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Regulation of polyaniline thickness and substitution position on Cu foams to optimize hydrogen evolution and ethanol oxidation performance

Inorg. Chem. Front., 2024, 11,2373-2383
DOI: 10.1039/D4QI00085D, Research Article
Haiqiang Mu, Pengyue Shan, Min Zhu, Zhenli Lv, Guorui Ma, Jiaxing Guo, Junzhuo Fang, Jin Zhang, Feng Li, Jing Li
The Cu foam decorated with integrated polyaniline (PANI/CF-210) based on direct electro-grafting technique has been successfully designed to develop for efficient hydrogen evolution and ethanol oxidation reaction.
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Boosting structural variety and catalytic activity of porphyrinic metal–organic frameworks by harnessing bifunctional ligands

Inorg. Chem. Front., 2024, 11,2281-2289
DOI: 10.1039/D4QI00314D, Research Article
Wei Wu, Xiu-Liang Lv, Tao He, Guang-Rui Si, Hongliang Huang, Lin-Hua Xie, Yabo Xie, Jian-Rong Li
High catalytic performance of porphyrin-based MOFs has been achieved by introducing multiple functionality into their ligands and modulating their conformation.
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Achieving a near-unity photoluminescence quantum yield and high stability of CsPbI3 nanoplatelets by hydroiodic acid-assisted ligand treatment

Inorg. Chem. Front., 2024, 11,2392-2401
DOI: 10.1039/D4QI00168K, Research Article
Zongnan Li, Yusheng Song, Sheng Cao, Ke Xing, Zhentao Du, Bingsuo Zou, Jialong Zhao
We demonstrate a near-unity photoluminescence quantum yield and high stability of CsPbI3 nanoplatelets achieved through a hydroiodic acid-assisted ligand treatment strategy, showcasing their application in perovskite LEDs.
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Electrochemical conversion of 5-hydroxymethylfurfural over CuNi bimetallic catalysts: the synergistic effect of interfacial active sites

Inorg. Chem. Front., 2024, 11,2479-2488
DOI: 10.1039/D4QI00145A, Research Article
Yiwei Zhao, Chao Zhang, Shuangxi Xing, Zuhang Jin, Tingting Xiao
ECO of HMF to FDCA and ECR to BHMF with high yield have been studied on CuNi-based bimetallic catalysts. The presence of the Cu–O–Ni interfacial area was beneficial for promoting the catalytic performance in ECO.
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Perovskite photoinitiated RAFT-mediated polymerization-induced self-assembly for organic–inorganic hybrid nanomaterials

Inorg. Chem. Front., 2024, 11,2471-2478
DOI: 10.1039/D4QI00233D, Research Article
Bingfeng Shi, Wanchao Hu, Shiyi Li, Zhinan Xia, Changli Lü
An efficient strategy is proposed to construct PQD/polymer organic–inorganic nanohybrids by PET-RAFT polymerization-mediated PISA and the nanohybrid assemblies can maintain excellent luminescence originating from PQDs with enhanced stability.
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Durable dielectric switching and photo-responsivity in a Dion–Jacobson hybrid perovskite semiconductor

Inorg. Chem. Front., 2024, 11,2436-2441
DOI: 10.1039/D3QI02685J, Research Article
Peng Wang, Xinling Li, Huang Ye, Qianwen Guan, Yifei Wang, Yaru Geng, Chengshu Zhang, Hang Li, Junhua Luo
D–J phase perovskite (BDA)MA2Pb3Br10 reveals excellent photo-responsivity antifatigue merits and remarkable switching stability.
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Electrodeposited Superaerophobic Nickel Catalyst on Pencil-Drawn Paper: A Novel Approach for Highly Efficient and Stable Hydrogen Evolution

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00101J, Research Article
Qian Sun, Xiaoyu Hao, Tianyi Zhang, Zelin Ma, Kui Hu, Ming Yang, Xiaolei Huang, Xuqing Liu
Electrocatalytic water splitting stands at the forefront of advancing renewable energy technologies. A critical challenge in this realm is the detrimental effect of gas bubble adhesion on electrode surfaces, which...
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Efficient photocatalytic hydrogen evolution of g-C3N4/Vs-SnS2/CdS through a sulfur vacancy-rich SnS2 induced charge storage effect

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00602J, Research Article
Fangyuan Xing, Junyan Li, Chengzhi Wang, Shaohua Jin, Haibo Jin, Jingbo Li
Photocatalytic hydrogen production using semiconductors is one of the most promising routes for sustainable energy production.
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Yolk-Shell type Carbon-Silica Nanoarchitecture Dispersed and Stabilized Ru Nanoparticles for Enhanced Hydrogenation of Aromatic Compounds

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00553H, Research Article
Lu Yan, Yue Shen, Zidan Zou, Xiao Zhang, Zhixin Yu, Guozhong Wang, Chun Chen
Hydrogenation of aromatic rings can be used not only for synthesis fine chemicals, but also for hydrogen storage and transportation using organic hydride. In this paper, yolk-shell structural SiO2@Ru@NC catalyst,...
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Solar heating catalytic formic acid dehydrogenation by graphene-porous foam-supported tungsten nitride nanoparticles

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00590B, Research Article
Jiarong Chang, Tianhua Hao, Cuncai Lv, Maoyu Xu, Deyi Zhang, Linjie Gao, Shangbo Ning, Yaguang Li, Jinhua Ye
WN/Gr PF exhibits significant solar heating catalytic formic acid dehydrogenation and the rate exceeds those of other reported photocatalysts.
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Why drugmakers are dialing C for current good manufacturing practices

For the industry under scrutiny over quality concerns, cGMP requires immediate attention




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Nutrition, hydration & neighbourhood runs

Marathoner shares 20-year fitness regime of cardio, strength, and stability, prioritising training and recovery for marathon success




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Towards a decade of healthy ageing

Ageing with grace: Healthcare is shifting its focus from treating illness to preventing it 




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‘Closing the gap’ to ensure healthy babies

Despite the benefits, only half of Indian infants are breastfed successfully—what’s holding us back?




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Why maternal nutrition is blue-chip investment

Guaranteed maternal nutrition can break the cycle of malnutrition passed from one generation to the next




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Hyderabad to host international poultry expo from November 27

A technical seminar with the theme ‘Unlocking Poultry Potential’ will be held on November 26




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Bomb threat: Hyderabad-Chandigarh flight being checked

A series of bomb threats have been received by various airlines on domestic and international routes. Most threats were received through social media and most of them turned out to be hoaxes




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Why construction gear is less in demand

After double-digit sales growth for two years, construction equipment makers brace for a muted FY25




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Akshay Kumar is the new face of Dabur Chyawanprash




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Procter & Gamble commissions its first in-house solar plant in India at its Hyderabad site

Spread over 16,000 sq. mt, it has a capacity of 1MW




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Rhythm rendezvous

Chi Udaka brings together Indian classical dances and Japanese music at The Hindu November Fest.




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Thyagaraja Jayanthi celebrated

The brief concert of Sriram Parasuram and Anuradha Parasuram was an excellent show of musical depth and command over aesthetics.




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A bit of rhythm, a bit of soul

Brazilian guitarist Ahmed El-Salamouny on how his life revolves around music




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Rhythm of celebration

Thudumbu and Thudumbattam are played at temple festivals in and around Coimbatore.




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Music on the streets of Mylapore: Why Carnatic vocalist Saketharaman is celebrating an age-old tradition

How Carnatic vocalist Saketharaman is taking the veedhi bhajan tradition to the younger generation




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Visible-light-responsive hybrid photocatalysts for quantitative conversion of CO2 to highly concentrated formate solutions

Chem. Sci., 2024, 15,18146-18160
DOI: 10.1039/D4SC05289G, Edge Article
Open Access
Ewan McQueen, Noritaka Sakakibara, Kei Kamogawa, Martijn A. Zwijnenburg, Yusuke Tamaki, Osamu Ishitani, Reiner Sebastian Sprick
This highly efficient hybrid photocatalytic system can quantitatively convert CO2 to formate and produce 0.4 M of formate solution without additional concentration enrichment.
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A perspective on next-generation hyperfluorescent organic light-emitting diodes

Chem. Sci., 2024, 15,17739-17759
DOI: 10.1039/D4SC05489J, Perspective
Open Access
Upasana Deori, Gyana Prakash Nanda, Caroline Murawski, Pachaiyappan Rajamalli
The evolution of next-generation HF-OLED technology and current challenges.
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Recent advances in hydrogel-based flexible strain sensors for harsh environment applications

Chem. Sci., 2024, 15,17799-17822
DOI: 10.1039/D4SC05295A, Review Article
Open Access
Miaoyu Li, Jie Pu, Qinghe Cao, Wenbo Zhao, Yong Gao, Ting Meng, Jipeng Chen, Cao Guan
The application of hydrogel-based flexible strain sensors in harsh environments, including extreme temperatures, humidity, high mechanical strain, and strong corrosion, is investigated.
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Quadrupolar dinuclear hypervalent tin(IV) compounds with near-infrared emission consisting of Schiff bases based on π-conjugated scaffolds

Chem. Sci., 2024, 15,17950-17961
DOI: 10.1039/D4SC05006A, Edge Article
Open Access
Kazuya Tanimura, Kento Tanaka, Masayuki Gon, Kazuo Tanaka
The study focuses on dinuclear hypervalent tin(IV) compounds with near-infrared (NIR) emission and unique quadrupolar orientations, showing potential for constructing electronic structures with narrow energy gaps.
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Enhancing hydrogen evolution reaction activity through defects and strain engineering in monolayer MoS2

Chem. Sci., 2024, 15,18127-18134
DOI: 10.1039/D4SC04874A, Edge Article
Open Access
Renjith Nadarajan, Sraboni Dey, Arijit Kayal, Joy Mitra, Manikoth M. Shaijumon
The synergistic creation of vacancy defects, along with strain-induced active sites is shown to enhance hydrogen evolution reaction (HER) performance of CVD-grown monolayer MoS2.
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Electrochemical trifluoromethylation of alkynes: the unique role of DMSO as a masking auxiliary

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06780K, Edge Article
Open Access
Jihoon Jang, Ho Seong Hwang, Haeryeong Jeong, Eun Jin Cho
An electrochemical trifluoromethylation method for terminal alkynes has been developed, facilitating the synthesis of CF3-alkynes with DMSO as a masking auxiliary.
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Correction: Second-shell modulation on porphyrin-like Pt single atom catalysts for boosting oxygen reduction reaction

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC90219J, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tayyaba Najam, Syed Shoaib Ahmad Shah, Hanqing Yin, Xin Xiao, Shamraiz Talib, Qianqian Ji, Yonggui Deng, Muhammad Sufyan Javed, Jie Hu, Ruo Zhao, Aijun Du, Xingke Cai, Qiang Xu
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Selective lignin depolymerization via transfer hydrogenolysis using Pd/hydrotalcite catalysts: model compounds to whole biomass

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC03942D, Edge Article
Open Access
Darren Dolan, Rebekah Brucato, Christopher William Reid, Adam F. Lee, Karen Wilson, Adelina M Voutchkova-Kostal
Cleavage of lignin ether bonds via transfer hydrogenolysis is a promising route to valorize lignin, but processes that use mild reaction conditions and exploit renewable hydrogen donor solvents (rather than...
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Phenacylselenoesters allow facile selenium transfer and hydrogen selenide generation

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05788K, Edge Article
Open Access
Utsav Dey Sarkar, Mahima Rana, Harinath Chakrapani
A new series of phenacylselenoesters that generate hydrogen selenide in the presence of esterase and a biological thiol under ambient conditions is reported.
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M12L24 nanospheres as supramolecular templates for the controlled synthesis of Ir-nanoclusters and their use in the chemo-selective hydrogenation of nitro styrene

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06324D, Edge Article
Open Access
Lotte L. Metz, Rens Ham, Eduard Bobylev, Kelly J. H. Brouwer, Alfons van Blaaderen, Rim van de Poll, Victor Drozhzhin, Emiel J. M. Hensen, Joost N. H. Reek
Controlled preparation of ultrafine metal nanoclusters (<2 nm) is challenging, yet important as the properties of these clusters are inherently linked to their size and local microenvironment. In the present...
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Analysis of the cryptic biosynthetic gene cluster encoding the RiPP curacozole reveals a phenylalanine-specific peptide hydroxylase

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC02262A, Edge Article
Open Access
Samantha Hollands, Julia Tasch, David J. Simon, Dimah Wassouf, Isobel Barber, Arne Gessner, Andreas Bechthold, David L. Zechel
The noncanonical biosynthesis of curacozole by Streptomyces curacoi is shown to be dependent on the bldA-encoded Leu-tRNAUUA. The minimal biosynthetic gene cluster is defined, and the functions of key biosynthetic enzymes are established in vitro.
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Understanding ketone hydrogenation catalysis with anionic iridium(III) complexes: The crucial role of counterion and solvation

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04629C, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Paven Kisten, Sandrine Vincendeau, Eric Manoury, Jason Martin Lynam, John M. Slattery, Simon B Duckett, Agusti Lledos, Rinaldo Poli
The catalytic asymmetric hydrogenation of ketones reflect an important way to prepare valuable chiral alcohols. Understanding how transition metals promote these reactions is key to the rational design of more...
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Simultaneous generation of hydroxyl and hydrogen radicals from H+/OH− pairs caused by water–solid contact electrification

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06227B, Edge Article
Open Access
Fengjie Chen, Jingde Wu, Dou Wang, Yu Xia, Qingyuan Song, Ying Liang, Pu Wang, Bolei Chen, Yong Liang, Yongguang Yin, Yawei Wang, Maoyong Song, Guibin Jiang
Water–solid contact electrification is a common physical phenomenon involving interfacial electron and ion transfer, recently discovered to trigger unique redox reactions.
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Electrochemical reconstruction of metal–organic gels into crystalline oxy-hydroxide heterostructures for efficient oxygen evolution electrocatalysis

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05799F, Edge Article
Open Access
Kang Liu, Haikuo Lan, Yuting Chen, Weicheng Tang, Zhenyu Xiao, Yunmei Du, Jun Xing, Zexing Wu, Lei Wang
An amorphous MOG electrochemically reconstitutes to a crystalline NiOOH/FeOOH heterostructure with the morphology changed from nanofibers to nanosheets as a high-performance OER electrocatalyst.
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Direct synthesis of N-perfluoro-tert-butyl secondary amines from N-trifluoromethyl secondary amines

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06335J, Edge Article
Open Access
Leibing Wang, Zhongyu Feng, Zhen Luo, Zihao Guo, Jieping Wang, Wenbin Yi
The one-step direct synthesis of N-perfluoro-tert-butyl secondary amines utilizes TMSCF3 as the sole CF3 source and the starting material N-CF3 secondary amine itself as the hydrogen source. PFtB amines can be effectively employed in 19F MRI.
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Photochemical carboborylation and three-component difunctionalization of α,β-unsaturated ketones with boronic acids via tosylhydrazones

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06537A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Álvaro Valdés-Maqueda, Manuel Plaza, Carlos Valdés
The photochemical carboborylation of α,β-unsaturated tosylhydrazones with boronic acids gives tertiary allylboronates. A one pot sequence involving an aldehyde allylation provides a powerful three-component method for diversity oriented synthesis.
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Cationic Al oxo-hydroxide clusters: syntheses, molecular structures, and functional applications

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05707D, Perspective
Open Access
Naoki Ogiwara, Wei Zhou, Sayaka Uchida
Al oxo-hydroxide clusters are formed through the hydrolysis of Al3+-containing solutions, exhibiting a diversity of sizes and shapes. The assembly of these clusters demonstrates functional applications, such as adsorption and heterogeneous catalysis.
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Synergetic effect of mild hypothermia and antioxidant treatment on ROS-mediated neuron injury under oxygen-glucose deprivation investigated by scanning electrochemical microscopy

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05977H, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Junjie Zhang, Yulin Liu, Yuxiang Zhao, Siyu Zhang, Feng Xu, Fei Li
Ischemic stroke and reperfusion injury result in neuronal damage and dysfunction associated with oxidative stress, leading to overproduction of cellular reactive oxygen species (ROS) and reactive nitrogen species (RNS). In...
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Triple-Function Porphyrin in Glycopolymeric Photosensitizer: From PhotoATRP to Targeted PDT

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06466F, Edge Article
Open Access
Jiahui Lin, Zhiyuan Ma, Weiwei Zuo, Meifang Zhu
Porphyrin derivatives serve as photocatalysts in reversible-deactivation radical polymerization and as photosensitizers in photodynamic therapy (PDT). Herein, a triple function porphyrin, ZnTPPC6Br, was synthesized as photocatalyst and initiator for photoATRP....
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Morphology of Lithium Halides in Tetrahydrofuran from Molecular Dynamics with Machine Learning Potentials

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04957H, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Marinella de Giovanetti, Sondre H. Hopen Eliasson, Sigbjørn L. Bore, Odile Eisenstein, Michele Cascella
The preferred structures of lithium halides (LiX, with X = Cl, Br, I) in organic solvents have been the subject of a wide scientific debate, and a large variety of...
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Photoactivated hydride therapy under hypoxia beyond ROS

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06576J, Edge Article
Open Access
Xia Wang, Yijian Gao, Ting Wang, Zhaobin Wang, He Hang, Shengliang Li, Fude Feng
As compared to oxidative phototherapy, studies on reactive reductive species-participating photodynamic therapy (PDT) are rare. Porphyrins are typical photosensitizers restricted with oxygen level, but efficacy and selectivity are always uncompatible...
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Why this balanced advantage fund is a useful addition amidst rough markets

ICICI Prudential Balanced Advantage juggles stocks, bonds and derivatives smartly for optimal returns




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Why this conservative hybrid fund makes sense amidst market volatility

Aditya Birla Sun Life Regular Savings has been a consistent outperformer while keeping risks at bay




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Why I hold a passive-only mutual fund portfolio: Vishal Jain, CEO, Zerodha Fund House

Vishal Jain of Zerodha Fund House on why he actively favours the passive route




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Why this equity savings fund is well-suited for volatile markets

HDFC Equity Savings fund delivers robust risk-adjusted returns by juggling stocks, bonds and derivatives