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A polychloride-enabled synthesis of [NEt3Me][PCl6] serving as a potential PCl3-storage and PCl5-reagent

Chem. Commun., 2024, 60,13372-13375
DOI: 10.1039/D4CC04319G, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Moritz J. Ernst, Merlin Kleoff, Patrick Voßnacker, Günther Thiele, Christian Müller, Sebastian Riedel
The reaction of the ionic liquid [NEt3Me][Cl3] with white phosphorus (P4) gives, quantitatively, hexachlorophosphate [NEt3Me][PCl6], which shows similar reactivity as PCl5 and can be used as a potential PCl3-storage material.
The content of this RSS Feed (c) The Royal Society of Chemistry




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PVDF nanocomposites with aligned boron nitride nanosheets and dispersed BaTiO3@PEG nanoparticles by a superspreading strategy towards high energy density

Chem. Commun., 2024, 60,13344-13347
DOI: 10.1039/D4CC04430D, Communication
Dajun Hou, Jingjing Zhou, Wen Chen, Jing Zhou, Pengchao Zhang
The limited improvement in discharge energy density (Ue) of polyvinylidene fluoride (PVDF) nanocomposites filled with low-dielectric-constant (εr) nanosheets has been addressed by using a superspreading layering strategy.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Polarizable AMOEBA force field predicts thin and dense hydration layer around monosaccharides.

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04415K, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Luke A Newman, Mackenzie G Patton, Breyanna A Rodriguez, Ethan W Sumner, Valerie Vaissier Welborn
Polarizable force fields crucially enhance the modeling of macromolecules in polar media. Here, we present new parameters to model six common monosaccharides with the polarizable AMOEBA force field. These parameters...
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Li2NbHO2: a new transition-metal oxyhydride with rock-salt-type structure

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05503A, Communication
F Takeiri, Keiko KUSUMOTO, Kosuke Kawai, Hiroshi Yaguchi, Takashi Saito, Kazuhiro Mori, Saburo Hosokawa, Masashi Okubo, Genki Kobayashi
Transition-metal oxyhydrides are an emerging class of functional materials; however, the known compounds have mostly been limited to perovskite-type structures. Here, we successfully synthesized Li2NbHO2, the first example of a...
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Effects of Mixed Phases on Ionic Conductivities for (LaF3)1–x(PbF2)x Fast-Fluoride-Ion-Conducting Solid Electrolytes

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01063A, Paper
Ming Zhang, Yaowei Hao, Qiaojun Nie, Xiaocao Cao, Jiafan Zheng, Kai Zhang, Jun Zheng, Haodong Wang, Yafang Zhao, Jiayi Liu, Zhiguang Lin, Zhongrong Shen
The research on all-solid-state fluoride-ion batteries (FIBs) with a high theoretical energy density has attracted considerable attention due to their enhanced safety features and superior capacity. The selection of solid...
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A boron nitride–carbon composite derived from ammonia borane and ZIF-8 with promises for the adsorption of carbon dioxide

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00643G, Paper
Open Access
Carlos A. Castilla-Martinez, Christophe Charmette, Jim Cartier, Umit B. Demirci
In the present study, we report the synthesis, characterization and assessment of the carbon dioxide adsorption capacity of a composite made of boron nitride and carbon.
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Photocatalytic degradation of tetracycline hydrochloride by BiVO4/MIL-88B(Fe) heterojunction

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01500B, Paper
Ziwei Zhao, Qi Ling, Shangkun Deng, Ziliang Li, Jianguo Lv, Lei Yang, Chunbin Cao, Zhaoqi Sun, Miao Zhang
A type II heterostructured BiVO4/MIL-88B(Fe) composite was successfully synthesised for the photocatalytic degradation of tetracycline hydrochloride (TC-HCl) by a simple hydrothermal method. Thin film materials avoid secondary pollution of powder...
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Effects of silylene ligands on the catalytic activity of [PSiP] pincer cobalt(II) chloride for N2 silylation

New J. Chem., 2024, 48,7334-7339
DOI: 10.1039/D4NJ00883A, Paper
Min Zhang, Yanhong Dong, Qingshuang Li, Xiaoyan Li, Hongjian Sun
Three silyl [PSiP] pincer cobalt(II) chlorides [(2-Ph2PC6H4)2MeSiCo(Cl)(PMe3)] (1), [(2-iPr2PC6H4)2MeSiCo(Cl)(PMe3)] (2) and [(2-Ph2PC6H4)2MeSiCo(Cl)(LSi:)] (LSi: = {PhC(NtBu)2}SiCl) (3) were used as catalysts for dinitrogen silylation was studied.
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Enhanced photocatalytic activity of carbon nitride nanosheets with alkali metal ion doping

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01210K, Paper
Xinhang Sun, Gang Zhao, Songyuan Li, Mingju Huang, Junhui Liu
Photocatalytic degradation of pollutants is one of the most promising strategies for addressing environmental issues associated with wastewater from textile and other dyeing industries. Graphitic carbon nitride (g-C3N4) has emerged...
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Evaluation of adsorption and degradation performance of lanthanum modified mesoporous carbon nitride composite materials for tetracycline wastewater

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00864B, Paper
Zhiqiang Wu, Yueyi Li, Pengxi Jiang, Sisi Ma, Wenfei Dong, Hongjian Zhao, Enke Feng, Xuming Wang
The lanthanum modified mesoporous graphite nitride carbon composites (La-g-C3N4) were synthesized using a thermal shrinkage polymerization method. The samples underwent characterization through the X-ray diffraction (XRD), the fourier transform infrared...
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A novel CuAl2O4/MoS2/BaFe12O19 magnetic photocatalyst simultaneously coupling type I and Z-scheme heterojunctions for the sunlight-driven removal of tetracycline hydrochloride

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00970J, Paper
Mengjun Han, Shifa Wang, Xinmiao Yu, Xianlun Yu, Huajing Gao, Xianju Zhou, Dengfeng Li, Leiming Fang, Jagadeesha Angadi V., Mohd Ubaidullah, Bidhan Pandit
A novel CuAl2O4/MoS2/BaFe12O19 photocatalyst is synthesized that simultaneously couples type I and Z-scheme heterojunctions and exhibits high photocatalytic activity for the degradation of TC under simulated sunlight irradiation.
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Noble-metal-free bimetallic nitride decorated CdS nanorods for photocatalytic hydrogen generation

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00216D, Paper
Lu Chen, Yu Zou Xia, Jiale Shi, Xiaohui Huang, Xiyao Liu, Guiyang Yan, Renkun Huang
Developing highly active and stable non-noble-metal cocatalyst-decorated semiconductors is desirable for the practical application of photocatalysis, which remains an open question. Herein, we report transition-metal nitride (Ni3FeN) loaded cadmium sulfide...
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Taking a ride on the wild side

The dry, salty plains of the Rann of Kutch are a great place for birdwatchers and wildlife photographers, writes DR. RAM GOPALAKRISHNAN




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A boat ride around the globe

On gentle waters inside a dark tunnel, SOMA BASU sets sail on the happiest cruise ever at the Walt Disney World, Florida, and feasts her eyes on the small world that we all live in




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Commuters ride cashless on BEST





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How to Override width and height HTML attributes with CSS

One of the HTML elements that frequently comes into collision with CSS is the img element. As we learned in Request Metrics’ Fixing Cumulative Layout Shift Problems on DavidWalshBlog article, providing image dimensions within the image tag will help to improve your website’s score. But in a world where responsive design is king, we need […]

The post How to Override width and height HTML attributes with CSS appeared first on David Walsh Blog.




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Direct access to pyrrole anhydrides via oxidative self-coupling of pyrrole carboxaldehydes

Org. Biomol. Chem., 2024, 22,3045-3052
DOI: 10.1039/D4OB00052H, Paper
Surabhi Panday, Tapas Maity, Pratibha Bhatti, Joydev K. Laha
An elegant synthesis of pyrrole-2-carboxylic acid anhydrides from pyrrole-2-carboxaldehydes using TBAI as a catalyst and tert-butyl hydroperoxide (TBHP) as an oxidant is described herein.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Discovery of selective monosaccharide receptors via dynamic combinatorial chemistry

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00015C, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Miguel Alena-Rodriguez, Marcos Fernandez-Villamarin, Ignacio Alfonso, Paula M. Mendes
An effective workflow to discover selective saccharide receptors by combining dynamic combinatorial chemistry with isothermal titration calorimetry and NMR.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Notes from a joyride

The new Land Rover Velar looks and acts like the concept car of your dreams




ride

Eğreti gelin = Borrowed bride (2005) / writtem and directed by Atıf Yılmaz [DVD].

Istanbul : Palermo, [2005]




ride

A tour in Scotland and voyage to the Hebrides, 1772 / by Thomas Pennant ; introduction by Charles W.J. Withers ; edited by Andrew Simmons.

Edinburgh : Birlinn ; Chester Springs, PA : U.S. distributor, Dufour Editions, 1998.




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Street stunt rider Danny MacAskill breaks down his most epic tricks | Expert Opinion

It’s been 10 years since Red Bull street trials rider Danny MacAskill burst onto our screens with his iconic 'Inspired Bicycles' video that has now clocked up close to 40 million views on YouTube. In the following 10 years, the Scotsman ditched his job as a bike mechanic and collaborated with Red Bull to bring his epic dreams to life in sensational videos like Way Back Home, Imaginate, Wee Day Out and many more. Danny's videos have clocked up nearly four hundred million views on YouTube. In this video, he looks back at some of his most challenging stunts and tells the stories behind how they came to be. #dannymacaskill #redbull #streettrials You can watch Danny MacAskill's full-length videos below: Wee Day Out: https://www.youtube.com/watch?v=K_7k3fnxPq0 Inspired: https://www.youtube.com/watch?v=Z19zFlPah-o& Imaginate: https://www.youtube.com/watch?v=Sv3xVOs7_No Way Back Home: www.youtube.com/watch?v=Cj6ho1-G6tw With thanks to Danny MacAskill, Red Bull Media House, Getty Images and Fusion Media.




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RE:WIRED GREEN 2022: James McBride on Decarbonizing the World

James McBride, cofounder and chief technology officer of Otherlab, will discuss some of the innovative solutions he and his team are working on to reduce our use of fossil fuels and decarbonize the world.




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Polymer-confined synthesis of gram-scale high-entropy perovskite fluoride nanocubes for improved electrocatalytic reduction of nitrate to ammonia

Nanoscale Horiz., 2024, Advance Article
DOI: 10.1039/D4NH00341A, Communication
Open Access
Guohao Xue, Tianlu Wang, Hele Guo, Nan Zhang, Claire J. Carmalt, Johan Hofkens, Feili Lai, Tianxi Liu
A high-entropy perovskite fluoride with a well-defined nanocubic structure was successfully prepared via a polyvinylpyrrolidone-confined nucleation strategy, demonstrating excellent electrocatalytic activity for nitrate reduction.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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S is for Scooter: A ride back to the future

Even as the wheels of time turn, the scooter will remain a steadfast symbol of resilience and adaptability




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Catalytic kinetic growth of a half-metallic hexagonal boron nitride-graphene lateral heterostructure using transition metal single-atom catalysts on Rh(111)

J. Mater. Chem. A, 2024, 12,30498-30507
DOI: 10.1039/D4TA05741D, Paper
Yandi Zhu, Weihu Li, Xiaoyan Ren, Lili Zhang, Xingju Zhao, Shunfang Li
Transition metal single-atom catalysts (TM = Mn, Zr, Nb, Mo, Hf, Ta, and W) promote growth of a h-BN-G heterostructure on C-dimer-unpreferred Rh(111).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Russian Mail Order Brides: Find Russian Lady For Marriage

Your new bride on-line while rapidly since attainable. Internet relationship websites make strategies easy and understandable. Thanks to the filters, you’ll be capable of place the capabilities in e-mail order brides catalog for the women you want quite presumably probably the most. You should simply order a bride on-line and start the interaction. If you […]




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Ukrainian Mail Purchase Brides ️ Meet Gals For Marriage

Articles Choose Your Mail Buy Brides Internet site Carefully Tips about how to Keep Away From Ukrainian Mail Buy Bride Con? I hesitated regarding utilizing a relationship platform because I thought this wouldn’t guide me have the desired outcomes. Yet, I’ve met Olga after a week of utilizing the setting and instantly felt the flicker […]




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Russian Mail Order Brides: Obtain a Russian Partner On-line

Content How To Warranty You Talk with An Actual Person? Find The Legit Snail mail Order Bride-to-be In 2023: A Complete Information Whilst it largely depend upon which individual’s tastes and situations, current research shows that the necessarily mean age with respect to mail purchase brides is definitely 25 to 35 years good old. So […]




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Bridesagency: Mail Order Bride Service For Top Matches

Content material Signing Up In Amourfeelcom Young Women Thus Far And Get married to Greatest Mail Order Bride Sites & Apps In 2023 Phone calls are available when you make a contact request. They will embrace private e-mail and phone quantity. Making a request is freed from cost after you spend https://mailorderbridereview.com/dominican-brides/ 3000 credits on […]




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How to be A -mail Order New bride And Find A high Bridal Shop?

Content Can you really order a Russian bride-to-be? How to Avoid Receiving Scammed When using a Foreign Online dating Site? Overall, Christian Café mail order brides is one of the greatest Christian dating sites. Christian Cafetín is the ideal strategy to individuals in the Christian community who are searching for a long-term relationship. You can […]




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Composer Vipin Mishra rides to Zanskar Valley with friends to record nomadic music

The travel resulted in a docu-series titled Folkroad, which was screened recently at the Red Lorry Festival in Mumbai.




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Win a stay at Sridevi’s beach house in Chennai, and get a private tour from Janhvi Kapoor

Janhvi Kapoor talks us through her family beach house, now available to guests and the only Indian property on the Airbnb Icons list, the others being the house from Up, a night at the Ferrari Museum, and Prince’s Purple Rain abode among others Win a stay at Sridevi’s beach house, as Janhvi Kapoor takes you through her favourite nooks and things to do, as part of Airbnb Icons



  • Life & Style

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Watch: A ride on the quaint Ooty toy train

The Nilgiri Mountain Railway, of UNESCO World Heritage fame, turned 125 recently




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On full throttle: Rider Anand Dharesan recalls his GS Trophy 2024 memories, his love for riding and more

Anand qualified for the international tournament on his first try competing in a riding event




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Enhanced photocatalytic degradation of tetracycline hydrochloride by hollow nanofiber Ag@ZnGa2O4/ZnO with synergistic effects of LSPR and S-scheme interface engineering

J. Mater. Chem. C, 2024, 12,17448-17457
DOI: 10.1039/D4TC02853H, Paper
Zhiyuan Chen, Wenhui Chen, Peipei Han, Jizhou Yang, Zhi Wan, Peng Hu, Feng Teng, Haibo Fan
Compared with traditional photocatalytic materials, hollow nanofibers can show greatly improved photocatalytic efficiency due to their large specific surface area and more surface-active sites.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Tailoring electromagnetic interference shielding, electrical and thermal properties of poly(vinylidene fluoride) based hybrid nanocomposites with carbon nanofiber and magnetite nanoparticles

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC02880E, Paper
Aleena Sabu, Sabarish Narayanan B. B, Pratheep Kumar Annamalai, Ramanujam Brahmadesam Thoopul Srinivasa Raghava
Flexible polymer nanocomposite films hold great potential for microwave absorption applications and their electromagnetic interference shielding effectiveness (EMI SE) can be tailored by optimising the electrical properties such as conductivity....
The content of this RSS Feed (c) The Royal Society of Chemistry




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Tb(III)-Functionalized MOF Hybridized Bis-crosslinked Networked Hydrogel Luminescent Films for Arginine and Dopamine Hydrochloride Sensing and Anticounterfeiting

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC03444A, Paper
Jiaxuan Pan, JZ Lu, Yichen Shang, Ying Li, Bing Yan
Dopamine and arginine are both important substances in the body and are closely related to human health. Timely detection of their concentration abnormalities is of great significance for dsaevention. In...
The content of this RSS Feed (c) The Royal Society of Chemistry




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New water rides and adventure rides at the water theme park in Mettupalayam

Take a plunge in newly-introduced water slides, fly through the sky, and enjoy the thrills of 5D experience at the Black Thunder Theme Park in Mettupalayam



  • Life & Style

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False Pride and Prejudice

Mallika Sherawat called a spade a spade when she said India is regressive for women. So, then, what elicited such jingoistic fervour among people like Priyanka Chopra and others?




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Symbiotic Strides

Helen Huang and her lab are building better prosthetics by enhancing them with robotics and AI.

The post Symbiotic Strides appeared first on UNC Research Stories.




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Co-culture of benzalkonium chloride promotes the biofilm formation and decreases the antibiotic susceptibility of a Pseudomonas aeruginosa strain

Environ. Sci.: Processes Impacts, 2024, Accepted Manuscript
DOI: 10.1039/D4EM00035H, Paper
Caihong Wang, Qiao Ma, Jiaxin Zhang, Nan Meng, Dan Xu
Benzalkonium chloride (BAC) is a disinfectant with broad-spectrum antibacterial properties, yet despite its widespread use and detection in the environments, the effects of BAC exposure on microorganisms remain poorly documented....
The content of this RSS Feed (c) The Royal Society of Chemistry




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Sweden rides on Ymer and Borg’s facile victories

Ramkumar did manage to save two set points on serve to hold for 3-5, but Borg sealed the first rubber at love in the next game




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A mechanochemical process to capture and separate carbon dioxide from natural gas using boron nitride nanosheets

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00188E, Communication
Srikanth Mateti, Ying (Ian) Chen, Gautham Sathikumar, Qi Han, Shiva Prasad, Reza Ghandehari Ferdowsi, Amrito Battacharjee
A mechanochemical process to store and separate CO2 gas using boron nitride nanosheets.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Pride Month | Of allies like Ujjal Dosanjh

Let’s not forget those who stand up for LGBTQIA+ rights even when they don’t necessarily have to




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For Onam 2023, Mahabali comes visiting Kerala astride a hornbill in Sabari Venu’s animated art work

Sabari Venu has been reimagining Mahabali to come up with images that do justice to the idea of what he represents to Malayalis




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The Value of Time : Evidence From Auctioned Cab Rides [electronic journal].

National Bureau of Economic Research




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Sharing when stranger equals danger: Ridesharing during Covid-19 pandemic [electronic journal].




ride

Riders on the Storm [electronic journal].

National Bureau of Economic Research