metal

Effects of surface oxygen vacancy on CO2 adsorption and its activation towards C2H4 using metal (Cu, Pd, CuPd) cluster-loaded TiO2 catalysts: A first principles study

By pubs.rsc.org
Published On ::

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03507K, Paper
Sajjad Hussain, Lina Zhang, Zhengzheng Xie, Jianjun Yang, Qiuye Li
The conversion of the highly selective CO2 reduction reaction (CO2RR) into desired value-added multicarbon compounds, like C2H4, is crucial, but it is mainly constrained by high energy barrier for C-C...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

20-electron exohedral alkaline-earth-metallofullerenes M(C60)3 (M = Ca, Sr, Ba)

By pubs.rsc.org
Published On ::

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03404J, Paper
Feiyang Huang, Jian Zhou, Tao Yang
Electron counting rules are powerful for determination of chemically stable complexes for various elemental groups. While the 18-electron rule has been established for transition metals, recent experiments have discovered that...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

A hydrogen passivation strategy for the electrocatalytic chlorine evolution reaction on metal–organic frameworks: a theoretical insight

By pubs.rsc.org
Published On ::

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03153A, Paper
Jiake Fan, Lei Yang, Hui Li, Zijian Sun, Mengyun Mei, Weihua Zhu
The chlorine evolution reaction (CER) is a crucial solution for treating chlorine-containing wastewater, a type of wastewater generated during the chemical production process.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Unlocking the potential of metal ligand cooperation for enantioselective transformations

By pubs.rsc.org
Published On ::

Chem. Soc. Rev., 2024, 53,3216-3223
DOI: 10.1039/D3CS00998J, Viewpoint
Open Access
Tizian-Frank Ramspoth, Johanan Kootstra, Syuzanna R. Harutyunyan
Metal–ligand cooperation, (MLC) is a versatile catalysis concept. Herein, we discuss the historical context, mechanisms, and applications, suggesting exploring MLC for enantioselective transformations beyond (de)hydrogenative processes.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Thermally activated structural phase transitions and processes in metal–organic frameworks

By pubs.rsc.org
Published On ::

Chem. Soc. Rev., 2024, 53,3606-3629
DOI: 10.1039/D3CS01105D, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Celia Castillo-Blas, Ashleigh M. Chester, David A. Keen, Thomas D. Bennett
The structural knowledge of metal–organic frameworks is crucial for understanding and developing new efficient materials for industrial implementation.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Progress and perspectives on iron-based electrode materials for alkali metal-ion batteries: a critical review

By pubs.rsc.org
Published On ::

Chem. Soc. Rev., 2024, 53,4154-4229
DOI: 10.1039/D3CS00819C, Review Article
Junzhe Li, Chao Wang, Rui Wang, Chaofeng Zhang, Guanjie Li, Kenneth Davey, Shilin Zhang, Zaiping Guo
This review critically evaluates recent advances in iron-based electrode materials and applications in alkali metal ion batteries, covering chemical synthesis, structural design, and modification strategies, with insights into future directions.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

The mechanism of water oxidation using transition metal-based heterogeneous electrocatalysts

By pubs.rsc.org
Published On ::

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS01031G, Review Article
Shujiao Yang, Xiaohan Liu, Sisi Li, Wenjie Yuan, Luna Yang, Ting Wang, Haoquan Zheng, Rui Cao, Wei Zhang
The oxygen evolution reaction (OER) mechanisms using transition metal-based electrocatalysts are instrumental in providing novel insights into both natural and artificial energy conversion processes.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Zirconium metal–organic framework photocatalysis with TEMPO for blue light-powered aerobic sulfoxidation

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05173D, Communication
Bing Zeng, Yuexin Wang, Kanghui Xiong, Keke Zhang, Siyu Zhang, Xianjun Lang
A catalytic amount of TEMPO, mobile in the reaction medium, enhances the hole transfer of NU-1003 photocatalysis for blue light-powered oxidation of organic sulfides with O2.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Functional metal–organic frameworks derived electrode materials for electrochemical energy storage: a review

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13292-13313
DOI: 10.1039/D4CC04086D, Highlight
Basree, Arif Ali, Khusboo Kumari, Musheer Ahmad, Ganesh Chandra Nayak
Pristine MOFs and their derivatives have been proven for supercapacitor as well as energy storage due to their versatile features like huge specific surface area, high porosity, redox active metal centre, high thermal stability, and so on.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Enhancing the performance of ionic conductivity for solid-state electrolytes: an effective strategy of injecting lithium ions within anionic metal–organic frameworks

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13416-13419
DOI: 10.1039/D4CC04515G, Communication
Lu Shi, Xin Wang, Zhiliang Liu
An ionotropic MOF (Li+[Cu-BTC]) with lithium ions in the pores of the lattice was synthesized, which displays outstanding lithium ionic conducting properties over a wide temperature range.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Rapid and sensitive detection of vanillylmandelic acid based on a luminescent fourteen-metal Tb(III) planar nanocluster

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC03667K, Communication
Yanheng Meng, Shiqing Wang, Xiaoli Lv, Xianfeng Huang, Wei-Bing Zhang, Xiaojun Wu, Desmond Schipper, Xiaoping Yang
A 14-metal Tb(III) nanocluster with four CO32- anions as templates was constructed for the quantitative and qualitative detection of vanillylmandelic acid (VMA) with high sensitivity and selectivity. The luminescence response...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Metal-free photocatalysts with charge-transfer excited states enable visible light-driven atom transfer radical polymerization

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04470C, Communication
Yuchen Huang, Yangxin Liu, Yingde Yan, Yanjun Gong, Yifan Zhang, Yanke Che, Jincai Zhao
Photoredox-catalyzed atom transfer radical polymerization (O-ATRP) offers powerful tools for the precise control of polymer synthesis. Metal-free photocatalysts are particularly desirable due to their high level of control in O-ATRP...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Ceria-based supported metal catalysts for the low-temperature water-gas shift reaction

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04072D, Feature Article
Xin-Pu Fu, hui zhao, Chun-Jiang Jia
Water-gas shift (WGS) reaction is a crucial step for the industrial production of hydrogen or upgrading hydrogen generated from fossil or biomass sources by removing the residual CO. However, current...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Li2NbHO2: a new transition-metal oxyhydride with rock-salt-type structure

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05503A, Communication
F Takeiri, Keiko KUSUMOTO, Kosuke Kawai, Hiroshi Yaguchi, Takashi Saito, Kazuhiro Mori, Saburo Hosokawa, Masashi Okubo, Genki Kobayashi
Transition-metal oxyhydrides are an emerging class of functional materials; however, the known compounds have mostly been limited to perovskite-type structures. Here, we successfully synthesized Li2NbHO2, the first example of a...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Catalytic Ethynylation of Formaldehyde for Selective Propargyl Alcohol Production Using the Copper Metal Organic Framework HKUST-1

By pubs.rsc.org
Published On ::

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D3NJ06001B, Paper
Wanxi Yang, Wencai Peng, Han Li, Jin Mao, Liqiang Qian, Qingyu Zhang
HKUST-1 with high crystallinity has been successfully synthesized by solvothermal method using Cu(NO3)2·3H2O as a copper source, 1,3,5-benzenetricarboxylic acid as organic ligand, and N,N-dimethylformamide as solvent. HKUST-1 exhibited a typical...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Metal–organic frameworks constructed using acid–base mixed ligands, carboxylic acids and N-containing chalcone, and their catalytic performance for Knoevenagel condensation

By pubs.rsc.org
Published On ::

New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ05164A, Paper
Limin Cheng, Junyong Zhang, Caihong Zhan, Hao Xu, Chunhua Gong, Jingli Xie
MOF materials constructed using acid–base mixed ligands serve as efficient and economical porous heterogeneous catalysts for Knoevenagel condensation.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Metal–organic framework-derived mesoporous Co3O4 with high specific surface area for enhanced xylene sensing

By pubs.rsc.org
Published On ::

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ01096E, Paper
Liwen Wang, Guanghui Zhang, Ruishu Zhang, Siqi Yang, Wenjuan Huang, Xiangbai Chen
Co3O4 hollow polyhedra have a high specific surface area and mesoporous structure. The Co3O4 gas sensor has excellent sensing performance and selectivity for xylene.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

3D interconnected polymer/mesoporous silica nanoparticle hybrid materials with hierarchical macro/meso-structures for heavy metal adsorption

By pubs.rsc.org
Published On ::

New J. Chem., 2024, 48,7503-7516
DOI: 10.1039/D3NJ05887E, Paper
Jae-Seo Park, Young Sunwoo, Debabrata Chakraborty, Chamila Gunathilake, Yanhai Du, Eun-Bum Cho
This work offers nanohybrid structures for heavy metal ion adsorption from water, which include a unique 3D cross-linked structure that combines organic polymer chains with mesoporous materials to improve adsorption efficiency.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Nanopolyhedral Zn/Fe-NC derived from bimetallic zeolitic imidazole frameworks as an efficient catalyst for the oxygen reduction reaction in an air-cathode microbial fuel cell

By pubs.rsc.org
Published On ::

New J. Chem., 2024, 48,7092-7101
DOI: 10.1039/D3NJ05279F, Paper
Qianwu Wang, Jingzhao Lu, Songlin Liu, Boqu Yu, Bolong Liang
The synergistic effect of Zn, N and moderate Fe doping enhances the ORR performance. The maximum power density of the Zn/Fe-NC-0.5 MFC is 1954 ± 20 mW m−2.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Enhanced photocatalytic activity of carbon nitride nanosheets with alkali metal ion doping

By pubs.rsc.org
Published On ::

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01210K, Paper
Xinhang Sun, Gang Zhao, Songyuan Li, Mingju Huang, Junhui Liu
Photocatalytic degradation of pollutants is one of the most promising strategies for addressing environmental issues associated with wastewater from textile and other dyeing industries. Graphitic carbon nitride (g-C3N4) has emerged...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Catalytic oxidative desulfurization performance of a modified nano-sized β zeolite loaded with different structural polyoxometalates

By pubs.rsc.org
Published On ::

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00214H, Paper
Jinhong Li, Haonan Li, Zhimei Song, Ying Guo, Mengxiao Tai, Mei Han, Xinyao Wang, Lidong Chen, Dongmei Ren
HPW/β-T+S has the best desulfurization activity among the composite catalysts supported by polyoxometalates with different structures.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Critical role of dissolved oxygen and iron–copper synergy in dual-metal/char catalyst systems

By pubs.rsc.org
Published On ::

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00911D, Paper
Yang Luo, Hong Li, Hailan Yang, Zhiming Yang, Chuang Li, Shaoheng Liu, Qiang Chen, Weihua Xu, Wei Zhang, Xiaofei Tan
The critical role of dissolved oxygen and iron–copper synergy in dual-metal/char catalyst system was studied.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Highly radiation-resistant Al-MOF selected based on the radiation stability rules of metal–organic frameworks with ultra-high thorium ion adsorption capacity

By pubs.rsc.org
Published On ::

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00076E, Paper
Xiaofan Ding, Zhanjun Zhang, Xinyan Li, Ke Ma, Tiantian Jin, Zhaoning Feng, Tian Lan, Jing Zhao, Songtao Xiao
Al-MOF synthesized based on MOF irradiation stability rules exhibits high stability against β-irradiation and ultra-high thorium adsorption capacity, which proves its huge potential application value in the field of radionuclide adsorption.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Biogenic synthesis of dual-emission chlorophyll-rich carbon quantum dots for detection of toxic heavy metal ions – Hg(II) and As(III) in water and mouse fibroblast cell line NIH-3T3

By pubs.rsc.org
Published On ::

Environ. Sci.: Nano, 2024, 11,1636-1653
DOI: 10.1039/D3EN00789H, Paper
Ravi Pratap, Nurul Hassan, Monika Yadav, Saurabh Kumar Srivastava, Shilpi Chaudhary, Anita Kamra Verma, Jayeeta Lahiri, Avanish S. Parmar
Due to the excessive residues and serious adverse effects, it is urgent to develop an efficient method to detect Hg2+ and As3+ in drinking water to protect human health.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Understanding the active sites and associated reaction pathways of metal-free carbocatalysts in persulfate activation and pollutant degradation

By pubs.rsc.org
Published On ::

Environ. Sci.: Nano, 2024, 11,1368-1393
DOI: 10.1039/D3EN00988B, Critical Review
Huawen Hu, Dongchu Chen, Yaoheng Liang, Wenyi Wang, Yinlei Lin, Xuejun Xu, Xiaowen Wang, Kun Wang, Yuyuan Zhang, Jian Zhen Ou
Environmental remediation based on peroxomonosulfate- and peroxydisulfate-activation-enabled radical/non-radical oxidation has gained growing interest due to the strong oxidation power, long life of reactive oxygen species, and wide pH adaptability.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Selective metal recovery by mucin: turning gold from wastewater into a peroxymonosulfate-activated catalyst

By pubs.rsc.org
Published On ::

Environ. Sci.: Nano, 2024, 11,1487-1498
DOI: 10.1039/D3EN00699A, Paper
Open Access
Shira Gavriely, Shachar Richter, Ines Zucker
This study explores mucin's ability to selectively recover gold (Au) from metal wastewater. The Au, in the form of a nanoparticle, was utilized in peroxymonosulfate activation for the degradation of bisphenol A.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Doped carbon dots affect heavy metal speciation in mining soil: changes of dissimilated iron reduction processes and microbial communities

By pubs.rsc.org
Published On ::

Environ. Sci.: Nano, 2024, 11,1724-1739
DOI: 10.1039/D3EN00823A, Paper
Xinyi Huang, Shaobo Liu, Xuanming Liu, Xiaofei Tan, Shuai Guo, Mingyang Dai, Qiang Chen, Gaobin Chen, Chenzhi Feng
Carbon dots (CDs) inevitably accumulate in soils due to their widespread use, affecting soil enzyme activities and microbial community structure.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Polymeric polyiodo-chlorotellurates(IV): new supramolecular hybrids in halometalate chemistry

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, 26,2018-2024
DOI: 10.1039/D4CE00088A, Paper
Nikita A. Korobeynikov, Andrey N. Usoltsev, Maxim N. Sokolov, Alexander S. Novikov, Sergey A. Adonin
Reaction between TeO2 and I2 in HCl afforded a series of supramolecular hybrids Cat2{[TeCl6](I2)} (1–5) where diiodine fragments are linked to [TeCl6]2− octahedra via halogen bonds (XB).
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Two multifunctional Dy(III)-based metal–organic frameworks exhibiting proton conduction, magnetic properties and second-harmonic generation

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, 26,2033-2042
DOI: 10.1039/D4CE00065J, Paper
Ya-Qing Liao, Tian-Zheng Xiong, Kang-Le Xie, Huan Zhang, Jun-Jie Hu, He-Rui Wen
Two novelty Dy-MOFs were synthesized using H4DTTP-2OMe ligand. MOF 1 displays a more superior proton conductivity, field-induced single molecule magnets behavior and obvious second-order nonlinear optical properties.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Extended isomerism in heteronuclear metal-organic frameworks: synthetic strategies and crystal structures of lanthanide-cobalt-oxydiacetate systems

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00168K, Paper
Fernando Igoa, Agustín López Cabrera, Javier Gonzalez-Platas, Leopoldo Suescun, Carlos Kremer, Julia Torres
Here, we present the synthesis and crystal structure of a series of heteronuclear metal-organic frameworks, which consists of cobalt(II) and lanthanide(III) ions or yttrium(III), connected by oxydiacetato (oda2-) as ligand....
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Metal–organic polyhedron from a flexible tetrakis(thiobenzyl-carboxylate)-tetrathiafulvalene

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, 26,2072-2077
DOI: 10.1039/D3CE01251D, Paper
Yohan Cheret, Narcis Avarvari, Nicolas Zigon
Wiggle, wiggle… Stay! A redox-active tetrakis(thiobenzyl-carboxylate)-TTF with a high degree of flexibility stands still in a self-assembled cage upon complexation with Cu(II).
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Enantioselective enrichment of chiral 1-phenylethanol in the camphor-based chiral metal–organic framework CFA-22

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, 26,2051-2055
DOI: 10.1039/D4CE00181H, Communication
Richard Röβ-Ohlenroth, Katharina Knippen, Maryana Kraft, Dirk Volkmer
The novel enantioselective CFA-22 metal–organic frameworks were successfully developed and investigated for chiral adsorption separation of e.g. racemic 1-phenylethanol.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Crystal growth and spontaneous polarization mechanism of polar metal borate halides: Mn3B7O13Cl

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, 26,2060-2064
DOI: 10.1039/D4CE00060A, Communication
Haodong Li, Duo Zhang, Jiesen Guo, Qiangqiang Wang, Yuxin Ma, Munan Hao, Yuetong Wu, Fanshu Meng, Tianming Liu, Yibo Xu, Xu Chen, Changchun Zhao, Dezhong Meng, Zhiyuan Zheng, Ruijin Sun
High-quality single crystals of Mn3B7O13Cl have been successfully synthesized, to unravel the elusive mechanism behind its spontaneous polarization.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Ionic liquid-functionalized metal organic frameworks and their composite membranes for enhanced proton transport

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00186A, Highlight
Jeong Hwa Song, Seyoung Koo, Dong Won Kang
Post-synthetic modification is gaining prominence as a highly effective strategy for enhancing the functionality of porous materials without significant structural changes. Recently, there is growing interest in research focusing on...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Noble-metal-free bimetallic nitride decorated CdS nanorods for photocatalytic hydrogen generation

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00216D, Paper
Lu Chen, Yu Zou Xia, Jiale Shi, Xiaohui Huang, Xiyao Liu, Guiyang Yan, Renkun Huang
Developing highly active and stable non-noble-metal cocatalyst-decorated semiconductors is desirable for the practical application of photocatalysis, which remains an open question. Herein, we report transition-metal nitride (Ni3FeN) loaded cadmium sulfide...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

A stable metal azolate framework with rare nonintersecting one-/two-dimensional pore channels

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00318G, Communication
Heng Yi, Mu-Yang Zhou, Le Ye, Xiao-Tong Lu, Dong-Dong Zhou, Jie-Peng Zhang
It is challenging to design and synthesize stable crystalline structures with heterogeneous pores. Herein, we design and synthesize a new azole ligand with rich aromatic moieties and trifluoromethyl groups, and...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Metal- and light-free decarboxylative direct C–H alkylation of heteroarenes at room temperature

By pubs.rsc.org
Published On ::

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00187G, Paper
Tong-Bo Zhang, Xi-Dong Guan, Yan Gao, Shi-Chao Lu, Bing-Long Li
This study reports a metal- and light-free decarboxylative C–H alkylation of heteroarenes at room temperature.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Recent advances in spirocyclization of maleimides via transition-metal catalyzed C–H activation

By pubs.rsc.org
Published On ::

Org. Biomol. Chem., 2024, 22,2916-2947
DOI: 10.1039/D3OB01904G, Review Article
Swadhin Swaraj Acharya, Sagarika Patra, Rojalini Maharana, Manaswini Dash, Liza Mama Barad, Bibhuti Bhusan Parida
In recent years, the maleimide scaffold has received a great deal of attention in C–H activation.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

A review on metal–organic frameworks (MOFs) and MOF–textile composites for personal protection

By pubs.rsc.org
Published On ::

Mater. Chem. Front., 2024, 8,3509-3527
DOI: 10.1039/D4QM00358F, Review Article
Junmei Li, Yinan Fan, Ruigan Zhang, Demao Ban, Zhixuan Duan, Xiaoyuan Liu, Lifang Liu
Metal–organic frameworks (MOFs) have become a research hotspot for effective adsorption and degradation of chemical warfare agents (CWAs) and toxic industrial chemicals (TICs).
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Dissociating high concentration lithium salts in LLZTO-based high dielectric polymer electrolytes for low temperature Li metal batteries

By pubs.rsc.org
Published On ::

Mater. Chem. Front., 2024, 8,3569-3576
DOI: 10.1039/D4QM00625A, Research Article
Jiajun Gong, Zhicheng Yao, Qimin Peng, Huizi Tang, Wenhao Han, Shimou Chen
A new composite electrolyte, combined with rigid fillers and high dielectric polymers, promotes the dissociation of lithium salts and the construction of multiple Li+ paths, improving Li metal batteries performances at room and low temperatures.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Porphyrin-linked graphdiyne as a substrate for constructing single-atom catalysts with transition metals towards oxygen reduction reactions and oxygen evolution reactions

By pubs.rsc.org
Published On ::

Mater. Chem. Front., 2024, 8,3741-3746
DOI: 10.1039/D4QM00555D, Research Article
Jiejie Ping, Mei Wu, Manyu Liu, Yan Jiang, Wenhui Shang, Menggai Jiao, Jiahao Ruan, Nan Wang, Zhiyu Jia
Porphyrin-linked graphdiyne anchored with transition metals exhibits outstanding electrochemical performance, attributed to the modifications in the coordination environment.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Why Want a Metal Hand? It's Complicated, Says Cyborg James Young

By www.wired.com
Published On :: Fri, 25 Jan 2019 08:35:44 +0000

BBC presenter, filmmaker and parttime cyborg James Young was a tech fanatic even before an accident six years ago that left him a double amputee. He has since been exploring the relationship between humans and technology, and has had his own arm's nerves rewired so that he can operate a bionic arm – he says it's a messy work in process. ABOUT WIRED NEXT GEN WIRED Next Generation is the inspiring one day event for teenagers – between 13 and 19. On November 3 in London, hundreds of young minds gathered to hear from the people reshaping the world. Discover some of the fascinating insights from speakers here: http://wired.uk/4SGWwi ABOUT WIRED EVENTS WIRED events shine a spotlight on the innovators, inventors and entrepreneurs who are changing our world for the better. Explore this channel for videos showing on-stage talks, behind-the-scenes action, exclusive interviews and performances from our roster of events. Join us as we uncover the most relevant, up-and-coming trends and meet the people building the future. ABOUT WIRED WIRED brings you the future as it happens - the people, the trends, the big ideas that will change our lives. An award-winning printed monthly and online publication. WIRED is an agenda-setting magazine offering brain food on a wide range of topics, from science, technology and business to pop-culture and politics. CONNECT WITH WIRED Web: http://po.st/WiredVideo Twitter: http://po.st/TwitterWired Facebook: http://po.st/FacebookWired Google+: http://po.st/GoogleWired Instagram: http://po.st/InstagramWired Magazine: http://po.st/MagazineWired Newsletter: http://po.st/NewslettersWired


Full Article

metal

Scientist Explains Unsinkable Metal That Could Prevent Disasters at Sea

By www.wired.com
Published On :: Fri, 22 Nov 2019 20:00:00 +0000

This piece of metal is unsinkable. WIRED's Matt Simon spoke with the inventor, Chunlei Guo, about how the superhydrophobic material was created and how it could help prevent disasters at sea.


Full Article

metal

Sweet MOFs: Exploring the Potential and Restraints of Integrating Carbohydrates with Metal-Organic Frameworks for Biomedical Applications

By pubs.rsc.org
Published On ::

Nanoscale Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D4NH00525B, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Alessio Zuliani, Victor Ramos, Alberto Escudero, Noureddine Khiar
The unique features of metal-organic frameworks (MOFs) such as biodegradability, reduced toxicity and high surface area offer the possibility of developing smart nanosystems for biomedical applications through the simultaneous functionalization...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Optimization of informative variables selection for quantitative analysis of heavy metal (Cu) contaminated Tegillarca granosa using laser-induced breakdown spectroscopy

By pubs.rsc.org
Published On ::

J. Anal. At. Spectrom., 2024, 39,2824-2831
DOI: 10.1039/D4JA00084F, Paper
Xudong Huang, Xiaojing Chen, Guangzao Huang, Zhonghao Xie, Wen Shi, Shujat Ali, Leiming Yuan, Xi Chen
The KMRCD algorithm successfully selected 50 informative variables from the 1520 variables in the LIBS spectra.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Research on a bimodal fusion detection method for surface defects of metal AM components based on LIBS

By pubs.rsc.org
Published On ::

J. Anal. At. Spectrom., 2024, 39,2917-2928
DOI: 10.1039/D4JA00159A, Paper
Xiaomei Lin, Jiangfei Yang, Yutao Huang, Jingjun Lin, Changjin Che
A bimodal fusion method using Laser-Induced Breakdown Spectroscopy (LIBS) is proposed to identify surface defects in metal additive manufacturing (AM) samples. This method integrates LIBS spectra with plasma image data to enhance defect detection.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Assessment of the metal grain size of 12Cr1MoV steel by LIBS coupled with acoustic wave information

By pubs.rsc.org
Published On ::

J. Anal. At. Spectrom., 2024, Advance Article
DOI: 10.1039/D4JA00285G, Paper
Feiqiang Tang, Meirong Dong, Junbin Cai, Zhichun Li, Kaiqing Chen, Weijie Li, Shunchun Yao, Jidong Lu
A modelling scheme that integrates spectral and acoustic data was put forth as a means of enhancing the precision of grain size detection in 12Cr1MoV steel.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Atomic spectrometry update: review of advances in the analysis of metals, chemicals and materials

By pubs.rsc.org
Published On ::

J. Anal. At. Spectrom., 2024, 39,2617-2693
DOI: 10.1039/D4JA90052A, Atomic Spectrometry Update
Eduardo Bolea-Fernandez, Robert Clough, Andy Fisher, Bridget Gibson, Ben Russell
This review covers advances in the analysis of advanced materials, metals, fuels and lubricants, nanostructures, ceramics, refractories, chemicals, catalysts and nuclear materials by a range of techniques including ICP-MS, non-destructive surface ablation and X-ray.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

INSIGHTS INTO THE ROLE OF TRANSITION AND NOBLE METALS MEDIATING PHOTOCHEMICAL VAPOR GENERATION

By pubs.rsc.org
Published On ::

J. Anal. At. Spectrom., 2024, Accepted Manuscript
DOI: 10.1039/D4JA00261J, Tutorial Review
Open Access
Ralph E Sturgeon, Enea Pagliano, Gisele Simone Lopes, Renato Neto, Jane Kelly Sousa Brito
Abstract The recent expansion of the suite of elements amenable to photochemical vapor generation (PVG) is primarily linked to the addition of mg/L concentrations of selected transition metals (TMs) to...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

metal

Fast analysis of metal components in coal dust using spark emission spectroscopy

By pubs.rsc.org
Published On ::

J. Anal. At. Spectrom., 2024, Advance Article
DOI: 10.1039/D4JA00322E, Paper
Jialin Li, Jing Huang, Lina Zheng, Shakila Naz, Xutong Liu
We present a fast method based on spark emission spectroscopy to quantify metal components such as Al, Si, Fe, Ca, and Ti in airborne coal dust.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article