J. Mater. Chem. A, 2024, 12,30169-30189
DOI: 10.1039/D4TA05143B, Review Article

Longkun Wu, Xinyan Zhu, Zhi Peng, Zekun Zhang, Ningning Zhao, Bin Li, Jing Zhu, Lei Dai, Ling Wang, ZhangXing He
Regulation strategies for zinc anode ion deposition.
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J. Mater. Chem. A, 2024, 12,30498-30507
DOI: 10.1039/D4TA05741D, Paper

Yandi Zhu, Weihu Li, Xiaoyan Ren, Lili Zhang, Xingju Zhao, Shunfang Li
Transition metal single-atom catalysts (TM = Mn, Zr, Nb, Mo, Hf, Ta, and W) promote growth of a h-BN-G heterostructure on C-dimer-unpreferred Rh(111).
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J. Mater. Chem. A, 2024, 12,30601-30610
DOI: 10.1039/D4TA05955G, Paper

Song-Bai Xiang, Xiyu Zhang, Yue Hou, Wenjing Li, Chengri Yin, Zhenxing Yin
A 3D soft current collector with excellent lithiophilicity was obtained by constructing a conductive Ag-CuNW/MWCNT network on a melamine foam, which can effectively reduce the local current density and guide the uniform Li deposition.
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J. Mater. Chem. A, 2024, 12,30582-30590
DOI: 10.1039/D4TA06282E, Paper

Zitong Chen, Linghui Cao, Aogang Liu, Pengda Liu, Yuan Chen, Juntao Yan, Bao Li
An indium-based metal–organic framework bearing a pyrazinoquinoxaline derivative is synthesized to facilitate two methods for the construction of CN bonds, and their mechanisms are investigated through detailed theoretical calculations.
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J. Mater. Chem. A, 2024, 12,30591-30600
DOI: 10.1039/D4TA06346E, Paper

Lingwen Zhao, Juanjuan Feng, Adeel Abbas, Hao Sun, Chunlei Wang, Hongchao Wang
Unsaturated coordination modulation alters the discharge path and increased pore size accelerates ion exchange and oxygen transport, synergistically improving the electrochemical performance of LOBs.
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J. Mater. Chem. A, 2024, 12,30743-30756
DOI: 10.1039/D4TA05082G, Paper

Niranjanmurthi Lingappan, Sandhiya Lakshmanan, Wonoh Lee
Designing an efficient and durable electrocatalyst is central to hydrogen production technologies such as hydrogen evolution reaction, oxygen evolution reaction, and urea oxidation reaction.
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J. Mater. Chem. A, 2024, 12,30190-30248
DOI: 10.1039/D4TA05386A, Review Article

Elmira Kohan, Roushan Khoshnavazi, Mir Ghasem Hosseini, Abdollah Salimi, Mehdi Salami-Kalajahi
Degradation phenomena in different components (cathode, anode, current collectors (CCs)) of mono- and divalent metal-based batteries affect their performance.
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J. Mater. Chem. A, 2024, 12,30318-30328
DOI: 10.1039/D4TA06211F, Paper

Wenqing Fan, Kang Liang, Jieying Liang
A one-pot strategy was developed for the first time to achieve the precise spatial arrangement of multiple enzymes in MOFs, improving multi-enzyme cascade efficiency.
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J. Mater. Chem. A, 2024, 12,30685-30691
DOI: 10.1039/D4TA05576D, Paper

Qian Xu, Peng Zhang, Yuanyuan Sun, Jishi Chen, Chuantao Hou, Zonghua Wang
A porphyrin box-based MOF with hierarchical superstructures was synthesized, exhibiting enhanced performance in singlet oxygen-mediated photooxidation.
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J. Mater. Chem. A, 2024, 12,30454-30464
DOI: 10.1039/D4TA02526A, Paper

Taylor Jade Self, Jiabin Niu, Wen Liu, Chaobin He, Mei Chee Tan
Sustainable substitutions in MOF fabrication and processing can confidently be made by employing redox engineering for synergistic valency and defect constitution, based on application, without sacrificing active site functionality.
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J. Mater. Chem. A, 2024, 12,30409-30419
DOI: 10.1039/D4TA05443A, Paper

Yue Cao, Shengbo Yuan, Wenbo Zhou, Yan Hai, Xiaoman Li, Min Luo
NO₃⁻ and H₂O molecules adsorbed on the surface of Co–N–C-500 are activated and dissociated. The generated active hydrogen species (*H) can promote the hydrogenation of the intermediates and thus increase the NH₃ yield.
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J. Mater. Chem. A, 2024, 12,30872-30884
DOI: 10.1039/D4TA05266H, Paper

Haijiao Lin, Hui Wang, Yongguang Yang, Yuxuan Zhang, Ling Li, Youwei Zhao, Wenming Zhang
Smart fabrics with liquid metal reinforced PU/CNT/MXene multilayer structures for constructing multifunctional sensors and wearable electronics.
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06515H, Communication

Hefeng Wang, Zixiao Li, Zhengwei Cai, Chaoxin Yang, Shengjun Sun, Xiaoyan Wang, Min Zhang, Meng Yue, Dongdong Zheng, Asmaa Farouk, Mohamed S. Hamdy, Xuping Sun, Bo Tang
Ir nanoparticle decorated NiFe metal–organic framework on Ni foam (Ir@NiFe-MOF/NF) acts as a bifunctional catalyst for the oxygen evolution reaction and the hydrogen evolution reaction in alkaline seawater with excellent performance and stability.
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06294A, Paper

Chao Wei, Ming Lu, Jing-Jing Li, Ze-Jiu Diao, Guoliang Liu, Xiao-Qin Liu, Lin-Bing Sun
A doubly interpenetrated perylene diimide-based zirconium metal–organic framework is developed as a heterogeneous photocatalyst for selective photocatalytic oxidation of organic sulfides powered by blue light.
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J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06468B, Review Article

Hansai Wu, junming Zhang, Zicong Wang, Xianglong Kong, Gaofu Li, Ying Zhao, Piaoping Yang, Zhiliang Liu
N-ethylcarbazole (NEC) hydrogen storage has garnered significant attention owing to its large-scale safe storage of hydrogen superiority. However, the sluggish hydrogenation kinetics in NEC are extremely dependent on catalysts with...
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06232A, Paper

Zahir Abbas, Shaikh M. Mobin
A c-MOF is grown on MX-CNF, which was prepared via electrospining method. Furthermore, it utilized for flexible supercapcitors with different flexibility angles.
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J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06497F, Paper

Mohsen Tamtaji, William A. Goddard III, Guanhua Chen
Metal complexes have been thoroughly investigated for a wide range of electrochemical reactions. However, mechanically interlocked molecular machines (MIM) have not been investigated for electrochemistry through a systematic high throughput...
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J. Mater. Chem. C, 2024, 12,17574-17586
DOI: 10.1039/D4TC02458C, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Zahida Malik, Sarah Broadley, Sebastian J. C. Herkelrath, Daniel W. Newbrook, Liam Kemp, George Rutt, Zoltán A. Gál, Jack N. Blandy, Joke Hadermann, Daniel W. Davies, Robert D. Smyth, David O. Scanlon, Ruomeng Huang, Simon J. Clarke, Geoffrey Hyett
The optoelectronic properties of two layered copper oxyselenide compounds, with nominal composition Sr₂ZnO₂Cu₂Se₂ and Ba₂ZnO₂Cu₂Se₂, have been investigated to determine their suitability as p-type conductors.
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J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC02970D, Paper

Chu Chu, Wenjing Zhang, Xuehua Yan, Yingnan Yan, Jianmei Pan, Zohreh Shahnavaz, Jamile Mohammadi Moradian
The specific capacitance of NCA₁₅-MOF/NF was 1317 F g⁻¹, which was significantly higher compared to the NCA₀-MOF/NF. After 15 000 charge–discharge cycles, the NCA₁₅-MOF/NF retained 89% of its initial specific capacitance.
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J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03273J, Review Article

Pingchun Guo, Shisong Ouyang, Hedong Jiang, Jiake Li, Hua Zhu, Yanxiang Wang
Metal–organic frameworks (MOFs) are regarded as potential candidate materials for the cathodes of aqueous zinc-ion batteries. This review presents the applications of MOFs and their derivatives in the cathodes of aqueous zinc-ion batteries.
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J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03148B, Paper

Ying Li, Zhongquan Yu, Jialuo Zhang, Enke Feng, Xiaoqin Li, Linan Cao, Zhiming Yang, Zhiqiang Wu
A UiO-66-NH₂ nanoparticle reinforced organohydrogel with anti-freezing and UV-blocking properties was synthesized for sensing complex human movements and transmitting different messages even at subzero temperature.
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Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00468F, Review Article

Open Access

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Jamal Abdul Nasir, Andrew M. Beale, C. Richard A. Catlow
Transition metal-containing zeolites have received considerable attention, owing to their application in the selective catalytic reduction of NO_x. To understand their chemistry, both structural and mechanistic aspects at the atomic level are needed.
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Chem. Soc. Rev., 2024, 53,10450-10490
DOI: 10.1039/D4CS00527A, Review Article

Open Access

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Denis Leybo, Ubong J. Etim, Matteo Monai, Simon R. Bare, Ziyi Zhong, Charlotte Vogt
Metal–support interactions (MSI) impact catalyst activity, stability, and selectivity. This review critically evaluates recent findings, theoretical advances, and MSI tuning strategies, offering new perspectives for future research in the field.
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Chem. Soc. Rev., 2024, 53,10409-10449
DOI: 10.1039/D4CS00802B, Tutorial Review

Brooke L. McNeil, Caterina F. Ramogida
This tutorial review explores the fundamentals and applications behind the production and purification of radiometals in the burgeoning field of radio-theranostics.
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Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00484A, Tutorial Review

Hao Lv, Ben Liu
This perspective summarizes recent progress in rational design and synthesis of multidimensionally ordered mesoporous intermetallics, and propose new frontier nanoarchitectonics for designing high-performance functional nanocatalysts.
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Chem. Soc. Rev., 2024, 53,10800-10826
DOI: 10.1039/D3CS00273J, Tutorial Review

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Zhixing Lin, Hai Liu, Joseph J. Richardson, Wanjun Xu, Jingqu Chen, Jiajing Zhou, Frank Caruso
This review provides a guideline for the rational design of metal–phenolic network (MPN) composites—which are fabricated from MPN and one or more functional components (e.g., drugs, proteins)—for various applications across diverse disciplines.
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Chem. Soc. Rev., 2024, 53,11004-11044
DOI: 10.1039/D4CS00742E, Review Article

Reena Balhara, Ritwika Chatterjee, Garima Jindal
This review provides a mechanistic overview of asymmetric Fe, Cu, Pd, Rh, Au and heme-based enzymes catalyzed carbene insertion reactions to construct  C–X (X = O, N, S, etc.) and C–C bonds, focusing on the stereochemical models.
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Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D3EM00546A, Paper

Manuella Ghanem, Laurent Y. Alleman, Davy Rousset, Esperanza Perdrix, Patrice Coddeville
Experimental conditions such as extraction methods and storage conditions induce biases on the measurement of the oxidative potential and the bioaccessibility of transition metals from welding fumes.
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Mater. Horiz., 2024, 11,1611-1637
DOI: 10.1039/D3MH01645E, Review Article

Yannan Liu, Shengyun Huang, Xing Huang, Dongling Ma
Metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) photocatalysts face challenge in poor photocatalytic efficiency, which was promoted by the introduction of plasmonic nanoparticles (NPs) and junctions.
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Mater. Horiz., 2024, 11,1797-1807
DOI: 10.1039/D3MH02090H, Communication

Yaning Fan, Junjun Zhang, Jie Han, Mengyuan Zhang, Weiwei Bao, Hui Su, Nailiang Wang, Pengfei Zhang, Zhenghong Luo
The obtained bimetallic sulfide catalyst can be reconstituted as FeCoOOH, which has high efficacy for water splitting. The activation energy barrier of key reaction steps can be effectively reduced by dual-metal cooperation.
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Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D3MH02185H, Communication

Zhanning Liu, Chengyong Xing, Shaowen Wu, Min Ma, Jian Tian
The large inherent flexibility and highly modular nature of metal-organic frameworks (MOFs) made them ideal candidates for the study of negative thermal expansion (NTE). Among the diverse organic ligands, the...
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Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00142G, Communication

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Tunde Blessed Shonde, He Liu, Oluwadara Joshua Olasupo, Alexander Bouchard, Sara Bouchard, Annaliese Franklin, Xinsong Lin, Luis M. Stand, Biwu Ma
An AIE organic zinc chloride complex scintillator, in which the metal halide serves as X-ray sensitizer for the organic component, is discovered to exhibit a light yield of 13 423 Photon per MeV and a radioluminescence decay lifetime of 5.24 ns.
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Mater. Horiz., 2024, 11,1989-1996
DOI: 10.1039/D3MH02025H, Communication

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Vincent R. F. Schröder, Nicolas Fratzscher, Nicolas Zorn Morales, Daniel Steffen Rühl, Felix Hermerschmidt, Eva L. Unger, Emil J. W. List-Kratochvil
Using a sequential inkjet printing process, we realize bicoloured PeLEDs by selectively dissolving a bromide-based perovskite film with an iodide-based perovskite ink, resulting in red light-emitting features on a green light-emitting background.
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Inorg. Chem. Front., 2024, 11,1998-2006
DOI: 10.1039/D4QI00113C, Research Article

Mengna Li, Benlai Wu, Maochun Hong
Highly stable Cr-HMOFs Cr-HMOF-1 and Cr-HMOF-2 were synthesized for the first time directly using enantiomerically pure chiral ligands, showing excellent enantioselective separation performance for aromatic alcohol racemates.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00255E, Review Article

Xunhuai Huang, Junpeng Song, Guanyu Wu, Zhihuan Miao, Yanhua Song, Zhao Mo
Modification strategy and synthesis method of a metal sulfide-mediated carbon nitride photocatalytic H₂ production system.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00254G, Research Article

Yan-Hu Wang, Ke-Wei Tong, Chao-Qin Chen, Jing Du, Guo-Ping Yang, Peng Yang
An adjustable template effect was employed to activate the evolution of polyoxovanadate-based metal–organic clusters, resulting in unprecedented structural archetypes as well as customized dye and iodine adsorption features.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00304G, Review Article

Xiao-Xiang Zhou, Yongshi Ye, Qia-Chun Lin, Wei-Ming Liao, Jun He
It outlines influencing factors of photocatalytic CO₂ reduction coupled with water oxidation, along with catalytic mechanisms and performance enhancement strategies.
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Inorg. Chem. Front., 2024, 11,2281-2289
DOI: 10.1039/D4QI00314D, Research Article

Wei Wu, Xiu-Liang Lv, Tao He, Guang-Rui Si, Hongliang Huang, Lin-Hua Xie, Yabo Xie, Jian-Rong Li
High catalytic performance of porphyrin-based MOFs has been achieved by introducing multiple functionality into their ligands and modulating their conformation.
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Inorg. Chem. Front., 2024, 11,2402-2412
DOI: 10.1039/D3QI02662K, Research Article

Ran An, Qiu-Yan Hu, Liu-Yang Song, Xu Zhang, Rui-Xuan Li, En-Qing Gao, Qi Yue
Two isostructural homochiral MOFs exhibit significantly different enantioselective recognition performances closely associated with the different coordination habits of the metal centers in the MOFs.
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Inorg. Chem. Front., 2024, 11,2479-2488
DOI: 10.1039/D4QI00145A, Research Article

Yiwei Zhao, Chao Zhang, Shuangxi Xing, Zuhang Jin, Tingting Xiao
ECO of HMF to FDCA and ECR to BHMF with high yield have been studied on CuNi-based bimetallic catalysts. The presence of the Cu–O–Ni interfacial area was beneficial for promoting the catalytic performance in ECO.
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Inorg. Chem. Front., 2024, 11,2300-2311
DOI: 10.1039/D4QI00391H, Research Article

Qiujun Wang, Xin He, Di Zhang, Zhaojin Li, Huilan Sun, Qujiang Sun, Bo Wang, Li-Zhen Fan
The introduction of Al₂O₃ regulates the solvation structure of Na⁺, which is conducive to the formation of inorganic-rich SEI. Na|THFA-5|Na cell maintains low polarization voltage, indicating that uniform Na depositions was successfully achieved.
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00038B, Research Article

Ting-Bo Liu, Jing-Wen Deng, Li Yi, Hai-Ying Fu, Liang-Wen Shi, Shi-Ying Lin, Yue Liu, Hao-Hong Li, Jing-Bo Liu, Jian-Zhi Liu
The development of green memorizers with distinct mechanism is significant. In this work, renewable polyphenol ellagic acid (EA) and environmentally friendly calcium were used to construct a unique 3D interpenetrated...
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00482E, Research Article

Yumeng Bian, Runze Wang, xinxin xu, Jin Chen, Qiang Wang
Biofouling is adhering of micro-organisms on submerged surfaces, which is a common phenomenon presents serious hazard to industry and public health. Nanozymes with haloperoxidase mimic activity are promising options to...
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D3QI02335D, Research Article

Jiayi Guo, Danni Hu, Chenqi Bai, Lina Xu, Hongping Xiao, Qian Shi, Xinhua Li, Xi'an Chen, Yingjin Ma, Guoyong Fang
Density functional theory calculations show that Ta_n+1C_n and Ta_n+1C_nO₂ MXenes have excellent open circuit voltages and maximum storage capacities for use in alkali metal-ion batteries.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00522H, Research Article

Ming Chen, Sha Luo, Zongyan Ma, Fei Yuan, Jing Chen, Linkun Dong, Weiwen Mao, Jiantai Ma
In this study, a novel FeNi sulfide catalyst loaded on carbon nanotubes (CNTs) (FeNiS/CNTs) shows excellent OER electrocatalytic performance in alkaline solutions.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00605D, Research Article

Xiaoxue Ma, Xin Li, Xueke Han, Lu Zhang, Ronghua Liu, Hongguo Hao, Hui Yan, Xin Zhao, Xiangjin Kong, Huawei Zhou, Xia Li, Hongjie Zhu, Suna Wang, Yunwu Li, Dichang Zhong, Fangna Dai
Two outstanding proton conducting materials have been obtained by loading TFA molecules onto/into the surface or pores of MOFs. After post-treatment, their proton conductivity values are greatly increased under the same conditions.
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