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An efficient approach to AviCys analogues via regio- and stereoselective hydrosulfuration of ynamides

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01572J, Research Article
Zhenjia Zhang, Zhe Ding, Jinhua Yang, Yongli Zhao, Zhenguang Zhao, Can Liu, Norman Metanis, Junfeng Zhao
A novel synthetic strategy for the construction of AviCys analogues via a highly efficient regio- and stereoselective hydrosulfuration of ynamides was reported.
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ici

Copper-catalyzed alkynyldisulfuration of arynes: an efficient access to unsymmetrical disulfides

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01844C, Research Article
Shuai Huang, Yumin Zhang, Yuekai Li, Chen-Ho Tung, Xin Li, Zhenghu Xu
This article investigates a copper-catalyzed alkynyl disulfuration reaction of aryne formed in situ to synthesize o‑alkynyl aryl disulfides. The transformation proceeds through the in situ generation of aryne, followed by...
The content of this RSS Feed (c) The Royal Society of Chemistry




ici

GHMC official sentenced to one-year RI in ACB case




ici

Telangana set to unveil new industrial sectoral policies 

Electric Mobility and Storage, Electronics, Life Sciences, Defence and Aerospace sectors to get new growth guiding documents as some existing policies have become outdated and those in other States are superior, senior official 




ici

Ponnam criticises BJP leader Laxman’s comments on caste census




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Trust deficit exists between citizens and healthcare system: former IAS officer




ici

Agitated villagers chase govt officials over proposed pharma plant in Vikarabad

The villagers have been protesting for several weeks against the proposed pharma company




ici

Hyderabad commissioner restricts city-wide ban to vicinity of Telangana Secretariat

The new order comes into effect from November 11 until further notice, said the commissioner




ici

Officials demand strict action against those involved in ‘confrontation’ at Vikarabad village




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BCCI vs PCB spar on CT venue as Mohsin Naqvi denies receiving any official note from Indian board

The Hybrid Model was followed during 2023 Asia Cup where Pakistan played its matches at home but India played its matches in Sri Lanka.




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Staving off cynicism

How can one ward off this negative feeling and retain a positive attitude?




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Pulluvanpattu musician Jayakumar Gopinath says he considers it his responsibility to keep his father’s legacy alive

Jayakumar Gopinath talks about Pulluvanpattu, the ritualistic art form of Kerala that sings songs for the snake gods, and how his community is trying to preserve it




ici

Newly synthesized sulfonamide derivatives explored for DNA binding, enzyme inhibitory, and cytotoxicity activities: a mixed computational and experimental analyses

RSC Adv., 2024, 14,35047-35063
DOI: 10.1039/D4RA06412G, Paper
Open Access
Nasima Arshad, Yasir Mehmood, Hammad Ismail, Fouzia Perveen, Aneela Javed, Pervaiz Ali Channar, Aamer Saeed, Sadia Naseem, Fatima Naseer
This work reports synthesis, characterization, DNA, enzyme binding and cytotoxicity activity of three 4-((3-arylthiazolo[3,4-d]isoxazol-5-yl)amino)benzene sulfonamide derivatives with a thaizaole(3,4-d)isoxazole-based fused ring heterocyclic system.
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ici

An exceptional water stable terbium-based metal–organic framework for selective detection of pesticides

RSC Adv., 2024, 14,35220-35226
DOI: 10.1039/D4RA06622G, Paper
Open Access
Ching-Ping Liu, Ting-En Lin, Jung-Chang Chiang, Bo-Jhen Chen, Po-Hsiu Chien, Su-Ying Chien, Gene-Hsiang Lee, Yen-Hsiang Liu, Kuang-Lieh Lu
The terbium-based metal–organic frameworks (Tb-MOFs) were synthesized successfully under hydrothermal conditions, which could maintain at least 90% of the emission intensity after storage in water for several months.
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ici

An efficient extraction device for microplastics in marine sediments and its applications

RSC Adv., 2024, 14,35610-35617
DOI: 10.1039/D4RA04347B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Wang Jiahan, Liu Xiaowei, Yang Feng, Yang Xiujiu, Jiao Wenguang, Tang Kai, Wang Jinli, Chen Yan
Microplastics, defined as small pieces of plastic with a size less than 5 millimeters, constitute a significant sink for microplastics in marine sediments.
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A safe and efficient synthesis of N-Boc-β3-amino acid methyl esters from α-amino acids: applications in the formal synthesis of sedum alkaloids

RSC Adv., 2024, 14,36016-36021
DOI: 10.1039/D4RA07506D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bohua Long, Lijie Ren, Mengmeng Jiang, Shengquan Hu, Qianqian Jiang, Limin Li, Xuanluan Chen, Zhengzhi Wu
β3-Amino acids are essential components in the synthesis of biologically active compounds.
The content of this RSS Feed (c) The Royal Society of Chemistry




ici

Bisphenol A (BPA) toxicity assessment and insights into current remediation strategies

RSC Adv., 2024, 14,35128-35162
DOI: 10.1039/D4RA05628K, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Joshua O. Ighalo, Setyo Budi Kurniawan, Banlambhabok Khongthaw, Junaidah Buhari, P. K. Chauhan, Jordana Georgin, Dison Stracke Pfingsten Franco
To mitigate the toxic effects of BPA, there is a need to utilize hybrid remediation strategies for its removal from the aqueous environment.
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Chitosan supported ionic liquid, a multifaceted catalyst for streamlined and efficient synthesis of carboxylic, amino acid and carbohydrate esters

RSC Adv., 2024, 14,36193-36208
DOI: 10.1039/D4RA05725B, Paper
Open Access
Praachi Kakati, Satish Kumar Awasthi
Development of a solid heterogeneous catalyst in the form of an ionic liquid incorporated in chitosan which shows high recyclability. This was used in a solvent free esterification reaction of carboxylic acids, amino acids and carbohydrates.
The content of this RSS Feed (c) The Royal Society of Chemistry




ici

Farmers in Rajasthan set to get electricity for irrigation of crops during day time

A memorandum of understanding was signed for two gas-based power plants in Jaipur, says Minister Nagar




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Protests erupt in Assam as first CAA beneficiary granted citizenship

Students’ organisations and Opposition parties said citizenship to a Bangladesh-born man was a violation of the Assam Accord of 1971




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U.S. FDA proposes ending use of popular decongestant present in cold medicines

An agency review of the available data determined that oral phenylephrine, a major component of popular products such as Benadryl, Advil and Tylenols was not effective against nasal congestion




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AAPI Chief Dr Kathula suggests fast-track green cards for Indian physicians in the US

Voices concerns that there are many physicians who are still on H-1B work visas even after staying in the US for over 15-20 years.




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Vice President Harris is in ‘excellent health,’ physician says

Her most recent physical exam in April was “unremarkable,” Simmons added




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24 killed, 46 injured in suicide bombing at railway station in Pakistan

The explosion ripped through the railway station of the provincial capital Quetta as passengers gathered on the platform before the departure of the Jaffar Express




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Taliban administration officials to attend UN climate conference in Azerbaijan

Taliban officials have taken part in U.N.-organised meetings on Afghanistan in Doha, and Taliban ministers have attended forums in China and Central Asia in the past two years




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Vinicius, Mbappe on target as Madrid crush plucky Espanyol

The comprehensive victory was Madrid's 38th consecutive La Liga game without defeat, their last loss in the competition coming just under a year ago, against Atletico Madrid in September 2023




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Vinicius hat-trick saves Real Madrid in Champions League, Villa go top

Real Madrid beats Borussia Dortmund 5-2 with Vinicius Junior’s hat-trick, while Aston Villa stays unbeaten in Champions League




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Vinicius favourite for Ballon d'Or in post-Messi/Ronaldo era

The men's shortlist for the 2023/24 edition of the prestigious individual award is the first since 2003 to feature neither Lionel Messi nor Cristiano Ronaldo




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Silver likely to rule at higher levels this year on supply deficit

Supply shortage forecast to increase by 17% even as industrial demand is projected to rise 9%



  • Gold & Silver

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Gold prices anticipated to surpass $3,000 per ounce: Citi report

The report attributes this projection to the weakening US labour market, disinflation, and the Federal Reserve’s dovish pivot at the upcoming July FOMC meeting



  • Gold & Silver

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Influence of triphosphine ligand coordination geometry in Mn(I) hydride complexes [(P∩P∩P)(CO)2MnH] on their kinetic hydricity

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02496F, Paper
Sergey A. Kovalenko, Ekaterina S. Gulyaeva, Elena S. Osipova, Oleg A. Filippov, Anastasia Danshina, Laure Vendier, Nikolay V. Kireev, Ivan A. Godovikov, Yves CANAC, Dmitry A. Valyaev, Natalia Belkova, Elena Shubina
Octahedral Mn(I) complexes bearing tridentate donor ligands [(L∩L’∩L’’)(CO)2MnX] have recently emerged as major players in catalytic (de)hydrogenation processes. While most of these systems are still based on structurally rigid pincer...
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Construction of efficient Pb(II) carboxylate catalysts for Oxygen and Hydrogen Evolution Reactions

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02958E, Paper
Janak ., Vijay Sarjerao Sapner, Bhaskar Ramchandra Sathe, Sadhika Khullar
The development of cost-effective and efficient electrocatalysts can solve the problem in the production of energy via water splitting reactions. In this work, we focused on two lead-based coordination polymers...
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Stable homogeneous silver(I) catalysts for the highly efficient cycloaddition of azides onto terminal alkynes in water

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02825B, Communication
Meysam Kakavand, Anna Kozakiewicz, Abdollah Neshat
To develop stable and efficient silver(I) catalysts and evaluate the role of sulfur and phosphorus donor ligands in the catalytic cycloaddition of selected organic azides and alkynes (AAC), a series...
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Construction of oxygen-rich vacancies and heterojunctions coupled with different morphologies of CeO2/mesoporous TiO2 framework structures for efficient photocatalytic CO2 reduction performance

Dalton Trans., 2024, 53,17963-17975
DOI: 10.1039/D4DT02014F, Paper
Morigejile Liu, Guangmei Jiang, Zaiwang Zhao, Ying Shi, Siqin Zhao
Construction of oxygen-rich vacancies and heterojunction-coupled CeO2/mesoporous TiO2 framework structures with different morphologies and efficient photocatalytic CO2 reduction performance.
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Coinage metal(I) clusters supported by a 1,10-phenanthroline-phosphine: orange-to-NIR phosphorescence, metallophilic interactions and enhanced cytotoxicity

Dalton Trans., 2024, 53,18027-18036
DOI: 10.1039/D4DT02642J, Paper
Alexander V. Artem'ev, Maria P. Davydova, Lyubov S. Klyushova, Evgeniy H. Sadykov, Mariana I. Rakhmanova, Taisiya S. Sukhikh
Based on 2-(diphenylphosphino)-1,10-phenanthroline, a series of small metal(I) clusters, exhibiting orange to NIR phosphorescence and strong dose-dependent cytotoxicity.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Price pooling mantra: Wake up to expensive electricity



  • Siddhartha P Saikia

ici

Appeal to Karnataka government to officially celebrate Shankar Nag’s birthday as ‘Driver’s Day’

Several auto drivers’ unions made an appeal to Transport Minister Ramalinga Reddy




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Guarantee money is deposited to beneficiaries’ bank accounts when election is around the corner, alleges B.Y. Vijayendra




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Shepherds, craftspersons to participate in ‘Kurubki’ event in Bengaluru




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Judicial Commission visits MUDA office in Mysuru

The State government constituted the Commission headed by Justice P.N. Desai to look into the alleged irregularities in the allotment of sites by the MUDA




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Vinicius 'tricks' Real Madrid to win!

Real Madrid forward Vinicius Jr scored a hat-trick to help the LaLiga champions snap a two-game winless run in all competitions.




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Maha CM asks officials to provide compensation for farm losses due to unseasonal rains




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EAM Jaishankar says success of Central govt's policies linked to state's intentions




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Maha: Malad residents saving money on medicines, courtesy Jan Aushadhi Kendras




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Maharashtra: Malad residents saving money on medicines, courtesy Jan Aushadhi Kendras




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Jan Aushadhi Kendras in Maharashtra: Bringing relief with low cost medicines




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Maha: Under PMBJP, Nalasopara residents buying cheaper medicines; thank PM Modi




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PMAY beneficiaries in Maharashtra's Beed thank PM Modi for affordable housing




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ICC continues discussion on Champions Trophy schedule with participating nations

Meanwhile, it was not a surprise that ICC has also put on hold the prestigious ODI tournament's launch event, which was scheduled to be held in Lahore on November 11.




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Enhanced removal efficiency of Tetradesmus obliquus for nevirapine removal via co-substrate supplementation: removal mechanisms, relative gene expression and metabolomics

Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00576G, Paper
Karen Reddy, Nirmal Renuka, Muneer Ahmad Malla, Brenda Moodley, Faizal Bux, Sheena Kumari
The bioremediation of pharmaceutical wastewater by microalgae has gained scientific attention due to its cost-effectiveness and environmental friendliness.
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