to love your neighbour as you love yourself." In his view, this orientation would cause a person to avoid any number of sins against his neighbour. This love, plus the love for God that could be the central focus of a person's faith, would be what Wesley referred to as "a fulfilment of the law of Christ." Wesley believed that this doctrine should be constantly preached, especially among the people called Methodists. In fact, he contended that the purpose of the Methodist movement was to "spread scriptural holiness across England." -- Advocacy of Arminianism: Wesley entered controversies as he tried to enlarge church practice. The most notable of his controversies was that on Calvinism. His father was of the Arminian school in the church. Wesley came to his own conclusions while in college and expressed himself strongly against the doctrines of Calvinistic election and reprobation. -- Whitefield inclined to Calvinism. In his first tour in America, he embraced the views of the New England School of Calvinism. When in 1739 Wesley preached a sermon on Freedom of Grace, attacking the Calvinistic understanding of predestination as blasphemous, as it represented "God as worse than the devil," Whitefield asked him not to repeat or publish the discourse, as he did not want a dispute. Wesley published his sermon anyway. Whitefield was one of many who responded. The two men separated their practice in 1741. Wesley wrote that those who held to unlimited atonement did not desire separation, but "those who held 'particular redemption' would not hear of any accommodation." -- Whitefield, Harris, Cennick, and others, became the founders of Calvinistic Methodism. Whitefield and Wesley, however, were soon back on friendly terms, and their friendship remained unbroken although they travelled different paths. In 1770 the controversy broke out anew with violence and bitterness, as people's view of God related to their views of men and their possibilities. Augustus Montague Toplady, Rowland, Richard Hill, and others were engaged on the one side, and Wesley and Fletcher on the other. Toplady was editor of The Gospel Magazine, which had articles covering the controversy. In 1778 Wesley began the publication of The Arminian Magazine, not, he said, to convince Calvinists, but to preserve Methodists. He wanted to teach the truth that "God willeth all men to be saved." A "lasting peace" could be secured in no other way. His system of thought has become known as Wesleyan Arminianism, the foundations of which were laid by Wesley and Fletcher.

The Wesley family was made famous by the two brothers, John and Charles, who worked together in the rise of Methodism in the British Isles during the 18th century. They were among the ten children surviving infancy born to Samuel Wesley (1662 - 1735), Anglican rector of Epworth, Lincolnshire, and Susanna Annesley Wesley, daughter of Samuel Annesley, a dissenting minister. -- John Wesley was born June 28, 1703, died Mar. 2, 1791, and was the principal founder of the Methodist movement. His mother was important in his emotional and educational development. John's education continued at Charterhouse School and at Oxford, where he studied at Christ Church and was elected (1726) fellow of Lincoln College. He was ordained in 1728. -- After a brief absence (1727 - 29) to help his father at Epworth, John returned to Oxford to discover that his brother Charles had founded a Holy Club composed of young men interested in spiritual growth. John quickly became a leading participant of this group, which was dubbed the Methodists. His Oxford days introduced him not only to the rich tradition of classical literature and philosophy but also to spiritual classics like Thomas a Kempis's Imitation of Christ, Jeremy Taylor's Holy Living and Dying, and William Law's Serious Call. -- In 1735 both Wesleys accompanied James Oglethorpe to the new colony of Georgia, where John's attempts to apply his then high-church views aroused hostility. Discouraged, he returned (1737) to England; he was rescued from this discouragement by the influence of the Moravian preacher Peter Boehler. At a small religious meeting in Aldersgate Street, London, on May 24, 1738, John Wesley had an experience in which his "heart was strangely warmed." After this spiritual conversion, which centered on the realization of salvation by faith in Christ alone, he devoted his life to evangelism. Beginning in 1739 he established Methodist societies throughout the country. He traveled and preached constantly, especially in the London-Bristol-Newcastle triangle, with frequent forays into Wales, Ireland, and Scotland. He encountered much opposition and persecution, which later subsided. -- Late in life Wesley married Mary Vazeille, a widow. He continued throughout his life a regimen of personal discipline and ordered living. He died at 88, still preaching, still traveling, and still a clergyman of the Church of England. In 1784, however, he had given the Methodist societies a legal constitution, and in the same year he ordained Thomas Coke for ministry in the United States; this action signaled an independent course for Methodism.

Did the Denominational name begin on shaky ground? At the beginning of TCotN [The Church of the Nazarene] both Phineas Bresee and Joseph Widney were made general superintendent "for life". This info is from the book by Carl Bangs "Phineas F. Bresee", 1995, Beacon Hill Press of Kansas City. p. 196-197; He goes on to write that the naming of the Church was the work of Joseph Widney. "For Widney, the name "Church of the Nazarene" conveyed nothing explicit about the Methodist doctrine or the experiences of conversion and entire sanctification. It was much more an expression of late-nineteenth-century "Jesus of history" theology, which preferred the name "Jesus" to the more exalted name "Jesus Christ." The "Jesus of history" was not so much the eternal Second Person of the Trinity who on the Cross made a full, perfect, and sufficient sacrifice, oblation, and satisfaction for the sins of the whole world," as He was the human Person remembered for words and deeds whom Christians were to follow as Teacher and Example. Widney's subsequent religious pilgrimage bears out the connoation of low Christology, and also low ecclesiology, that the term suggested." It is suggested that Bresee accepted the Name because he did not know Widney's true theology. To Bresee the name "Nazarene" represented Jesus association with the common man. So what was the outcome with Widney? He became increasing seperated from the Nazarenes and eventually started his own church. "He wrote a number of books on the borderline of politics, history, and culture. These were laced with mysticism and with a core theme of Aryan racial theory (Q. Nazism?). He developed a syncetistic religion followed by relatives and friends in his privately built "Beth-El", A Chapel and Manse of the Church of the All-Father" (or "All Fader")." (P. 214). Notice that this was not someone outside the Naz. throwing mud. This was published by Beacon Hill. Are we seeing sowing and reaping? It is amazing to me how quickly things seemed to change. Yet as we see from the origins our name, one of our first Generals began on shaky ground. -- posted by Robert Bruce Fruehling at 'Concerned Nazarenes' Facebook Page

2020 is the 250th anniversary of Ludwig van Beethoven's birth. Beethoven was raised in Bonn and a master at writing unique compositions. In the spirit of that, Deutsche Telekom plans to create a huge mosaic of Beethoven comprising many small photographs.

In the week before the US presidential election on 5 November 2024, it is the artists who are calling the tune – impulsive, powerful and mighty, as only music can be.

7:00 pm Sat, 10/5: RSU-TV is running a live pledge drive celebrating the 25th anniversary of Weird Al's movie "UHF", shot in Tulsa. There will be actors from the movie, talent acts and surprises. Premiums include location tours hosted by Emily Elliott and myself. Channel 35.1 broadcast, 109 or 793 on Cox, 35 on DISH and DirecTV.Also streamed live on RSU's web site. Free tickets still available.

SABRE has secured the first long-term location for SOTO Method, an emerging leader in fitness, solidifying its presence in the New York City market. [PR.com]

Network Hotfix Scanner is a free advanced hotfix check utility that scans network computers for missing hotfixes and patches, and helps you download and install them. NetHotfixScanner gives you a quick look at the hotfixes and patches installed or missed on any remote computer in your corporate network, it tells you by colored icons specific security bulletin rating ( critical, important, moderate ), title, description and bulletin URL. The tool is designed with a user-friendly interface and is easy to use.

2 techniques to use to help you fall asleep.

Keep track of your fitness level over time by using various methods to measure your fitness progress.

1 MILLION FREE VISITORS ON YOUR WEBSITE !!! Hurry up downloading the secrets while it's in here!

Frederica speaks on Orthodox worship at Southern Methodist College in Spartanburg, SC.

In August I published a post examining a common question in email marketing – do email subscription pop-ups work? The post detailed how I went about implementing pop-ups via OptinMonster (affiliate), as well as the results I attained in using them on two separate sites. Despite “most people” claiming they hate them, the results were…

The post Comparing Email Subscribers Acquired from Pop-Ups vs. Other Methods appeared first on Sugarrae.

Fr. John talks about Ss. Methodius and Cyril.

He was born to wealthy parents in Syracuse of Sicily. He entered monastic life and in time became a priest in the service of Patriarch Nikephoros. Because of his great and well-known zeal for the holy icons, he was cruelly persecuted by a succession of iconoclast emperors. Around 815, he was sent as an ambassador to Rome on behalf of the Patriarch, who had been exiled by the Emperor Leo the Armenian. When he returned to Constantinople upon Leo's death, he was immediately exiled and imprisoned by Leo's successor, Michael the Stutterer. Upon Michael's death he was freed for a short time, but soon the Emperor Theophilus had him exiled to an island where, says the Prologue, "he spent seven years in prison with two common robbers, in damp conditions, without light and without sufficient food, as if in a grave." When the pious Empress Theodora restored the Empire to Orthodoxy, he was freed and elevated to Patriarch of Constantinople. On the Sunday of Orthodoxy, we commemorate the restoration of the Holy Icons by Theodora and Methodios. Despite many attacks by heretics while he was Patriarch, he served faithfully and reposed in peace.

Noted in his own time for his wisdom and virtue, he was called Eubolos, meaning "of good counsel." He was among the first to oppose the heretical writings of Origen. He was bishop in Patara (according to some sources) or Olympia (according to others), then of Tyre in Phoenecia. Under the Emperor Maximinus, he was attacked by the pagans and received the crown of martyrdom in Chalkis in Greece.

The two saints were brothers, born in Thessalonica. St Methodius, the elder brother, served as a soldier for ten years before becoming a monk. Cyril was librarian at the Hagia Sophia in Constantinople; then he too became a monk.   Their first missionary work was not among the Slavs: When the king of the Khazars (a Mongol people who then inhabited much of what is now Russia) petitioned the Emperor Michael to sent teachers to instruct his people, the Emperor chose Cyril and Methodius as his emissaries. They converted the Khazar king to the Christian faith, along with many of his nobles and commoners.   When King Rostislav of Moravia likewise sought teachers of the Christian faith, Cyril and Methodius were again sent forth. This time they devised an alphabet for the Slavic language and used it to translate many of the Greek service books into the language of the people. (In theory, the Orthodox people have always been privileged to hear the Church's services in their own tongue, though often attachment to dead languages has prevented this ideal from becoming reality.) Both brothers were repeatedly attacked by Germanic priests of the region, who opposed the use of the common tongue in the liturgy. At different times, both brothers were forced to appeal for exoneration and protection to the Pope of Rome, who supported them warmly each time.   After the two Saints reposed, attacks on their work continued, and their disciples were eventually driven from Moravia. The disciples, fleeing southward, found a warmer welcome among the southern Slavic peoples, and their work bore much fruit in Bulgaria (including modern-day Serbia) and other countries. And, of course, the alphabet that they devised, called Cyrillic after St Cyril, remains the standard alphabet of both the Slavonic service books of the Church and the Slavic languages of today.

He was born to wealthy parents in Syracuse of Sicily. He entered monastic life and in time became a priest in the service of Patriarch Nikephoros. Because of his great and well-known zeal for the holy icons, he was cruelly persecuted by a succession of iconoclast emperors. Around 815, he was sent as an ambassador to Rome on behalf of the Patriarch, who had been exiled by the Emperor Leo the Armenian. When he returned to Constantinople upon Leo's death, he was immediately exiled and imprisoned by Leo's successor, Michael the Stutterer. Upon Michael's death he was freed for a short time, but soon the Emperor Theophilus had him exiled to an island where, says the Prologue, "he spent seven years in prison with two common robbers, in damp conditions, without light and without sufficient food, as if in a grave." When the pious Empress Theodora restored the Empire to Orthodoxy, he was freed and elevated to Patriarch of Constantinople. On the Sunday of Orthodoxy, we commemorate the restoration of the Holy Icons by Theodora and Methodios. Despite many attacks by heretics while he was Patriarch, he served faithfully and reposed in peace.