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CBIC issues valuation norms for foreign company supplies to Indian subsidiaries

Additionally, CBIC clarified that for calculating the time limit to avail ITC under the Reverse Charge Mechanism, the relevant financial year will be when the recipient issues the invoice




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“Not asking Punjab for anything, in fact they do not have anything to give,” says Himachal Pradesh CM Sukhvinder Singh Sukhu 

As per the Punjab Reorganisation Act, 1966, Himachal Pradesh is entitled to a 7.19% share in Chandigarh; being deprived of this right is a grave injustice to the people, says CM Sukhu




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JIPMER closure for Ram temple ceremony | Madras HC records emergency services will not be disrupted

JIPMER in Puducherry will be closed until 2:30 p.m. due to the consecration of Ram temple in Uttar Pradesh’s Ayodhya




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MCD starts demolition drive in Bhalswa colony in north-west Delhi

The Municipal Corporation of Delhi on August 13 began a demolition drive in north-west Delhi's Bhalswa Dairy colony; heavy deployment of security personnel has been made at the site




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Golf | Diksha aspires to be at her best against Chiara and company




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Netanyahu says he okayed Lebanon pager attacks

Hezbollah had previously blamed its arch-foe for the blasts that dealt a major blow to the Iran-backed militant group, and vowed revenge




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 Political instability, economic woes stare at Germany 

The German economy, the largest in Europe, has not been performing well and is looking at a second consecutive year of contraction; Germany was the only G-7 country to contract in 2024, with its economy expected to shrink by 0.2%




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Analysis of O-acetylated sialic acids by 3-nitrophenylhydrazine derivatization combined with LC-MS/MS

Anal. Methods, 2024, Advance Article
DOI: 10.1039/D4AY00330F, Paper
Chenhao Zhao, Xingdan Wang, Jing Wu, Yeli Hu, Qiwei Zhang, Qi Zheng
The 3-NPH-labeled sialic acids produce a high abundance of reporter ions, which can improve the accuracy of quantitative analysis of O-acetylated species.
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Phenylboronic acid modification-based novel dumbbell-shaped Au–Ag nanorod SERS substrates for ultrasensitive detection of SO42−

Anal. Methods, 2024, 16,2311-2321
DOI: 10.1039/D3AY01831H, Paper
Kang Shen, Caili Bi, Haifan Yang, Miaowen Xu, Lili Huang, Youwei Wang
Based on the coordination principle of Lewis acids, a novel 4-MPBA-modified dumbbell-shaped Au–Ag nanorod (4-MPBA@DS Au–AgNR) SERS substrate was developed to realize the high sensitivity and specificity of SO42− detection.
The content of this RSS Feed (c) The Royal Society of Chemistry




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How to Disable JavaScript in Almost Any Browser

In 2022 I think it’s still important as a web developer to test your how your websites look and function when users disable JavaScript in their browser. Developing in this way used to be a cornerstone of Progressive Enhancement and can be handy on both desktop or mobile.

I still find myself wanting disabling JavaScript on pages I visit. Sometimes it’s to test a page I’m working on, but in other instances it’s simply to visit a web page that’s not functioning correctly and I want to see if JavaScript is the culprit.

The post How to Disable JavaScript in Almost Any Browser appeared first on Impressive Webs.




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Towards Europe: On the India visits by the leaders of Germany, Spain

India used visits by leaders of Germany and Spain to balance ties in Europe 




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Ananya-Suhana Party Together

Ananya Panday celebrated her birthday with family and the media, but she really wasn't done yet.




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meso-Substituted AB3-type phenothiazinyl porphyrins and their indium and zinc complexes photosensitising properties, cytotoxicity and phototoxicity on ovarian cancer cells

RSC Med. Chem., 2024, Advance Article
DOI: 10.1039/D4MD00601A, Research Article
Open Access
Brém Balázs, Bianca Stoean (Vasile), Éva Molnár, Eva Fischer-Fodor, Ovidiu Bălăcescu, Raluca Borlan, Monica Focsan, Adriana Grozav, Patriciu Achimaş-Cadariu, Emese Gál, Luiza Gaina
New meso-substituted AB3-type phenothiazinyl porphyrins and ferrocenylvinyl phenothiazinyl porphyrin were synthesised by Suzuki–Miyaura and Mizoroki–Heck cross-coupling reactions, respectively.
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Generation and capture of naphthoquinonynes: a new frontier in the development of trypanocidal quinones via aryne chemistry

RSC Med. Chem., 2024, Advance Article
DOI: 10.1039/D4MD00558A, Research Article
Laura P. R. Figueroa, Renato L. de Carvalho, Renata G. Almeida, Esther R. S. Paz, Emilay B. T. Diogo, Maria H. Araujo, Warley S. Borges, Victor F. S. Ramos, Rubem F. S. Menna-Barreto, James M. Wood, John F. Bower, Eufrânio N. da Silva Júnior
This article presents A-ring functionalized quinones via a modern and efficient new strategy involving the generation and capture of benzyne quinones and their evaluation against Trypanosoma cruzi.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Property owners block the entrance to Balasubramanya temple in Karur




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IECD holds graduation ceremony of SUITS

As many as 93,435 students from Grade V to Grade IX in 358 schools across the State appeared for 2023-2024 BDU examinations




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551: PlanetScale with Iheanyi Ekechukwu and Mike Coutermarsh

Iheanyi Ekechukwu and Mike Coutermarsh talk about PlanetScale, what Vitess is, if PlanetScale is for both side and big projects, what read only regions are, what schema changes are, and how PlanetScale compares to other projects.




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597: How Many VS Code Plugins, Poor Charlie’s Almanack, and Where to Start in 2024?

We're closing in on episode 600 and need your help to celebrate! Listen in to learn how to contribute to the episode. We're also talking GitHub desktop apps and code editors, how many VS Code plugins are needed, reading long form like Poor Charlie's Almanack, InVision shutting down, and answering our first Q of the year: how would you approach learning web development in 2024?




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Sunny days are here again

Despite the cost, a solar energy system is a great energy saver and a boon during power cuts, says Anamika Mukherjee




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In harmony with nature

Minimal energy consumption and carbon footprint, use of biogas and solar panels, decentralised water treatment… a look at life in Auroville




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Congress gears up for Delhi poll battle with month-long ‘Nyay Yatra’

Maken, Sukhu flag off foot march; Kharge, Rahul expected to join at different junctures; yatra scheduled to end on Dec. 4; people won’t forget Cong.’s tie-up with AAP in Lok Sabha election: BJP




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Congress holds 25-km ‘Nyay Yatra’ in old Delhi




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16 leaders, as many economic verities

Vince Cable profiles 16 personalities who rung in deep rooted economic change in their societies




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Eyebrows raised as Central team visits Anantapur to assess rabi drought during rainy kharif

The team choosing mandals like Vidapanakallu and Vajrakarur which received excessive rain in June, draws flak from farmers and district officials alike; farmers worry as to how to present their drought woes to the officials who are visiting their fields which are now rain-fed and green




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A Match of Many Records

The first One-Day International between India and Sri Lanka witnessed important milestones being set and new records being made.




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Delhi Ganesh: An actor who could be anyone on screen

Delhi Ganesh, one of the most versatile artists of Tamil cinema, leaves behind a legacy of warmth, trust, and laughter




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No water supply in many areas of Tiruchi on Wednesday




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Development of a coarse-grained molecular dynamics model for poly(dimethyl-co-diphenyl)siloxane

Soft Matter, 2024, 20,8480-8492
DOI: 10.1039/D4SM00875H, Paper
Weikang Xian, Amitesh Maiti, Andrew P. Saab, Ying Li
Polydimethylsiloxane and its copolymer systems have a wide range of application. We systematically develop a coarse-grained MD model for PDMS-co-PDPS system. The model preserves the structural and dynamic properties of the material quantitatively.
The content of this RSS Feed (c) The Royal Society of Chemistry




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pH and glucose dual-responsive phenylboronic acid hydrogels for smart insulin delivery

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM01004C, Paper
Keke Yang, Hou Bo, Dewei Ma, Mingwei Peng, Qinglong Liu, Ziwen Heng, Zhongwei Gu, Xuhan Liu, Siyuan Chen
Phenylboronic acid (PBA) is a widely exploited glucose-sensitive element for constructing glucose-responsive hydrogels to enable smart insulin delivery.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Hydrophobic fouling-resistant electrospun nanofiber membranes from poly(vinylidene fluoride)/polyampholyte blends

Soft Matter, 2024, 20,8654-8662
DOI: 10.1039/D4SM00817K, Paper
Anuja S. Jayasekara, Luca Mazzaferro, Ryan O’Hara, Ayse Asatekin, Peggy Cebe
This study reports the fabrication of non-woven fibrous membranes from electrospinning blended solutions of PVDF with a random polyampholyte amphiphilic copolymer (r-PAC) in N,N-dimethylformamide and methanol.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Is anyone listening?

Archana Shah says it is time people heard the stories of our craftspeople and gave them a place in the sun




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The Circle / directed by: Mort Ransen ; produced by: John Kemeny ; production agency: National Film Board of Canada (Montreal)

Montreal : National Film Board of Canada, 2020




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The Agony of Jimmy Quinlan / directed by: George Mihalka, George Williams ; produced by: Robert Duncan, Janice Brown, Andy Thomson, Peter Katadotis ; production agency: National Film Board of Canada (Montreal)

Montreal : National Film Board of Canada, 2008




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Five arrested in attack case; police deny political angle in attack on YSRC activist

The attacker was a tenant of the victim and had a grudge as he had been asked to vacate the by the victim, the police said




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Wine merchants deny allegations of giving money for Maharashtra polls




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As its industry struggles, Germany services sector offers untapped growth potential




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Wagah: A misfire on many levels

Vast stretches of 'Wagah' play out like a dubbed movie.




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Neer Dose: Serving up a heavy dose of misogyny




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‘Custody’ movie review: Venkat Prabhu’s mix of conflict and humour works for this Naga Chaitanya, Arvind Swami actioner

Director Venkat Prabhu’s Telugu-Tamil bilingual ‘Custody’ is not among his best, but has plenty going for it




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Nyati Group onboards Navigo’s futuristic capabilities to boost sales 

The move aligns with the Group’s vision of utilizing cutting-edge technology to improve the home-buying experience and boost operational efficiency in property sales




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Iron-catalyzed thiolation of C(sp3)–H with sulfonyl chlorides via photoinduced ligand-to-metal charge transfer

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01488J, Research Article
Sheng-Ping Liu, Lan Yang, Yan-Hong He, Zhi Guan
A photoinduced FeCl3/HCl synergistic catalytic method enables C(sp3)–S bond formation via reductive cross-coupling of activated/inert C(sp3)–H and aryl/alkyl sulfonyl chlorides through ligand-to-metal charge transfer (LMCT).
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Palladium-catalyzed hydrocarbonylative cross-coupling with two different alkenes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01312C, Research Article
Yi Chen, Jianing Wu, Yongzheng Ding, Hanmin Huang
Transition metal-catalyzed hydrocarbonylation of alkenes has been widely studied; however, the hydrocarbonylation reaction that took place between two alkenes has been largely unexplored.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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General ppm-level Pd-catalysed asymmetric diarylalkyne hydrosilylation to access structurally diverse Si-stereogenic vinylsilanes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01698J, Research Article
Heng Xu, Han-Xiao Yu, An-Jiu Wen, Fang-Ying Ling, Fei Ye, Li Li, Fuk Yee Kwong, Li-Wen Xu
The first example of enantioselective Pd-catalyzed hydrosilylation of symmetric and asymmetric diarylalkynes to access novel Si-stereogenic vinylsilanes with excellent ee and a high TON is realized under mild reaction conditions.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Metal-free visible-light-induced borylative/silylative pyridylation of vinylarenes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01702A, Research Article
Yiting Zhou, Bin Liu
We present a metal-free and mild three-component reaction involving vinylarenes, NHC–BH3 complexes, hydrosilanes, and 4-cyanopyridine. Remarkably, this reaction was performed with simple and inexpensive benzophenone.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Palladium-catalyzed synthesis of indene-1-acetates via sequential double carbopalladation and aryloxycarbonylation

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01570C, Research Article
Fei Sun, Yiyi Zheng, Zhongyao Jiang, Mingxia Wu, Zeng Lv, Hongsen Ji, Xin-Xing Wu
A novel palladium-catalyzed cascade reaction of o-iodostyrenes, internal alkynes and formates to access various indene-1-acetates through sequential double carbopalladation and aryloxycarbonylation under a palladium/air system was developed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Photoinduced cobaloxime catalysis for allylic mono- and diphosphinylation of alkenes with hydrogen evolution

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01638F, Research Article
Aijun Zhang, Miao-Miao Li, Lei Guo, Huaixiang Yang, Jiefei Guo, Da Xu, Wei Ding
A highly efficient allylic radical mono- and diphosphinylation of alkenes with secondary phosphine oxides is developed, via visible-light-induced cobaloxime catalysis.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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The reactivity of alkenyl boron reagents in catalytic reactions: recent advances and perspectives

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01703J, Review Article
Ya-Li Feng, Bo-Wen Zhang, Youzhi Xu, Shengnan Jin, Daniele Mazzarella, Zhong-Yan Cao
Recent advances focusing on novel reactivity of alkenyl boron reagents in polar or radical pathways within catalytic reactions by employing transition metal catalysis, organocatalysis have been summarized and discussed.
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Visible-light mediated selective phosphonylation modification of tryptophan residues in oligopeptides

Org. Chem. Front., 2024, 11,6287-6292
DOI: 10.1039/D4QO01028K, Research Article
Wenfang Xiong, Junye He, Jinyao Liu, Peiru Chen, Shiqi Xu, Yipeng Liu, Shiting Chen, Yuanyuan You, Zhenyu Chen, Jinwu Zhao
A direct C2-H phosphonylation strategy driven by visible light for specific modification of tryptophan-containing peptides has been reported, providing a plethora of phosphorylated tryptophan-containing peptides
The content of this RSS Feed (c) The Royal Society of Chemistry




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Transition-metal-catalyzed regiodivergent sulfonylation of aziridrines for the synthesis of β-amino sulfones

Org. Chem. Front., 2024, 11,6340-6346
DOI: 10.1039/D4QO01376J, Research Article
Qinqiong Zeng, Yujia Gong, Xiaochun He, Xuemei Zhang, Zhong Lian
We developed the first transition-metal-catalyzed, regiodivergent sulfonylation of aziridines, enabling the efficient synthesis of diverse β-amino sulfones under mild conditions with broad substrate compatibility and high regioselectivity.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Phosphine-controlled divergent reactions of MBH-carbonates with azaheptafulvenes: access to o-anilinyl diene and benzazepine derivatives

Org. Chem. Front., 2024, 11,6418-6425
DOI: 10.1039/D4QO01298D, Research Article
Wei Hao, Yiwen Zhang, Xiao Han, Zhen Wang, Weijun Yao
A phosphine controlled divergent cascade reaction of MBH-carbonates with azaheptafulvenes was disclosed. PPh3 provided o-aminophenyl diene while PCy3 offered benzazepine derivative through formal [8 + 3] annulation/ring contraction cascade.
The content of this RSS Feed (c) The Royal Society of Chemistry