Dalton Trans., 2024, 53,17918-17933
DOI: 10.1039/D4DT02542C, Paper

Krishnendu M. Nair, Pavithra Shankar, Selvaraju Thangavelu
Electrocatalytic overall water splitting is achieved with ease at 1.58 V together with exciting stability over 48 h.
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Dalton Trans., 2024, 53,17902-17908
DOI: 10.1039/D4DT02609H, Paper

Xiang Yu, Xinyu Xu, Lei Gao, Rengan Luo, Yi-Fan Liu, Yu-Hao Gu, Shuai Yuan
A series of isostructural polyoxometalate-based MOFs were constructed by linking polyoxometalates and metal clusters with imine bonds under mild conditions.
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Dalton Trans., 2024, 53,18027-18036
DOI: 10.1039/D4DT02642J, Paper

Alexander V. Artem'ev, Maria P. Davydova, Lyubov S. Klyushova, Evgeniy H. Sadykov, Mariana I. Rakhmanova, Taisiya S. Sukhikh
Based on 2-(diphenylphosphino)-1,10-phenanthroline, a series of small metal(I) clusters, exhibiting orange to NIR phosphorescence and strong dose-dependent cytotoxicity.
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Dalton Trans., 2024, 53,17934-17947
DOI: 10.1039/D4DT01996B, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Katarzyna Choroba, Joanna Palion-Gazda, Mateusz Penkala, Patrycja Rawicka, Barbara Machura
The impact of cyclometalating ligands on the photophysical behaviour of heteroleptic Ir(III) complexes with imidazo[4,5-f][1,10]phenanthroline. [Ir(ppy)₂(imphen)]⁺ is a ³MLLCT emitter, while [Ir(pybzth)₂(imphen)]⁺ has a predominant ³LC_N∩C character.
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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02873B, Paper

Sofie S. Leiszner, Mauro Perfetti, Emil Damgaard-Møller, Yu-Sheng Chen, Bo B. Iversen
By investigating second coordination sphere effects on the magnetic anisotropy of a Co(II) single molecule magnet (SMM), we aim to clarify their role in magneto-structural correlations to enhance the performance of transition metal SMMs.
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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02258K, Paper

Ceyda Icsel, Seyma Aydinlik, Muhittin Aygun, Veysel T. Yilmaz
Highly cytotoxic dinuclear oxo-bridged Fe(III) saccharinate complex with tris(2-pyridylmethyl)amine induces excessive ROS generation, mitochondrial and DNA damage in HT29 colon cancer cells.
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Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02605E, Paper

Junxun Zhou, Mengyue Jiang, Qiangqiang Zhang, Yuan Jiang, Haifang Wang, Lining Sun
Photodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...
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Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00388H, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Philipp Stinshoff, Yannic Henn, Steffen H. Rommel, Brigitte Helmreich
Heavy metals bound to filter media from stormwater control measures can leach out under unfavorable conditions. The potential overestimation due to different prestressing (lab vs. field) was evaluated with respect to the potential mobile fraction.
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Energy Environ. Sci., 2024, 17,8349-8359
DOI: 10.1039/D4EE03232B, Paper

Da-Qian Cai, Haiyang Cheng, Jin-Lin Yang, Huan Liu, Tao Xiao, Xin Liu, Minghua Chen, Hong Jin Fan
The Zn/electrolyte interface with parallelly adsorbed Pym molecules can efficiently suppress corrosion and HER and simultaneously accelerate Zn redox kinetics by inducing zincophilicity.
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Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03289F, Paper

Ya Chen, Xin Gao, Zheng Zhen, Xiao Chen, Ling Huang, Deli Zhou, Tengfei Hu, Bozhen Ren, Runjing Xu, Jiayi Chen, Xiaodong Chen, Lifeng Cui, Guoxiu Wang
The established multifunctional interlayers effectively eliminate both anode-initiated and GB-initiated dendrites and guarantee satisfactory battery performance for ASSLMBs.
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Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03468F, Review Article

Zhi Zheng, Xue Fang, Wei Deng, Peng Li, Xiaobo Zheng, Hang Zhang, Lin Li, Shulei Chou, Yuan Chen, Yongbing Tang, Jiazhao Wang
Quantitative detection and characterization methods for analysis of metallic Li and related inactive components of Li batteries and their related characteristics are discussed.
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Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03673E, Paper

Jiaming Zhu, Cong Kang, Xiangjun Xiao, Ya Mao, Ying Luo, Yuheng Wang, Quansheng Zhang, Yulin Ma, Chunyu Du, Shuaifeng Lou, Fanpeng Kong, Jingying Xie, Geping Yin
A heterogeneous collector featuring hard-base sites and soft-acid sites is proposed, which significantly reduces nucleation and growth barriers, with no dendrite formation. This finding offers a pathway to rationally design highly efficient collectors for AFLMBs.
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Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04122D, Paper

Mengyu Liu, Wentao Yuan, Xinghan Qu, Xianghao Ru, Xiaotong Li, Tingxuan Wang, Xinke Wang, Yuanyuan Wang, Yongchang Liu, Ning Zhang
Realizing stable zinc (Zn) metal anodes under deep cycling conditions is the prerequisite for practical rechargeable Zn batteries but remains a significant challenge, due to severe water erosion and dendrite...
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Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04442H, Review Article

Xiaomin Han, Ran Zhao, Jingjing Yang, Yahui Wang, Anqi Zhang, Zhifan Hu, Mengge Lv, Chuan Wu, Ying Bai
To meet the challenges raised by the utilization of intermittent clean energies, rechargeable aqueous zinc ion battery (AZIB) stands at the forefront due to its competitive capacity, low cost, and...
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Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03978E, Paper

Xueyu Lian, Liang Xu, Zhijing Ju, Ziang Chen, Xiaopeng Chen, Yuyang Yi, Zhengnan Tian, Tao Cheng, Shi Xue Dou, Xinyong Tao, Jingyu Sun
The electric double layer (EDL) plays a key role in constructing solid electrolyte interphase (SEI) for high-energy metal anodes. Nevertheless, the significance of EDL and its associated influence remain elusive...
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Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04320K, Paper

Meihua Tang, Chunping Wang, Zhenying Zheng, Xiaoxiao Wang, Fulong Zhu, Shengli Chen
The oxygen reduction reaction (ORR) in proton exchange membrane fuel cells (PEMFCs) is severely hindered by the strong adsorption of sulfonate groups in perfluorinated sulfonic acid (PFSA) ionomers on Pt,...
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Energy Environ. Sci., 2024, 17,8855-8865
DOI: 10.1039/D4EE03102D, Paper

Dongmin Li, Yunpeng Zhong, Xieyu Xu, Daren Zhou, Yan Tang, Liangbing Wang, Shuquan Liang, Bingan Lu, Yangyang Liu, Jiang Zhou
Asymmetry of stripping/plating of the Zn anode dominates dendrite evolution and cell failure. To regulate it, a 2H8D electrolyte with a water-poor solvated structure is designed to construct a Cl-rich SEI, achieving long-lasting reversibility of ZBs.
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Energy Environ. Sci., 2024, 17,8457-8481
DOI: 10.1039/D4EE03097D, Review Article

Xinyuan Shan, Zhaowei Song, Hang Ding, Lengwan Li, Yuhang Tian, Alexei P. Sokolov, Ming Tian, Kang Xu, Peng-Fei Cao
The high-cation transport number polymer electrolytes (HTPEs) with simultaneously high cation transport number and high ionic conductivity could provide a solution to enable high-performance solid-state batteries.
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Energy Environ. Sci., 2024, 17,8874-8884
DOI: 10.1039/D4EE02777A, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Ievgen Obraztsov, Rostislav Langer, Jean G. A. Ruthes, Volker Presser, Michal Otyepka, Radek Zbořil, Aristides Bakandritsos
Mesoscale engineering of small organic molecules towards a 3D nanowire network offers a potent toolkit for improved energy storage performance.
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Energy Environ. Sci., 2024, 17,8915-8925
DOI: 10.1039/D4EE03406F, Paper

Seungbok Lee, Sungjun Oh, Seungseok Han, Dongchan Lee, Jihyung Lee, Yonghwi Kim, Hoe-Yeon Jeong, Jin-Woo Lee, Min-Ho Lee, Wu Bin Ying, Seonju Jeong, Seungjae Lee, Junho Kim, Yun Hoo Kim, Bumjoon J. Kim, Eun-chae Jeon, Taek-Soo Kim, Shinuk Cho, Jung-Yong Lee
Highly efficient and stretchable organic solar cells were developed with a novel liquid metal top electrode. Metallic interlayers enabled its fabrication via thermal evaporation, achieving 14.6% PCE and 70% PCE retention under 63% strain.
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Energy Environ. Sci., 2024, 17,8966-8977
DOI: 10.1039/D4EE02815E, Paper

Mi Xu, Beinuo Zhang, Yudong Sang, Dan Luo, Rui Gao, Qianyi Ma, Haozhen Dou, Zhongwei Chen
A bicontinuous-phase electrolyte with a well-balanced solvation sheath is proposed, which delivers fast desolvation kinetics and generates a uniform in situ solid electrolyte interface, thus achieving a long-lasting Zn anode at low temperatures.
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Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04085F, Paper

Zongliang Xie, Zhiyuan Huang, He Li, Tianlei Xu, Haoyu Zhao, Yunfei Wang, Pang Xi, Zhiqiang Cao, Virginia Altoe, Liana M Klivansky, Zaiyu Wang, Steven Shelton, Shiqi Lai, Peng Liu, Chenhui Zhu, Michael D. Connolly, Corie Y. Ralston, Xiaodan Gu, Zongren Peng, Jian Zhang, Yi Liu
High-performance, thermally resilient polymer dielectrics are essential for film capacitors used in advanced electronic devices and renewable energy systems, particularly at elevated temperatures where conventional polymers fail to perform. Compositing...
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React. Chem. Eng., 2024, 9,940-949
DOI: 10.1039/D3RE00605K, Paper

Jiayao Qi, Hanqiong Jia, Fei Wang, Hang Gao, Bo Qin, Xinwei Zhang, Jinghong Ma, Yanze Du, Ruifeng Li
An effective approach for upgrading light cycle oil (LCO) is the targeted conversion of poly-aromatic hydrocarbons to valuable monoaromatic hydrocarbons.
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React. Chem. Eng., 2024, 9,816-824
DOI: 10.1039/D3RE00513E, Paper

Pariyawalee Sangteantong, Kunpirom Chainarong, Waleeporn Donphai, Metta Chareonpanich
In this work, the green synthesis of mesoporous silica (MPS) was carried out using low-cost sodium silicate as a precursor.
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React. Chem. Eng., 2024, 9,967-973
DOI: 10.1039/D3RE00525A, Paper

Shaoyuan Guo, Xinli Tong, Jipeng Wang, Hang Tang
A stable and efficient high entropy catalyst is developed for the selective oxidative C–C bond cleavage in the presence of O₂.
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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00129J, Paper

Weixiao Sun, Fuzeyu Zhong, Xiaohu Ge, Wenyao Chen, Gang Qian, Yueqiang Cao, Xuezhi Duan, Xinggui Zhou, Jing Zhang
5-Hydroxymethylfurfural (HMF) has been listed as the “TOP 14” most important biomass-derived platform molecules, which can be converted into 2,5-bis(hydroxymethyl)furan (BHF) via selective hydrogenation of the carbonyl group on HMF.
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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00014E, Paper

Open Access

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Soritz S., Sommitsch A., Irndorfer S., Brouczek D., Schwentenwein M., Priestley I. J. G., Iosub A. V., Krieger J. P., Gruber-Woelfler H.
A ceramic flow calorimeter for metal-sensitive reactions is characterized and used to obtain thermokinetic data on highly exothermic reactions.
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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00070F, Paper

Zhihui Wang, Wenbo Li, Xinyao Fu, Chen Zhang, Wei Zhang, Long Huang, Cuiqing Li
LDH-derived CuCeMgAl mixed metal oxide catalysts were synthesized. Ce addition promoted Cu dispersion and improved catalyst basicity, resulting in high activity in furfuryl alcohol hydrogenolysis and high selectivity toward 1,2-pentanediol.
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Food Funct., 2024, Accepted Manuscript
DOI: 10.1039/D4FO01929F, Paper

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Eduard Flores Ventura, Manuel Bernabeu, Belén Callejón Leblic, Raúl Cabrera-Rubio, Laxmi Yeruva, Javier Estañ-Capell, Cecilia Martínez-Costa, Tamara García-Barrera, Maria Carmen Collado
Background: The profile of metal (loid)s in human milk is essential for infant growth and development, yet its impact on the development of the infant microbiota remains unclear. Elements such...
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01028K, Paper

Open Access

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Dominik Neukum, Maya Eyleen Ludwig, Georgios Uzunidis, Ajai Raj Lakshmi Nilayam, Baerbel Krause, Silke Behrens, Jan-Dierk Grunwaldt, Erisa Saraçi
The synthesis of renewable bio-based monomers, like 2,5-furandicarboxylic acid (FDCA), is of high interest in the shift toward a circular economy. Bimetallic catalysts offer the variation of different properties, enabling...
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00685B, Paper

Ray Miyazaki, Somayeh Faraji, Sergey V. Levchenko, Lucas Foppa, Matthias Scheffler
Vibrational frequencies can be utilized as a reference to assess the reliability of the exchange–correlation functionals.
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Catal. Sci. Technol., 2024, 14,6411-6419
DOI: 10.1039/D4CY00808A, Paper

Manish Kumar, Bharat Singh, Sugandha Singh, Indresh Verma, Kamal K. Kar, Manas K. Ghorai
A metal-free, conjugated organic polymer (TPA-PQ)-catalyzed intramolecular C–H functionalization strategy for the synthesis of imidazolidines in the presence of light and O₂ is reported.
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Catal. Sci. Technol., 2024, 14,6321-6330
DOI: 10.1039/D4CY00807C, Paper

Andrija Kokanović, Dunja Pupavac, Stéphane Chenot, Stéphane Guilet, Igor M. Opsenica, Slavica Stankic
In this study, we explore the catalytic activity of highly pure PdZn–ZnO nanopowder, synthesized via an innovative metal–organic chemical vapor synthesis (MOCVS) method.
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Catal. Sci. Technol., 2024, 14,6198-6206
DOI: 10.1039/D4CY00945B, Paper

Jinwon Choi, Amol Pophali, Byeongseok Kim, Kwangsuk Yoon, Thomas You-Seok Kim, Hocheol Song, Sang Eun Shim, Jaewoo Kim, Taejin Kim
RuO_x/BNNT catalysts were prepared with varying metal loadings and under oxidation and reduction conditions. RuO_x/BNNT showed superior catalytic activity than Ru/BNNT. The catalyst will be favorable to the ER mechanism over the LH mechanism.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01007H, Paper

Andrew C. Chien, Corinna C. Chi
The La/Ni/SDC catalyst from one pot microwave-heating gives higher methanation activity than La–Ni/SDC and Ni–La/SDC from stepwise heating.
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY00981A, Paper

Yufeng Wu, Jiajie Kang, Li Jianing, Mingshu Bi, Qingwei Meng
Debenzylations are widely used in fields such as pharmaceuticals and fine chemicals. In this study, metal-free tubular carbon nitride (CN-T) was prepared and used to the photocatalytic debenzylations with molecular...
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Catal. Sci. Technol., 2024, 14,6651-6661
DOI: 10.1039/D4CY01000K, Paper

Jonathan Y. C. Ting, George Opletal, Amanda S. Barnard
The structural patterns and catalytic activities of the surface atoms of simulated metal nanoparticles are characterised by an automatable data-driven unsupervised machine learning approach.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01004C, Paper

Pavan Dongapure, Jyoti Tekawadia, V. Satyam Naidu, R. Nandini Devi
Supported metal catalysts have made prominent contributions to CO₂ mitigation through conversion into useful chemicals.
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Nanoscale, 2024, 16,20342-20353
DOI: 10.1039/D4NR02984D, Paper

Open Access

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Rocío Sánchez-de-Armas, Nicolás Montenegro-Pohlhammer, Emilio M. Pérez, Enrique Burzurí, Carmen J. Calzado
A DFT study of mechanically bonded magnetic Co²⁺ and Cu²⁺ dimeric metal–porphyrin rings around carbon nanotubes (mMINTs) points to defcts in the NT as responsible for the different dimer–nanotube interactions and the loss of the Co²⁺ EPR signal.
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Nanoscale, 2024, 16,20168-20181
DOI: 10.1039/D4NR03397C, Paper

Open Access

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Daniel Garstenauer, Patrick Guggenberger, Ondřej Zobač, Franz Jirsa, Klaus W. Richter
The intermetallic phases Ni₃Te₂, NiTe, NiTe_2−x & NiTe₂ were synthesized as carbon-black supported nanoparticles using the vapour–solid synthesis approach and were characterized for their performance in electrocatalytic hydrogen evolution.
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Nanoscale, 2024, 16,20082-20088
DOI: 10.1039/D4NR03940H, Communication

Minling Zheng, Yubo Liu, Qifu Zhang, Wenjing Li, Yong Zhang, Guangxue Feng, Yating Hu, Shaoming Huang
A bimetallic CoNi-MET with fixed metal occupancy combines the strong water resistance of Co-MET with the high porosity of a Ni-MET.
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Nanoscale, 2024, 16,19998-20026
DOI: 10.1039/D4NR01354A, Review Article

Raja Muthuramalingam Thangavelu, Washington Luis da Silva, Nubia Zuverza-Mena, Christian O. Dimkpa, Jason C. White
This critical review comprehensively analyses nano-sized metal oxide fertilizers (NMOFs) and their transformative potential in sustainable agriculture.
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02663B, Paper

Open Access

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Joshua Nicks, Thomas M. Roseveare, Michael S. Harris, David J. Ashworth, George Danczuk, Lee Brammer, Jonathan A. Foster
The effects of linker length on nanosheet dimensions and properties are investigated through the ultrasonic liquid exfoliation of an isoreticular series of layered metal–organic frameworks.
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03640A, Paper

Jia-Lin Li, Ting-Yu Tien, Hung-Chun Liao, Hsin-Lun Wu
Size-tuned intermetallic PdCd nanocubes, synthesized via a quantum dot-like method, reveal novel size-dependent optical properties.
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Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR02556C, Paper

Saman Bagheri, Rashmeet Kaur Khurana, Md. Ibrahim Kholil, Michael J. Loes, Shengyuan Luo, Alexander Sinitskii
MXenes are a large family of two-dimensional transition metal carbides, nitrides, and carbonitrides. While MXenes have great potential for applications in analytical chemistry, most of the studies in this field...
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02845G, Paper

Na Zhou, Yanning Wang, Jiao Wang, Panchao Zhao, Hang Zhang
Exploiting efficient and inexpensive electrocatalysts for the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is of great significance for the rapid development of renewable energy technologies.
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Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03431G, Paper

Suman Yadav, Sarvesh Kumar Pandey, Shikha Awasthi
Polyvinyl alcohol (PVA) is a well-known cost-effective synthetic polymer that offers a variety of applications including medical, aerospace, automotive, and construction industries. However, weak bonding with low mechanical and tribological...
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03369H, Paper

Jeongmin Kim, Seonhye Youn, Damin Lee, Chan Woong Kim, Hongjae Moon, Seok-Hwan Chung, Hoyoung Kim, Dong Hwan Kim, Sumin Kim, Jong Wook Roh, Joonho Bang, Wooyoung Lee
Two-dimensional (2D) metallic transition metal dichalcogenides (TMDCs) have attracted extensive interest in various fields owing to their unique electronic properties.
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Biomater. Sci., 2024, 12,1871-1882
DOI: 10.1039/D3BM01922E, Paper

Meng Zhang, Hongjin Xue, Jiaxin Yang, Xin Zhao, Mei Xue, Wei Sun, Jianfeng Qiu, Zhihong Zhu
A Cu/ZIF-8/Vc-Ca/HA nanosystem synchronously releases Fenton catalytic Cu²⁺ and Vc-Ca to achieve improved chemodynamic therapy via H₂O₂ self-supply and GSH depletion.
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Biomater. Sci., 2024, Advance Article
DOI: 10.1039/D4BM00289J, Paper

Rui Ding, Pandi Peng, Jingjing Huo, Kun Wang, Pengxiang Liu, Hanxue Wu, Likun Yan, Peng Li
This work demonstrates that CT coatings would be a promising material against implant-related infection in a pH-responsive manner including but not limited to the field of hernioplasty.
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