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Mesoscopic spiral nanoplates formed by porphyrin-spaced coordination frameworks for enhanced H2O2 photosynthesis

Inorg. Chem. Front., 2024, 11,8037-8046
DOI: 10.1039/D4QI01580K, Research Article
Liang He, Er-Xia Chen, Ju-Qiang Xiang, Yu-Jun Guo, Jian Zhang, Qipu Lin
Two-dimensional chiral bismuth–porphyrin metal–organic frameworks featuring mesoscopic square spiral terrace morphology significantly enhance H2O2 photosynthesis.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Active molecular units in metal organic frameworks for artificial photosynthesis

Inorg. Chem. Front., 2024, 11,7682-7755
DOI: 10.1039/D4QI01363H, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Subrata Mandal, Sahar Yoosefi, Alexander K. Mengele, Sven Rau, Andrea Pannwitz
Metal–organic frameworks (MOFs) integrate photoactive and catalytic entities within a 3D structure. This review classifies photocatalytic MOFs by photosensitizer and catalyst localization and their roles in artificial photosynthesis.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Dual-functional nano-photosensitizers: Eosin-Y decorated gold nanorods for plasmon-enhanced fluorescence and singlet oxygen generation

RSC Adv., 2024, 14,12417-12427
DOI: 10.1039/D4RA01551G, Paper
Open Access
Sravani Kaja, Ashin Varghese Mathews, Amit Nag
Enhancement factors of 110 and 18 for metal-enhanced fluorescence and metal-enhanced SOG, respectively, are obtained from polymer coated gold nanorod cores adsorbed with Eosin Y.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A dual-functional photosensitizer for mitochondria-targeting photodynamic therapy and synchronous polarity monitoring

J. Mater. Chem. B, 2024, 12,11259-11264
DOI: 10.1039/D4TB01872A, Paper
Liu Yang, Shenglong Gan, Jie Zhang, Yin Jiang, Qingxin Chen, Hongyan Sun
A dual-functional photosensitizer was developed, exhibiting potent phototoxicity and sensitivity to polarity changes.
The content of this RSS Feed (c) The Royal Society of Chemistry




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H2O2-activated mitochondria-targeting photosensitizer for fluorescence imaging-guided combination photodynamic and radiotherapy

J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01653J, Paper
Qiufen Tian, Zifan Zhu, Yun Feng, Shirui Zhao, Hui Lin, Wen Zhang, Zhiai Xu
Radiotherapy is a primary modality in cancer treatment but accompanied by severe side effects to healthy tissues and radiation resistance to some extent. To overcome these limitations, we developed a...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Yeh Hai Mohabbatein actress Karishma Sharma's HOT photoshoot

Lensman Amit Khanna's fabulous pictures confirm that she's really hot!





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Electronic Relaxation Pathways in Thio-Acridone and Thio-Coumarin: Two Heavy-Atom-Free Photosensitizers Absorbing Visible Light

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03720K, Paper
Open Access
Chris Acquah, Sean J. Hoehn, Sarah E. Krul, Steffen Jockusch, Shudan Yang, Sourav Kanti Seth, Eric Lee, Han Xiao, Carlos E. Crespo-Hernández
Heavy-atom-free photosensitizers (HAF-PSs) have emerged as a new class of photosensitizers aiming to broaden their applicability and versatility across various fields of the photodynamic therapy of cancers. The strategy involves...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Bioinspired hydrogels: polymeric designs towards artificial photosynthesis

Chem. Commun., 2024, 60,13314-13324
DOI: 10.1039/D4CC04033C, Feature Article
Open Access
Reina Hagiwara, Ryo Yoshida, Kosuke Okeyoshi
This Feature Article outlines the design of polymer networks for water splitting induced by visible light to develop artificial chloroplasts. The network serves as a mediator for photoinduced electron transfer among precisely organised molecules.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Updates to the Google Photos APIs: Picker API launch and Library API changes

The new Picker API enables secure photo selection, while the Library API will focus on managing photos and videos uploaded by your application.




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Selenium nanomaterials promoted ferredoxin and iron–sulfur protein synthesis and acetyl CoA carboxylase activity to improve the photosynthesis and fatty-acid synthesis in soybean

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00978E, Paper
Lian Zhang, Xiaona Li, Le Yue, Xuesong Cao, Bingxu Cheng, Chuanxi Wang, Zhenyu Wang
Herein, the effect of selenium engineered nanomaterials (Se ENMs) on soybean photosynthesis and fatty-acid synthesis by regulating ferredoxin (Fd) and iron–sulfur (Fe/S) protein synthesis and acetyl CoA carboxylase (ACC) activity was explored.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Sara's Stunning Photoshoot

Sara Ali Khan makes pretty pictures, and she knows it.




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Clean facts on global warming and photosynthesis

Global warming and climate change has led to rise in mean temperatures which has suppressed photosynthesis and the ability of the global ecosystem to assimilate carbon




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I just pulled a 2006 and uploaded my holiday photos to Flickr with a Creative Commons Licence

I just returned from a holiday on the gorgeous island of Corfu in Greece and spent quite some time taking photos. Instead of releasing those piecemeal on various social media channels, I thought it would be fun to go back to our ways of early social media, and put them all up on Flickr with […]




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PHOTOS: Man City dominate Slovan; Arsenal stun PSG

IMAGES from the Champions League matches played on Tuesday.




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iOS18 Photos: Tab Bar to Single Scroll View

The most significant user interface change from iOS 17 to iOS 18 are the navigation differences in Apple's Photos app. The ubiquitous tab bar that's became the default navigation model in mobile apps is gone and in its place is one long scrolling page. So how does it work and why?

Most mobile applications have adopted a bottom bar for primary navigation controls. On Android it's called bottom navigation and on iOS, a tab bar, but the purpose is the same: make the top-level sections of an application visible and let people move between them.

And it works. Across multiple studies and experiments, companies found when critical parts of an application are made more visible, usage of them increases. For example, Facebook saw that not only did engagement go up when they moved from a “hamburger” menu to a bottom tab bar in their iOS app, but several other important metrics went up as well. Results like this made use of tab bars grow.

But in iOS 18, Apple removed the tab bar in their Photos app. Whereas the prior version had visible tabs for the top-level sections (Library, For You, Albums, Search), the redesign is just a single scroll view. The features previously found in each tab are now accessed by scrolling up and down vs. switching between tabs. One notable exception is Search which stays anchored at the top of the screen.

In addition to the persistent Search button, there's also a Select action and user profile image that opens a sheet with account settings. As you scroll up into your Photo library a persistent set of View controls appears at the bottom of the screen as well. The Close action scrolls you to the end of your Photo library and reveals a bit of the actions below making the location of features previously found in tabs more clear.

It's certainly a big change and given the effectiveness of tab bars, its also a change that has people questioning why? I have no inside information on Apple's decision-making process here but based on what I've learned about how people use Google Photos, Yahoo! Photos, and Flickr, I can speculate.

  1. By far the dominant use of a Photo gallery is scrolling to find an image whether to share, view, or just browse.
  2. Very few people organize their photo libraries and those that do, do it rarely.
  3. People continue to have poor experiences with searching images, despite lots of improvements, so they default to browsing when trying to find photos.
  4. Most automatic curation features like those found in For You just get ignored.

All that together can easily get you to the design answer of "the app should just be a scrolling list of all your Photos". Of course there's trade-offs. The top-level sections, and their features are much less visible, and thereby less obvious. The people who do make use of features like Albums and Memories now need to scroll to them vs. tapping once. But as iOS18 rolls out to everyone in the Fall, we'll see if these trade-offs were worth it.




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Suzy Embo : foto's = photos, 1953-1980 / textes, Ivan Alechine, Tamara Berghmans, Ann Deckers, Pieter De Reuse.

Bruxelles : CFC-Editions, [2017]




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Self-assembled phthalocyanine-based nano-photosensitizers in photodynamic therapy for hypoxic tumors

Mater. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QM00602J, Review Article
Lin He, Ding Ma
This paper reviews the potential of self-assembled phthalocyanine-based nano-photosensitizers for overcoming the limitations of photodynamic therapy (PDT) in treating hypoxic tumors.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Why Smartphone Night Photos Are So Good Now

Taking photos at night on your phone used to look terrible, but recent phones have much improved capabilities. Julian Chokkattu, reviews editor at WIRED, explains how smartphone camera technology has gotten so much better.




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Re:WIRED GREEN 2022: Camille Seaman Discusses Her Most Striking Photos

Photographer Camille Seaman has spent years documenting our changing world through her lens. In this talk she shares some of her most striking work.




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8 Photos That Tell The History of Humans In Space

ESA Astronaut Tim Peake visits WIRED to have a look back at pivotal moments in the history of human space flight, captured in 8 unforgettable photographs.




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Visible light mediated efficient photoswitching of dimethyldihydropyrenes in thin films for all-photonic logic gate applications and dynamic encryption/decryption capabilities

J. Mater. Chem. C, 2024, 12,17511-17518
DOI: 10.1039/D4TC03321C, Paper
Sariful Molla, Subhajit Bandyopadhyay
Dimethyldihydropyrene (DHP) photoswitches exhibit visible light-induced ring-opening photoisomerization, reversed by UV/visible light or heat in thin films.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Stimulus-responsive multifunctions in a zinc(II) sulfate complex: photochromism, photoswitching nonlinear optical properties, amine detection and visual film application

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC04169K, Paper
Shuai Liang, Shi-Kun Yan, Yu-Xuan Wen, Yan-Rui Zhao, Jin Zhang, Ji-Xiang Hu
A novel complex combining photo- and amine-induced chromic, switchable photoluminescence, and photomodulated nonlinear optical properties has been prepared using electron-rich sulfate and electron-deficient 2,4,6-tri(4-pyridyl)-1,3,5-triazine.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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An E/Z isomer strategy of photosensitizers with tunable generation processes of reactive oxygen species

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03028A, Paper
Xiaochun Liu, Hairong Li, Hui Tang, Ning Ma, Shiyu Wu, Wenbo Dai, Yahui Zhang, Xiaoqi Yu
An E/Z isomer strategy was designed to precisely regulate the type of ROS and enable tumor imaging and PDT.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Triple-Function Porphyrin in Glycopolymeric Photosensitizer: From PhotoATRP to Targeted PDT

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06466F, Edge Article
Open Access
Jiahui Lin, Zhiyuan Ma, Weiwei Zuo, Meifang Zhu
Porphyrin derivatives serve as photocatalysts in reversible-deactivation radical polymerization and as photosensitizers in photodynamic therapy (PDT). Herein, a triple function porphyrin, ZnTPPC6Br, was synthesized as photocatalyst and initiator for photoATRP....
The content of this RSS Feed (c) The Royal Society of Chemistry




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meso-Substituted AB3-type phenothiazinyl porphyrins and their indium and zinc complexes photosensitising properties, cytotoxicity and phototoxicity on ovarian cancer cells

RSC Med. Chem., 2024, Advance Article
DOI: 10.1039/D4MD00601A, Research Article
Open Access
Brém Balázs, Bianca Stoean (Vasile), Éva Molnár, Eva Fischer-Fodor, Ovidiu Bălăcescu, Raluca Borlan, Monica Focsan, Adriana Grozav, Patriciu Achimaş-Cadariu, Emese Gál, Luiza Gaina
New meso-substituted AB3-type phenothiazinyl porphyrins and ferrocenylvinyl phenothiazinyl porphyrin were synthesised by Suzuki–Miyaura and Mizoroki–Heck cross-coupling reactions, respectively.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Light enhanced cytotoxicity and antitumoral effect of a ruthenium-based photosensitizer inspired from natural alkaloids

RSC Med. Chem., 2024, Advance Article
DOI: 10.1039/D4MD00600C, Research Article
Open Access
Gennaro Sanità, Maria Laura Alfieri, Barbara Carrese, Serena Damian, Vincenza Mele, Gaetano Calì, Brigida Silvestri, Sebastiano Marra, Susan Mohammadi, Giuseppina Luciani, Paola Manini, Annalisa Lamberti
Biological assays carried out on melanoma and breast cancer cells highlighted the role of light in boosting the cytotoxic effect of a ruthenium complex featuring a dihydroisoquinoline ligand suggesting applications in photodynamic therapy.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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PHOTOS: New Zealand stun India to end 36-year wait

Rachin Ravindra and Will Young remained calm under pressure after the loss of two early wickets to get the job done, earning New Zealand only their third win on Indian soil in 38 attempts going back to 1955.




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Neutral mononuclear indium(III) photosensitizers for CO2 photoreduction

Dalton Trans., 2024, 53,17772-17776
DOI: 10.1039/D4DT02595D, Communication
Zaichao Zhang, Li-Zhi Fu, Piao He, Xiao-Yi Yi
Neutral mononuclear indium(III) complexes (In-1–In-3) containing 2,6-di(1H-pyrrol-2-yl)pyridine and substituted dipyridylpyrrole pincer ligands are employed as photosensitizers in photocatalytic CO2 reduction.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A bioinspired water oxidation catalyst that is ∼1/10th as active as the photosystem II oxygen evolving center at pH 7: a study of activity and stability factors

Dalton Trans., 2024, 53,17783-17788
DOI: 10.1039/D4DT02336F, Communication
Danijel Boskovic, Richard Terrett, Matthew Longhurst, Sabeel Basheer, Alireza Ariafard, Pawel Wagner, Ronald J. Pace, Rob Stranger, Gerhard F. Swiegers
Ca-doped birnessite MnOx on liquid crystalline reduced graphene oxide exhibits unprecedented performance for an abiological catalyst at pH 7, including a very low onset overpotential of 0.52 V and high activity per unit area at 0.56 V overpotential.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Glycosylated AIE-active Fe (III) photosensitizer activated by tumor microenvironment for synergistic type I photodynamic and chemodynamic therapy

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03871A, Paper
Gai-li Feng, Wei Zhou, Jinping Qiao, Guang-Jian Liu, Guo-Wen Xing
Photodynamic therapy (PDT) and chemodynamic therapy (CDT) are both promising cancer treatments to inhibit tumor cells by generating highly cytotoxic reactive oxygen species (ROS). Herein, we report a novel tumor...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Conduction band photonic trapping via band gap reversal of brookite quantum dots using controlled graphitization for tuning a multi-exciton photoswitchable high-performance semiconductor

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03616F, Paper
Sanjiv Sonkaria, Tae Woo Lee, Aniket Kumar, Soo-Kyung Hwang, Piotr Jablonski, Versha Khare
The photocatalytic competence of brookite relative to polymorphs anatase and rutile has generally been considered structurally and energetically unfavourable for reasons that remain largely unknown and unchallenged. Here, we demonstrate...
The content of this RSS Feed (c) The Royal Society of Chemistry




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How to edit Diwali photos on your phone for better lighting and colour

Diwali photos usually mean many nighttime shots and intense light sources. Here are some ways to make the most of your phone camera to get studio-quality shots




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Seed partners unveil photosynthesis trait

Benson Hill and Beck’s say corn varieties with the modified gene will yield more per acre




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Sobhita Dhulipala Will Convince You To Up Your Saree Fashion Game And Get A Unique Photoshoot Done

Sobhita Dhulipala's Instagram feed is lit up with perceptive photoshoots. She looks striking in each picture of hers and particularly her sarees looks are what we find the most interesting. Sobhita has sported sarees on a number of occasions




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Happy Mother's Day: Anushka Sharma wishes 'maa' with photos from her wedding with Virat Kohli

Anushka Sharma shared sweet images of her mother from the Virushka wedding




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Photos: Purdue visits Wisconsin in Big Ten play

Boilermakers and the Badgers meet on Feb. 18, 2020

      




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Photos: Purdue takes on Michigan St. in Big Ten women's tournament

Photos: Purdue takes on Michigan St. in Big Ten women's tournament

      




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Photos: Maryland defeats Purdue women in Big Ten tournament

Photos: Maryland defeats Purdue women in Big Ten tournament

      




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In Photos: Notable deaths of 2020

Rock 'n' roll icon Little Richard, singer-songwriter John Prine, New Orleans jazz legend Ellis Marsalis, soul singer Bill Withers, jazz icon Manu Dibango, country music icon Kenny Rogers, NASA mathematician Katherine Johnson, Oscar-winning actor Kirk Douglas, NBA legend Kobe Bryant, and WWE wrestler Rocky Johnson are among the famous people who have died in 2020.




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Mysteries of history: can you identify these forgotten photos?

A call has gone out for help to identify thousands of mystery Scottish scenes, finds Sandra Dick.




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Over 1,000 line up for FREE FOOD in Geneva amid coronavirus lockdown (PHOTOS)

More than 1,000 people queued up in Geneva to get free food parcels. The anti-coronavirus measures that have been in place since mid-March have taken a heavy toll on the country’s poor.
Read Full Article at RT.com




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Satellite Photos Take You Inside Gadhafi's Compound




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Vanessa Bryant files claim over crash-site photos

Vanessa Bryant filed a claim against the Los Angeles County Sheriff's Department, contending deputies shared unauthorized photos of the site where her husband and daughter died in a helicopter crash in January.




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Vanessa Bryant files claim over crash-site photos

Vanessa Bryant filed a claim against the Los Angeles County Sheriff's Department, contending deputies shared unauthorized photos of the site where her husband and daughter died in a helicopter crash in January.




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Who Needs Photoshop When These 23 Unbelievable Pictures Are Completely REAL? Whoa.

It's not a trick - each of these photos are completely real.




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He Doesn’t Use Photoshop, But This Makeup Artist Still Makes His Clients Look Way Younger

He's able to hide so many flaws that make his clients self-conscious.




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See photos: Arjun Rampal gives mother, partner adorable Mother's Day shout-out

Not just for his mother, Bollywood actor Arjun Rampal on Saturday has penned an adorable Mother's Day special post for his partner, too. The 47-year-old actor, in an Instagram post, shared his thoughts for his mother and his lady love -- Gabriella Demetriades.

"She is a new Mom and a very fine one too. Happy first Mother's Day, mamma, love you," wrote 'Om Shanti Om' actor as he shared a dashing picture of themselves.

Meanwhile, taking to another post, the 'Roy' actor shared a throwback picture with his mom and wrote: "She is the most beautiful soul. She is my Mom." He wrapped up the post by extending his Mother's Day wishes to "all the mothers out there". "Thank you for just being you. #happymothersday," he concluded.

The actor is currently staying at home observing the lockdown guidelines, to prevent the spread of coronavirus.

Earlier he along with his family have extended a helping hand in providing PPE kits to the hospitals, doctors, and nurses to help them in the fight against coronavirus. He also urged people to donate 1 uniform for these corona warriors to keep them safe and healthy.

Catch up on all the latest entertainment news and gossip here. Also, download the new mid-day Android and iOS apps.

Mid-Day is now on Telegram. Click here to join our channel (@middayinfomedialtd) and stay updated with the latest news

This story has been sourced from a third party syndicated feed, agencies. Mid-day accepts no responsibility or liability for its dependability, trustworthiness, reliability and data of the text. Mid-day management/mid-day.com reserves the sole right to alter, delete or remove (without notice) the content in its absolute discretion for any reason whatsoever




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Mother's Day: Sara Ali Khan, Ishaan Khatter, Ananya Panday, Vicky Kaushal share childhood photos with mommas

As the nation celebrates the indomitable spirit of motherhood on Sunday, Bollywood celebrities also dedicated heart-warming messages to their mom's on the occasion of Mother's Day."

Sara Ali Khan shared a heart-melting throwback picture where she is seen as an infant in the arms of her grandmother while her mother is looking at baby Sara in a moment of affection. The actor captioned the post as, "Meri Maa ki Maa. Thank you for creating Mommy. #HappyMothersDay."

Vicky Kaushal put out a childhood throwback picture on Instagram where the actor is seen caught in a moment of mischief as he jogs at the shore of a beach, while his mother is seen scolding him. Along with the picture Vicky wrote," Dodging them till date. Keep them coming Maa. Love you! 

 
 
 
View this post on Instagram

Dodging them till date. Keep them coming Maa. Love you! ❤ï¸Â

A post shared by Vicky Kaushal (@vickykaushal09) onMay 9, 2020 at 5:40pm PDT

Ananya Panday shared an adorable video from her childhood days where she is seen sporting a while kurta-churidar with a red dotted dupatta. The video initiates with a question by a person behind the camera who asks, "Whom do you love the most in the world?"

To which baby Ananya innocently replies, "Mama."

And he asks, "And the second?"

She smilingly replies, "Nobody."

 
 
 
View this post on Instagram

The answer is still the same 😜 love u @bhavanapandey ❤ï¸Â

A post shared by Ananya 💛💫 (@ananyapanday) onMay 9, 2020 at 12:16pm PDT

Along with the caption she wrote, "The answer is still the same. love u @bhavanapandey."

Recalling his childhood moments spent with her mom, Ishaan Khatter shared a couple of throwback pictures with his mom in an Instagram post.

 
 
 
View this post on Instagram

Mom for president ✌🏼

A post shared by Ishaan (@ishaankhatter) onMay 9, 2020 at 1:16pm PDT

The special post featured 3 pictures of which the first one shows baby Ishaan lying in bed while his mother is seen pecking a kiss on his little arms. The second one shows his mom in a glamorous monochromatic picture, and the third one shows baby Ishaan in his childhood days, where he is seen sitting in his mother's lap and passing a smile at the camera.Along with the post he wrote, "Mom for president."

Catch up on all the latest entertainment news and gossip here. Also, download the new mid-day Android and iOS apps.

Mid-Day is now on Telegram. Click here to join our channel (@middayinfomedialtd) and stay updated with the latest news

This story has been sourced from a third party syndicated feed, agencies. Mid-day accepts no responsibility or liability for its dependability, trustworthiness, reliability and data of the text. Mid-day management/mid-day.com reserves the sole right to alter, delete or remove (without notice) the content in its absolute discretion for any reason whatsoever




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Happy Mother’s Day 2020: Wishes, images, Whatsapp messages, status, quotes and photos - The Indian Express

  1. Happy Mother’s Day 2020: Wishes, images, Whatsapp messages, status, quotes and photos  The Indian Express
  2. Mother’s Day 2020: 5 Easy DIY Gift Ideas to Make Your Mom Smile  News18
  3. Happy Mother's Day Greeting Card: Easy ways to make a greeting card at home  Times of India
  4. Five ways to make your mother feel special, every day  The Indian Express
  5. Mother’s Day 2020: These apps might be the best gifts (you can install) for mom  Hindustan Times
  6. View Full coverage on Google News